JP5539854B2 - ヒドロクロロフルオロオレフィンおよびヒドロフルオロオレフィンの発泡剤組成物 - Google Patents
ヒドロクロロフルオロオレフィンおよびヒドロフルオロオレフィンの発泡剤組成物 Download PDFInfo
- Publication number
- JP5539854B2 JP5539854B2 JP2010501249A JP2010501249A JP5539854B2 JP 5539854 B2 JP5539854 B2 JP 5539854B2 JP 2010501249 A JP2010501249 A JP 2010501249A JP 2010501249 A JP2010501249 A JP 2010501249A JP 5539854 B2 JP5539854 B2 JP 5539854B2
- Authority
- JP
- Japan
- Prior art keywords
- isomer
- agent composition
- blowing agent
- hcfo
- hfo
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 37
- 239000004604 Blowing Agent Substances 0.000 title claims abstract description 24
- 239000006260 foam Substances 0.000 claims abstract description 23
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 11
- FXRLMCRCYDHQFW-UHFFFAOYSA-N 2,3,3,3-tetrafluoropropene Chemical compound FC(=C)C(F)(F)F FXRLMCRCYDHQFW-UHFFFAOYSA-N 0.000 claims description 11
- 229920000642 polymer Polymers 0.000 claims description 10
- RWRIWBAIICGTTQ-UHFFFAOYSA-N difluoromethane Chemical compound FCF RWRIWBAIICGTTQ-UHFFFAOYSA-N 0.000 claims description 9
- 239000004088 foaming agent Substances 0.000 claims description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- GTLACDSXYULKMZ-UHFFFAOYSA-N pentafluoroethane Chemical compound FC(F)C(F)(F)F GTLACDSXYULKMZ-UHFFFAOYSA-N 0.000 claims description 6
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 claims description 5
- UJPMYEOUBPIPHQ-UHFFFAOYSA-N 1,1,1-trifluoroethane Chemical compound CC(F)(F)F UJPMYEOUBPIPHQ-UHFFFAOYSA-N 0.000 claims description 5
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 150000002430 hydrocarbons Chemical class 0.000 claims description 4
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 claims description 4
- YFMFNYKEUDLDTL-UHFFFAOYSA-N 1,1,1,2,3,3,3-heptafluoropropane Chemical compound FC(F)(F)C(F)C(F)(F)F YFMFNYKEUDLDTL-UHFFFAOYSA-N 0.000 claims description 3
- NUPBXTZOBYEVIR-UHFFFAOYSA-N 1,1,2,3,3,4,4-heptafluorobut-1-ene Chemical class FC(F)C(F)(F)C(F)=C(F)F NUPBXTZOBYEVIR-UHFFFAOYSA-N 0.000 claims description 3
- SXKNYNUXUHCUHX-UHFFFAOYSA-N 1,1,2,3,3,4-hexafluorobut-1-ene Chemical class FCC(F)(F)C(F)=C(F)F SXKNYNUXUHCUHX-UHFFFAOYSA-N 0.000 claims description 3
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical compound CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 claims description 3
- FDMFUZHCIRHGRG-UHFFFAOYSA-N 3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C FDMFUZHCIRHGRG-UHFFFAOYSA-N 0.000 claims description 3
- IZHPSCJEIFFRLN-UHFFFAOYSA-N 3,3,4,4,4-pentafluorobut-1-ene Chemical class FC(F)(F)C(F)(F)C=C IZHPSCJEIFFRLN-UHFFFAOYSA-N 0.000 claims description 3
- LQAPOTKKMIZDGP-UHFFFAOYSA-N 3,3,4,4,5,5,5-heptafluoropent-1-ene Chemical class FC(F)(F)C(F)(F)C(F)(F)C=C LQAPOTKKMIZDGP-UHFFFAOYSA-N 0.000 claims description 3
- BNLLWAALHYCOQM-UHFFFAOYSA-N 3,3,4,4-tetrafluorobut-1-ene Chemical class FC(F)C(F)(F)C=C BNLLWAALHYCOQM-UHFFFAOYSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 239000001569 carbon dioxide Substances 0.000 claims description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000004215 Carbon black (E152) Substances 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920005830 Polyurethane Foam Polymers 0.000 claims description 2
