CN101641303A - 用于玻璃纤维的施胶组合物 - Google Patents
用于玻璃纤维的施胶组合物 Download PDFInfo
- Publication number
- CN101641303A CN101641303A CN200780048596A CN200780048596A CN101641303A CN 101641303 A CN101641303 A CN 101641303A CN 200780048596 A CN200780048596 A CN 200780048596A CN 200780048596 A CN200780048596 A CN 200780048596A CN 101641303 A CN101641303 A CN 101641303A
- Authority
- CN
- China
- Prior art keywords
- forming agent
- polyurethane film
- composition
- blocked isocyanate
- silane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 172
- 239000003365 glass fiber Substances 0.000 title claims abstract description 111
- 238000004026 adhesive bonding Methods 0.000 title claims abstract description 49
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 84
- 239000000835 fiber Substances 0.000 claims abstract description 83
- 238000004513 sizing Methods 0.000 claims abstract description 77
- 229920002635 polyurethane Polymers 0.000 claims abstract description 58
- 239000004814 polyurethane Substances 0.000 claims abstract description 58
- 239000002131 composite material Substances 0.000 claims abstract description 52
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 32
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 20
- 238000001035 drying Methods 0.000 claims abstract description 18
- 230000002708 enhancing effect Effects 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 43
- 239000012948 isocyanate Substances 0.000 claims description 39
- 150000002513 isocyanates Chemical class 0.000 claims description 39
- 239000000463 material Substances 0.000 claims description 35
- 239000003292 glue Substances 0.000 claims description 32
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 28
- 229910000077 silane Inorganic materials 0.000 claims description 28
- 239000011521 glass Substances 0.000 claims description 22
- 238000001746 injection moulding Methods 0.000 claims description 19
- -1 silicon ester Chemical class 0.000 claims description 17
- 239000012783 reinforcing fiber Substances 0.000 claims description 15
- 239000004593 Epoxy Substances 0.000 claims description 13
- 229920000098 polyolefin Polymers 0.000 claims description 11
- 229920001296 polysiloxane Polymers 0.000 claims description 11
- 239000000654 additive Substances 0.000 claims description 10
- 229920000728 polyester Polymers 0.000 claims description 10
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical group [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea group Chemical group NC(=O)N XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- NLSFWPFWEPGCJJ-UHFFFAOYSA-N 2-methylprop-2-enoyloxysilicon Chemical compound CC(=C)C(=O)O[Si] NLSFWPFWEPGCJJ-UHFFFAOYSA-N 0.000 claims description 9
- 150000004678 hydrides Chemical class 0.000 claims description 9
- BUZRAOJSFRKWPD-UHFFFAOYSA-N isocyanatosilane Chemical compound [SiH3]N=C=O BUZRAOJSFRKWPD-UHFFFAOYSA-N 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 claims description 9
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 150000002148 esters Chemical class 0.000 claims description 7
- 229920000570 polyether Polymers 0.000 claims description 7
- 229920001225 polyester resin Polymers 0.000 claims description 6
- 239000004645 polyester resin Substances 0.000 claims description 6
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 238000009827 uniform distribution Methods 0.000 claims description 4
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 4
- 230000002238 attenuated effect Effects 0.000 claims description 3
