CN101180364B - 低光泽的热塑性组合物 - Google Patents
低光泽的热塑性组合物 Download PDFInfo
- Publication number
- CN101180364B CN101180364B CN2006800181157A CN200680018115A CN101180364B CN 101180364 B CN101180364 B CN 101180364B CN 2006800181157 A CN2006800181157 A CN 2006800181157A CN 200680018115 A CN200680018115 A CN 200680018115A CN 101180364 B CN101180364 B CN 101180364B
- Authority
- CN
- China
- Prior art keywords
- gloss
- composition
- polyester
- parts
- molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 122
- 229920001169 thermoplastic Polymers 0.000 title description 2
- 239000004416 thermosoftening plastic Substances 0.000 title description 2
- 229920000728 polyester Polymers 0.000 claims abstract description 44
- 239000000654 additive Substances 0.000 claims abstract description 42
- 230000000996 additive effect Effects 0.000 claims abstract description 38
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 32
- 239000004417 polycarbonate Substances 0.000 claims abstract description 32
- 239000004609 Impact Modifier Substances 0.000 claims abstract description 31
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 21
- -1 polybutylene terephthalate Polymers 0.000 claims description 46
- 238000000465 moulding Methods 0.000 claims description 42
- 229920001707 polybutylene terephthalate Polymers 0.000 claims description 38
- 238000000034 method Methods 0.000 claims description 33
- 238000005259 measurement Methods 0.000 claims description 18
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 17
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 17
- 239000000126 substance Substances 0.000 claims description 14
- 230000009467 reduction Effects 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 9
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 claims description 7
- 238000010438 heat treatment Methods 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 5
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 5
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 claims description 5
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 125000002723 alicyclic group Chemical group 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 4
- DENFJSAFJTVPJR-UHFFFAOYSA-N triethoxy(ethyl)silane Chemical compound CCO[Si](CC)(OCC)OCC DENFJSAFJTVPJR-UHFFFAOYSA-N 0.000 claims description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- SBRXLTRZCJVAPH-UHFFFAOYSA-N ethyl(trimethoxy)silane Chemical compound CC[Si](OC)(OC)OC SBRXLTRZCJVAPH-UHFFFAOYSA-N 0.000 claims description 3
- 239000000178 monomer Substances 0.000 claims description 3
- 238000000518 rheometry Methods 0.000 claims description 3
- 229920001897 terpolymer Polymers 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- KLIYQWXIWMRMGR-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate Chemical compound C=CC=C.COC(=O)C(C)=C KLIYQWXIWMRMGR-UHFFFAOYSA-N 0.000 claims 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims 2
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical group C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 claims 2
- 229920000638 styrene acrylonitrile Polymers 0.000 claims 2
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical group C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims 1
- 239000000206 moulding compound Substances 0.000 description 17
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 11
- 125000003118 aryl group Chemical group 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000004593 Epoxy Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 229960003742 phenol Drugs 0.000 description 7
- 238000005498 polishing Methods 0.000 description 7
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 239000003153 chemical reaction reagent Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 6
- 150000004678 hydrides Chemical class 0.000 description 6
- 229920001296 polysiloxane Polymers 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 5
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 5
- 239000006085 branching agent Substances 0.000 description 5
- KZTYYGOKRVBIMI-UHFFFAOYSA-N diphenyl sulfone Chemical compound C=1C=CC=CC=1S(=O)(=O)C1=CC=CC=C1 KZTYYGOKRVBIMI-UHFFFAOYSA-N 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000994 depressogenic effect Effects 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002148 esters Chemical group 0.000 description 4
- 229920001519 homopolymer Polymers 0.000 description 4
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 239000007858 starting material Substances 0.000 description 4
- 101100272412 Arabidopsis thaliana BIA1 gene Proteins 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 125000001118 alkylidene group Chemical group 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 125000000524 functional group Chemical group 0.000 description 3
- 239000002932 luster Substances 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 239000003973 paint Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 239000002243 precursor Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- CQOZJDNCADWEKH-UHFFFAOYSA-N 2-[3,3-bis(2-hydroxyphenyl)propyl]phenol Chemical compound OC1=CC=CC=C1CCC(C=1C(=CC=CC=1)O)C1=CC=CC=C1O CQOZJDNCADWEKH-UHFFFAOYSA-N 0.000 description 2
- ZNPSUQQXTRRSBM-UHFFFAOYSA-N 4-n-Pentylphenol Chemical class CCCCCC1=CC=C(O)C=C1 ZNPSUQQXTRRSBM-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 229920004142 LEXAN™ Polymers 0.000 description 2
- 239000004418 Lexan Substances 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 229920000297 Rayon Polymers 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 238000012937 correction Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- SYJPAKDNFZLSMV-HYXAFXHYSA-N (Z)-2-methylpropanal oxime Chemical compound CC(C)\C=N/O SYJPAKDNFZLSMV-HYXAFXHYSA-N 0.000 description 1
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
- GRBSHVCIKYLDAO-UHFFFAOYSA-N 4-(3,5-diethyl-4-hydroxyphenyl)sulfonyl-2,6-diethylphenol Chemical compound CCC1=C(O)C(CC)=CC(S(=O)(=O)C=2C=C(CC)C(O)=C(CC)C=2)=C1 GRBSHVCIKYLDAO-UHFFFAOYSA-N 0.000 description 1
- KLSLBUSXWBJMEC-UHFFFAOYSA-N 4-Propylphenol Chemical compound CCCC1=CC=C(O)C=C1 KLSLBUSXWBJMEC-UHFFFAOYSA-N 0.000 description 1
- HXDOZKJGKXYMEW-UHFFFAOYSA-N 4-ethylphenol Chemical compound CCC1=CC=C(O)C=C1 HXDOZKJGKXYMEW-UHFFFAOYSA-N 0.000 description 1
- XDYJVMIZUVTNNV-UHFFFAOYSA-N 4-methyl-3,5-dioxabicyclo[5.2.2]undeca-1(9),7,10-triene-2,6-dione Chemical compound C1(C2=CC=C(C(=O)OC(C)O1)C=C2)=O XDYJVMIZUVTNNV-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- GXGJIOMUZAGVEH-UHFFFAOYSA-N Chamazulene Chemical group CCC1=CC=C(C)C2=CC=C(C)C2=C1 GXGJIOMUZAGVEH-UHFFFAOYSA-N 0.000 description 1
- PWSYABYHJUCCAT-UHFFFAOYSA-N ClC(=O)C1CC2C(C(=O)OC2=O)C=C1 Chemical compound ClC(=O)C1CC2C(C(=O)OC2=O)C=C1 PWSYABYHJUCCAT-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 229920013646 Hycar Polymers 0.000 description 1
- 229920006309 Invista Polymers 0.000 description 1
- AJBXRBRVQMZREG-UHFFFAOYSA-N OC(CC)(C1=CC=CC=C1)O.OC1=CC=C(C=C1)CCC Chemical compound OC(CC)(C1=CC=CC=C1)O.OC1=CC=C(C=C1)CCC AJBXRBRVQMZREG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ORLQHILJRHBSAY-UHFFFAOYSA-N [1-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1(CO)CCCCC1 ORLQHILJRHBSAY-UHFFFAOYSA-N 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- YXVFYQXJAXKLAK-UHFFFAOYSA-N biphenyl-4-ol Chemical group C1=CC(O)=CC=C1C1=CC=CC=C1 YXVFYQXJAXKLAK-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 description 1
- WWNGFHNQODFIEX-UHFFFAOYSA-N buta-1,3-diene;methyl 2-methylprop-2-enoate;styrene Chemical compound C=CC=C.COC(=O)C(C)=C.C=CC1=CC=CC=C1 WWNGFHNQODFIEX-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000021523 carboxylation Effects 0.000 description 1
- 238000006473 carboxylation reaction Methods 0.000 description 1
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- FNIATMYXUPOJRW-UHFFFAOYSA-N cyclohexylidene Chemical group [C]1CCCCC1 FNIATMYXUPOJRW-UHFFFAOYSA-N 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 150000007520 diprotic acids Chemical class 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical compound [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- RPHYLOMQFAGWCD-UHFFFAOYSA-N ethane;phenol Chemical compound CC.OC1=CC=CC=C1 RPHYLOMQFAGWCD-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- YLQWCDOCJODRMT-UHFFFAOYSA-N fluoren-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3C2=C1 YLQWCDOCJODRMT-UHFFFAOYSA-N 0.000 description 1
- 238000005227 gel permeation chromatography Methods 0.000 description 1
- 125000005067 haloformyl group Chemical group 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- HRRDCWDFRIJIQZ-UHFFFAOYSA-N naphthalene-1,8-dicarboxylic acid Chemical compound C1=CC(C(O)=O)=C2C(C(=O)O)=CC=CC2=C1 HRRDCWDFRIJIQZ-UHFFFAOYSA-N 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- QWVGKYWNOKOFNN-UHFFFAOYSA-N o-cresol Chemical compound CC1=CC=CC=C1O QWVGKYWNOKOFNN-UHFFFAOYSA-N 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- SJDACOMXKWHBOW-UHFFFAOYSA-N oxyphenisatine Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2NC1=O SJDACOMXKWHBOW-UHFFFAOYSA-N 0.000 description 1
- IWDCLRJOBJJRNH-UHFFFAOYSA-N p-cresol Chemical compound CC1=CC=C(O)C=C1 IWDCLRJOBJJRNH-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000000843 phenylene group Chemical group C1(=C(C=CC=C1)*)* 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 229910000319 transition metal phosphate Inorganic materials 0.000 description 1
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical group C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/15—Heterocyclic compounds having oxygen in the ring
- C08K5/151—Heterocyclic compounds having oxygen in the ring having one oxygen atom in the ring
- C08K5/1515—Three-membered rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/541—Silicon-containing compounds containing oxygen
- C08K5/5435—Silicon-containing compounds containing oxygen containing oxygen in a ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
- C08L23/0884—Epoxide containing esters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Abstract
Description
粘度 | 465 | 390 | 329 | 390 | 387 | 353 | 381 | 315 | 410 | 707 | 460 | 538 | 397 | 469 |
20°光泽 | 4.2 | 14.6 | 3.7 | 7.5 | 32.6 | 9.6 | 5.8 | 14.9 | 4.6 | 3.2 | 10.2 | 2.3 | 4.3 | 2.1 |
60°光泽 | 34.6 | 60.2 | 37.5 | 52.4 | 79.2 | 56.8 | 37.4 | 63.5 | 40.6 | 24.3 | 59.2 | 16.9 | 38.9 | 16.7 |
原料 | 15 | 16 | 17 |
PC2 | 50.00 | 49.50 | 49.00 |
PBT | 20.00 | 20.00 | 20.00 |
PET | 18.75 | 18.75 | 18.75 |
ABS1 | 8.75 | 8.75 | 8.75 |
稳定剂和颜料 | 2.50 | 2.50 | 2.50 |
CS1770 | 0.00 | 0.50 | 1.00 |
总计 | 100.00 | 100.00 | 100.00 |
85℃分钟 | 20°光泽 | 20°光泽 | 20°光泽 |
0 | 54.4 | 35.0 | 29.2 |
15 | 16.5 | 10.0 | 6.6 |
30 | 14.9 | 8.8 | 5.9 |
60 | 14.9 | 9.6 | 5.5 |
120 | 14.2 | 6.8 | 5.7 |
Claims (50)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US68382605P | 2005-05-23 | 2005-05-23 | |
US60/683,826 | 2005-05-23 | ||
US11/316,227 | 2005-12-22 | ||
US11/316,227 US8084550B2 (en) | 2005-05-23 | 2005-12-22 | Low gloss thermoplastic composition |
PCT/US2006/017611 WO2006127245A2 (en) | 2005-05-23 | 2006-05-08 | Low gloss thermoplastic composition |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101180364A CN101180364A (zh) | 2008-05-14 |
CN101180364B true CN101180364B (zh) | 2011-08-31 |
Family
ID=37103047
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006800181157A Expired - Fee Related CN101180364B (zh) | 2005-05-23 | 2006-05-08 | 低光泽的热塑性组合物 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8084550B2 (zh) |
EP (1) | EP1893690B1 (zh) |
JP (1) | JP2008540803A (zh) |
CN (1) | CN101180364B (zh) |
AT (1) | ATE474015T1 (zh) |
DE (1) | DE602006015466D1 (zh) |
WO (1) | WO2006127245A2 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105385094A (zh) * | 2015-12-21 | 2016-03-09 | 上海锦湖日丽塑料有限公司 | 低光泽abs树脂组合物及其制备方法 |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20070213471A1 (en) * | 2006-03-09 | 2007-09-13 | General Electric Company | Composition and method of use |
US8642700B2 (en) * | 2006-11-03 | 2014-02-04 | Bayer Materialscience Llc | Thermoplastic composition having low gloss and low temperature impact performance |
US8434377B2 (en) * | 2007-06-29 | 2013-05-07 | U.S. Coatings Ip Co. Llc | Method for measuring sandability of coating and the use thereof |
US20090043038A1 (en) * | 2007-08-10 | 2009-02-12 | Bayer Materialscience Llc | Thermoplastic composition having low gloss |
CN101280099B (zh) * | 2008-05-23 | 2010-09-01 | 华南理工大学 | 耐溶剂二甲苯的聚碳酸酯尼龙聚合物合金及其制备方法 |
CN102051034B (zh) * | 2009-10-30 | 2013-04-17 | 上海普利特复合材料股份有限公司 | 一种低光泽、高耐热聚碳酸酯组合物 |
KR101276454B1 (ko) | 2009-12-10 | 2013-06-19 | 주식회사 삼양사 | 저광택 열가소성 수지 조성물 |
CN102666623A (zh) * | 2010-02-05 | 2012-09-12 | 巴斯夫涂料有限公司 | 用于涂料组合物中的树脂 |
KR101486564B1 (ko) * | 2012-07-04 | 2015-01-26 | 제일모직 주식회사 | 열가소성 수지 조성물 및 이를 이용한 성형품 |
US9395351B2 (en) | 2013-12-16 | 2016-07-19 | Sunpower Corporation | Solar glass angle of incidence reflectance |
BR112017000872B1 (pt) * | 2014-07-14 | 2022-06-14 | Vertellus Holdings Llc | Composição de liga de polímero compatibilizada peletizável termoplástica |
KR102018713B1 (ko) | 2016-12-21 | 2019-11-04 | 롯데첨단소재(주) | 수지 조성물 및 이로부터 제조된 성형품 |
CN107586447A (zh) * | 2017-08-29 | 2018-01-16 | 合肥会通新材料有限公司 | 一种哑光pc/pbt合金材料及其制备方法 |
CN109943009A (zh) * | 2018-11-19 | 2019-06-28 | 任静儿 | 一种高韧性abs复合材料 |
EP3725846A1 (en) * | 2019-04-15 | 2020-10-21 | Prisma Renewable Composites, LLC | Thermoplastic acrylonitrile containing copolymer/lignin blends |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5001178A (en) * | 1989-03-06 | 1991-03-19 | General Electric Company | Thermoplastic molding compositions |
US5369154A (en) * | 1990-04-12 | 1994-11-29 | The Dow Chemical Company | Polycarbonate/aromatic polyester blends containing an olefinic modifier |
US5508344A (en) * | 1994-11-22 | 1996-04-16 | Bayer Corporation | Low temperature drying of impact modified polycarbonate/polyester compositions |
Family Cites Families (40)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2465319A (en) * | 1941-07-29 | 1949-03-22 | Du Pont | Polymeric linear terephthalic esters |
US2822348A (en) * | 1951-11-14 | 1958-02-04 | Du Pont | Ester interchange catalysts |
US2720502A (en) * | 1952-10-03 | 1955-10-11 | Eastman Kodak Co | Organo-metallic titanium catalysts for the preparation of polyesters |
US2727881A (en) * | 1952-10-03 | 1955-12-20 | Eastman Kodak Co | Organo-titanium catalysts for the preparation of polyesters |
US3153008A (en) * | 1955-07-05 | 1964-10-13 | Gen Electric | Aromatic carbonate resins and preparation thereof |
US3038365A (en) * | 1958-05-16 | 1962-06-12 | Richard H Peterson | Electronic organ |
US3047539A (en) * | 1958-11-28 | 1962-07-31 | Goodyear Tire & Rubber | Production of polyesters |
US2999835A (en) * | 1959-01-02 | 1961-09-12 | Gen Electric | Resinous mixture comprising organo-polysiloxane and polymer of a carbonate of a dihydric phenol, and products containing same |
NL276020A (zh) * | 1962-03-16 | |||
GB1045533A (en) * | 1963-02-21 | 1966-10-12 | Gen Electric | Flame-resistant polycarbonate compositions |
US3302243A (en) * | 1964-04-16 | 1967-02-07 | Herbert P Ludwig | Apparatus for the injection molding of plastic articles especially shoes |
US3635895A (en) * | 1965-09-01 | 1972-01-18 | Gen Electric | Process for preparing thermoplastic polycarbonates |
US3671487A (en) * | 1971-05-05 | 1972-06-20 | Gen Electric | Glass reinforced polyester resins containing polytetrafluoroethylene and flame retardant additives |
US3953394A (en) * | 1971-11-15 | 1976-04-27 | General Electric Company | Polyester alloys and molding compositions containing the same |
CA1006666A (en) * | 1973-10-29 | 1977-03-15 | Ladislav Hujik | Mold filling insert for injection molding machine |
US4131575A (en) * | 1975-02-22 | 1978-12-26 | Bayer Aktiengesellschaft | Thermoplastic polycarbonate molding materials with improved mold release |
US4001184A (en) * | 1975-03-31 | 1977-01-04 | General Electric Company | Process for preparing a branched polycarbonate |
US4123436A (en) * | 1976-12-16 | 1978-10-31 | General Electric Company | Polycarbonate composition plasticized with esters |
US4128526A (en) * | 1976-12-23 | 1978-12-05 | General Electric Company | Copolyesters of poly(alkylene glycol aromatic acid esters) and diesters comprising aromatic diols |
DE2712171C2 (de) * | 1977-03-19 | 1984-09-27 | Bayer Ag, 5090 Leverkusen | Thermoplastische Formmassen |
DE3521956A1 (de) * | 1985-06-20 | 1987-01-02 | Basf Ag | Kaelteschlagzaehe thermoplastische formmassen aus polyester und polycarbonat |
US5087663A (en) * | 1989-03-08 | 1992-02-11 | The Dow Chemical Company | Molding compositions with methyl (meth)acrylate-butadiene-styrene graft copolymers |
WO1992014787A1 (en) | 1991-02-26 | 1992-09-03 | The Dow Chemical Company | Blends of thermoplastic molding compositions containing epoxy resins |
US5196479A (en) * | 1991-02-27 | 1993-03-23 | The Dow Chemical Company | Impact resistant blends of high heat polycarbonate and aromatic polyester |
ES2078388T3 (es) | 1991-06-19 | 1995-12-16 | Gen Electric | Mezcla basada en un polimero de un carbonato aromatico con poco brillo. |
WO1993019128A2 (en) | 1992-03-10 | 1993-09-30 | The Dow Chemical Company | Polymers and polymer blends modified with poly(phenylene ether) |
JPH08319406A (ja) | 1995-05-26 | 1996-12-03 | Kanegafuchi Chem Ind Co Ltd | 難燃性樹脂組成物 |
US5648411A (en) * | 1995-06-07 | 1997-07-15 | General Electric Company | Thermoplastic blend compositions containing polyester resins and an organosulfate salt |
EP0884366A4 (en) * | 1996-02-29 | 1999-05-06 | Kaneka Corp | FLAME RETARDANT THERMOPLASTIC RESIN COMPOSITION |
JP2001506680A (ja) | 1996-11-27 | 2001-05-22 | ザ・ダウ・ケミカル・カンパニー | ポリカーボネートブレンド組成物 |
JPH10168297A (ja) | 1996-12-16 | 1998-06-23 | Kanegafuchi Chem Ind Co Ltd | 難燃性熱可塑性樹脂組成物 |
JPH11116782A (ja) | 1997-10-21 | 1999-04-27 | Kanegafuchi Chem Ind Co Ltd | 熱可塑性樹脂組成物 |
CN1288187C (zh) * | 1998-10-29 | 2006-12-06 | 通用电气公司 | 耐候嵌段共聚酯碳酸酯、其制备方法和包含它们的共混物 |
JP2001123042A (ja) | 1999-10-25 | 2001-05-08 | Daicel Chem Ind Ltd | エステル系熱可塑性樹脂組成物 |
US6541550B1 (en) * | 2000-04-05 | 2003-04-01 | 3M Innovative Properties Company | Low temperature thermally activated water-dispersed adhesive compositions |
US6784253B2 (en) * | 2001-07-24 | 2004-08-31 | General Electric Company | Enhanced polymerization process |
US20040127653A1 (en) * | 2002-08-30 | 2004-07-01 | General Electric Company | Polycarbonate/polyester copolymer blends and process for making thereof |
US7544726B2 (en) * | 2002-10-14 | 2009-06-09 | Akzo Nobel N.V. | Colloidal silica composition |
JP2004137396A (ja) | 2002-10-18 | 2004-05-13 | Techno Polymer Co Ltd | 熱可塑性樹脂組成物及び成形品 |
WO2005071012A1 (en) | 2004-01-13 | 2005-08-04 | Polyone Corporation | Use of a thermoplastic vulcanizate as an impact modifier in blends of polyester and polycarbonate |
-
2005
- 2005-12-22 US US11/316,227 patent/US8084550B2/en not_active Expired - Fee Related
-
2006
- 2006-05-08 AT AT06770065T patent/ATE474015T1/de not_active IP Right Cessation
- 2006-05-08 DE DE602006015466T patent/DE602006015466D1/de active Active
- 2006-05-08 JP JP2008512334A patent/JP2008540803A/ja not_active Withdrawn
- 2006-05-08 WO PCT/US2006/017611 patent/WO2006127245A2/en active Application Filing
- 2006-05-08 EP EP06770065A patent/EP1893690B1/en not_active Not-in-force
- 2006-05-08 CN CN2006800181157A patent/CN101180364B/zh not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5001178A (en) * | 1989-03-06 | 1991-03-19 | General Electric Company | Thermoplastic molding compositions |
US5369154A (en) * | 1990-04-12 | 1994-11-29 | The Dow Chemical Company | Polycarbonate/aromatic polyester blends containing an olefinic modifier |
US5508344A (en) * | 1994-11-22 | 1996-04-16 | Bayer Corporation | Low temperature drying of impact modified polycarbonate/polyester compositions |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105385094A (zh) * | 2015-12-21 | 2016-03-09 | 上海锦湖日丽塑料有限公司 | 低光泽abs树脂组合物及其制备方法 |
CN105385094B (zh) * | 2015-12-21 | 2018-11-13 | 上海锦湖日丽塑料有限公司 | 低光泽abs树脂组合物及其制备方法 |
Also Published As
Publication number | Publication date |
---|---|
DE602006015466D1 (de) | 2010-08-26 |
JP2008540803A (ja) | 2008-11-20 |
WO2006127245A3 (en) | 2007-03-15 |
EP1893690B1 (en) | 2010-07-14 |
ATE474015T1 (de) | 2010-07-15 |
WO2006127245A2 (en) | 2006-11-30 |
CN101180364A (zh) | 2008-05-14 |
EP1893690A2 (en) | 2008-03-05 |
US20060264579A1 (en) | 2006-11-23 |
US8084550B2 (en) | 2011-12-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101180364B (zh) | 低光泽的热塑性组合物 | |
US8592523B2 (en) | Low gloss thermoplastic articles | |
US6989190B2 (en) | Transparent polycarbonate polyester composition and process | |
CN105419205B (zh) | 一种高光泽免喷涂的pmma/asa合金树脂组合物及其制备方法 | |
CN102276955B (zh) | 一种抗静电玻璃纤维增强abs复合材料 | |
CN101805504A (zh) | 一种玻纤增强聚碳酸酯材料及其制备方法 | |
CN102051042B (zh) | 一种低光泽、耐刮擦尼龙/丙烯腈-丁二烯-苯乙烯树脂共混材料 | |
CA2811532A1 (en) | Weather-resistant, dyed molded part having improved shine and wipe resistance | |
CN111154252B (zh) | 一种高光钢琴黑pc/pmma合金树脂组合物及其制备方法 | |
CN102464877A (zh) | 一种低光泽聚碳酸酯苯乙烯类树脂组合物及其制备方法 | |
JP2002326331A (ja) | 車輌外装材に適する合成樹脂成形品およびインサート成形用シート状成形体 | |
JP6595241B2 (ja) | 熱可塑性樹脂組成物及びその成形体 | |
CN101812223A (zh) | 聚碳酸酯/聚对苯二甲酸乙二醇酯树脂组合物及制备方法 | |
CN112646348A (zh) | 一种高硬度高耐刮擦免喷涂高光pc/pbt合金材料及制备方法 | |
EP3722370B1 (en) | Thermoplastic resin composition and molded article using same | |
CN106164169B (zh) | 用于方向盘远端控制座圈的聚合树脂组合物 | |
CN1882656B (zh) | 基于冲击改性聚对苯二甲酸亚烷二醇酯/聚碳酸酯共混物的均匀模塑色和耐天候稳定组合物 | |
KR101583223B1 (ko) | 열가소성 수지 조성물 및 이를 이용한 성형품 | |
CN110938295B (zh) | 一种高光耐候低气味高流动pc/npg-pet合金及其制备方法 | |
KR20230050572A (ko) | 고휘도 무도장 메탈릭 소재용 열가소성 수지 조성물 및 이를 포함하는 성형품 | |
CN105175926A (zh) | 一种超低光泽abs树脂组合物及其制备方法 | |
WO2023149504A1 (ja) | 樹脂組成物、および、成形体 | |
CN117866406A (zh) | 一种低光泽pc/abs合金材料及其制备方法 | |
CN116194292A (zh) | 用于漫射性透射的多层制品 | |
KR20220125509A (ko) | 자동차 내장재용 복합수지 조성물 및 이를 이용한 자동차 내장재 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20090116 Address after: Bergen Op Zoom Holland Applicant after: Sabic Innovative Plastics Ip Address before: American New York Applicant before: General Electric Company |
|
ASS | Succession or assignment of patent right |
Owner name: SHABO BASE CREATION PLASTICS INTELLECTUAL PROPERTY Free format text: FORMER OWNER: GENERAL ELECTRIC CO. Effective date: 20090116 |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: Bergen Op Zoom Holland Patentee after: Sabic Innovative Plastics IP Address before: Bergen Op Zoom Holland Patentee before: Sabic Innovative Plastics Ip |
|
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110831 Termination date: 20170508 |
|
CF01 | Termination of patent right due to non-payment of annual fee |