CN101370778B - 制备单亚胺化合物的方法、不对称铁络合物及催化剂体系 - Google Patents
制备单亚胺化合物的方法、不对称铁络合物及催化剂体系 Download PDFInfo
- Publication number
- CN101370778B CN101370778B CN200780003011.3A CN200780003011A CN101370778B CN 101370778 B CN101370778 B CN 101370778B CN 200780003011 A CN200780003011 A CN 200780003011A CN 101370778 B CN101370778 B CN 101370778B
- Authority
- CN
- China
- Prior art keywords
- ethyl
- alkyl
- compounds
- groups
- aryl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 0 ***(*)=C(C(*)=O)N=C(*=*)C(*)=O Chemical compound ***(*)=C(C(*)=O)N=C(*=*)C(*)=O 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/26—Radicals substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/53—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyridine Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006001959A DE102006001959A1 (de) | 2006-01-13 | 2006-01-13 | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| DE102006001959.8 | 2006-01-13 | ||
| PCT/EP2007/000096 WO2007080081A2 (en) | 2006-01-13 | 2007-01-08 | Process for the preparation of unsymmetric bis(imino) compounds |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101370778A CN101370778A (zh) | 2009-02-18 |
| CN101370778B true CN101370778B (zh) | 2014-10-22 |
Family
ID=38190018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200780003011.3A Active CN101370778B (zh) | 2006-01-13 | 2007-01-08 | 制备单亚胺化合物的方法、不对称铁络合物及催化剂体系 |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8252875B2 (enExample) |
| EP (1) | EP1971577B1 (enExample) |
| JP (1) | JP5165587B2 (enExample) |
| KR (1) | KR101373915B1 (enExample) |
| CN (1) | CN101370778B (enExample) |
| AU (1) | AU2007204447A1 (enExample) |
| BR (1) | BRPI0706486C8 (enExample) |
| DE (1) | DE102006001959A1 (enExample) |
| RU (1) | RU2434854C2 (enExample) |
| WO (1) | WO2007080081A2 (enExample) |
| ZA (1) | ZA200805967B (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050187418A1 (en) | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
| US20050187098A1 (en) | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
| US20070043181A1 (en) | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
| US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US7384886B2 (en) | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| EP2222724A1 (en) * | 2007-12-21 | 2010-09-01 | Basell Polyolefine GmbH | Catalyst sytem for olefin polymerization comprising phenantroline-comprising iron complexes |
| US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
| ATE535552T1 (de) * | 2007-12-21 | 2011-12-15 | Basell Polyolefine Gmbh | Phenantrolinhaltige komplexe |
| CN101391979B (zh) * | 2008-10-24 | 2011-08-31 | 中南民族大学 | 含卤素的不对称吡啶双亚胺类铁和钴配合物、制备方法及用途 |
| WO2012152857A1 (en) * | 2011-05-12 | 2012-11-15 | Basell Polyolefine Gmbh | Process for the manufacture of a mixed catalyst system for the copolymerization of ethylene with c1-c12 alpha-olefins |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| RU2758673C2 (ru) * | 2016-09-23 | 2021-11-01 | Чайна Петролеум Энд Кемикал Корпорейшн | Компонент катализатора для полимеризации олефина, катализатор и их применение |
| US10927204B2 (en) | 2017-11-14 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Iron tridentate carbene single site catalysts |
| RU2672868C1 (ru) * | 2017-12-07 | 2018-11-20 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ получения производных 2,6-бис[1-(фенилимино)этил]пиридина с электроноакцепторными заместителями |