- 229920006395 saturated elastomer Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 2
- 230000002787 reinforcement Effects 0.000 claims description 2
- 239000004433 Thermoplastic polyurethane Substances 0.000 claims 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims 1
- 239000004412 Bulk moulding compound Substances 0.000 abstract description 18
- 238000004519 manufacturing process Methods 0.000 abstract description 9
- 238000005516 engineering process Methods 0.000 abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- 239000003677 Sheet moulding compound Substances 0.000 description 17
- 238000000748 compression moulding Methods 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 13
- 238000002360 preparation method Methods 0.000 description 13
- 230000008569 process Effects 0.000 description 11
- 229920003009 polyurethane dispersion Polymers 0.000 description 10
- 230000002344 fibroplastic effect Effects 0.000 description 9
- 239000007787 solid Substances 0.000 description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 7
- 230000008901 benefit Effects 0.000 description 7
- 239000003153 chemical reaction reagent Substances 0.000 description 7
- 239000000314 lubricant Substances 0.000 description 7
- 230000035939 shock Effects 0.000 description 7
- 230000000996 additive effect Effects 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000004634 thermosetting polymer Substances 0.000 description 6
- 238000000465 moulding Methods 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 150000001412 amines Chemical class 0.000 description 4
- 125000001261 isocyanato group Chemical group *N=C=O 0.000 description 4
- 238000007493 shaping process Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000007822 coupling agent Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000012634 fragment Substances 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000008188 pellet Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- QFXBYZKQOKCTQA-UHFFFAOYSA-N (carbamoylamino) 2-methylprop-2-enoate Chemical group CC(=C)C(=O)ONC(N)=O QFXBYZKQOKCTQA-UHFFFAOYSA-N 0.000 description 2
- NHUXFMNHQIITCP-UHFFFAOYSA-N 2-butoxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCOCCCC NHUXFMNHQIITCP-UHFFFAOYSA-N 0.000 description 2
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical class CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 2
- 241001599832 Agave fourcroydes Species 0.000 description 2
- 244000198134 Agave sisalana Species 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 2
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 2
- 239000000284 extract Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 2
- 239000006060 molten glass Substances 0.000 description 2
- DLSOILHAKCBARI-UHFFFAOYSA-N n-benzyl-2-methylpropan-2-amine Chemical compound CC(C)(C)NCC1=CC=CC=C1 DLSOILHAKCBARI-UHFFFAOYSA-N 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 238000010136 thermoset moulding Methods 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- CPUDPFPXCZDNGI-UHFFFAOYSA-N triethoxy(methyl)silane Chemical compound CCO[Si](C)(OCC)OCC CPUDPFPXCZDNGI-UHFFFAOYSA-N 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- MUHFRORXWCGZGE-KTKRTIGZSA-N 2-hydroxyethyl (z)-octadec-9-enoate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCO MUHFRORXWCGZGE-KTKRTIGZSA-N 0.000 description 1
- OXYZDRAJMHGSMW-UHFFFAOYSA-N 3-chloropropyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)CCCCl OXYZDRAJMHGSMW-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- 235000011624 Agave sisalana Nutrition 0.000 description 1
- 241000609240 Ambelania acida Species 0.000 description 1
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 240000008564 Boehmeria nivea Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 240000000491 Corchorus aestuans Species 0.000 description 1
- 235000011777 Corchorus aestuans Nutrition 0.000 description 1
- 235000010862 Corchorus capsularis Nutrition 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- IYXGSMUGOJNHAZ-UHFFFAOYSA-N Ethyl malonate Chemical class CCOC(=O)CC(=O)OCC IYXGSMUGOJNHAZ-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 240000006240 Linum usitatissimum Species 0.000 description 1
- 235000004431 Linum usitatissimum Nutrition 0.000 description 1
- OTGQIQQTPXJQRG-UHFFFAOYSA-N N-(octadecanoyl)ethanolamine Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCO OTGQIQQTPXJQRG-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002565 Polyethylene Glycol 400 Polymers 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 206010047571 Visual impairment Diseases 0.000 description 1
- GSFXLBMRGCVEMO-UHFFFAOYSA-N [SiH4].[S] Chemical class [SiH4].[S] GSFXLBMRGCVEMO-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000010905 bagasse Substances 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 238000005056 compaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- FIRQYUPQXNPTKO-UHFFFAOYSA-N ctk0i2755 Chemical class N[SiH2]N FIRQYUPQXNPTKO-UHFFFAOYSA-N 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 239000004815 dispersion polymer Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229910001651 emery Inorganic materials 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000011152 fibreglass Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000004811 fluoropolymer Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000009998 heat setting Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000005055 methyl trichlorosilane Substances 0.000 description 1
- JLUFWMXJHAVVNN-UHFFFAOYSA-N methyltrichlorosilane Chemical compound C[Si](Cl)(Cl)Cl JLUFWMXJHAVVNN-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 210000003205 muscle Anatomy 0.000 description 1
- 239000012802 nanoclay Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- MSRJTTSHWYDFIU-UHFFFAOYSA-N octyltriethoxysilane Chemical compound CCCCCCCC[Si](OCC)(OCC)OCC MSRJTTSHWYDFIU-UHFFFAOYSA-N 0.000 description 1
- 229960003493 octyltriethoxysilane Drugs 0.000 description 1
- 238000000643 oven drying Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- VGTPKLINSHNZRD-UHFFFAOYSA-N oxoborinic acid Chemical compound OB=O VGTPKLINSHNZRD-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005596 polymer binder Polymers 0.000 description 1
- 239000002491 polymer binding agent Substances 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/326—Polyureas; Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/2805—Compounds having only one group containing active hydrogen
- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
- C08G18/289—Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/80—Masked polyisocyanates
- C08G18/8061—Masked polyisocyanates masked with compounds having only one group containing active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/08—Ingredients of unknown constitution and ingredients covered by the main groups C08K3/00 - C08K9/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/544—Silicon-containing compounds containing nitrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/249921—Web or sheet containing structurally defined element or component
- Y10T428/249924—Noninterengaged fiber-containing paper-free web or sheet which is not of specified porosity
- Y10T428/249933—Fiber embedded in or on the surface of a natural or synthetic rubber matrix
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2962—Silane, silicone or siloxane in coating
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Reinforced Plastic Materials (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Moulding By Coating Moulds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/648,237 | 2006-12-29 | ||
| US11/648,237 US20080160281A1 (en) | 2006-12-29 | 2006-12-29 | Sizing composition for glass fibers |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101641303A true CN101641303A (zh) | 2010-02-03 |
Family
ID=39345228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780048596A Pending CN101641303A (zh) | 2006-12-29 | 2007-12-14 | 用于玻璃纤维的施胶组合物 |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US20080160281A1 (enExample) |
| EP (1) | EP2118033A2 (enExample) |
| JP (1) | JP2010514951A (enExample) |
| KR (1) | KR20090101205A (enExample) |
| CN (1) | CN101641303A (enExample) |
| BR (1) | BRPI0720887A2 (enExample) |
| CA (1) | CA2670816A1 (enExample) |
| MX (1) | MX2009006954A (enExample) |
| RU (1) | RU2009128250A (enExample) |
| WO (1) | WO2008085304A2 (enExample) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898044A (zh) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | 玄武岩纤维表面改性浸润剂及其制备方法 |
| CN102976632A (zh) * | 2012-11-28 | 2013-03-20 | 巨石集团有限公司 | 一种增强热固性树脂的bmc用短切玻纤浸润剂 |
| CN103159887A (zh) * | 2011-12-09 | 2013-06-19 | 北京东方亚科力化工科技有限公司 | 改性聚醋酸乙烯酯玻璃纤维成膜剂的制备方法,及玻璃纤维成膜剂 |
| CN103906717A (zh) * | 2011-09-23 | 2014-07-02 | Ocv智识资本有限责任公司 | 增强纤维及它们在混凝土增强中的用途 |
| CN105723023A (zh) * | 2013-10-16 | 2016-06-29 | Ocv智识资本有限责任公司 | 弹性无纺垫 |
| CN106458737A (zh) * | 2014-04-04 | 2017-02-22 | Ppg工业俄亥俄公司 | 用于湿式和干式长丝缠绕的上浆组合物 |
| CN108291072A (zh) * | 2015-10-08 | 2018-07-17 | Ocv智识资本有限责任公司 | 用于增强纤维的后-涂布组合物 |
| CN108495748A (zh) * | 2016-01-20 | 2018-09-04 | 泽费罗斯股份有限公司 | 具有核壳相的热塑性环氧材料 |
| CN108821610A (zh) * | 2018-08-07 | 2018-11-16 | 苏州华龙化工有限公司 | 一种玻璃纤维浸润剂及其制备方法 |
| CN108996922A (zh) * | 2017-06-07 | 2018-12-14 | 巨石集团有限公司 | 一种增强结构型smc的玻纤浸润剂及其在生产无捻粗纱中的应用 |
| CN109333859A (zh) * | 2018-09-17 | 2019-02-15 | 航天特种材料及工艺技术研究所 | 3d打印构件的制备方法及3d打印空间构件 |
| CN110171490A (zh) * | 2019-02-28 | 2019-08-27 | 山东中瑞德电动汽车有限公司 | 一种新能源汽车复合材料模块化车身结构件 |
| CN111893652A (zh) * | 2019-05-05 | 2020-11-06 | 南京和润隆环保科技有限公司 | 一种储罐吊顶保冷玻璃棉毡的制备方法 |
| CN112292361A (zh) * | 2018-03-28 | 2021-01-29 | 卓尔泰克公司 | 用于碳纤维的导电胶料 |
| CN112724466A (zh) * | 2020-12-29 | 2021-04-30 | 江苏绿材谷新材料科技发展有限公司 | 一种玄武岩纤维增强聚乙烯树脂用浸润剂及其制备方法 |
| CN113056444A (zh) * | 2018-10-26 | 2021-06-29 | 欧文斯科宁知识产权资产有限公司 | 用于陶瓷的截切玻璃纤维 |
| CN118290043A (zh) * | 2024-04-01 | 2024-07-05 | 巨石集团有限公司 | 一种玻璃纤维表面处理剂及其制备方法、玻璃纤维及其应用 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TW201024034A (en) * | 2008-12-30 | 2010-07-01 | Saint Gobain Abrasives Inc | Bonded abrasive tool and method of forming |
| CN102317339B (zh) * | 2009-02-11 | 2014-10-22 | Ppg工业俄亥俄公司 | 纤维增强的聚合复合材料及其制造方法 |
| CN106084706B (zh) * | 2011-07-06 | 2019-06-14 | 米尔泰奇有限公司 | 树脂、树脂/纤维复合材料、其使用方法及制备方法 |
| US9340454B2 (en) | 2011-12-22 | 2016-05-17 | Johns Manville | Methods for making reinforced thermoset composites with sized fibers |
| DK2834402T3 (en) * | 2012-04-04 | 2018-01-15 | Ucomposites As | Process for converting a fiberglass material and products obtained by the process |
| CN103160235B (zh) * | 2012-04-17 | 2014-10-29 | 南京彤天广元高分子材料有限公司 | 一种树脂粉末粘结剂 |
| CA2880548A1 (en) * | 2012-08-03 | 2014-02-06 | Ocv Intellectual Capital, Llc | Improved fiberglass reinforced composites |
| CN105273365B (zh) * | 2014-06-30 | 2019-03-26 | 康廷南拓结构塑料有限公司 | 包含表面改性玻璃填料的片状模塑组合物 |
| RU2565301C1 (ru) * | 2014-10-28 | 2015-10-20 | Общество с ограниченной ответственностью "КомАР" | Замасливатель для стеклянного и базальтового волокна |
| CN104448785A (zh) * | 2014-11-24 | 2015-03-25 | 宿州市紫金塑业有限公司 | 一种tpu可分解包装膜 |
| CN105541127B (zh) * | 2015-12-25 | 2018-04-24 | 巨石集团有限公司 | 玻璃纤维浸润剂及其在生产增强smc-a级表面用玻璃纤维纱中的应用 |
| CN105819709B (zh) * | 2016-03-29 | 2019-01-29 | 巨石集团有限公司 | 一种快速浸透的玻纤浸润剂及其在生产无捻粗纱中的应用 |
| JP2020516780A (ja) * | 2017-04-06 | 2020-06-11 | オーシーヴィー インテレクチュアル キャピタル リミテッド ライアビリティ カンパニー | 改善された剛性を有する強化繊維 |
| JP7084157B2 (ja) * | 2018-02-21 | 2022-06-14 | 帝人株式会社 | サイジング剤組成物、炭素繊維の製造方法及びサイジング剤付着炭素繊維 |
| CN108264246A (zh) * | 2018-03-03 | 2018-07-10 | 郭迎庆 | 一种采光板用玻璃纤维增强型浸润剂 |
| CN116023046B (zh) * | 2023-02-24 | 2024-03-01 | 中国科学院新疆理化技术研究所 | 一种有机-无机纳米杂化玄武岩纤维浸润剂及制备方法 |
| CN117024006A (zh) * | 2023-08-22 | 2023-11-10 | 巨石集团有限公司 | 一种玻璃纤维用浸润剂及其制备方法、产品和应用 |
Family Cites Families (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2007727B1 (enExample) * | 1968-05-03 | 1973-03-16 | Ppg Industries Inc | |
| US3869268A (en) * | 1973-12-11 | 1975-03-04 | Ppg Industries Inc | Method and apparatus for chopping fibers |
| US4455343A (en) * | 1980-12-29 | 1984-06-19 | Ppg Industries, Inc. | Aqueous treating composition for glass fiber strands used to produce mats for thermoplastics |
| US4394418A (en) * | 1981-12-24 | 1983-07-19 | Ppg Industries, Inc. | Aqueous sizing composition and glass fibers made therewith for reinforcing thermosetting polymers |
| DE3336845A1 (de) * | 1983-10-11 | 1985-04-25 | Bayer Ag, 5090 Leverkusen | Schlichtemittel fuer glasfasern |
| US4615946A (en) * | 1985-03-29 | 1986-10-07 | Ppg Industries, Inc. | Chemically treated glass fibers for reinforcing polymeric matrices |
| US5236982A (en) * | 1992-07-13 | 1993-08-17 | Owens-Corning Fiberglas Technology, Inc. | Size composition |
| US5300547A (en) * | 1992-10-30 | 1994-04-05 | Phillips Petroleum Company | Reinforced polypropylene compounds with improved properties |
| US6207737B1 (en) * | 1994-03-14 | 2001-03-27 | Ppg Industries Ohio, Inc. | Glass fiber sizing, sized glass fibers and polyolefin reinforced articles |
| US5753164A (en) * | 1995-08-30 | 1998-05-19 | The Budd Company | Automated thermoset molding method |
| DE19914882A1 (de) * | 1999-04-01 | 2000-10-05 | Bayer Ag | Selbstvernetzende Polyurethan-, Polyurethan-Polyharnstoff- bzw. Polyharnstoff-Dispersionen für Schlichten |
| DE10226924A1 (de) * | 2002-06-17 | 2003-12-24 | Bayer Ag | Schlichtezusammensetzung |
| FR2888255B1 (fr) * | 2005-07-06 | 2007-11-16 | Saint Gobain Vetrotex | Fils de renforcement et composites ayant une tenue au feu amelioree |
| US20070059506A1 (en) * | 2005-09-12 | 2007-03-15 | Hager William G | Glass fiber bundles for mat applications and methods of making the same |
-
2006
- 2006-12-29 US US11/648,237 patent/US20080160281A1/en not_active Abandoned
-
2007
- 2007-12-14 CN CN200780048596A patent/CN101641303A/zh active Pending
- 2007-12-14 KR KR1020097013441A patent/KR20090101205A/ko not_active Withdrawn
- 2007-12-14 CA CA 2670816 patent/CA2670816A1/en not_active Abandoned
- 2007-12-14 MX MX2009006954A patent/MX2009006954A/es unknown
- 2007-12-14 WO PCT/US2007/025651 patent/WO2008085304A2/en not_active Ceased
- 2007-12-14 BR BRPI0720887-1A2A patent/BRPI0720887A2/pt not_active IP Right Cessation
- 2007-12-14 EP EP07853401A patent/EP2118033A2/en not_active Withdrawn
- 2007-12-14 RU RU2009128250/03A patent/RU2009128250A/ru not_active Application Discontinuation
- 2007-12-14 JP JP2009544017A patent/JP2010514951A/ja not_active Abandoned
-
2011
- 2011-05-11 US US13/105,645 patent/US20110305904A1/en not_active Abandoned
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103906717A (zh) * | 2011-09-23 | 2014-07-02 | Ocv智识资本有限责任公司 | 增强纤维及它们在混凝土增强中的用途 |
| CN103159887A (zh) * | 2011-12-09 | 2013-06-19 | 北京东方亚科力化工科技有限公司 | 改性聚醋酸乙烯酯玻璃纤维成膜剂的制备方法,及玻璃纤维成膜剂 |
| CN103159887B (zh) * | 2011-12-09 | 2014-12-10 | 北京东方亚科力化工科技有限公司 | 改性聚醋酸乙烯酯玻璃纤维成膜剂的制备方法,及玻璃纤维成膜剂 |
| CN102898044A (zh) * | 2012-10-19 | 2013-01-30 | 四川航天拓鑫玄武岩实业有限公司 | 玄武岩纤维表面改性浸润剂及其制备方法 |
| CN102898044B (zh) * | 2012-10-19 | 2015-01-21 | 四川航天拓鑫玄武岩实业有限公司 | 玄武岩纤维表面改性浸润剂及其制备方法 |
| CN102976632A (zh) * | 2012-11-28 | 2013-03-20 | 巨石集团有限公司 | 一种增强热固性树脂的bmc用短切玻纤浸润剂 |
| CN102976632B (zh) * | 2012-11-28 | 2016-08-03 | 巨石集团有限公司 | 一种增强热固性树脂的bmc用短切玻纤浸润剂 |
| CN105723023A (zh) * | 2013-10-16 | 2016-06-29 | Ocv智识资本有限责任公司 | 弹性无纺垫 |
| CN106458737A (zh) * | 2014-04-04 | 2017-02-22 | Ppg工业俄亥俄公司 | 用于湿式和干式长丝缠绕的上浆组合物 |
| CN108291072A (zh) * | 2015-10-08 | 2018-07-17 | Ocv智识资本有限责任公司 | 用于增强纤维的后-涂布组合物 |
| CN108495748A (zh) * | 2016-01-20 | 2018-09-04 | 泽费罗斯股份有限公司 | 具有核壳相的热塑性环氧材料 |
| CN108996922A (zh) * | 2017-06-07 | 2018-12-14 | 巨石集团有限公司 | 一种增强结构型smc的玻纤浸润剂及其在生产无捻粗纱中的应用 |
| CN112292361A (zh) * | 2018-03-28 | 2021-01-29 | 卓尔泰克公司 | 用于碳纤维的导电胶料 |
| US11566369B2 (en) | 2018-03-28 | 2023-01-31 | Zoltek Corporation | Electrically conductive sizing for carbon fibers |
| CN108821610A (zh) * | 2018-08-07 | 2018-11-16 | 苏州华龙化工有限公司 | 一种玻璃纤维浸润剂及其制备方法 |
| CN109333859A (zh) * | 2018-09-17 | 2019-02-15 | 航天特种材料及工艺技术研究所 | 3d打印构件的制备方法及3d打印空间构件 |
| CN109333859B (zh) * | 2018-09-17 | 2020-10-16 | 航天特种材料及工艺技术研究所 | 3d打印构件的制备方法及3d打印空间构件 |
| CN113056444A (zh) * | 2018-10-26 | 2021-06-29 | 欧文斯科宁知识产权资产有限公司 | 用于陶瓷的截切玻璃纤维 |
| CN110171490A (zh) * | 2019-02-28 | 2019-08-27 | 山东中瑞德电动汽车有限公司 | 一种新能源汽车复合材料模块化车身结构件 |
| CN111893652A (zh) * | 2019-05-05 | 2020-11-06 | 南京和润隆环保科技有限公司 | 一种储罐吊顶保冷玻璃棉毡的制备方法 |
| CN112724466A (zh) * | 2020-12-29 | 2021-04-30 | 江苏绿材谷新材料科技发展有限公司 | 一种玄武岩纤维增强聚乙烯树脂用浸润剂及其制备方法 |
| CN118290043A (zh) * | 2024-04-01 | 2024-07-05 | 巨石集团有限公司 | 一种玻璃纤维表面处理剂及其制备方法、玻璃纤维及其应用 |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20090101205A (ko) | 2009-09-24 |
| US20080160281A1 (en) | 2008-07-03 |
| BRPI0720887A2 (pt) | 2014-03-25 |
| RU2009128250A (ru) | 2011-02-10 |
| WO2008085304A2 (en) | 2008-07-17 |
| MX2009006954A (es) | 2009-07-08 |
| EP2118033A2 (en) | 2009-11-18 |
| US20110305904A1 (en) | 2011-12-15 |
| JP2010514951A (ja) | 2010-05-06 |
| WO2008085304A3 (en) | 2008-09-18 |
| CA2670816A1 (en) | 2008-07-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101641303A (zh) | 用于玻璃纤维的施胶组合物 | |
| CN103906717A (zh) | 增强纤维及它们在混凝土增强中的用途 | |
| CN101300204A (zh) | 具有改善的高温湿抗拉强度的湿成形毡垫 | |
| US20120190263A1 (en) | Soft, flexible nonwoven chopped strand mat for use in pultrusion processes | |
| EP3058126B1 (en) | Flexible non-woven mat | |
| CN104812696A (zh) | 改进的玻璃纤维增强的复合材料 | |
| CA2672136A1 (en) | Chemical coating composition for glass fibers for improved fiber dispersion | |
| WO2009086152A2 (en) | Variable dispersion of wet use chopped strand glass fibers in a chopped strand mat | |
| CN101827796B (zh) | 用于玻璃原丝的呈物理凝胶形式的上胶组合物、所获得的玻璃原丝和包括所述原丝的复合材料 | |
| US20070059506A1 (en) | Glass fiber bundles for mat applications and methods of making the same | |
| US7169463B2 (en) | Sizing composition for sheet molding compound roving | |
| WO2003020658A1 (en) | Calcium carbonate filled epoxy urethane string binders |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20100203 |