CN101522782B - 制备多相丙烯共聚物的气相方法 - Google Patents

制备多相丙烯共聚物的气相方法 Download PDF

Info

Publication number
CN101522782B
CN101522782B CN2007800366482A CN200780036648A CN101522782B CN 101522782 B CN101522782 B CN 101522782B CN 2007800366482 A CN2007800366482 A CN 2007800366482A CN 200780036648 A CN200780036648 A CN 200780036648A CN 101522782 B CN101522782 B CN 101522782B
Authority
CN
China
Prior art keywords
propylene
polymerization
weight
reactor
component
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2007800366482A
Other languages
English (en)
Chinese (zh)
Other versions
CN101522782A (zh
Inventor
G·戈沃尼
M·科维兹
G·彭佐
A·查罗奇
A·德卢西亚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
Original Assignee
Basell Poliolefine Italia SRL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Basell Poliolefine Italia SRL filed Critical Basell Poliolefine Italia SRL
Publication of CN101522782A publication Critical patent/CN101522782A/zh
Application granted granted Critical
Publication of CN101522782B publication Critical patent/CN101522782B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/34—Polymerisation in gaseous state
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04—Monomers containing three or four carbon atoms
    • C08F210/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • C08F297/083—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins the monomers being ethylene or propylene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65—Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/02—Heterophasic composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C08L23/14—Copolymers of propene
    • C08L23/142—Copolymers of propene at least partially crystalline copolymers of propene with other olefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2308/00—Chemical blending or stepwise polymerisation process with the same catalyst

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN2007800366482A 2006-08-04 2007-07-20 制备多相丙烯共聚物的气相方法 Active CN101522782B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP06118457.8 2006-08-04
EP06118457 2006-08-04
PCT/EP2007/057539 WO2008015113A2 (en) 2006-08-04 2007-07-20 Gas-phase process for preparing heterophasic propylene copolymers

Publications (2)

Publication Number Publication Date
CN101522782A CN101522782A (zh) 2009-09-02
CN101522782B true CN101522782B (zh) 2011-12-28

Family

ID=38596398

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2007800366482A Active CN101522782B (zh) 2006-08-04 2007-07-20 制备多相丙烯共聚物的气相方法

Country Status (9)

Country Link
EP (1) EP2046846B1 (https=)
JP (1) JP2009545659A (https=)
KR (1) KR101422554B1 (https=)
CN (1) CN101522782B (https=)
AT (1) ATE510868T1 (https=)
BR (1) BRPI0714250B1 (https=)
CA (1) CA2659749A1 (https=)
RU (1) RU2444547C2 (https=)
WO (1) WO2008015113A2 (https=)

Families Citing this family (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101790446B (zh) 2007-08-27 2013-08-07 博里利斯技术有限公司 生产聚合物粒料的设备和方法
WO2009153213A1 (en) * 2008-06-16 2009-12-23 Borealis Ag Thermoplastic polyolefins with high flowability and excellent surface quality produced by a multistage process
CN102190748B (zh) * 2010-03-19 2013-03-27 中国石油天然气股份有限公司 一种丙烯/1-丁烯无规共聚树脂的制备方法
EP2368921B1 (en) * 2010-03-26 2014-11-26 Borealis AG Process for the preparation of flowable comonomer rich polypropylene
CN102399395B (zh) * 2010-09-07 2013-02-13 中国石油天然气股份有限公司 一种高流动高乙烯含量无规共聚透明聚丙烯树脂的制备方法
EP2452956A1 (en) * 2010-11-12 2012-05-16 Borealis AG Improved process for polymerising propylene
EP2452959B1 (en) * 2010-11-12 2015-01-21 Borealis AG Process for producing propylene random copolymers and their use
EP2452957A1 (en) * 2010-11-12 2012-05-16 Borealis AG Improved process for producing heterophasic propylene copolymers
EP2557118B1 (en) * 2011-08-09 2015-12-30 Borealis AG Preparation of a soft heterophasic propylene copolymer
WO2013127760A1 (en) * 2012-02-27 2013-09-06 Borealis Ag Polypropylene composition combining softness, toughness, low haze and high thermal resistance
CN103788258B (zh) * 2012-10-30 2019-02-19 中国石油化工股份有限公司 一种丙烯的聚合方法
DE102013221849B4 (de) * 2012-10-30 2021-07-29 Beijing Research Institute Of Chemical Industry, China Petroleum & Chemical Corporation Verfahren zur Herstellung eines Propylenpolymers
CN105051075B (zh) 2013-03-14 2018-03-30 格雷斯公司 丙烯/丁烯互聚物制备系统和方法
CN104558335B (zh) * 2013-10-11 2017-06-09 中国石油化工股份有限公司 一种基于丙烯的三元共聚物的制备方法
US9683062B2 (en) * 2013-10-24 2017-06-20 Basell Poliolefin Italia S.R.L. Process for the preparation of porous propylene polymers
PL3074429T3 (pl) 2013-11-26 2024-07-08 W.R. Grace & Co. - Conn. Wytwarzanie udarowych kopolimerów propylenu i wyrobów
EP3170864B1 (en) * 2015-11-17 2018-10-17 Borealis AG High flow tpo composition with excellent balance in mechanical properties for automotive interior
WO2017202597A1 (en) * 2016-05-25 2017-11-30 Basell Poliolefine Italia S.R.L. Film for stretch hood applications
WO2018025864A1 (ja) * 2016-08-03 2018-02-08 住友化学株式会社 ヘテロファジックプロピレン重合材料の製造方法
CN110198963B (zh) * 2016-12-12 2022-06-24 Sabic环球技术有限责任公司 制造低排放异相聚丙烯的方法
CN108586644A (zh) * 2018-06-13 2018-09-28 浙江卫星能源有限公司 一种丙烯的多段聚合方法及装置
US11976198B2 (en) * 2019-01-10 2024-05-07 Basell Poliolefine Italia S.R.L. Mixtures of bitumen and polymer compositions
CN110183782A (zh) * 2019-06-25 2019-08-30 陕西延长中煤榆林能源化工有限公司 一种双无规抗冲共聚聚丙烯材料及其工业化生产方法
JP7453801B2 (ja) * 2020-02-14 2024-03-21 住友化学株式会社 プロピレン重合体の製造方法
PL3868793T3 (pl) * 2020-02-24 2026-04-20 Borealis Gmbh Sposób produkcji polimerów alfa-olefinowych w procesie polimeryzacji wieloetapowej
CA3172744A1 (en) * 2020-04-21 2021-10-28 Monica Galvan Improved asphalt material
US11254761B1 (en) * 2020-10-15 2022-02-22 Chevron Phillips Chemical Company Lp Catalyst pretreatment and feeding system for polypropylene production
EP4005669A1 (en) * 2020-11-25 2022-06-01 Borealis AG Propylene polymerization plant revamping process
EP4008732A1 (en) * 2020-12-01 2022-06-08 Borealis AG Process for the production of polyolefin compositions in a multistage process
CN112979845B (zh) * 2021-02-09 2022-01-25 河北海航石化新型材料有限公司 一种特级电工级聚丙烯生产方法及装置
CN115475581A (zh) * 2021-06-15 2022-12-16 中国石油化工股份有限公司 一种多反应器烯烃聚合系统和聚合方法
EP4359448A1 (en) 2021-06-25 2024-05-01 Braskem, S.A. Propylene preliminary polymerization
KR20230083820A (ko) 2021-12-03 2023-06-12 에스케이이노베이션 주식회사 폴리올레핀 제조 장치
CN115926076A (zh) * 2022-12-05 2023-04-07 北京鑫美格工程设计有限公司 一种聚丙烯合金的生产方法及装置
KR102925514B1 (ko) * 2023-05-24 2026-02-09 한화솔루션 주식회사 폴리프로필렌이 분산된 고밀도폴리에틸렌 조성물의 제조 방법 및 이에 의해 제조된 물품

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1047302A (zh) * 1989-04-28 1990-11-28 希蒙特公司 用于烯烃聚合的催化组分及催化剂
WO1992021706A1 (en) * 1991-06-03 1992-12-10 Himont Incorporated Process for the gas-phase polymerization of olefins
EP0640649A1 (en) * 1993-08-30 1995-03-01 Montell North America Inc. Polyolefin compositions having high balance of stiffness and impact strength
CN1275139A (zh) * 1998-08-19 2000-11-29 蒙特克美国有限公司 多相聚合物组合物的制备方法及如此获得的组合物
EP1279699A1 (en) * 2001-07-27 2003-01-29 Baselltech USA Inc. Soft polyolefin compositions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2834214B2 (ja) * 1989-09-13 1998-12-09 三菱化学株式会社 プロピレンブロック共重合体の製造法
JP3443849B2 (ja) * 1992-11-12 2003-09-08 東ソー株式会社 プロピレンブロック共重合体の製造方法
ATE288941T1 (de) * 1998-11-03 2005-02-15 Basell Poliolefine Spa Polyolefinzusammensetzung mit gleichzeitig hoher steifheit und schlagfestigkeit

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1047302A (zh) * 1989-04-28 1990-11-28 希蒙特公司 用于烯烃聚合的催化组分及催化剂
WO1992021706A1 (en) * 1991-06-03 1992-12-10 Himont Incorporated Process for the gas-phase polymerization of olefins
EP0640649A1 (en) * 1993-08-30 1995-03-01 Montell North America Inc. Polyolefin compositions having high balance of stiffness and impact strength
CN1275139A (zh) * 1998-08-19 2000-11-29 蒙特克美国有限公司 多相聚合物组合物的制备方法及如此获得的组合物
EP1279699A1 (en) * 2001-07-27 2003-01-29 Baselltech USA Inc. Soft polyolefin compositions

Also Published As

Publication number Publication date
KR101422554B1 (ko) 2014-07-24
EP2046846A2 (en) 2009-04-15
WO2008015113A3 (en) 2008-03-27
WO2008015113A2 (en) 2008-02-07
CA2659749A1 (en) 2008-02-07
ATE510868T1 (de) 2011-06-15
RU2444547C2 (ru) 2012-03-10
JP2009545659A (ja) 2009-12-24
RU2009107703A (ru) 2010-09-10
CN101522782A (zh) 2009-09-02
EP2046846B1 (en) 2011-05-25
KR20090034955A (ko) 2009-04-08
BRPI0714250B1 (pt) 2018-04-17
BRPI0714250A2 (pt) 2015-04-22

Similar Documents

Publication Publication Date Title
CN101522782B (zh) 制备多相丙烯共聚物的气相方法
US5326639A (en) Thermoplastic olefin polymer and method of preparing same
CN100523076C (zh) 耐冲击的聚烯烃组合物
RU2531352C2 (ru) Полиолефиновая маточная смесь и композиция, подходящая для литьевого формования
CN101679557B (zh) 用于制备软质丙烯聚合物组合物的方法
CN100351277C (zh) 丙烯共聚物的制备方法
CN101065437B (zh) 弹性体聚烯烃组合物
JP3239184B2 (ja) 線状低密度ポリエチレンの製造法
CN1898274B (zh) 乙烯的(共)聚合方法
JP2001522903A (ja) ポリプロピレンの製造方法
SK646389A3 (en) Process for the in situ blending of polymers
KR20230019995A (ko) 폴리프로필렌 조성물
US20160122453A1 (en) Methods of Catalyst Activation
RU2697706C9 (ru) Пропилен-полимерные композиции
JPH0987328A (ja) エチレン／α−オレフィン共重合体の連続多段重合法
JP5203587B2 (ja) プロピレン系重合体及び発泡成形体
CN102325798A (zh) 加宽在水平搅拌气相反应器中制造的聚烯烃材料的分子量分布
CN115210267A (zh) 生产双峰聚烯烃和抗冲共聚物的方法
JPH10287707A (ja) オレフィン（共）重合体組成物及びその製造方法
CN116143958B (zh) 一种聚丙烯基组合物的制备方法
JP2008516025A (ja) エラストマーポリオレフィン組成物
JP6980932B2 (ja) 高いスウェル比、ｆｎｃｔ及び衝撃耐性を有するポリエチレン組成物
JP2000017124A (ja) オレフィン（共）重合体組成物及びオレフィン（共）重合体組成物成型品
JP2025529119A (ja) 改善された膨潤挙動を有するブロー成形用ポリエチレン組成物
JP2025529117A (ja) 改善された膨潤挙動を有するブロー成形用ポリエチレン組成物

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant