GB805503A - Improved fluorination catalyst and process - Google Patents
Improved fluorination catalyst and processInfo
- Publication number
- GB805503A GB805503A GB818956A GB818956A GB805503A GB 805503 A GB805503 A GB 805503A GB 818956 A GB818956 A GB 818956A GB 818956 A GB818956 A GB 818956A GB 805503 A GB805503 A GB 805503A
- Authority
- GB
- United Kingdom
- Prior art keywords
- catalyst
- alumina
- dry
- cbrf3
- halogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
Abstract
A catalyst for the fluorination of halogen-substituted hydrocarbons, contains basic aluminium fluoride, and is formed by impregnating porous alumina with an aqueous solution of a halide of Cr, Co, Ni or Pd and treating the wet alumina with anhydrous hydrofluoric acid until it is dry. In examples, a porous alumina, e.g. chi, gamma, alpha or kappa alumina made by controlled calcination of aluminium hydrate, or calcined aluminium tri-hydrate obtained from bauxite, is impregnated with 6N solution of hydrochloric acid containing NiCl2. After standing, the mixture is filtered and the wet impregnated alumina is treated with dry HF for several hours, until the alumina is dry. Mild heating is applied in the later stage of drying. The dry catalyst may be further treated with HF while heating at 150 DEG to 500 DEG C. The product contains unchanged alumina, aluminium fluoride and basic aluminium fluoride in addition to from 0.1 to 10 per cent of nickel which may be chemically combined with the aluminium fluoride. Nickel chloride may be replaced by nickel fluoride, cobalt chloride, chromium hydroxide dissolved in HF, or palladium chloride dissolved in HF. After use, the catalyst may be regenerated by treating at 400 DEG C. with oxygen or air pre-heated to 300 DEG C. The carbon-free catalyst is then treated with anhydrous HF at about 400 DEG C. The halo-alkane, which preferably contains 1 to 4 C atoms, and is free from iodine, is passed as vapour in admixture with HF over the catalyst at about 300 DEG C. The gaseous products are fractionated, washed with alkali, water, and dried, (see Group IV (b)). U.S.A. Specifications 2,005,707, 2,110,369, 2,458,551, 2,531,372 and 2,553,518 are referred to.ALSO:Halogen-substituted alkanes are fluorinated by passing vapours of them together with at least an equimolecular proportion of HF over a catalyst containing basic aluminium fluoride, and made by impregnating porous alumina with an aqueous solution of a halide of Cr, Co, Ni or Pd and treating with anhydrous HF until it is dry. The starting material preferably contains 1 to 4 C atoms and the halogen substituents may be F, Cl or Br, but not I. Compounds specified include halogenated methanes containing at least two halogen atoms which may be the same or different and halogenated ethanes, propanes and butanes containing at least two halogen atoms attached to the same carbon atom. For example, CBr4 vapour admixed with an equimolecular amount of HF is passed over the catalyst at a temperature of 150 DEG to 500 DEG C., and preferably about 300 DEG C. The gaseous reaction products are cooled and fractionated, and the main product consisting of CBrF3 is washed with alkali, water and dried. Other examples describe the conversion of CBr4 to CBr2F2 with lesser amounts of CBrF3, CHBr2F, CBr3F and CHBr3, of CH2Br2 to CH2F2 and some CH2BrF, of CH2Cl2 to CH2F2 and some CH2ClF, of Cl3CH3 to CH3CF3 and some CH3CClF2 and CH2=CClF, of CCl3CCl3 to CClF2CClF2 CClF2 CCl2F and some CF3CClF2 and CCl2FCCl2F, of CCL- to CClF3, CCl2F2, CCl3F and CF- (different proportions of these products being obtained with different catalysts and under different reaction conditions), of CBr2F2 to CBrF3 and some CHF3 and CHBrF2, and of CBr4 to CBrF3 and some CF4, CBr2F2, CHF3, CHBr2F and CBr3F (the proportions varying as above). U.S.A. Specifications 2,005,707, 2,110,369, 2,458,551, 2,531,372 and 2,553,518 are referred to.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB818956A GB805503A (en) | 1956-03-15 | 1956-03-15 | Improved fluorination catalyst and process |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB818956A GB805503A (en) | 1956-03-15 | 1956-03-15 | Improved fluorination catalyst and process |
Publications (1)
Publication Number | Publication Date |
---|---|
GB805503A true GB805503A (en) | 1958-12-10 |
Family
ID=9847552
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB818956A Expired GB805503A (en) | 1956-03-15 | 1956-03-15 | Improved fluorination catalyst and process |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB805503A (en) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3187060A (en) * | 1962-03-20 | 1965-06-01 | Pechiney Saint Gobain | Process for hydrofluorination of acetylenic hydrocarbons |
US4766259A (en) * | 1987-08-13 | 1988-08-23 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process |
US4766260A (en) * | 1987-07-07 | 1988-08-23 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process |
US5319147A (en) * | 1991-12-23 | 1994-06-07 | Ausimont S.P.A. | Process for the neutralization of perfluoropolyoxyalkylenes |
WO2012098422A1 (en) * | 2011-01-21 | 2012-07-26 | Akrema France | Catalytic gas phase fluorination |
CN112672821A (en) * | 2018-09-27 | 2021-04-16 | 切弗朗菲利浦化学公司 | Method for producing fluorinated solid oxides and use thereof in metallocene-based catalyst systems |
WO2022244481A1 (en) * | 2021-05-20 | 2022-11-24 | 昭和電工株式会社 | Method for producing bromofluoromethane |
-
1956
- 1956-03-15 GB GB818956A patent/GB805503A/en not_active Expired
Cited By (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3187060A (en) * | 1962-03-20 | 1965-06-01 | Pechiney Saint Gobain | Process for hydrofluorination of acetylenic hydrocarbons |
US4766260A (en) * | 1987-07-07 | 1988-08-23 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process |
US4766259A (en) * | 1987-08-13 | 1988-08-23 | E. I. Du Pont De Nemours And Company | Gas-phase fluorination process |
US5319147A (en) * | 1991-12-23 | 1994-06-07 | Ausimont S.P.A. | Process for the neutralization of perfluoropolyoxyalkylenes |
JP2014511351A (en) * | 2011-01-21 | 2014-05-15 | アルケマ フランス | Gas phase catalytic fluorination |
CN103313960A (en) * | 2011-01-21 | 2013-09-18 | 阿克马法国公司 | Catalytic gas phase fluorination |
WO2012098422A1 (en) * | 2011-01-21 | 2012-07-26 | Akrema France | Catalytic gas phase fluorination |
US9302961B2 (en) | 2011-01-21 | 2016-04-05 | Arkema France | Catalytic gas phase fluorination |
CN103313960B (en) * | 2011-01-21 | 2016-06-08 | 阿克马法国公司 | Catalyzed gas fluoride |
US9758449B2 (en) | 2011-01-21 | 2017-09-12 | Arkema France | Catalytic gas phase fluorination |
US9969663B2 (en) | 2011-01-21 | 2018-05-15 | Arkema France | Catalytic gas phase fluorination |
CN112672821A (en) * | 2018-09-27 | 2021-04-16 | 切弗朗菲利浦化学公司 | Method for producing fluorinated solid oxides and use thereof in metallocene-based catalyst systems |
CN112672821B (en) * | 2018-09-27 | 2023-11-07 | 切弗朗菲利浦化学公司 | Method for producing fluorinated solid oxides and use thereof in metallocene-based catalyst systems |
WO2022244481A1 (en) * | 2021-05-20 | 2022-11-24 | 昭和電工株式会社 | Method for producing bromofluoromethane |
TWI816355B (en) * | 2021-05-20 | 2023-09-21 | 日商力森諾科股份有限公司 | Manufacturing method of bromofluoromethane |
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