- 239000011496 polyurethane foam Substances 0.000 claims description 2
- WXGNWUVNYMJENI-UHFFFAOYSA-N 1,1,2,2-tetrafluoroethane Chemical compound FC(F)C(F)F WXGNWUVNYMJENI-UHFFFAOYSA-N 0.000 claims 2
- PGJHURKAWUJHLJ-UHFFFAOYSA-N 1,1,2,3-tetrafluoroprop-1-ene Chemical compound FCC(F)=C(F)F PGJHURKAWUJHLJ-UHFFFAOYSA-N 0.000 claims 2
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- LDTMPQQAWUMPKS-OWOJBTEDSA-N (e)-1-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)\C=C\Cl LDTMPQQAWUMPKS-OWOJBTEDSA-N 0.000 abstract description 9
- OQISUJXQFPPARX-UHFFFAOYSA-N 2-chloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C(Cl)=C OQISUJXQFPPARX-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- -1 HCFO-1223 Chemical compound 0.000 abstract description 2
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 9
- 238000010792 warming Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 6
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 3
- 229920000582 polyisocyanurate Polymers 0.000 description 3
- 239000011495 polyisocyanurate Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 210000003850 cellular structure Anatomy 0.000 description 2
- 229920005903 polyol mixture Polymers 0.000 description 2
- 239000006269 thermoset foam Substances 0.000 description 2
- RIQRGMUSBYGDBL-UHFFFAOYSA-N 1,1,1,2,2,3,4,5,5,5-decafluoropentane Chemical compound FC(F)(F)C(F)C(F)C(F)(F)C(F)(F)F RIQRGMUSBYGDBL-UHFFFAOYSA-N 0.000 description 1
- ISCYUDAHBJMFNT-UHFFFAOYSA-N 1,1-dichloro-3,3,3-trifluoroprop-1-ene Chemical compound FC(F)(F)C=C(Cl)Cl ISCYUDAHBJMFNT-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 239000004620 low density foam Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical class CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004634 thermosetting polymer Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K23/00—Use of substances as emulsifying, wetting, dispersing, or foam-producing agents
- C09K23/017—Mixtures of compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
- C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/16—Unsaturated hydrocarbons
- C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/18—Binary blends of expanding agents
- C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08J2300/104—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
- C08J2300/10—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups
- C08J2300/106—Polymers characterised by the presence of specified groups, e.g. terminal or pendant functional groups containing nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Description
Claims (9)
- (a)HFO−1234yfを(b)HCFO−1233zdと併せて含み、かつ前記HFO−1234yfが、ポリマー発泡剤組成物の5重量%以上を占める、熱硬化性発泡体用のポリマー発泡剤組成物。
- ヒドロフルオロカーボンをさらに含む、請求項1に記載のポリマー発泡剤組成物。
- 前記ヒドロフルオロカーボンが、ジフルオロメタン(HFC32);1,1,1,2,2−ペンタフルオロエタン(HFC125);1,1,1−トリフルオロエタン(143a);1,1,2,2−テトラフルオロエタン(HFC134);1,1,1,2−テトラフルオロエタン(HFC134a);1,1−ジフルオロエタン(HFC152a);1,1,1,2,3,3,3−ヘプタフルオロプロパン(HFC227ea);1,1,1,3,3−ペンタフルオロプロパン(HFC245fa);1,1,1,3,3−ペンタフルオロブタン(HFC365mfc)および1,1,1,2,2,3,4,5,5,5−デカフルオロペンタン(HFC4310mee)からなる群から選択される、請求項2に記載のポリマー発泡剤組成物。
- テトラフルオロプロペン(HFO1234ze);トリフルオロプロペン(HFO1243zf);テトラフルオロブテン異性体(HFO1354);ペンタフルオロブテン異性体(HFO1345);ヘキサフルオロブテン異性体(HFO1336);ヘプタフルオロブテン異性体(HFO1327);ヘプタフルオロペンテン異性体(HFO1447);オクタフルオロペンテン異性体(HFO1438)およびノナフルオロペンテン異性体(HFO1429)からなる群から選択される第2ヒドロフルオロオレフィンをさらに含む、請求項1に記載のポリマー発泡剤組成物。
- 第2ヒドロフルオロオレフィン(HFO)、ヒドロフルオロカーボン、炭化水素、アルコール、エステル、アルデヒド、ケトン、エーテル/ジエーテル、二酸化炭素およびその混合物からなる群から選択される成分をさらに含む、請求項1に記載のポリマー発泡剤組成物。
- (a)HFO−1234yfを(b)HCFO−1233zdと併せて含み、かつさらに前記HFO−1234yfが、前記ポリマー発泡剤組成物の5重量%以上を占める発泡体用発泡剤と、ポリマー発泡体成分とを混合することを含む、ポリウレタン発泡体を発泡する方法。
- 前記ポリマー発泡剤組成物が、ヒドロフルオロカーボンをさらに含む、請求項6に記載の方法。
- 前記ヒドロフルオロカーボンが、ジフルオロメタン(HFC32);1,1,1,2,2−ペンタフルオロエタン(HFC125);1,1,1−トリフルオロエタン(HFC143a);1,1,2,2−テトラフルオロエタン(HFC134);1,1,1,2−テトラフルオロエタン(HFC134a);1,1−ジフルオロエタン(HFC152a);1,1,1,2,3,3,3−ヘプタフルオロプロパン(HFC227ea);1,1,1,3,3−ペンタフルオロプロパン(HFC245fa);1,1,1,3,3−ペンタフルオロブタン(HFC365mfc)および1,1,1,2,2,3,4,5,5,5−デカフルオロペンタン(HFC4310mee)からなる群から選択される、請求項7に記載の方法。
- テトラフルオロプロペン(HFO1234ze);トリフルオロプロペン(HFO1243zf);テトラフルオロブテン異性体(HFO1354);ペンタフルオロブテン異性体(HFO1345);ヘキサフルオロブテン異性体(HFO1336);ヘプタフルオロブテン異性体(HFO1327);ヘプタフルオロペンテン異性体(HFO1447);オクタフルオロペンテン異性体(HFP1438)およびノナフルオロペンテン異性体(HFP1429)からなる群から選択される第2ヒドロフルオロオレフィンをさらに含む、請求項6に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US90875107P | 2007-03-29 | 2007-03-29 | |
US60/908,751 | 2007-03-29 | ||
PCT/US2008/058607 WO2008121790A1 (en) | 2007-03-29 | 2008-03-28 | Blowing agent composition of hydrochlorofluoroolefin and hydrofluoroolefin |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2010522822A JP2010522822A (ja) | 2010-07-08 |
JP5539854B2 true JP5539854B2 (ja) | 2014-07-02 |
Family
ID=39808678
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010501245A Active JP5416086B2 (ja) | 2007-03-29 | 2008-03-28 | ヒドロクロロフルオロオレフィンおよびヒドロフルオロオレフィンの発泡剤組成物 |
JP2010501249A Active JP5539854B2 (ja) | 2007-03-29 | 2008-03-28 | ヒドロクロロフルオロオレフィンおよびヒドロフルオロオレフィンの発泡剤組成物 |
JP2010501247A Active JP5416087B2 (ja) | 2007-03-29 | 2008-03-28 | ヒドロフルオロプロペンおよびヒドロクロロフルオロオレフィンの発泡剤組成物 |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010501245A Active JP5416086B2 (ja) | 2007-03-29 | 2008-03-28 | ヒドロクロロフルオロオレフィンおよびヒドロフルオロオレフィンの発泡剤組成物 |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2010501247A Active JP5416087B2 (ja) | 2007-03-29 | 2008-03-28 | ヒドロフルオロプロペンおよびヒドロクロロフルオロオレフィンの発泡剤組成物 |
Country Status (9)
Country | Link |
---|---|
US (8) | US9279039B2 (ja) |
EP (3) | EP2129714B1 (ja) |
JP (3) | JP5416086B2 (ja) |
CN (6) | CN101652413A (ja) |
AT (3) | ATE547459T1 (ja) |
CA (3) | CA2681838C (ja) |
ES (3) | ES2367542T3 (ja) |
PL (3) | PL2129714T3 (ja) |
WO (3) | WO2008121787A1 (ja) |
Families Citing this family (81)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090253820A1 (en) * | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US9499729B2 (en) * | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
TW201336906A (zh) † | 2005-06-24 | 2013-09-16 | Honeywell Int Inc | 含有經氟取代之烯烴之發泡劑及組合物,及發泡方法 |
US9695267B2 (en) * | 2009-08-11 | 2017-07-04 | Honeywell International Inc. | Foams and foamable compositions containing halogenated olefin blowing agents |
CN105001440A (zh) * | 2007-03-29 | 2015-10-28 | 阿科玛股份有限公司 | 氢氯氟烯烃类的发泡剂组合物 |
BRPI0813018A2 (pt) * | 2007-07-20 | 2014-12-23 | Du Pont | " composição de formação de espuma, espuma de polímero de poliuretano ou poliisocianurato e processo para produzir uma espuma " |
US8512591B2 (en) | 2007-10-12 | 2013-08-20 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
US8333901B2 (en) | 2007-10-12 | 2012-12-18 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
WO2009047542A1 (en) * | 2007-10-12 | 2009-04-16 | Ineos Fluor Holdings Limited | Heat transfer compositions |
US8628681B2 (en) | 2007-10-12 | 2014-01-14 | Mexichem Amanco Holding S.A. De C.V. | Heat transfer compositions |
GB201002625D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
WO2009089400A1 (en) * | 2008-01-11 | 2009-07-16 | E. I. Du Pont De Nemours And Company | Compositions and use of 2-chloro-3,3,3-trifluoropropene foam-forming composition in the preparation of polyisocyanate-based foams |
CN101808966A (zh) | 2008-03-07 | 2010-08-18 | 阿科玛股份有限公司 | 用氯-3,3,3-三氟丙烯配制的稳定系统 |
EP2271725B1 (en) | 2008-05-07 | 2018-02-21 | The Chemours Company FC, LLC | Compositions comprising 2,3,3,3-tetrafluoropropene and 1,1,1-trifluoropropene |
WO2010019428A1 (en) * | 2008-08-13 | 2010-02-18 | E. I. Du Pont De Nemours And Company | Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and hydrocarbon and their uses in the preparation of polyisocyanate-based foams |
US8163196B2 (en) * | 2008-10-28 | 2012-04-24 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
EP2367896A1 (en) * | 2008-12-02 | 2011-09-28 | Mexichem Amanco Holding S.A. de C.V. | Heat transfer compositions |
WO2010088320A1 (en) * | 2009-01-29 | 2010-08-05 | Arkema Inc. | Tetrafluoropropene based blowing agent compositions |
US20100216904A1 (en) * | 2009-02-24 | 2010-08-26 | E. I. Du Pont De Nemours And Company | Foam-forming compositions containing mixtures of 2-chloro-3,3,3-trifluoropropene and at least one hydrofluoroolefin and their uses in the preparation of polyisocyanate-based foams |
TW201103972A (en) | 2009-04-01 | 2011-02-01 | Solvay Fluor Gmbh | Process for the manufacture of etched items |
US8541478B2 (en) | 2009-05-21 | 2013-09-24 | Huntsman International Llc | Rigid polyurethane foam and system and method for making the same |
ES2644518T3 (es) * | 2009-06-02 | 2017-11-29 | The Chemours Company Fc, Llc | Composiciones azeotrópicas y similares a azeótropos de Z-1,1,1,4,4,4-hexafluoro-2-buteno |
JP2013500386A (ja) * | 2009-07-27 | 2013-01-07 | アーケマ・インコーポレイテッド | ポリウレタンフォームでの使用のためのHCFO−1233zdとポリオールブレンドとの組成物 |
DE102009028061A1 (de) | 2009-07-29 | 2011-02-10 | Evonik Goldschmidt Gmbh | Verfahren zur Herstellung von Polyurethanschaum |
JP2013504658A (ja) * | 2009-09-09 | 2013-02-07 | ハネウェル・インターナショナル・インコーポレーテッド | モノクロロトリフルオロプロペン化合物及び組成物並びにそれを用いる方法 |
JP2013508512A (ja) * | 2009-10-23 | 2013-03-07 | アーケマ・インコーポレイテッド | ポリウレタンフォームのためのテトラフルオロブテン発泡剤組成物 |
US8846754B2 (en) * | 2009-12-16 | 2014-09-30 | Honeywell International Inc. | Azeotrope-like compositions of cis-1,1,1,4,4,4-hexafluoro-2-butene |
PL2845891T3 (pl) | 2009-12-22 | 2020-04-30 | The Chemours Company Fc, Llc | Kompozycje zawierające 2,3,3,3-tetrafluoropropen i 2,3-dichloro-3,3-difluoropropen |
GB201002622D0 (en) | 2010-02-16 | 2010-03-31 | Ineos Fluor Holdings Ltd | Heat transfer compositions |
US8821749B2 (en) * | 2010-04-26 | 2014-09-02 | E I Du Pont De Nemours And Company | Azeotrope-like compositions of E-1,1,1,4,4,4-hexafluoro-2-butene and 1-chloro-3,3,3-trifluoropropene |
KR20130082095A (ko) | 2010-05-20 | 2013-07-18 | 멕시켐 아만코 홀딩 에스.에이. 데 씨.브이. | 열전달 조성물 |
EP2571952B1 (en) | 2010-05-20 | 2015-07-29 | Mexichem Fluor S.A. de C.V. | Heat transfer compositions |
GB2481443B (en) | 2010-06-25 | 2012-10-17 | Mexichem Amanco Holding Sa | Heat transfer compositions |
US20120043492A1 (en) * | 2010-08-17 | 2012-02-23 | Honeywell International Inc. | Compositions Containing 1-Chloro-3,3,3 Trifluoropropene And 1-Fluoro-1,1 Dichloroethane |
US20120046372A1 (en) * | 2010-08-18 | 2012-02-23 | Honeywell International Inc. | Blowing agents, foamable compositions and foams |
US9145480B2 (en) * | 2010-10-28 | 2015-09-29 | Honeywell International Inc. | Mixtures containing 1,1,1,3,3,3-hexafluorobutene and 1-chloro-3,3,3-trifluoropropene |
US8680168B2 (en) | 2010-11-17 | 2014-03-25 | Fomo Products, Inc. | Method for filling wall cavities with expanding foam insulation |
US8734671B2 (en) * | 2010-11-19 | 2014-05-27 | Honeywell International Inc. | Azeotrope-like compositions comprising 1-chloro-3,3,3-trifluoropropene |
EP3543311B1 (en) * | 2010-11-25 | 2022-11-09 | Arkema France | Use of compositions of chloro-trifluoropropene and hexafluorobutene |
FR2968310B1 (fr) * | 2010-12-03 | 2012-12-07 | Arkema France | Compositions a base de 1,1,1,4,4,4-hexafluorobut-2-ene et de 3,3,4,4,4-pentafluorobut-1-ene |
US20140364528A1 (en) | 2010-12-21 | 2014-12-11 | Dow Global Technologies Llc | Polyol formulations for improved cold temperature skin cure of polyurethane rigid foams |
US9724684B2 (en) | 2011-02-21 | 2017-08-08 | The Chemours Company Fc, Llc | Selective catalytical dehydrochlorination of hydrochlorofluorocarbons |
FR2977256B1 (fr) * | 2011-07-01 | 2013-06-21 | Arkema France | Compositions de 2,4,4,4-tetrafluorobut-1-ene et de cis-1,1,1,4,4,4-hexafluorobut-2-ene |
WO2013016632A2 (en) * | 2011-07-28 | 2013-01-31 | Honeywell International Inc. | Foams and flame resistant articles made from foams containing 1-chloro-3,3,3-trifluoropropene (1233zd) |
US9896558B2 (en) | 2011-08-01 | 2018-02-20 | Basf Se | HFO/water-blown rigid foam systems |
DK2739676T3 (da) | 2011-08-01 | 2019-12-09 | Basf Se | Hfo/vanddrevne systemer af hårdt skum |
JP6228122B2 (ja) | 2011-10-14 | 2017-11-08 | ダウ グローバル テクノロジーズ エルエルシー | ポリウレタン硬質発泡体における向上した離型膨張のためのハイブリッドポリエステル−ポリエーテルポリオール |
EP2768893B1 (en) | 2011-10-20 | 2016-04-06 | E. I. du Pont de Nemours and Company | Azeotrope-like compositions of e-1-chloro-2,3,3,3-tetrafluoropropene and uses thereof |
US20140312261A1 (en) * | 2011-12-09 | 2014-10-23 | Honeywell International Inc. | Foams and articles made from foams containing hcfo or hfo blowing agents |
EP2794806A4 (en) * | 2011-12-22 | 2015-10-14 | Honeywell Int Inc | AZEOTROPÄHNLICHE COMPOSITIONS WITH CIS-1-CHLORO-3,3,3-TRIFLUORPROPEN |
US8921621B2 (en) | 2012-02-15 | 2014-12-30 | Honeywell International Inc. | Process for the production of HCFC-1233zd |
US9000239B2 (en) * | 2012-05-15 | 2015-04-07 | Honeywell International Inc. | Methods for producing 1-chloro-3,3,3-trifluoropropene from 2-chloro-3,3,3-trifluoropropene |
CN104334599B (zh) | 2012-05-25 | 2019-04-05 | 陶氏环球技术有限责任公司 | 聚异氰脲酸酯泡沫面板的制造 |
CN104781315B (zh) * | 2012-09-07 | 2019-03-08 | 巴斯夫欧洲公司 | 减小收缩的硬质聚氨酯泡沫 |
CN102850571A (zh) * | 2012-09-28 | 2013-01-02 | 关志强 | 保温聚氨酯塑料的发泡剂 |
FR3000094B1 (fr) * | 2012-12-26 | 2019-10-18 | Arkema France | Composition comprenant du 1,1-difluoroethane et du 3,3,3-trifluoropropene |
CN111925775A (zh) * | 2013-03-14 | 2020-11-13 | 霍尼韦尔国际公司 | 用于高温热泵应用的低gwp流体 |
CA3122485C (en) | 2013-03-15 | 2023-08-08 | Owens Corning Intellectual Capital, Llc | Processing aids for use in manufacturing extruded polystyrene foams using low global warming potential blowing agents |
US20150210818A1 (en) * | 2014-01-27 | 2015-07-30 | E I Du Pont De Nemours And Company | Cryogenic insulation foam |
CN103881131A (zh) * | 2014-03-17 | 2014-06-25 | 浙江衢化氟化学有限公司 | 一种环保型发泡剂组合物 |
RU2016142531A (ru) * | 2014-04-30 | 2018-05-30 | Ханивелл Интернешнл Инк. | Эластичные термоотверждающиеся пенопласты с открытыми порами и вспенивающие средства и способы их получения |
US10330364B2 (en) | 2014-06-26 | 2019-06-25 | Hudson Technologies, Inc. | System and method for retrofitting a refrigeration system from HCFC to HFC refrigerant |
CN104119490A (zh) * | 2014-07-10 | 2014-10-29 | 合肥美的电冰箱有限公司 | 组合物和由其制备的泡沫材料及泡沫材料的制法和用途 |
CN106661260A (zh) * | 2014-07-16 | 2017-05-10 | 欧文斯科宁知识产权资产有限公司 | 用于采用低全球变暖潜力的发泡剂制造泡沫体的非‑voc加工助剂 |
JP6626674B2 (ja) * | 2014-10-08 | 2019-12-25 | 積水ソフランウイズ株式会社 | 硬質ポリウレタンフォーム用ポリオール組成物、及び硬質ポリウレタンフォームの製造方法 |
WO2016152988A1 (ja) * | 2015-03-24 | 2016-09-29 | 積水化学工業株式会社 | フェノール樹脂発泡体及びフェノール樹脂発泡体の製造方法 |
CN107207758A (zh) * | 2015-03-24 | 2017-09-26 | 旭化成建材株式会社 | 酚醛树脂发泡体及其制造方法 |
US10301236B2 (en) | 2015-05-21 | 2019-05-28 | The Chemours Company Fc, Llc | Hydrofluorination of a halogenated olefin with SbF5 in the liquid phase |
JP6274363B2 (ja) * | 2015-07-27 | 2018-02-07 | 旭硝子株式会社 | 溶剤組成物、洗浄方法、塗膜の形成方法、熱移動媒体および熱サイクルシステム |
CN105885080A (zh) * | 2016-05-05 | 2016-08-24 | 巨化集团技术中心 | 一种发泡剂组合物及其制备方法 |
CH712779A1 (de) * | 2016-07-20 | 2018-01-31 | Brugg Rohr Ag Holding | Barriereschichten. |
US10131758B2 (en) | 2016-07-25 | 2018-11-20 | Accella Polyurethane Systems, Llc | Polyurethane foam-forming compositions, methods of making low density foams using such compositions, and foams formed therefrom |
CN106750488B (zh) * | 2016-12-26 | 2019-05-17 | 浙江衢化氟化学有限公司 | 一种低碳环保型发泡剂组合物 |
CN108727551A (zh) * | 2017-04-19 | 2018-11-02 | 科思创德国股份有限公司 | 一种硬质聚氨酯泡沫及其制备方法与应用 |
CN108102333A (zh) * | 2017-12-27 | 2018-06-01 | 上海东大聚氨酯有限公司 | 一种超低温保温箱用组合聚醚、聚氨酯原料组合物、聚氨酯泡沫及其制备方法 |
CN112236510B (zh) * | 2018-07-27 | 2022-04-22 | 中央硝子株式会社 | 溶剂组合物 |
CN110105520B (zh) * | 2019-05-05 | 2021-09-21 | 深圳市盈石科技有限公司 | 一种保温硬质聚氨酯泡沫及其制备方法 |
MX2022009160A (es) * | 2020-02-04 | 2022-08-16 | Chemours Co Fc Llc | Agentes de nucleacion para espumas de poliisocianurato (pir). |
JPWO2022009801A1 (ja) * | 2020-07-08 | 2022-01-13 | ||
CN114149790B (zh) * | 2021-11-10 | 2023-09-05 | 浙江巨化新材料研究院有限公司 | 一种共沸或类共沸组合物及其制备方法 |
WO2023221694A1 (zh) * | 2022-05-20 | 2023-11-23 | 海信容声(广东)冰箱有限公司 | 聚氨酯泡沫材料及其制备方法、冰箱和冰柜 |
Family Cites Families (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2039008A (en) | 1932-07-28 | 1936-04-28 | Burgess Lab Inc C F | Method of making a material for absorbing sound |
JPH02221388A (ja) | 1989-02-23 | 1990-09-04 | Asahi Glass Co Ltd | 脱脂洗浄剤 |
JP2751428B2 (ja) * | 1989-06-30 | 1998-05-18 | 旭硝子株式会社 | 3,3―ジクロロ―1,1,1,2,2―ペンタフルオロプロパン系組成物 |
JPH05179042A (ja) * | 1991-11-18 | 1993-07-20 | Daikin Ind Ltd | フルオロプロペンからなる発泡剤およびプラスチック発泡体の製造方法 |
US5710352A (en) | 1996-09-19 | 1998-01-20 | Alliedsignal Inc. | Vapor phase process for making 1,1,1,3,3-pentafluoropropane and 1-chloro-3,3,3-trifluoropropene |
EP0864554B1 (en) | 1997-03-11 | 2002-09-18 | Central Glass Company, Limited | Method for purifying crude 1,1,1,3,3-pentafluoropropane |
US6013846A (en) * | 1998-03-05 | 2000-01-11 | Elf Atochem North America, Inc. | Azeotrope of HF and 1233zd |
US20050096246A1 (en) * | 2003-11-04 | 2005-05-05 | Johnson Robert C. | Solvent compositions containing chlorofluoroolefins |
ES2321796T5 (es) * | 2002-10-25 | 2017-06-28 | Honeywell International Inc. | Uso de una composición que comprende 1,3,3,3-tetrafluoropropeno (HFO 1234ze) en calidad de agente de soplado |
US7279451B2 (en) * | 2002-10-25 | 2007-10-09 | Honeywell International Inc. | Compositions containing fluorine substituted olefins |
US20090253820A1 (en) | 2006-03-21 | 2009-10-08 | Honeywell International Inc. | Foaming agents and compositions containing fluorine sustituted olefins and methods of foaming |
US9796848B2 (en) * | 2002-10-25 | 2017-10-24 | Honeywell International Inc. | Foaming agents and compositions containing fluorine substituted olefins and methods of foaming |
US9499729B2 (en) | 2006-06-26 | 2016-11-22 | Honeywell International Inc. | Compositions and methods containing fluorine substituted olefins |
US7098176B2 (en) * | 2004-04-16 | 2006-08-29 | Honeywell International Inc. | Azeotrope-like compositions of tetrafluoropropene and pentafluoropropene |
EP1846534B1 (en) * | 2004-12-21 | 2011-07-06 | Honeywell International Inc. | Stabilized iodocarbon compositions |
US20060243945A1 (en) * | 2005-03-04 | 2006-11-02 | Minor Barbara H | Compositions comprising a fluoroolefin |
US20060243944A1 (en) * | 2005-03-04 | 2006-11-02 | Minor Barbara H | Compositions comprising a fluoroolefin |
TWI558685B (zh) * | 2005-06-24 | 2016-11-21 | 哈尼威爾國際公司 | 含有經氟取代之烯烴之組合物 |
TW201336906A (zh) * | 2005-06-24 | 2013-09-16 | Honeywell Int Inc | 含有經氟取代之烯烴之發泡劑及組合物,及發泡方法 |
JP5562827B2 (ja) | 2007-03-29 | 2014-07-30 | アーケマ・インコーポレイテッド | ヒドロクロロフルオロオレフィンの発泡剤組成物 |
CN100488925C (zh) | 2007-04-11 | 2009-05-20 | 西安近代化学研究所 | 1,3,3,3-四氟丙烯的制备方法 |
-
2008
- 2008-03-28 US US12/532,202 patent/US9279039B2/en active Active
- 2008-03-28 JP JP2010501245A patent/JP5416086B2/ja active Active
- 2008-03-28 CN CN200880010224A patent/CN101652413A/zh active Pending
- 2008-03-28 CN CN201410244732.5A patent/CN103992498B/zh active Active
- 2008-03-28 CA CA2681838A patent/CA2681838C/en active Active
- 2008-03-28 AT AT08744559T patent/ATE547459T1/de active
- 2008-03-28 PL PL08744561T patent/PL2129714T3/pl unknown
- 2008-03-28 ES ES08744561T patent/ES2367542T3/es active Active
- 2008-03-28 AT AT08744563T patent/ATE528341T1/de not_active IP Right Cessation
- 2008-03-28 US US12/532,194 patent/US20100087557A1/en not_active Abandoned
- 2008-03-28 AT AT08744561T patent/ATE518905T1/de not_active IP Right Cessation
- 2008-03-28 US US12/532,189 patent/US20100056657A1/en not_active Abandoned
- 2008-03-28 ES ES08744559T patent/ES2380080T3/es active Active
- 2008-03-28 CA CA2681872A patent/CA2681872C/en active Active
- 2008-03-28 EP EP08744561A patent/EP2129714B1/en active Active
- 2008-03-28 PL PL08744559T patent/PL2129713T3/pl unknown
- 2008-03-28 JP JP2010501249A patent/JP5539854B2/ja active Active
- 2008-03-28 CN CN200880010511A patent/CN101646723A/zh active Pending
- 2008-03-28 WO PCT/US2008/058604 patent/WO2008121787A1/en active Application Filing
- 2008-03-28 ES ES08744563T patent/ES2372785T3/es active Active
- 2008-03-28 WO PCT/US2008/058602 patent/WO2008121785A1/en active Application Filing
- 2008-03-28 EP EP08744563A patent/EP2129715B1/en active Active
- 2008-03-28 PL PL08744563T patent/PL2129715T3/pl unknown
- 2008-03-28 EP EP08744559A patent/EP2129713B1/en not_active Revoked
- 2008-03-28 CN CN2008800101448A patent/CN101652412B/zh active Active
- 2008-03-28 WO PCT/US2008/058607 patent/WO2008121790A1/en active Application Filing
- 2008-03-28 CA CA2681642A patent/CA2681642C/en active Active
- 2008-03-28 JP JP2010501247A patent/JP5416087B2/ja active Active
- 2008-03-28 CN CN200880010501A patent/CN101646722A/zh active Pending
- 2008-03-28 CN CN201510455772.9A patent/CN104962070B/zh active Active
-
2014
- 2014-06-16 US US14/305,287 patent/US9228071B2/en active Active
- 2014-07-24 US US14/339,732 patent/US20140336293A1/en not_active Abandoned
-
2015
- 2015-12-10 US US14/964,896 patent/US20160090462A1/en not_active Abandoned
-
2016
- 2016-02-04 US US15/015,184 patent/US9914815B2/en active Active
- 2016-08-24 US US15/245,412 patent/US20160362531A1/en not_active Abandoned
Also Published As
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5539854B2 (ja) | ヒドロクロロフルオロオレフィンおよびヒドロフルオロオレフィンの発泡剤組成物 | |
JP6441983B2 (ja) | ヒドロクロロフルオロオレフィンの発泡剤組成物 | |
JP2022188050A (ja) | フッ素置換されたオレフィンを含む発泡剤及び組成物、並びに発泡方法 | |
KR101863113B1 (ko) | 1-클로로-3,3,3 트리플루오로프로펜 및 1-플루오로-1,1 디클로로에탄을 함유하는 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20110308 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130625 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130924 |
|
A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20131015 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20140213 |
|
A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20140220 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140401 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5539854 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140501 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |