CN101421032B - 用于生产金属颗粒的方法,由其制备的金属颗粒及其用途 - Google Patents
用于生产金属颗粒的方法,由其制备的金属颗粒及其用途 Download PDFInfo
- Publication number
- CN101421032B CN101421032B CN2007800135647A CN200780013564A CN101421032B CN 101421032 B CN101421032 B CN 101421032B CN 2007800135647 A CN2007800135647 A CN 2007800135647A CN 200780013564 A CN200780013564 A CN 200780013564A CN 101421032 B CN101421032 B CN 101421032B
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- metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J14/00—Chemical processes in general for reacting liquids with liquids; Apparatus specially adapted therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/0004—Preparation of sols
- B01J13/0043—Preparation of sols containing elemental metal
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G55/00—Compounds of ruthenium, rhodium, palladium, osmium, iridium, or platinum
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/52—Electrically conductive inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
- Colloid Chemistry (AREA)
- Non-Insulated Conductors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006017696.0 | 2006-04-15 | ||
| DE102006017696A DE102006017696A1 (de) | 2006-04-15 | 2006-04-15 | Verfahren zur Herstellung von Metallpartikeln, hieraus hergestellte Metallpartikel und deren Verwendung |
| PCT/EP2007/003258 WO2007118669A1 (de) | 2006-04-15 | 2007-04-12 | Verfahren zur herstellung von metallpartikeln, hieraus hergestellte metallpartikel und deren verwendung |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101421032A CN101421032A (zh) | 2009-04-29 |
| CN101421032B true CN101421032B (zh) | 2013-04-24 |
Family
ID=38222224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007800135647A Active CN101421032B (zh) | 2006-04-15 | 2007-04-12 | 用于生产金属颗粒的方法,由其制备的金属颗粒及其用途 |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US8133932B2 (enExample) |
| EP (1) | EP2010314A1 (enExample) |
| JP (1) | JP5427602B2 (enExample) |
| KR (1) | KR101085653B1 (enExample) |
| CN (1) | CN101421032B (enExample) |
| CA (1) | CA2649005C (enExample) |
| DE (1) | DE102006017696A1 (enExample) |
| WO (1) | WO2007118669A1 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009006318A1 (en) | 2007-06-29 | 2009-01-08 | Artificial Muscle, Inc. | Electroactive polymer transducers for sensory feedback applications |
| GB0724870D0 (en) * | 2007-12-21 | 2008-01-30 | Univ Lincoln The | Preparation of metal colloids |
| JP2011517728A (ja) * | 2008-03-19 | 2011-06-16 | ビーエーエスエフ ソシエタス・ヨーロピア | 誘導体化されたポリエチレンイミン又はポリビニルアミンで安定化された金属ナノ粒子 |
| EP2108386A1 (de) | 2008-04-08 | 2009-10-14 | Bayer MaterialScience AG | Medizinische Geräte mit einer antimikrobiellen Polyurethanharnstoffbeschichtung |
| EP2108383A1 (de) | 2008-04-08 | 2009-10-14 | Bayer MaterialScience AG | Medizinische Geräte mit einer antibakteriellen Polyurethanharnstoffbeschichtung |
| EP2108382A1 (de) | 2008-04-08 | 2009-10-14 | Bayer MaterialScience AG | Silberhaltige Polyurethanharnstofflösung |
| EP2108387A1 (de) | 2008-04-08 | 2009-10-14 | Bayer MaterialScience AG | Wässrige silberhaltige nichtionische Polyurethandispersionen |
| DE102008023882A1 (de) | 2008-05-16 | 2009-11-19 | Bayer Materialscience Ag | Druckbare Zusammensetzung auf Basis von Silberpartikeln zur Erzeugung elektrisch leitfähiger Beschichtungen |
| US10370789B2 (en) * | 2008-06-30 | 2019-08-06 | Bar Ilan University | Sonochemical coating of textiles with metal oxide nanoparticles for antimicrobial fabrics |
| EP2239793A1 (de) | 2009-04-11 | 2010-10-13 | Bayer MaterialScience AG | Elektrisch schaltbarer Polymerfilmaufbau und dessen Verwendung |
| KR100936281B1 (ko) | 2009-08-25 | 2010-01-13 | 한국지질자원연구원 | ZnO 나노입자의 제조방법 및 이를 이용한 ZnO 나노유체의 제조방법 |
| JP5537873B2 (ja) * | 2009-09-02 | 2014-07-02 | 国立大学法人北海道大学 | 銅微粒子の製造方法 |
| JP5368925B2 (ja) * | 2009-09-25 | 2013-12-18 | 三菱製紙株式会社 | 銀超微粒子の製造方法 |
| US20110256383A1 (en) * | 2010-04-01 | 2011-10-20 | Bayer Materialscience Ag | Polymer material comprising a polymer and silver nanoparticles dispersed herein |
| US7935173B1 (en) | 2010-07-23 | 2011-05-03 | Metals Recovery Technology Inc. | Process for recovery of precious metals |
| WO2012035005A1 (en) | 2010-09-14 | 2012-03-22 | Bayer Technology Services Gmbh | Multistage surface modification procedure of semiconducting nanoparticles for use in hybrid solar cells and printable electronics |
| EP2444148A1 (de) | 2010-10-25 | 2012-04-25 | Bayer Material Science AG | Metallpartikelsol mit dotierten Silbernanopartikeln |
| GB2486190A (en) * | 2010-12-06 | 2012-06-13 | P V Nano Cell Ltd | Concentrated dispersion of nanometric silver particles |
| ES2453217T3 (es) | 2010-12-21 | 2014-04-04 | Agfa-Gevaert | Dispersión que contiene nanopartículas metálicas, de óxido de metal o de precursor de metal |
| JP2014513510A (ja) | 2011-03-01 | 2014-05-29 | バイエル・インテレクチュアル・プロパティ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング | 変形可能なポリマー装置及び変形可能なポリマーフィルムを作るための自動化された製造プロセス |
| US9195058B2 (en) | 2011-03-22 | 2015-11-24 | Parker-Hannifin Corporation | Electroactive polymer actuator lenticular system |
| US9714472B2 (en) | 2011-09-23 | 2017-07-25 | Covestro Deutschland Ag | Gas diffusion electrodes and process for production thereof |
| JP5900846B2 (ja) * | 2011-11-18 | 2016-04-06 | 国立研究開発法人産業技術総合研究所 | ナノインク塗布装置 |
| CN102515560B (zh) * | 2011-12-13 | 2014-05-28 | 江苏大学 | 一种制备石墨烯/Ag复合导电薄膜的方法 |
| CN102513544B (zh) * | 2011-12-13 | 2014-04-09 | 江苏大学 | 一种制备纳米银溶胶的方法 |
| ES2496440T3 (es) | 2011-12-21 | 2014-09-19 | Agfa-Gevaert | Dispersión que contiene nanopartículas metálicas, de óxido de metal o de precursor de metal, un dispersante polimérico y un agente térmicamente escindible |
| EP2608217B1 (en) | 2011-12-21 | 2014-07-16 | Agfa-Gevaert | A dispersion comprising metallic, metal oxide or metal precursor nanoparticles, a polymeric dispersant and a sintering additive |
| CN102554256A (zh) * | 2011-12-30 | 2012-07-11 | 宁波大学 | 一种钴纳米颗粒的制备方法 |
| EP2610365B1 (en) * | 2011-12-31 | 2020-02-26 | Rohm and Haas Electronic Materials LLC | Electroless plating method |
| EP2610366A3 (en) * | 2011-12-31 | 2014-07-30 | Rohm and Haas Electronic Materials LLC | Plating catalyst and method |
| WO2013142552A1 (en) | 2012-03-21 | 2013-09-26 | Bayer Materialscience Ag | Roll-to-roll manufacturing processes for producing self-healing electroactive polymer devices |
| EP2671927B1 (en) | 2012-06-05 | 2021-06-02 | Agfa-Gevaert Nv | A metallic nanoparticle dispersion |
| US9761790B2 (en) | 2012-06-18 | 2017-09-12 | Parker-Hannifin Corporation | Stretch frame for stretching process |
| US9590193B2 (en) | 2012-10-24 | 2017-03-07 | Parker-Hannifin Corporation | Polymer diode |
| US10184025B2 (en) * | 2013-01-25 | 2019-01-22 | Imra America, Inc. | Methods for preparing aqueous suspension of precious metal nanoparticles |
| EP2781562B1 (en) | 2013-03-20 | 2016-01-20 | Agfa-Gevaert | A method to prepare a metallic nanoparticle dispersion |
| KR20170119747A (ko) | 2013-07-04 | 2017-10-27 | 아그파-게바에르트 엔.브이. | 전도성 금속 층 또는 패턴의 제조 방법 |
| EP2821164A1 (en) | 2013-07-04 | 2015-01-07 | Agfa-Gevaert | A metallic nanoparticle dispersion |
| WO2015000937A1 (en) | 2013-07-04 | 2015-01-08 | Agfa-Gevaert | A metallic nanoparticle dispersion |
| CN103341641A (zh) * | 2013-07-24 | 2013-10-09 | 厦门大学 | CoSb3热电纳米粉体材料的制备方法 |
| DE102013108664A1 (de) | 2013-08-09 | 2015-02-12 | Leibniz-Institut Für Neue Materialien Gemeinnützige Gmbh | Oberflächenmodifizierte Metallkolloide und ihre Herstellung |
| EP2835402B1 (en) | 2013-08-09 | 2020-07-08 | Leibniz-Institut für Neue Materialien gemeinnützige GmbH | Formation of surface modified metal colloids |
| CN103752846A (zh) * | 2014-01-17 | 2014-04-30 | 昆明理工大学 | 一种微通道连续快速制备纳米铜的方法 |
| US9622483B2 (en) | 2014-02-19 | 2017-04-18 | Corning Incorporated | Antimicrobial glass compositions, glasses and polymeric articles incorporating the same |
| US11039621B2 (en) | 2014-02-19 | 2021-06-22 | Corning Incorporated | Antimicrobial glass compositions, glasses and polymeric articles incorporating the same |
| US11039620B2 (en) | 2014-02-19 | 2021-06-22 | Corning Incorporated | Antimicrobial glass compositions, glasses and polymeric articles incorporating the same |
| JP2014129609A (ja) * | 2014-03-07 | 2014-07-10 | Hokkaido Univ | 銅微粒子の製造方法 |
| CN104028745A (zh) * | 2014-06-11 | 2014-09-10 | 浙江大学 | 一种利用丝素蛋白调控金纳米颗粒自组装的方法 |
| KR20160053352A (ko) | 2014-11-03 | 2016-05-13 | 경희대학교 산학협력단 | 다기능성 고분자와 환원제를 이용한 금속나노입자의 제조방법 |
| EP3037161B1 (en) | 2014-12-22 | 2021-05-26 | Agfa-Gevaert Nv | A metallic nanoparticle dispersion |
| US9557648B2 (en) | 2015-03-18 | 2017-01-31 | Eastman Kodak Company | Articles with silver-containing polymeric complexes |
| US10745570B2 (en) | 2015-05-18 | 2020-08-18 | Eastman Rodack Company | Copper-containing articles |
| US9963614B2 (en) | 2015-05-18 | 2018-05-08 | Eastman Kodak Company | Copper-containing articles and methods for providing same |
| EP3099146B1 (en) | 2015-05-27 | 2020-11-04 | Agfa-Gevaert | Method of preparing a silver layer or pattern comprising a step of applying a silver nanoparticle dispersion |
| EP3099145B1 (en) | 2015-05-27 | 2020-11-18 | Agfa-Gevaert | Method of preparing a silver layer or pattern comprising a step of applying a silver nanoparticle dispersion |
| JP6074777B2 (ja) * | 2015-07-06 | 2017-02-08 | 国立研究開発法人産業技術総合研究所 | ナノインク塗布装置 |
| US9676950B2 (en) | 2015-09-17 | 2017-06-13 | Eastman Kodak Company | Articles prepared using ink jettable, UV-curable compositions |
| US9731513B2 (en) | 2015-09-17 | 2017-08-15 | Eastman Kodak Company | Methods for using ink jettable, UV-curable compositions |
| US10040957B2 (en) | 2015-09-17 | 2018-08-07 | Eastman Kodak Company | Ink jettable, UV-curable compositions |
| US10116000B1 (en) * | 2015-10-20 | 2018-10-30 | New Jersey Institute Of Technology | Fabrication of flexible conductive items and batteries using modified inks |
| WO2017071949A1 (de) | 2015-10-30 | 2017-05-04 | Clariant International Ltd | Metalldispersion mit erhöhter stabilität |
| CZ306931B6 (cs) * | 2016-04-22 | 2017-09-20 | Univerzita Tomáše Bati ve Zlíně | Způsob syntézy nanokompozitu obsahujícího magnetické nanočástice na bázi oxidu železitého a polyelektrolyt tvořený ligninsulfonovou kyselinou nebo jejími solemi |
| EP3287499B1 (en) | 2016-08-26 | 2021-04-07 | Agfa-Gevaert Nv | A metallic nanoparticle dispersion |
| US9975110B1 (en) | 2016-11-23 | 2018-05-22 | Honda Motor Co., Ltd. | Method for producing metal catalyst nanoparticles |
| EP3385342B1 (en) * | 2017-04-03 | 2020-03-25 | Nano and Advanced Materials Institute Limited | Water-based conductive ink for rapid prototype in writable electronics |
| CN107880866B (zh) * | 2017-05-23 | 2021-03-23 | 西南石油大学 | 一种稠油原位催化改质金属纳米晶降粘剂及其制备方法 |
| DE102017121595A1 (de) * | 2017-09-18 | 2019-03-21 | Aktiengesellschaft der Dillinger Hüttenwerke | Verfahren zur Analyse von Partikeln in Stahl, insbesondere von Ausscheidungen oder/und Einschlüssen |
| CN107745133B (zh) * | 2017-10-07 | 2020-05-29 | 江西省科学院能源研究所 | 一种纳米铜的低成本绿色制备方法 |
| CN108529693A (zh) * | 2018-04-03 | 2018-09-14 | 岭南师范学院 | 一种肽功能化纳米钯及其制备方法 |
| CN108500292B (zh) * | 2018-04-08 | 2021-03-23 | 合肥学院 | 一种链状金属镍纳米粉体的制备方法 |
| US20210253887A1 (en) | 2018-05-08 | 2021-08-19 | Agfa-Gevaert Nv | Conductive inks |
| CN109202096B (zh) * | 2018-09-27 | 2021-09-10 | 安徽建筑大学 | 一种零价铁陶粒及其制备方法 |
| CN111889136B (zh) * | 2019-05-05 | 2022-02-01 | 中国科学院青岛生物能源与过程研究所 | 一种制备负载有第一元金属和第二元金属的催化剂载体的方法 |
| EP4066968A4 (en) * | 2019-11-28 | 2023-08-02 | M. Technique Co., Ltd. | PROCESS FOR PRODUCTION OF FINE SILVER PARTICLES |
| CN114425444B (zh) * | 2020-10-14 | 2024-01-26 | 中国石油化工股份有限公司 | 乙烯法合成醋酸乙烯催化剂及其制备方法 |
| CN111922359B (zh) * | 2020-10-19 | 2021-01-05 | 西安宏星电子浆料科技股份有限公司 | 一种纯净银纳米线的制备方法 |
| DE102020134302A1 (de) | 2020-12-18 | 2022-06-23 | IRCCS Ospedale Specializzato in Gastroenterologia "Saverio de Bellis" | Molekularer Sensor |
| CN113263186B (zh) * | 2021-05-24 | 2023-05-19 | 北京理工大学珠海学院 | 一种纳米铜线及制备方法 |
| CN113560562B (zh) * | 2021-06-17 | 2022-06-14 | 佛山华智新材料有限公司 | 纳米银颗粒及其制备方法、纳米银浆与焊接接头 |
| EP4163343A1 (en) | 2021-10-05 | 2023-04-12 | Agfa-Gevaert Nv | Conductive inks |
| CN114406278A (zh) * | 2021-12-10 | 2022-04-29 | 深圳市百翱生物科技有限公司 | 一种钯纳米立方体颗粒的制备方法 |
| CN116727679B (zh) * | 2023-06-15 | 2025-08-01 | 云南贵金属实验室有限公司 | 一种pem电解水制氢铱钌合金催化剂的制备方法 |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2806798A (en) * | 1953-07-08 | 1957-09-17 | Du Pont | Process for preparing yellow colloidal silver |
| US2902400A (en) * | 1956-05-08 | 1959-09-01 | Moudry Zdenek Vaclav | Methods for producing liquid oligodynamic compositions |
| US3615789A (en) * | 1966-06-28 | 1971-10-26 | Ciba Ltd | Process for the manufacture of enriched colloidal silver |
| US4652311A (en) * | 1984-05-07 | 1987-03-24 | Shipley Company Inc. | Catalytic metal of reduced particle size |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH434588A (de) * | 1962-11-15 | 1967-04-30 | Tesla Np | Verfahren zur Herstellung von Silberpulver |
| US4634468A (en) * | 1984-05-07 | 1987-01-06 | Shipley Company Inc. | Catalytic metal of reduced particle size |
| US4651311A (en) * | 1984-12-05 | 1987-03-17 | Southwest Research Institute | Electrodeless spark discharge acoustic pulse transducer for borehole operation |
| JP4505084B2 (ja) * | 1999-09-13 | 2010-07-14 | アイノベックス株式会社 | 金属コロイドの製造方法およびその方法によって製造された金属コロイド |
| JP4526200B2 (ja) * | 2001-02-20 | 2010-08-18 | バンドー化学株式会社 | 金属コロイド液の製造方法 |
| JP2003193119A (ja) * | 2001-12-20 | 2003-07-09 | Fuji Photo Film Co Ltd | ナノ粒子の製造方法および該ナノ粒子含有分散液の調製方法 |
| TWI251018B (en) | 2002-04-10 | 2006-03-11 | Fujikura Ltd | Electroconductive composition, electroconductive coating and method of producing the electroconductive coating |
| JP2005019028A (ja) * | 2003-06-23 | 2005-01-20 | Bando Chem Ind Ltd | 金属コロイド液およびそれを用いた導電インク |
| US7470308B2 (en) * | 2004-02-10 | 2008-12-30 | Fujifilm Corporation | Method of producing magnetic particles and reaction method using microreactor and microreactor |
| JP3952027B2 (ja) * | 2004-03-01 | 2007-08-01 | 住友電気工業株式会社 | 金属コロイド溶液 |
-
2006
- 2006-04-15 DE DE102006017696A patent/DE102006017696A1/de not_active Withdrawn
-
2007
- 2007-04-12 US US12/297,065 patent/US8133932B2/en active Active
- 2007-04-12 KR KR1020087027880A patent/KR101085653B1/ko active Active
- 2007-04-12 JP JP2009505755A patent/JP5427602B2/ja active Active
- 2007-04-12 EP EP07724199A patent/EP2010314A1/de not_active Withdrawn
- 2007-04-12 CN CN2007800135647A patent/CN101421032B/zh active Active
- 2007-04-12 WO PCT/EP2007/003258 patent/WO2007118669A1/de not_active Ceased
- 2007-04-12 CA CA2649005A patent/CA2649005C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2806798A (en) * | 1953-07-08 | 1957-09-17 | Du Pont | Process for preparing yellow colloidal silver |
| US2902400A (en) * | 1956-05-08 | 1959-09-01 | Moudry Zdenek Vaclav | Methods for producing liquid oligodynamic compositions |
| US3615789A (en) * | 1966-06-28 | 1971-10-26 | Ciba Ltd | Process for the manufacture of enriched colloidal silver |
| US4652311A (en) * | 1984-05-07 | 1987-03-24 | Shipley Company Inc. | Catalytic metal of reduced particle size |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101085653B1 (ko) | 2011-11-22 |
| CN101421032A (zh) | 2009-04-29 |
| JP2009533558A (ja) | 2009-09-17 |
| JP5427602B2 (ja) | 2014-02-26 |
| WO2007118669A1 (de) | 2007-10-25 |
| CA2649005C (en) | 2014-12-02 |
| EP2010314A1 (de) | 2009-01-07 |
| CA2649005A1 (en) | 2007-10-25 |
| US8133932B2 (en) | 2012-03-13 |
| US20090263496A1 (en) | 2009-10-22 |
| KR20090008345A (ko) | 2009-01-21 |
| DE102006017696A1 (de) | 2007-10-18 |
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