| CN107855134B (zh) * | 2017-12-11 | 2020-08-07 | 中国科学院理化技术研究所 | 一种不对称亚胺-吡啶-钴类金属催化剂及其制备方法和应用 |
| CN110092744B (zh) * | 2018-01-29 | 2023-04-18 | 中国科学院化学研究所 | 一类高热稳定的含叔丁基不对称二亚胺吡啶配合物、其制备方法及应用 |
| CN109718855A (zh) * | 2018-12-22 | 2019-05-07 | 中国科学院山西煤炭化学研究所 | 一种封装金属配合物于材料表面的方法 |
| CN111961090B (zh) * | 2019-05-20 | 2021-10-22 | 中国科学院化学研究所 | 一类含大位阻取代基的不对称吡啶亚胺配合物、其制备方法及应用 |
| CN112851711B (zh) * | 2019-11-27 | 2022-04-08 | 中国科学院化学研究所 | 吡啶二亚胺铬配合物及其制备方法和用于制备聚烯烃的用途 |
| WO2021126692A1 (en) | 2019-12-16 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Iron bis(imino) aryl catalysts and methods thereof |
| US11738334B2 (en) | 2020-08-11 | 2023-08-29 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and processes for use thereof |
| WO2022076216A1 (en) | 2020-10-08 | 2022-04-14 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and processes for use thereof |
| EP4493567A1 (en) | 2022-03-14 | 2025-01-22 | ExxonMobil Chemical Patents Inc. | Metal bis(imino) aryl compounds and methods thereof |
| EP4493598A1 (en) | 2022-03-14 | 2025-01-22 | ExxonMobil Chemical Patents Inc. | Metal-containing bis(imino) per-substituted aryl compounds and methods thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998027124A1 (en) * | 1996-12-17 | 1998-06-25 | E.I. Du Pont De Nemours And Company | Polymerization of ethylene with specific iron or cobalt complexes, novel pyridinebis(imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| CN1322717A (zh) * | 2001-01-21 | 2001-11-21 | 中国科学院上海有机化学研究所 | 卤代苯基吡啶基双亚胺后过渡金属配合物、合成方法及用途 |
| CN1398257A (zh) * | 2000-02-09 | 2003-02-19 | 国际壳牌研究有限公司 | 用于乙烯低聚反应生成直链α-烯烃的非对称配体及其催化剂体系 |
| CN1440311A (zh) * | 2000-06-30 | 2003-09-03 | 国际壳牌研究有限公司 | 乙烯低聚生成线型α烯烃的配体及其催化剂体系 |
| CN1468205A (zh) * | 2000-10-03 | 2004-01-14 | ���ʿ����о�����˾ | 乙烯与α-烯烃的共低聚方法 |
| WO2005097712A2 (en) * | 2004-04-08 | 2005-10-20 | Basell Polyolefine Gmbh | Process for preparing diimine compounds |
Family Cites Families (68)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3242150A (en) | 1960-03-31 | 1966-03-22 | Phillips Petroleum Co | Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone |
| US3125547A (en) | 1961-02-09 | 1964-03-17 | Extrudable composition consisting of | |
| US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
| US4438238A (en) | 1981-01-30 | 1984-03-20 | Sumitomo Chemical Company, Limited | Low density copolymer composition of two ethylene-α-olefin copolymers |
| US4461873A (en) | 1982-06-22 | 1984-07-24 | Phillips Petroleum Company | Ethylene polymer blends |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US7163907B1 (en) | 1987-01-30 | 2007-01-16 | Exxonmobil Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5382630A (en) | 1988-09-30 | 1995-01-17 | Exxon Chemical Patents Inc. | Linear ethylene interpolymer blends of interpolymers having narrow molecular weight and composition distribution |
| NZ235032A (en) | 1989-08-31 | 1993-04-28 | Dow Chemical Co | Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component |
| ATE186918T1 (de) | 1990-01-02 | 1999-12-15 | Exxon Chemical Patents Inc | Ionische metallocenkatalysatoren auf träger für olefinpolymerisation |
| KR930006090A (ko) | 1991-09-18 | 1993-04-20 | 제이 이이 휘립프스 | 에틸렌 중합체 조성물 |
| KR930006089A (ko) | 1991-09-18 | 1993-04-20 | 제이 이이 휘립프스 | 폴리에틸렌 블렌드 |
| KR930006091A (ko) | 1991-09-18 | 1993-04-20 | 제이 이이 휘립프스 | 폴리에틸렌 블렌드 및 그로부터 제조된 필름, 병 또는 파이프 |
| CA2078366A1 (en) | 1991-09-18 | 1993-03-19 | Joel L. Martin | Polyethylene blends |
| TW309523B (enExample) | 1991-11-30 | 1997-07-01 | Hoechst Ag | |
| US5530065A (en) | 1992-01-07 | 1996-06-25 | Exxon Chemical Patents Inc. | Heat sealable films and articles made therefrom |
| TW294669B (enExample) | 1992-06-27 | 1997-01-01 | Hoechst Ag | |
| ES2096949T3 (es) | 1992-10-02 | 1997-03-16 | Du Pont | Pelicula retractil mejorada y procedimientos relacionados con la misma. |
| US5372980A (en) | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
| US5350807A (en) | 1993-06-25 | 1994-09-27 | Phillips Petroleum Company | Ethylene polymers |
| DE69426936T3 (de) | 1993-10-21 | 2006-07-27 | Exxonmobil Oil Corp. | Polyolefinmischungen aus bimodaler molekulargewichstverteilung |
| FI945958L (fi) | 1993-12-21 | 1995-06-22 | Hoechst Ag | Menetelmä polyolefiinien valmistamiseksi |
| FI945959L (fi) | 1993-12-21 | 1995-06-22 | Hoechst Ag | Metalloseenejä ja niiden käyttö katalyytteinä |
| CN1145082A (zh) | 1994-03-31 | 1997-03-12 | 美孚石油公司 | Lldpe树脂掺混物 |
| ES2143636T3 (es) | 1994-06-24 | 2000-05-16 | Exxon Chemical Patents Inc | Sistemas de catalizadores de polimerizacion, su produccion y uso. |
| IT1275573B (it) | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| WO1997036937A1 (en) | 1996-03-29 | 1997-10-09 | The Dow Chemical Company | Metallocene cocatalyst |
| AU3961797A (en) | 1996-07-23 | 1998-02-10 | E.I. Du Pont De Nemours And Company | Polymerization processes for olefins |
| US6432862B1 (en) | 1996-12-17 | 2002-08-13 | E. I. Du Pont De Nemours And Company | Cobalt catalysts for the polymerization of olefins |
| US6423848B2 (en) | 1996-12-17 | 2002-07-23 | E. I. Du Pont De Nemours And Company | Tridentate ligand |
| EP0968158B1 (en) | 1997-03-07 | 2005-08-10 | Basell Polyolefine GmbH | Method of preparing substituted indanones, the substituted indanones and metallocenes prepared therefrom |
| DE19757563A1 (de) | 1997-03-07 | 1999-07-08 | Targor Gmbh | Geträgertes Katalysatorsystem, Verfahren zur Herstellung und seine Verwendung zur Polymerisation von Olefinen |
| DE19733017A1 (de) | 1997-07-31 | 1999-02-04 | Hoechst Ag | Chemische Verbindung |
| ID24448A (id) | 1997-09-05 | 2000-07-20 | Bp Chemical Ltd | Katalis-katalis polimerisasi |
| ID26574A (id) | 1998-03-12 | 2001-01-18 | Bp Chem Int Ltd | Katalis-katalis polimerisasi |
| CA2323457A1 (en) | 1998-03-12 | 1999-09-16 | Bp Chemicals Limited | Homopolymer of ethylene |
| DE19828271A1 (de) | 1998-06-25 | 1999-12-30 | Elenac Gmbh | Verfahren zur Herstellung eines geträgerten Katalysatorsystems |
| DE19833170A1 (de) | 1998-07-23 | 2000-01-27 | Targor Gmbh | Verfahren zur Herstellung eines metallhaltigen Trägerkatalysators oder einer Trägerkatalysatorkomponente durch Tränkung einer Trägersubstanz |
| WO2000020427A1 (en) | 1998-10-02 | 2000-04-13 | Bp Chemicals Limited | Polymerisation catalysts |
| US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
| US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
| US6160145A (en) | 1998-10-23 | 2000-12-12 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components |
| BR9915708B1 (pt) | 1998-11-25 | 2010-07-13 | processo para preparação de monoariloxi-metalocenos. | |
| CN100340568C (zh) | 1998-11-25 | 2007-10-03 | 塔戈尔股份有限公司 | 茂金属一卤化物 |
| GB9906296D0 (en) | 1999-03-18 | 1999-05-12 | Bp Chem Int Ltd | Polymerisation catalysts |
| US6365690B1 (en) | 1999-05-06 | 2002-04-02 | E. I. Du Pont De Nemours And Company | Polymerization of ethylene |
| CA2285723C (en) | 1999-10-07 | 2009-09-15 | Nova Chemicals Corporation | Multimodal polyolefin pipe |
| US6548442B1 (en) | 1999-12-03 | 2003-04-15 | Phillips Petroleum Company | Organometal compound catalyst |
| SG124236A1 (en) | 2000-03-30 | 2006-08-30 | Sumitomo Chemical Co | Prepolymerization catalyst for use in gas phase polymerization of olefins and process for producing the same |
| US6900153B2 (en) | 2001-03-28 | 2005-05-31 | E.I. Du Pont De Nemours And Company | Supported olefin polymerization catalysts |
| EP1430088B1 (de) * | 2001-09-14 | 2008-10-22 | Basell Polyolefine GmbH | Verfahren zur polymerisation von olefinen |
| AU2003264065A1 (en) * | 2002-08-22 | 2004-03-11 | Basell Polyolefine Gmbh | Monocyclopentadienyl complexes |
| DE60305715T2 (de) * | 2002-09-25 | 2007-05-31 | Shell Internationale Research Maatschappij B.V. | Katalysatorsysteme für die ethylen-oligomerisierung zu linearen alpha-olefinen |
| EP1403288A1 (en) | 2002-09-27 | 2004-03-31 | ATOFINA Research | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins |
| DE10317395A1 (de) | 2003-04-15 | 2004-11-04 | Basell Polyolefine Gmbh | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung |
| WO2005090371A1 (en) * | 2004-03-24 | 2005-09-29 | Shell Internationale Research Maatschappij B.V. | Transition metal complexes |
| US7674910B2 (en) | 2004-04-08 | 2010-03-09 | Basell Polyolefine Gmbh | Process for preparing diimine compounds |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| CN100372609C (zh) | 2005-04-22 | 2008-03-05 | 中国科学院化学研究所 | 一种用于乙烯齐聚和聚合的催化剂及制备方法和用途 |
| CN101287768A (zh) | 2005-10-14 | 2008-10-15 | 巴塞尔聚烯烃股份有限公司 | 担载在卤化镁上的杂化催化剂系统 |
| DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| US7795411B2 (en) * | 2006-10-05 | 2010-09-14 | Fred Hutchinson Cancer Research Center | Vectors for expressing in vivo biotinylated recombinant proteins |
| KR101523783B1 (ko) | 2007-03-06 | 2015-05-28 | 바젤 폴리올레핀 게엠베하 | 철 착물 및 중합 방법에서의 이의 용도 |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| ATE535552T1 (de) | 2007-12-21 | 2011-12-15 | Basell Polyolefine Gmbh | Phenantrolinhaltige komplexe |
-
2006
- 2006-01-13 DE DE102006001959A patent/DE102006001959A1/de not_active Withdrawn
-
2007
- 2007-01-08 CN CN200780003011.3A patent/CN101370778B/zh active Active
- 2007-01-08 JP JP2008549819A patent/JP5165587B2/ja active Active
- 2007-01-08 BR BRPI0706486A patent/BRPI0706486C8/pt active IP Right Grant
- 2007-01-08 RU RU2008133220/04A patent/RU2434854C2/ru active
- 2007-01-08 EP EP07702617.7A patent/EP1971577B1/en active Active
- 2007-01-08 AU AU2007204447A patent/AU2007204447A1/en not_active Abandoned
- 2007-01-08 WO PCT/EP2007/000096 patent/WO2007080081A2/en not_active Ceased
- 2007-01-08 KR KR1020087016982A patent/KR101373915B1/ko active Active
- 2007-01-08 US US12/087,554 patent/US8252875B2/en active Active
-
2008
- 2008-07-09 ZA ZA200805967A patent/ZA200805967B/xx unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998027124A1 (en) * | 1996-12-17 | 1998-06-25 | E.I. Du Pont De Nemours And Company | Polymerization of ethylene with specific iron or cobalt complexes, novel pyridinebis(imines) and novel complexes of pyridinebis(imines) with iron and cobalt |
