CN1035174C - 全氯乙烯或五氯乙烷氟化法 - Google Patents
全氯乙烯或五氯乙烷氟化法 Download PDFInfo
- Publication number
- CN1035174C CN1035174C CN94101166A CN94101166A CN1035174C CN 1035174 C CN1035174 C CN 1035174C CN 94101166 A CN94101166 A CN 94101166A CN 94101166 A CN94101166 A CN 94101166A CN 1035174 C CN1035174 C CN 1035174C
- Authority
- CN
- China
- Prior art keywords
- catalyzer
- nickel
- chromium
- fluorination
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/202—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction
- C07C17/206—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms two or more compounds being involved in the reaction the other compound being HX
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/125—Halogens; Compounds thereof with scandium, yttrium, aluminium, gallium, indium or thallium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/128—Halogens; Compounds thereof with iron group metals or platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/132—Halogens; Compounds thereof with chromium, molybdenum, tungsten or polonium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C17/00—Preparation of halogenated hydrocarbons
- C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
- C07C17/20—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms
- C07C17/21—Preparation of halogenated hydrocarbons by replacement by halogens of halogen atoms by other halogen atoms with simultaneous increase of the number of halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C19/00—Acyclic saturated compounds containing halogen atoms
- C07C19/08—Acyclic saturated compounds containing halogen atoms containing fluorine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/125—Compounds comprising a halogen and scandium, yttrium, aluminium, gallium, indium or thallium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/128—Compounds comprising a halogen and an iron group metal or a platinum group metal
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- C07C2527/06—Halogens; Compounds thereof
- C07C2527/132—Compounds comprising a halogen and chromium, molybdenum, tungsten or polonium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Description
实验号 | 11 | 12 |
操作条件:—温度(℃)—摩尔比HF/C2Cl4—接触时间(秒)—催化剂寿命(小时) | 3506.815.924 | 3007.016.748 |
结果:—C2Cl4总转化率(%)—选择性(摩尔百分比)F125F124F124aF123F123aF122F121F133aF115F114+F114aF1111 | 96.023.432.90.438.90.20.201.31.00.70.7 | 98.31.927.10.668.70.20.400.30.10.30.3 |
实验号 | 21 | 22 | 23 | 24 | ||
操作条件:—温度(℃)—摩尔比HF/C2Cl4—接触时间(秒)—催化剂寿命(小时) | 3507.41544 | 3507.215.5556 | 3307.216.5315 | 3007.316.8453 | ||
结果 :—C2Cl4总转化率(%)—选择性(摩尔百分比)F125F124F124aF123F123aF122F121F133aF115F114+F114aF1111 | 95.63228.40.433.30.20.2微量1.61.31.21.0 | 94.634.124.20.333.10.30.302.51.42.21.4 | 9525.531.30.339.30.20.300.90.40.80.9 | 94.18.333.50.654.60.40.600.50.0050.50.9 |
实施例 | 3 | 4 | 5 | |||
操作条件:—催化剂—温度(℃)—摩尔比HF/C2Cl4—接触时间(秒)—催化剂寿命(小时) | C3506.815.943 | D3507.314.948 | D3007.514.0291 | D3007.214.7434 | E3506.915.624 | E3208.316.948 |
结果—选择性(摩尔百分比)—C2Cl4总转化率(%)F125F124F124aF123F123aF122F121F133aF115F114+F114aF1111 | 60.5323.60.651.41.42.900.7微量0.714.4 | 95.444.213.30.319.10.10.107.29.91.91 | 89.81733.51.139.30.70.802.30.52.41.7 | 68.95.829.92.12.24.13.302.40.22.76.7 | 50.22.55.827.12.91.7微量21.13.93 510.9 | 35.71.34.51.411.34.74.60.11727.418 |
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9300779 | 1993-01-27 | ||
FR9300779A FR2700766B1 (fr) | 1993-01-27 | 1993-01-27 | Procédé de fluoration de perchloréthylène ou du pentachloréthane. |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1101338A CN1101338A (zh) | 1995-04-12 |
CN1035174C true CN1035174C (zh) | 1997-06-18 |
Family
ID=9443385
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN94101166A Expired - Lifetime CN1035174C (zh) | 1993-01-27 | 1994-01-27 | 全氯乙烯或五氯乙烷氟化法 |
Country Status (13)
Country | Link |
---|---|
US (1) | US5932776A (zh) |
EP (1) | EP0609123B1 (zh) |
JP (1) | JP2510127B2 (zh) |
KR (1) | KR960009678B1 (zh) |
CN (1) | CN1035174C (zh) |
AU (1) | AU663818B2 (zh) |
BR (1) | BR9400337A (zh) |
CA (1) | CA2113510C (zh) |
DE (1) | DE69400034T2 (zh) |
ES (1) | ES2081225T3 (zh) |
FR (1) | FR2700766B1 (zh) |
GR (1) | GR3019016T3 (zh) |
TW (1) | TW277054B (zh) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2700770B1 (fr) * | 1993-01-27 | 1995-03-24 | Atochem Elf Sa | Procédé de fabrication du 1,1,1,2-tétrafluoro-2-chloroéthane et du pentafluoroéthane. |
US5561095A (en) * | 1994-03-31 | 1996-10-01 | Exxon Chemical Patents Inc. | Supported lewis acid catalysts for hydrocarbon conversion reactions |
ES2130606T3 (es) * | 1994-03-31 | 1999-07-01 | Exxon Chemical Patents Inc | Catalizadores de acido de lewis soportados para reacciones de conversion de hidrocarburos. |
US5545778A (en) * | 1994-05-25 | 1996-08-13 | Alliedsignal Inc. | Single stage process for producing hydrofluorocarbons from perchloroethylene |
DE19510024C2 (de) * | 1995-03-20 | 1997-02-06 | Hoechst Ag | Verfahren zur Herstellung von Pentafluorethan (R 125) |
JP3853397B2 (ja) * | 1995-05-11 | 2006-12-06 | イネオス フラウアー ホールデイングス リミテッド | ペンタフルオロエタンの製造方法及びペンタフルオロエタンに転化するのに適当な組成物 |
US5981813A (en) * | 1996-05-22 | 1999-11-09 | Ausimont S.P.A. | Fluorination process of halogenated organic compounds |
FR2771027B1 (fr) * | 1997-11-20 | 2000-01-14 | Atochem Elf Sa | Catalyseur mixte de fluoration |
JP3520900B2 (ja) * | 1997-12-12 | 2004-04-19 | ダイキン工業株式会社 | ペンタフルオロエタンの製造方法、並びにフッ素化用触媒及びその製造方法 |
US6368997B2 (en) * | 1998-05-22 | 2002-04-09 | Conoco Inc. | Fischer-Tropsch processes and catalysts using fluorided supports |
FR2807752A1 (fr) * | 2000-04-12 | 2001-10-19 | Solvay | Procede pour la preparation d'un hydrochlorofluoroalcane et catalyseur |
FR2807751B1 (fr) | 2000-04-12 | 2005-05-20 | Solvay | Procede pour la preparation d'un hydro (chloro) fluoroalcane et catalyseur |
ES2216736T1 (es) * | 2001-06-28 | 2004-11-01 | Honeywell International Inc. | Proceso para preparar un catalizador en la fluoracion. |
EP1502906A1 (en) * | 2003-07-31 | 2005-02-02 | Solvay Solexis S.p.A. | Process for activation of AIF3 based catalysts and process for isomerising hydrochlorofluorocarbons |
CN100338001C (zh) * | 2004-11-17 | 2007-09-19 | 浙江莹光化工有限公司 | 一种同时制备1,1,1,2-四氟乙烷和五氟乙烷的方法 |
FR2894250B1 (fr) * | 2005-12-06 | 2008-01-18 | Arkema Sa | Procede de fabrication du pentafluoroethane |
GB0525700D0 (en) | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
GB0525701D0 (en) | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
GB0525699D0 (en) | 2005-12-17 | 2006-01-25 | Ineos Fluor Holdings Ltd | Process |
FR2902780B1 (fr) * | 2006-06-21 | 2008-09-05 | Arkema France | Procede de recuperation de l'acide fluorhydrique |
FR2902788B1 (fr) * | 2006-06-21 | 2008-09-05 | Arkema France | Procede de fabrication du pentafluoroethane |
FR2907449B1 (fr) * | 2006-10-20 | 2009-01-02 | Arkema France | Procede de fabrication du pentafluorethane. |
JP5146466B2 (ja) * | 2007-12-14 | 2013-02-20 | ダイキン工業株式会社 | ペンタフルオロエタンの製造方法 |
DK2766117T3 (en) * | 2011-10-12 | 2018-06-25 | Bayer Ip Gmbh | CATALYTIC GAS PHASE FLUORATION OF 1,1,2-TRICHLORETHANE AND / OR 1,2-DICHLORETHANE TO PREPARE 1-CHLOR-2,2-DIFLUORETHANE |
CN103041819B (zh) * | 2013-01-17 | 2014-07-30 | 金华氟特催化科技有限公司 | 一种用于氟化反应的催化剂及其制备方法 |
CN104001534B (zh) * | 2013-02-21 | 2017-07-07 | 江苏理文化工有限公司 | 一种五氯乙烷催化脱HCl制四氯乙烯的催化剂及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0298662A1 (en) * | 1987-07-07 | 1989-01-11 | E.I. Du Pont De Nemours And Company | Gas-phase fluorination process |
EP0328127A1 (en) * | 1988-02-12 | 1989-08-16 | E.I. Du Pont De Nemours And Company | Gas-phase fluorination process |
EP0486333A1 (fr) * | 1990-11-13 | 1992-05-20 | Elf Atochem S.A. | Procédé de fabrication du tétrafluoro-1,1,1,2-éthane |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2435551A (en) * | 1944-04-20 | 1948-02-03 | Standard Oil Dev Co | Production of hydrocarbons from carbon monoxide and hydrogen |
US2900423A (en) * | 1957-12-13 | 1959-08-18 | Allied Chem | Manufacture of perfluoropropene |
NO125478B (zh) * | 1968-07-25 | 1972-09-18 | Montedison Spa | |
DK138673B (da) * | 1968-10-10 | 1978-10-16 | Montedison Spa | Katalysator til fremstilling af chlorfluorerede ethaner. |
US3661805A (en) * | 1969-11-21 | 1972-05-09 | Universal Oil Prod Co | Method of manufacturing an extruded catalyst composition |
NL171235C (nl) * | 1970-06-10 | 1983-03-01 | Montedison Spa | Werkwijze voor het bereiden van katalysatoren die in hoofdzaak uit aluminiumfluoride bestaan en werkwijze voor het bereiden van gefluoreerde of gechloorfluoreerde koolwaterstoffen met behulp van een dergelijke katalysator. |
FR2135473B1 (zh) * | 1971-05-06 | 1973-05-11 | Rhone Progil | |
US4131616A (en) * | 1974-06-24 | 1978-12-26 | E. I. Du Pont De Nemours And Company | Methanation catalyst |
FR2407021A1 (fr) * | 1977-10-26 | 1979-05-25 | Anvar | Nouveaux derives metalliques, leur preparation et leur application en tant que catalyseurs, en particulier pour la fabrication de nitriles par ammoxydation d'alcanes a l'aide de monoxyde d'azote |
FR2501062A1 (fr) * | 1980-12-29 | 1982-09-10 | Ugine Kuhlmann | Catalyseurs de fluoruration en phase gazeuse de derives chlores aliphatiques, a base de microbilles d'oxyde de chrome, et procedes de fluoruration utilisant ces catalyseurs |
EP0128510A3 (en) * | 1983-06-07 | 1985-05-15 | Showa Denko Kabushiki Kaisha | Process for producing difluoromethane |
DE3415055A1 (de) * | 1984-04-21 | 1985-10-24 | Berkenhoff GmbH, 6301 Heuchelheim | Schnellschneide-elektrode zur schneiderosionsbearbeitung |
US4912270A (en) * | 1987-03-13 | 1990-03-27 | Allied-Signal Inc. | Chromia aerogel, method of producing same and fluorination process utilizing same |
IN171977B (zh) * | 1988-06-29 | 1993-02-27 | Du Pont | |
JP2764980B2 (ja) * | 1988-12-28 | 1998-06-11 | 旭硝子株式会社 | パークロロエチレンのフッ素化方法 |
IT1251957B (it) * | 1991-10-18 | 1995-05-27 | Ausimont Spa | Procedimento per isomerizzare 1,1,2-trifluoro-1,2-dicloroetano a 1,1,1- trifluoro-2,2,-dicloroetano |
FR2700770B1 (fr) * | 1993-01-27 | 1995-03-24 | Atochem Elf Sa | Procédé de fabrication du 1,1,1,2-tétrafluoro-2-chloroéthane et du pentafluoroéthane. |
-
1993
- 1993-01-27 FR FR9300779A patent/FR2700766B1/fr not_active Expired - Fee Related
-
1994
- 1994-01-14 CA CA002113510A patent/CA2113510C/fr not_active Expired - Fee Related
- 1994-01-21 TW TW083100517A patent/TW277054B/zh not_active IP Right Cessation
- 1994-01-24 DE DE69400034T patent/DE69400034T2/de not_active Expired - Lifetime
- 1994-01-24 ES ES94400139T patent/ES2081225T3/es not_active Expired - Lifetime
- 1994-01-24 EP EP94400139A patent/EP0609123B1/fr not_active Expired - Lifetime
- 1994-01-24 AU AU53970/94A patent/AU663818B2/en not_active Ceased
- 1994-01-26 KR KR94001392A patent/KR960009678B1/ko not_active IP Right Cessation
- 1994-01-26 BR BR9400337A patent/BR9400337A/pt not_active IP Right Cessation
- 1994-01-27 CN CN94101166A patent/CN1035174C/zh not_active Expired - Lifetime
- 1994-01-27 JP JP6007543A patent/JP2510127B2/ja not_active Expired - Fee Related
-
1996
- 1996-02-20 GR GR960400417T patent/GR3019016T3/el unknown
- 1996-11-06 US US08/999,882 patent/US5932776A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0298662A1 (en) * | 1987-07-07 | 1989-01-11 | E.I. Du Pont De Nemours And Company | Gas-phase fluorination process |
EP0328127A1 (en) * | 1988-02-12 | 1989-08-16 | E.I. Du Pont De Nemours And Company | Gas-phase fluorination process |
EP0486333A1 (fr) * | 1990-11-13 | 1992-05-20 | Elf Atochem S.A. | Procédé de fabrication du tétrafluoro-1,1,1,2-éthane |
Also Published As
Publication number | Publication date |
---|---|
US5932776A (en) | 1999-08-03 |
DE69400034D1 (de) | 1996-01-18 |
KR960009678B1 (en) | 1996-07-23 |
GR3019016T3 (en) | 1996-05-31 |
JP2510127B2 (ja) | 1996-06-26 |
CA2113510C (fr) | 1999-01-12 |
ES2081225T3 (es) | 1996-02-16 |
CN1101338A (zh) | 1995-04-12 |
CA2113510A1 (fr) | 1994-07-28 |
FR2700766A1 (fr) | 1994-07-29 |
DE69400034T2 (de) | 1996-06-27 |
AU5397094A (en) | 1994-08-18 |
TW277054B (zh) | 1996-06-01 |
KR940018340A (ko) | 1994-08-16 |
JPH06247884A (ja) | 1994-09-06 |
FR2700766B1 (fr) | 1995-03-24 |
BR9400337A (pt) | 1994-08-16 |
EP0609123A1 (fr) | 1994-08-03 |
EP0609123B1 (fr) | 1995-12-06 |
AU663818B2 (en) | 1995-10-19 |
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Owner name: ATOFINA Free format text: FORMER NAME OR ADDRESS: ATUOFEINA CORP. Owner name: ATUOFEINA CORP. Free format text: FORMER NAME OR ADDRESS: ELF ATOCHEM S. A. Owner name: ARKEMA FRANCE CO., LTD. Free format text: FORMER NAME OR ADDRESS: ATOFINA |
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Address after: French Cologne Patentee after: ARKEMA FRANCE Address before: French pitot Patentee before: ARKEMA Address after: French pitot Patentee after: ARKEMA Address before: French Maputo Patentee before: ATOFINA Address after: French Maputo Patentee after: ATOFINA Address before: French Maputo Patentee before: Elf Atochem S.A. |
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Expiration termination date: 20140127 Granted publication date: 19970618 |