CN101384663A - 低光泽热塑性制品 - Google Patents
低光泽热塑性制品 Download PDFInfo
- Publication number
- CN101384663A CN101384663A CNA2006800533086A CN200680053308A CN101384663A CN 101384663 A CN101384663 A CN 101384663A CN A2006800533086 A CNA2006800533086 A CN A2006800533086A CN 200680053308 A CN200680053308 A CN 200680053308A CN 101384663 A CN101384663 A CN 101384663A
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- CN
- China
- Prior art keywords
- composition
- gloss
- polybutylene terephthalate
- goods
- polyester
- Prior art date
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- Granted
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- 229920001169 thermoplastic Polymers 0.000 title description 7
- 239000004416 thermosoftening plastic Substances 0.000 title description 7
- 239000000203 mixture Substances 0.000 claims abstract description 150
- -1 polybutylene terephthalate Polymers 0.000 claims abstract description 57
- 229920001707 polybutylene terephthalate Polymers 0.000 claims abstract description 54
- 239000000654 additive Substances 0.000 claims abstract description 52
- 229920000728 polyester Polymers 0.000 claims abstract description 52
- 230000000996 additive effect Effects 0.000 claims abstract description 49
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- 239000004609 Impact Modifier Substances 0.000 claims abstract description 36
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 36
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 30
- 238000001746 injection moulding Methods 0.000 claims abstract description 20
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- 238000000518 rheometry Methods 0.000 claims description 2
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- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 11
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- CQOZJDNCADWEKH-UHFFFAOYSA-N 2-[3,3-bis(2-hydroxyphenyl)propyl]phenol Chemical compound OC1=CC=CC=C1CCC(C=1C(=CC=CC=1)O)C1=CC=CC=C1O CQOZJDNCADWEKH-UHFFFAOYSA-N 0.000 description 2
- ZNPSUQQXTRRSBM-UHFFFAOYSA-N 4-n-Pentylphenol Chemical compound CCCCCC1=CC=C(O)C=C1 ZNPSUQQXTRRSBM-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
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- 239000006229 carbon black Substances 0.000 description 2
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
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- 229920001577 copolymer Polymers 0.000 description 2
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
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- 229910052751 metal Inorganic materials 0.000 description 2
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- UFWIBTONFRDIAS-UHFFFAOYSA-N naphthalene-acid Natural products C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
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- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- SYJPAKDNFZLSMV-HYXAFXHYSA-N (Z)-2-methylpropanal oxime Chemical compound CC(C)\C=N/O SYJPAKDNFZLSMV-HYXAFXHYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- JMRKBGGTRCRBEM-UHFFFAOYSA-N 1h-indole-2,3-dione;phenol Chemical compound OC1=CC=CC=C1.OC1=CC=CC=C1.C1=CC=C2C(=O)C(=O)NC2=C1 JMRKBGGTRCRBEM-UHFFFAOYSA-N 0.000 description 1
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical class N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- HJZJMARGPNJHHG-UHFFFAOYSA-N 2,6-dimethyl-4-propylphenol Chemical compound CCCC1=CC(C)=C(O)C(C)=C1 HJZJMARGPNJHHG-UHFFFAOYSA-N 0.000 description 1
- LROZSPADHSXFJA-UHFFFAOYSA-N 2-(4-hydroxyphenyl)sulfonylphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=CC=C1O LROZSPADHSXFJA-UHFFFAOYSA-N 0.000 description 1
- YJPFPFGPHQAZGB-UHFFFAOYSA-N 3-methyl-6-(7-oxabicyclo[4.1.0]heptan-1-yl)-7-oxabicyclo[4.1.0]heptane-3-carboxylic acid Chemical compound C1CCCC2OC21C12CCC(C(O)=O)(C)CC1O2 YJPFPFGPHQAZGB-UHFFFAOYSA-N 0.000 description 1
- ASURBSPIYIISGI-UHFFFAOYSA-N 4-(3,3,5-trimethylcyclohexyl)phenol Chemical compound C1C(C)(C)CC(C)CC1C1=CC=C(O)C=C1 ASURBSPIYIISGI-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
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- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical class C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
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- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
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- 150000002989 phenols Chemical class 0.000 description 1
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- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
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- 229920001230 polyarylate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- 238000010107 reaction injection moulding Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012549 training Methods 0.000 description 1
- 229910000319 transition metal phosphate Inorganic materials 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- NJMOHBDCGXJLNJ-UHFFFAOYSA-N trimellitic anhydride chloride Chemical compound ClC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 NJMOHBDCGXJLNJ-UHFFFAOYSA-N 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0001—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor characterised by the choice of material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C51/00—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor
- B29C51/002—Shaping by thermoforming, i.e. shaping sheets or sheet like preforms after heating, e.g. shaping sheets in matched moulds or by deep-drawing; Apparatus therefor characterised by the choice of material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2067/00—Use of polyesters or derivatives thereof, as moulding material
- B29K2067/006—PBT, i.e. polybutylene terephthalate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2069/00—Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2995/00—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds
- B29K2995/0018—Properties of moulding materials, reinforcements, fillers, preformed parts or moulds having particular optical properties, e.g. fluorescent or phosphorescent
- B29K2995/0022—Bright, glossy or shiny surface
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
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- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0884—Epoxide containing esters
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- C08L2555/00—Characteristics of bituminous mixtures
- C08L2555/40—Mixtures based upon bitumen or asphalt containing functional additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
- C08L33/10—Homopolymers or copolymers of methacrylic acid esters
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
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- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C08L9/06—Copolymers with styrene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Graft Or Block Polymers (AREA)
Abstract
Description
粘度 | 465 | 390 | 329 | 390 | 387 | 353 | 381 | 315 | 410 | 707 | 460 | 538 | 397 | 469 |
光泽20 | 4.2 | 14.6 | 3.7 | 7.5 | 32.6 | 9.6 | 5.8 | 14.9 | 4.6 | 3.2 | 10.2 | 2.3 | 4.3 | 2.1 |
光泽60 | 34.6 | 60.2 | 37.5 | 52.4 | 79.2 | 56.8 | 37.4 | 63.5 | 40.6 | 24.3 | 59.2 | 16.9 | 38.9 | 16.7 |
原料 | 15 | 16 | 17 |
PC2 | 50.00 | 49.50 | 49.00 |
PBT | 20.00 | 20.00 | 20.00 |
PET | 18.75 | 18.75 | 18.75 |
ABS1 | 8.75 | 8.75 | 8.75 |
稳定剂和颜料 | 2.50 | 2.50 | 2.50 |
CS1770 | 0.00 | 0.50 | 1.00 |
总计 | 100.00 | 100.00 | 100.00 |
在85℃时的分钟数 | 20°光泽 | 20°光泽 | 20°光泽 |
0 | 54.4 | 35.0 | 29.2 |
15 | 16.5 | 10.0 | 6.6 |
30 | 14.9 | 8.8 | 5.9 |
60 | 14.9 | 9.6 | 5.5 |
120 | 14.2 | 6.8 | 5.7 |
PET(IV=.54) | PET(IV=.73) | ||
商品名 | 添加剂官能度 化学名 | 光泽(20°) | 光泽(20°) |
CoatoSil1770 | 具有一个环氧基的 β-(3,4-环氧环己基)乙基三乙氧基硅烷多官能添加剂 | 3.5 | 4.3 |
SilquestA-186 | 具有一个环氧基的 β-(3,4-环氧环己基)乙基三甲氧基硅烷多官能添加剂 | 2.8 | 3.3 |
SilquestY-15589 | 具有一个环氧基的 3-环氧丙氧基丙基三乙氧基硅烷多官能添加剂 | 3.4 | 7.1 |
ERL 4221 | 具有两个环氧基的 3,4-环氧环己基甲基-3,4-环氧环己烷羧双官能添加剂 酸酯 | 6.8 | 5.8 |
AOE X68 | 具有一个环氧基的 α-烯烃环氧化物C16-18(Alpha-olephin多官能添加剂 epoxide C16-18) | 11.4 | 9.2 |
n-OTEOS无 | 不含有环氧基的 正十八烷基三乙氧基硅烷单官能添加剂无添加剂 无(对照样品) | 12.26.2 | 9.26.8 |
材料 | 含量(wt%) |
58.37 | |
聚对苯二甲酸丁二醇酯 | 21.28 |
聚对苯二甲酸乙二醇酯 | 9.76 |
ABS抗冲改性剂,BLENDEX 362,购自于Crompton | 8.76 |
Joncryl ADR 4368环氧共聚物 | 0.30 |
Ultratalc | 1.00 |
SEENOX(412S) | 0.05 |
亚磷酸水溶液(Phosphorus Acid In Water) | 0.03 |
受阻酚抗氧化剂 | 0.20 |
炭黑 | 0.25 |
实施例 25 26 27 28 29 30 31聚碳酸酯-间苯二酚共聚物 63.58 58.58 68.58 63.58 58.58 63.58 68.58聚对苯二甲酸乙二醇酯 20.00 20.00 20.00 25.00 25.00 15.00 15.00ABS抗冲改性剂 15.00 20.00 10.00 10.00 15.00 20.00 15.00SEENOX(412S) 0.10 0.10 0.10 0.10 0.10 0.10 0.1045%亚磷酸水溶液 0.02 0.02 0.02 0.02 0.02 0.02 0.02Irganox 1010 0.30 0.30 0.30 0.30 0.30 0.30 0.30环氧硅烷Coatosil 1770 0.50 0.50 0.50 0.50 0.50 0.50 0.50Tinuvin 234 0.25 0.25 0.25 0.25 0.25 0.25 0.25炭黑 0.25 0.25 0.25 0.25 0.25 0.25 0.25 |
100.00 100.00 100.00 100.00 100.00 100.00 100.00挤出后60度光泽 70.7 58.0 86.0 81.0 43.6 56.5 81.0热成型后60度光泽 14.7 7.1 9.4 14.2 9.2 17.0 13.5 |
Claims (11)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US11/316,227 US8084550B2 (en) | 2005-05-23 | 2005-12-22 | Low gloss thermoplastic composition |
US11/316,227 | 2005-12-22 | ||
US11/419,912 | 2006-05-23 | ||
US11/419,912 US20070173619A1 (en) | 2005-05-23 | 2006-05-23 | Low gloss thermoplastic articles |
PCT/US2006/020956 WO2007073399A1 (en) | 2005-12-22 | 2006-05-31 | Low gloss thermoplastic articles |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101384663A true CN101384663A (zh) | 2009-03-11 |
CN101384663B CN101384663B (zh) | 2011-11-16 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN2006800533086A Expired - Fee Related CN101384663B (zh) | 2005-12-22 | 2006-05-31 | 低光泽热塑性制品 |
Country Status (7)
Country | Link |
---|---|
US (2) | US20070173619A1 (zh) |
EP (1) | EP1966309B1 (zh) |
JP (1) | JP2009521538A (zh) |
CN (1) | CN101384663B (zh) |
AT (1) | ATE463534T1 (zh) |
DE (1) | DE602006013509D1 (zh) |
WO (1) | WO2007073399A1 (zh) |
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-
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- 2006-05-23 US US11/419,912 patent/US20070173619A1/en not_active Abandoned
- 2006-05-31 EP EP06771624A patent/EP1966309B1/en not_active Not-in-force
- 2006-05-31 CN CN2006800533086A patent/CN101384663B/zh not_active Expired - Fee Related
- 2006-05-31 AT AT06771624T patent/ATE463534T1/de not_active IP Right Cessation
- 2006-05-31 DE DE602006013509T patent/DE602006013509D1/de active Active
- 2006-05-31 WO PCT/US2006/020956 patent/WO2007073399A1/en active Application Filing
- 2006-05-31 JP JP2008547206A patent/JP2009521538A/ja not_active Withdrawn
-
2008
- 2008-07-10 US US12/170,636 patent/US8592523B2/en not_active Expired - Fee Related
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107429022A (zh) * | 2015-03-31 | 2017-12-01 | Sabic环球技术有限责任公司 | 变色发生率减少的光泽聚合物添加剂 |
CN109910275A (zh) * | 2019-01-24 | 2019-06-21 | 苏州艾纽智能科技有限公司 | 一种遥控器外壳挤压成型工艺 |
Also Published As
Publication number | Publication date |
---|---|
US20090005477A1 (en) | 2009-01-01 |
JP2009521538A (ja) | 2009-06-04 |
EP1966309B1 (en) | 2010-04-07 |
US20070173619A1 (en) | 2007-07-26 |
ATE463534T1 (de) | 2010-04-15 |
EP1966309A1 (en) | 2008-09-10 |
DE602006013509D1 (de) | 2010-05-20 |
US8592523B2 (en) | 2013-11-26 |
CN101384663B (zh) | 2011-11-16 |
WO2007073399A1 (en) | 2007-06-28 |
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