| CN1398257A (zh) * | 2000-02-09 | 2003-02-19 | 国际壳牌研究有限公司 | 用于乙烯低聚反应生成直链α-烯烃的非对称配体及其催化剂体系 |
| CN1440311A (zh) * | 2000-06-30 | 2003-09-03 | 国际壳牌研究有限公司 | 乙烯低聚生成线型α烯烃的配体及其催化剂体系 |
| CN1468205A (zh) * | 2000-10-03 | 2004-01-14 | ���ʿ����о�����˾ | 乙烯与α-烯烃的共低聚方法 |
| CN1322717A (zh) * | 2001-01-21 | 2001-11-21 | 中国科学院上海有机化学研究所 | 卤代苯基吡啶基双亚胺后过渡金属配合物、合成方法及用途 |
| WO2005097712A2 (en) * | 2004-04-08 | 2005-10-20 | Basell Polyolefine Gmbh | Process for preparing diimine compounds |
Non-Patent Citations (4)
| Title |
|---|
| Fre´de´ric Pelascini, et al..Pyridine bis(imino) iron and cobalt complexes for ethylene polymerization: influence of the aryl imino substituents.《European Polymer Journal》.2005,第41卷第1288-1295页. * |
| Miguel A. Esteruelas, et al..Preparation, Structure, and Ethylene Polymerization Behavior of Bis(imino)pyridyl Chromium(III) Complexes.《Organometallics》.2003,第22卷(第3期),第395-406页. * |
| S. K. Thabet, et al..2,2"-[2,6-Pyridinediylbis( methylidynenitrilo)]diphenol: A Highly Selective Reagent for the Detection of U(VI), Sb(lll), and Bi(lll).《ANALYTICAL CHEMISTRY》.1975,第47卷(第11期),第1870-1871页. * |
| Yaofeng Chen, et al..Halogen-Substituted 2,6-Bis(imino)pyridyl Iron and Cobalt Complexes: Highly Active Catalysts for Polymerization and Oligomerization of Ethylene.《Organometallics》.2003,第22卷(第21期),第4312-4321页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5165587B2 (ja) | 2013-03-21 |
| WO2007080081A2 (en) | 2007-07-19 |
| US20090054609A1 (en) | 2009-02-26 |
| BRPI0706486C8 (pt) | 2019-08-13 |
| WO2007080081A3 (en) | 2007-08-30 |
| AU2007204447A1 (en) | 2007-07-19 |
| US8252875B2 (en) | 2012-08-28 |
| EP1971577A2 (en) | 2008-09-24 |
| EP1971577B1 (en) | 2014-11-26 |
| DE102006001959A1 (de) | 2007-07-19 |
| KR20080083316A (ko) | 2008-09-17 |
| RU2008133220A (ru) | 2010-02-20 |
| JP2009523146A (ja) | 2009-06-18 |
| CN101370778A (zh) | 2009-02-18 |
| ZA200805967B (en) | 2009-04-29 |
| BRPI0706486A2 (pt) | 2011-03-29 |
| BRPI0706486B1 (pt) | 2019-03-19 |
| RU2434854C2 (ru) | 2011-11-27 |
| KR101373915B1 (ko) | 2014-03-14 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101370778B (zh) | 制备单亚胺化合物的方法、不对称铁络合物及催化剂体系 | |
| US20100267910A1 (en) | Catalyst system for olefin polymerization comprising phenanthroline-comprising iron complexes | |
| CN101652178B (zh) | 铁络合物及其在聚合方法中的用途 | |
| EP2222722B1 (en) | Phenantroline-comprising complexes | |
| JP2006516668A (ja) | 重合触媒、有機遷移金属化合物、ポリオレフィンの製造方法及びポリオレフィン | |
| JP2006511679A (ja) | エチレンとα−オレフィンのコポリマー | |
| KR20050084392A (ko) | 모노시클로펜타디에닐 착물 | |
| US6653417B2 (en) | Catalyst precursor and olefin polymerization processes | |
| EP1697428B1 (en) | Catalyst system for olefin polymerization | |
| CN102015784A (zh) | 聚乙烯及制备其的方法和催化剂组合物 | |
| JP6867761B2 (ja) | 金属錯体およびその製造方法、当該金属錯体を含むオレフィン重合用触媒成分およびオレフィン重合用触媒、並びに、当該オレフィン重合用触媒を用いたα−オレフィン重合体の製造方法 | |
| JP2009518291A (ja) | 遷移金属化合物、リガンド系、触媒系、及びポリオレフィンの製造方法 | |
| US8247587B2 (en) | Mono-hydroindacenyl complexes | |
| JP2006528951A (ja) | 三座の窒素含有リガンドを有する遷移金属錯体 | |
| WO2005042592A1 (en) | Ethylene polymerization employing bis-imino pyridinyl transition metal catalyst components | |
| CN102227452B (zh) | 乙烯聚合的方法和具有宽的分子量分布和长支链的乙烯聚合物 | |
| JP2023146093A (ja) | 化合物、金属錯体、金属錯体の製造方法、オレフィン重合用触媒、及び(共)重合体の製造方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |