CN1014404B - 气相氟化方法 - Google Patents

气相氟化方法

Info

Publication number
CN1014404B
CN1014404B CN88104212A CN88104212A CN1014404B CN 1014404 B CN1014404 B CN 1014404B CN 88104212 A CN88104212 A CN 88104212A CN 88104212 A CN88104212 A CN 88104212A CN 1014404 B CN1014404 B CN 1014404B
Authority
CN
China
Prior art keywords
metal
catalyzer
cobalt
contact
halogen ethene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CN88104212A
Other languages
English (en)
Chinese (zh)
Other versions
CN1031073A (zh
Inventor
利奥·欧内斯特·曼塞
维利尤尔·诺特·马利卡荣纳
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=22097611&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN1014404(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Publication of CN1031073A publication Critical patent/CN1031073A/zh
Publication of CN1014404B publication Critical patent/CN1014404B/zh
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/07—Preparation of halogenated hydrocarbons by addition of hydrogen halides
    • C07C17/087—Preparation of halogenated hydrocarbons by addition of hydrogen halides to unsaturated halogenated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
    • C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN88104212A 1987-07-07 1988-07-07 气相氟化方法 Expired CN1014404B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US07/070,826 US4766260A (en) 1987-07-07 1987-07-07 Gas-phase fluorination process
US070826 1987-07-07

Publications (2)

Publication Number Publication Date
CN1031073A CN1031073A (zh) 1989-02-15
CN1014404B true CN1014404B (zh) 1991-10-23

Family

ID=22097611

Family Applications (1)

Application Number Title Priority Date Filing Date
CN88104212A Expired CN1014404B (zh) 1987-07-07 1988-07-07 气相氟化方法

Country Status (18)

Country Link
US (1) US4766260A (US20110009641A1-20110113-C00116.png)
EP (1) EP0298662B2 (US20110009641A1-20110113-C00116.png)
JP (1) JP2578923B2 (US20110009641A1-20110113-C00116.png)
KR (1) KR890001916A (US20110009641A1-20110113-C00116.png)
CN (1) CN1014404B (US20110009641A1-20110113-C00116.png)
AR (1) AR244651A1 (US20110009641A1-20110113-C00116.png)
AT (1) ATE73748T1 (US20110009641A1-20110113-C00116.png)
AU (1) AU600212B2 (US20110009641A1-20110113-C00116.png)
BR (1) BR8803356A (US20110009641A1-20110113-C00116.png)
CA (1) CA1308743C (US20110009641A1-20110113-C00116.png)
DE (1) DE3869242D1 (US20110009641A1-20110113-C00116.png)
ES (1) ES2033432T3 (US20110009641A1-20110113-C00116.png)
GR (1) GR3004106T3 (US20110009641A1-20110113-C00116.png)
HK (1) HK56792A (US20110009641A1-20110113-C00116.png)
MX (1) MX166813B (US20110009641A1-20110113-C00116.png)
RU (1) RU1799375C (US20110009641A1-20110113-C00116.png)
SG (1) SG54092G (US20110009641A1-20110113-C00116.png)
ZA (1) ZA884845B (US20110009641A1-20110113-C00116.png)

Families Citing this family (63)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5008475A (en) * 1987-07-07 1991-04-16 E. I. Du Pont De Nemours And Company Gas-phase fluorination process
JPH01108292A (ja) * 1987-10-19 1989-04-25 Daikin Ind Ltd 冷媒
US4843181A (en) * 1987-10-22 1989-06-27 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1-trifluorodichloroethane and 1,1,1,2-tetrafluorochloroethane
IN170774B (US20110009641A1-20110113-C00116.png) * 1988-05-23 1992-05-16 Du Pont
DE68909598T2 (de) * 1988-06-23 1994-04-14 Du Pont Katalysiertes hydrofluorierungsverfahren.
US5094773A (en) * 1988-08-01 1992-03-10 E. I. Du Pont De Nemours And Company Azeotropes of HF and process for the separation of HF via azeotropic distillation
MX169984B (es) * 1988-10-25 1993-08-03 Du Pont Proceso mejorado para la preparacion de 1,1,1,2 tetrafluoroetano
GB8828544D0 (en) * 1988-12-07 1989-01-11 Ici Plc Chemical process
IT1230779B (it) * 1989-07-12 1991-10-29 Ausimont Srl Procedimento per preparare 1,1,1,2 tetrafluoroetano.
IT1230780B (it) * 1989-07-12 1991-10-29 Ausimont Srl Procedimento per la preparazione di 1,2 dicloro 1,1,2 trifluoroetano.
DE69031344D1 (de) * 1989-10-04 1997-10-02 Du Pont Verfahren zur reinigung von fluorkohlenwasserstoffen
US5171901A (en) * 1990-02-14 1992-12-15 Bayer Aktiengesellschaft Process for the preparation of 1,1,1,3,3,3-hexafluoropropane and 2-chloro-1,1,1,3,3,3-hexafluoropropane
FR2661906B1 (fr) * 1990-05-11 1993-10-01 Atochem Procede de fabrication du 1,1,1,2-tetrafluoro-chloroethane et du pentafluoroethane.
US5030372A (en) * 1990-07-31 1991-07-09 E. I. Du Pont De Nemours And Company Catalytic equilibration to improve the relative yield of selected halocarbons
JPH06501921A (ja) * 1990-07-31 1994-03-03 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 選択されたハロカーボンの触媒平衡化
DE69212821T2 (de) * 1991-03-20 1996-12-19 Du Pont Verfahren zur herstellung von 2-chlor-1,1,1-trifluorethan
US5300710A (en) * 1991-03-20 1994-04-05 E. I. Du Pont De Nemours And Company Process for the manufacture of 2-chloro-1,1,1,2-tetrafluoroethane and pentafluoroethane
US5300711A (en) * 1991-03-20 1994-04-05 E. I. Du Pont De Nemours And Company Process for the manufacture of 2,2-dichloro-1,1,1-trifluoroethane, 2-chloro-1,1,1,2-tetrafluoroethane and pentafluoroethane
US5321170A (en) * 1991-03-20 1994-06-14 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2-tetrafluoroethane
JP2748720B2 (ja) * 1991-05-23 1998-05-13 ダイキン工業株式会社 ハロゲン化炭化水素のフッ素化方法
US5243108A (en) * 1991-06-03 1993-09-07 E. I. Du Pont De Nemours And Company Aluminum fluoride catalyst compositions and use thereof in a chlorofluorination process for preparing 1,1-dichloro-1,2,2,2-tetrafluoroethane
US5243106A (en) * 1991-06-03 1993-09-07 E. I. Du Pont De Nemours And Company Processes using aluminum fluoride catalyst compositions for preparing 1,1-dichloro-1,2,2,2-tetrafluoroethane
IT1251951B (it) * 1991-10-18 1995-05-27 Ausimont Spa Procedimento per purificare 1,1,1-trifluoro-,2,2 dicloroetano dall`isomero 1,1,2-trifluoro-1,2-dicloroetano.
IT1251957B (it) * 1991-10-18 1995-05-27 Ausimont Spa Procedimento per isomerizzare 1,1,2-trifluoro-1,2-dicloroetano a 1,1,1- trifluoro-2,2,-dicloroetano
US5334785A (en) * 1991-10-25 1994-08-02 Allied-Signal Inc. Process for the manufacture of 1,1,1,2-tetrafluoroethane
JP2661441B2 (ja) * 1991-11-27 1997-10-08 ダイキン工業株式会社 １，１，１−トリフルオロ−２−クロロエタンおよび／または１，１，１，２−テトラフルオロエタンの製法
JPH05194287A (ja) * 1992-01-13 1993-08-03 Daikin Ind Ltd ハロゲン化ブテンおよびブタンの製造方法
JP3369604B2 (ja) * 1992-09-04 2003-01-20 ダイキン工業株式会社 １，１，１，２，３，３−ヘキサフルオロプロパンの製造方法及びテトラフルオロクロロプロペンの製造方法
US5345017A (en) * 1992-12-08 1994-09-06 E. I. Du Pont De Nemours And Company Process for reducing the fluorine content of halocarbons
US5523498A (en) * 1992-12-08 1996-06-04 E. I. Du Pont De Nemours And Company Process for reducing the fluorine content of hydrofluorocarbons and hydrohalofluorocarbons
FR2700770B1 (fr) * 1993-01-27 1995-03-24 Atochem Elf Sa Procédé de fabrication du 1,1,1,2-tétrafluoro-2-chloroéthane et du pentafluoroéthane.
FR2700766B1 (fr) * 1993-01-27 1995-03-24 Atochem Elf Sa Procédé de fluoration de perchloréthylène ou du pentachloréthane.
US5827492A (en) * 1993-01-28 1998-10-27 E. I. Du Pont De Nemours And Company Hydrogen chloride purification process
US5866730A (en) * 1993-04-02 1999-02-02 E. I. Du Pont De Nemours And Company Process for enriching 1,2-dichloro-1,1,2,2-tetrafluoroethane from a mixture of dichlorotetrafluoroethane isomers
US5409625A (en) * 1993-05-24 1995-04-25 E. I. Du Pont De Nemours And Company Azeotropic mixture of linear hydrofluorocarbon and HF
US5396000A (en) * 1993-05-24 1995-03-07 E. I. Du Pont De Nemours And Company Process for the manufacture of 1,1,1,2,3,-pentafluoropropane
US5274190A (en) * 1993-05-24 1993-12-28 E. I. Du Pont De Nemours And Company Process for the manufacture of linear hydrofluorocarbons containing end group hydrogen substituents
US5274189A (en) * 1993-05-24 1993-12-28 E. I. Du Pont De Nemours And Company Process for the manufacture of linear hydrofluorocarbons containing end group hydrogen substituents
WO1995011875A1 (en) * 1993-10-28 1995-05-04 Alliedsignal Inc. Process for purifying 1,1-dichloro-2,2,2-trifluoroethane and 1-chloro-1,2,2,2-tetrafluoroethane
US5411583A (en) * 1993-11-15 1995-05-02 E. I. Du Pont De Nemours And Company HF-resistant ceramics and use thereof
JP2865554B2 (ja) * 1994-04-08 1999-03-08 セントラル硝子株式会社 フルオロメチル−１，１，１，３，３，３−ヘキサフルオロイソプロピルエーテルのガスクロマトグラフ分析
US5545778A (en) * 1994-05-25 1996-08-13 Alliedsignal Inc. Single stage process for producing hydrofluorocarbons from perchloroethylene
US5569794A (en) * 1994-05-24 1996-10-29 Alliedsignal Inc. Vapor phase process for producing hydroflourocarbons from perchloroethylene having a phenolic inhibitor
US5563304A (en) * 1994-05-26 1996-10-08 E. I. Du Pont De Nemours And Company Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF
JP3873289B2 (ja) * 1994-10-07 2007-01-24 ダイキン工業株式会社 ペンタフルオロエタンの分離方法およびそれを利用するペンタフルオロエタンの製造方法
JP3558385B2 (ja) * 1994-10-13 2004-08-25 昭和電工株式会社 クロム系フッ素化触媒、及びフッ素化方法
US5847242A (en) * 1995-05-19 1998-12-08 E. I. Du Pont De Nemours And Company Catalysts for halogenated hydrocarbon processing, their precursors and their preparation and use
IT1303074B1 (it) * 1998-05-07 2000-10-23 Ausimont Spa Catalizzatore per la fluorurazione di composti organici alogenati
US6365544B2 (en) 1998-05-22 2002-04-02 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided alumina supports
US6368997B2 (en) * 1998-05-22 2002-04-09 Conoco Inc. Fischer-Tropsch processes and catalysts using fluorided supports
US6472574B2 (en) 1999-12-10 2002-10-29 E. I. Du Pont Nemours And Company Production of 1,2-dihydro and 2,2-dihydro hexafluoropropanes and azeotropes thereof with HF
US6333440B1 (en) 2000-04-07 2001-12-25 E. I. Du Pont De Nemours And Company Process for perfluorocyclobutane purification
US7897823B2 (en) * 2004-10-29 2011-03-01 E. I. Du Pont De Nemours And Company Process for production of azeotrope compositions comprising hydrofluoroolefin and hydrogen fluoride and uses of said azeotrope compositions in separation processes
US7476771B2 (en) 2005-11-01 2009-01-13 E.I. Du Pont De Nemours + Company Azeotrope compositions comprising 2,3,3,3-tetrafluoropropene and hydrogen fluoride and uses thereof
GB0525701D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525702D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525699D0 (en) 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
GB0525700D0 (en) * 2005-12-17 2006-01-25 Ineos Fluor Holdings Ltd Process
CN101415664B (zh) * 2006-03-31 2012-05-30 纳幕尔杜邦公司 氢氟烯烃的同时制备
US8232435B2 (en) * 2006-09-05 2012-07-31 E I Du Pont De Nemours And Company 1,2,3,3,3-pentafluoropropene production processes
MX337217B (es) 2006-10-03 2016-02-18 Mexichem Amanco Holding Sa Procedimiento de dehidrogenacion-halogenacion para la produccion de (hidro)fluoroalquenos de c3-c6.
CN103755519A (zh) * 2014-02-24 2014-04-30 山东联创节能新材料股份有限公司 六氟丁烯的合成方法
CN112946126B (zh) * 2021-02-02 2022-07-15 福建德尔科技有限公司 高纯三氟化氯中杂质定量、定性装置及方法

Family Cites Families (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2755313A (en) * 1951-08-03 1956-07-17 Allied Chem & Dye Corp Manufacture of saturated halocarbons
US2669590A (en) * 1951-08-03 1954-02-16 Allied Chem & Dye Corp Production of fluorine compounds
US2744148A (en) * 1952-02-04 1956-05-01 Dow Chemical Co Process for fluorination of haloalkanes using a hydrogen fluoride activated catalyst containing alumina, a metal fluoride and basic aluminum fluoride
US2744147A (en) * 1952-02-04 1956-05-01 Dow Chemical Co Fluorination of haloalkanes with a catalyst containing gamma alumina
US2724004A (en) * 1952-04-08 1955-11-15 Goodrich Co B F Preparation of 1, 1-difluoro-1, 2, 2-trichloroethane
US2850543A (en) * 1954-02-17 1958-09-02 Allied Chem Manufacture of 1, 2, 2-trichloro-1, 1, 2-trifluoroethane
GB805503A (en) * 1956-03-15 1958-12-10 Dow Chemical Co Improved fluorination catalyst and process
US3258500A (en) * 1959-08-17 1966-06-28 Du Pont Process for fluorinating halohydro-carbons
US3157707A (en) * 1961-02-20 1964-11-17 Union Carbide Corp Method of reacting tetrachloroethylene, chlorine and hydrogen fluoride
NL274475A (US20110009641A1-20110113-C00116.png) * 1962-02-07
GB1000485A (en) * 1962-02-07 1965-08-04 Sicedison Spa Improvements in or relating to the fluorination of halo-olefines
NL301934A (US20110009641A1-20110113-C00116.png) * 1962-12-28 1900-01-01
US3607955A (en) * 1968-04-08 1971-09-21 Phillips Petroleum Co Hydrofluorination and dehydrofluorination and catalysts therefor
NL169036C (nl) * 1968-07-25 1982-06-01 Montedison Spa Werkwijze voor het bereiden van gefluoreerde of gechloorfluoreerde koolwaterstoffen door middel van fluorerings- of chloorfluoreringsreacties in de gasfase.
NL173393C (nl) * 1968-10-10 1984-01-16 Montedison Spa Werkwijze voor het bereiden van volledig ge(chloor)fluoreerd ethaan met symmetrische verdeling van de fluoratomen over de koolstofatomen.
DE1910529C3 (de) * 1969-03-01 1978-09-28 Dynamit Nobel Ag, 5210 Troisdorf Verfahren zur katalytischen Hydrofluorierung von bestimmten gesattigten und ungesättigten halogenierten Kohlenwasserstoffen
GB1307224A (en) * 1969-06-27 1973-02-14 Ici Ltd Chromium oxide catalyst
SE374675B (US20110009641A1-20110113-C00116.png) * 1970-06-10 1975-03-17 Montedison Spa
US3752850A (en) * 1970-12-24 1973-08-14 Hoechst Ag Fluorination of aliphatic compounds
NL274474A (US20110009641A1-20110113-C00116.png) * 1973-09-24 1900-01-01
US4147733A (en) * 1978-05-22 1979-04-03 The Dow Chemical Company Fluorination of chlorinated hydrocarbons
DE3009760A1 (de) * 1980-03-14 1981-09-24 Hoechst Ag, 6000 Frankfurt Verfahren zur herstellung von hochreinen teilfluorierten aethanen
IT1202652B (it) * 1987-03-09 1989-02-09 Ausimont Spa Processo per la preparazione di 1,1,1-trifluoro-2,2-dicloroetano mediante idrofluorurazione in presenza di catalizzatori

Also Published As

Publication number Publication date
AR244651A1 (es) 1993-11-30
GR3004106T3 (US20110009641A1-20110113-C00116.png) 1993-03-31
ES2033432T3 (es) 1993-03-16
ATE73748T1 (de) 1992-04-15
CN1031073A (zh) 1989-02-15
AU600212B2 (en) 1990-08-02
CA1308743C (en) 1992-10-13
MX166813B (es) 1993-02-08
AU1877188A (en) 1989-01-12
RU1799375C (ru) 1993-02-28
JP2578923B2 (ja) 1997-02-05
EP0298662B2 (en) 1999-08-11
SG54092G (en) 1992-07-24
EP0298662A1 (en) 1989-01-11
DE3869242D1 (de) 1992-04-23
ZA884845B (en) 1990-03-28
HK56792A (en) 1992-08-07
EP0298662B1 (en) 1992-03-18
KR890001916A (ko) 1989-04-06
BR8803356A (pt) 1989-01-24
US4766260A (en) 1988-08-23
JPH01221338A (ja) 1989-09-04

Similar Documents

Publication Publication Date Title
CN1014404B (zh) 气相氟化方法
CN1035174C (zh) 全氯乙烯或五氯乙烷氟化法
JP2557936B2 (ja) 触媒の存在下でのフッ化水素化による１，１，１−トリフルオロ−２，２−ジクロロエタンの製法
JP2695042B2 (ja) １，１，１，２―テトラフルオロエタンの製造
CN1091651C (zh) 氟化卤代烃的催化剂
CN1059334A (zh) 增加组合物中多氟乙烷相对摩尔分数的催化平衡
EP2417086B1 (en) Process for preparing 3,3,3-trifluoropropene
CN1014988B (zh) 制备1，1，1-三氟二氯乙烷和1，1，1，2-四氟氯乙烷的改进方法
JPH05220400A (ja) クロム含有弗素化触媒、クロム含有弗素化触媒の活性の増大方法及び弗素化炭化水素の製造方法
JP6107467B2 (ja) １−クロロ−３，３，３−トリフルオロプロペンの製造方法
JPH04145033A (ja) ヘキサフルオロプロピレンの多段階合成
CN102892735A (zh) 含氯烃气相氟化中催化剂寿命的提高
CN1192995C (zh) 生产全卤环戊烯的方法
CN1405130A (zh) 1,1,1－三氟－2,2－二氯乙烷的新制备方法
CN1019107B (zh) 气相氟化方法
CN1019106B (zh) 气相氟化方法
CN1675150A (zh) 制备1,1,1,2,2－五氟乙烷的方法
CN1066441A (zh) 五氟乙烷的生产方法
CN1016777B (zh) 气相氢氟化方法
CN111875473B (zh) 一种HFC-365mfc和HFC-245fa的制备方法
CN1111606A (zh) 氟化烃的生产方法
CN1651137A (zh) 氟化催化剂及其制造方法和用途
CN1680029A (zh) 氟化反应用催化剂
JPS5821900B2 (ja) ヘキサフルオルプロパノン −２ ノセイゾウホウ
JP5397483B2 (ja) 含フッ素プロパンの製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C13 Decision
GR02 Examined patent application
C14 Grant of patent or utility model
GR01 Patent grant
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee