BRPI0706486C8 - processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas - Google Patents
processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinasInfo
- Publication number
- BRPI0706486C8 BRPI0706486C8 BRPI0706486A BRPI0706486A BRPI0706486C8 BR PI0706486 C8 BRPI0706486 C8 BR PI0706486C8 BR PI0706486 A BRPI0706486 A BR PI0706486A BR PI0706486 A BRPI0706486 A BR PI0706486A BR PI0706486 C8 BRPI0706486 C8 BR PI0706486C8
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- catalyst system
- compounds
- compound
- polyolefins
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 4
- 150000004698 iron complex Chemical class 0.000 title abstract 2
- 229920000098 polyolefin Polymers 0.000 title abstract 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 abstract 2
- 125000001931 aliphatic group Chemical group 0.000 abstract 1
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000003849 aromatic solvent Substances 0.000 abstract 1
- -1 dicarbonyl compound Chemical class 0.000 abstract 1
- 125000001841 imino group Chemical group [H]N=* 0.000 abstract 1
- 150000002505 iron Chemical class 0.000 abstract 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract 1
- 238000006116 polymerization reaction Methods 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/26—Radicals substituted by halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/44—Radicals substituted by doubly-bound oxygen, sulfur, or nitrogen atoms, or by two such atoms singly-bound to the same carbon atom
- C07D213/53—Nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
- B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/84—Metals of the iron group
- B01J2531/842—Iron
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Pyridine Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE102006001959A DE102006001959A1 (de) | 2006-01-13 | 2006-01-13 | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| DE102006001959.8 | 2006-01-13 | ||
| US81101306P | 2006-06-05 | 2006-06-05 | |
| US60/811,013 | 2006-06-05 | ||
| PCT/EP2007/000096 WO2007080081A2 (en) | 2006-01-13 | 2007-01-08 | Process for the preparation of unsymmetric bis(imino) compounds |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0706486A2 BRPI0706486A2 (pt) | 2011-03-29 |
| BRPI0706486B1 BRPI0706486B1 (pt) | 2019-03-19 |
| BRPI0706486C8 true BRPI0706486C8 (pt) | 2019-08-13 |
Family
ID=38190018
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0706486A BRPI0706486C8 (pt) | 2006-01-13 | 2007-01-08 | processo para a preparação de compostos, composto, complexo de ferro não simétrico, sistema catalisador, uso de um sistema catalisador, e, processo para a preparação de poliolefinas |
Country Status (11)
| Country | Link |
|---|---|
| US (1) | US8252875B2 (enExample) |
| EP (1) | EP1971577B1 (enExample) |
| JP (1) | JP5165587B2 (enExample) |
| KR (1) | KR101373915B1 (enExample) |
| CN (1) | CN101370778B (enExample) |
| AU (1) | AU2007204447A1 (enExample) |
| BR (1) | BRPI0706486C8 (enExample) |
| DE (1) | DE102006001959A1 (enExample) |
| RU (1) | RU2434854C2 (enExample) |
| WO (1) | WO2007080081A2 (enExample) |
| ZA (1) | ZA200805967B (enExample) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050187418A1 (en) | 2004-02-19 | 2005-08-25 | Small Brooke L. | Olefin oligomerization |
| US9550841B2 (en) | 2004-02-20 | 2017-01-24 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US7384886B2 (en) | 2004-02-20 | 2008-06-10 | Chevron Phillips Chemical Company Lp | Methods of preparation of an olefin oligomerization catalyst |
| US20050187098A1 (en) | 2004-02-20 | 2005-08-25 | Knudsen Ronald D. | Methods of preparation of an olefin oligomerization catalyst |
| US20070043181A1 (en) | 2005-08-19 | 2007-02-22 | Knudsen Ronald D | Methods of preparation of an olefin oligomerization catalyst |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| US7271121B2 (en) | 2005-07-21 | 2007-09-18 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7268096B2 (en) | 2005-07-21 | 2007-09-11 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and methods of using in oligomerization and polymerization |
| US7727926B2 (en) | 2005-07-21 | 2010-06-01 | Chevron Phillips Chemical Company Lp | Diimine metal complexes, methods of synthesis, and method of using in oligomerization and polymerization |
| DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| US7902415B2 (en) | 2007-12-21 | 2011-03-08 | Chevron Phillips Chemical Company Lp | Processes for dimerizing or isomerizing olefins |
| US20100234548A1 (en) * | 2007-12-21 | 2010-09-16 | Basell Polyolefine Gmbh | Phenanthroline-comprising complexes |
| CN101952329A (zh) * | 2007-12-21 | 2011-01-19 | 巴塞尔聚烯烃股份有限公司 | 包括含菲咯啉的铁络合物的烯烃聚合催化剂体系 |
| CN101391979B (zh) * | 2008-10-24 | 2011-08-31 | 中南民族大学 | 含卤素的不对称吡啶双亚胺类铁和钴配合物、制备方法及用途 |
| WO2012152857A1 (en) * | 2011-05-12 | 2012-11-15 | Basell Polyolefine Gmbh | Process for the manufacture of a mixed catalyst system for the copolymerization of ethylene with c1-c12 alpha-olefins |
| US9586872B2 (en) | 2011-12-30 | 2017-03-07 | Chevron Phillips Chemical Company Lp | Olefin oligomerization methods |
| US9944661B2 (en) | 2016-08-09 | 2018-04-17 | Chevron Phillips Chemical Company Lp | Olefin hydroboration |
| FI3517553T3 (fi) * | 2016-09-23 | 2024-02-02 | China Petroleum & Chem Corp | Katalyyttikomponentti käytettäväksi olefiinin polymeroinnissa, katalyytti, ja niiden käyttö |
| US10927204B2 (en) | 2017-11-14 | 2021-02-23 | Exxonmobil Chemical Patents Inc. | Iron tridentate carbene single site catalysts |
| RU2672868C1 (ru) * | 2017-12-07 | 2018-11-20 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук (ИК СО РАН) | Способ получения производных 2,6-бис[1-(фенилимино)этил]пиридина с электроноакцепторными заместителями |
| CN107855134B (zh) * | 2017-12-11 | 2020-08-07 | 中国科学院理化技术研究所 | 一种不对称亚胺-吡啶-钴类金属催化剂及其制备方法和应用 |
| CN110092744B (zh) * | 2018-01-29 | 2023-04-18 | 中国科学院化学研究所 | 一类高热稳定的含叔丁基不对称二亚胺吡啶配合物、其制备方法及应用 |
| CN109718855A (zh) * | 2018-12-22 | 2019-05-07 | 中国科学院山西煤炭化学研究所 | 一种封装金属配合物于材料表面的方法 |
| CN111961090B (zh) * | 2019-05-20 | 2021-10-22 | 中国科学院化学研究所 | 一类含大位阻取代基的不对称吡啶亚胺配合物、其制备方法及应用 |
| CN112851711B (zh) * | 2019-11-27 | 2022-04-08 | 中国科学院化学研究所 | 吡啶二亚胺铬配合物及其制备方法和用于制备聚烯烃的用途 |
| WO2021126692A1 (en) | 2019-12-16 | 2021-06-24 | Exxonmobil Chemical Patents Inc. | Iron bis(imino) aryl catalysts and methods thereof |
| US11738334B2 (en) | 2020-08-11 | 2023-08-29 | Exxonmobil Chemical Patents Inc. | Supported catalyst systems and processes for use thereof |
| US20230322972A1 (en) | 2020-10-08 | 2023-10-12 | Exxonmobil Chemical Patents Inc. | Supported Catalyst Systems and Processes for Use Thereof |
| WO2023177957A1 (en) | 2022-03-14 | 2023-09-21 | Exxonmobil Chemical Patents Inc. | Metal-containing bis(imino) per-substituted aryl compounds and methods thereof |
| WO2023177956A1 (en) | 2022-03-14 | 2023-09-21 | Exxonmobil Chemical Patents Inc. | Metal bis(imino) aryl compounds and methods thereof |
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| KR930006089A (ko) | 1991-09-18 | 1993-04-20 | 제이 이이 휘립프스 | 폴리에틸렌 블렌드 |
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| US5372980A (en) | 1993-06-03 | 1994-12-13 | Polysar | Bimetallic metallocene alumoxane catalyst system and its use in the preparation of ethylene-alpha olefin and ethylene-alpha olefin-non-conjugated diolefin elastomers |
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| JP3400988B2 (ja) | 1997-09-05 | 2003-04-28 | ビーピー ケミカルズ リミテッド | 重合触媒 |
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| DE19828271A1 (de) | 1998-06-25 | 1999-12-30 | Elenac Gmbh | Verfahren zur Herstellung eines geträgerten Katalysatorsystems |
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| US6812182B2 (en) | 1998-10-23 | 2004-11-02 | Albemarle Corporation | Compositions formed from hydroxyaluminoxane and their use as catalyst components |
| US6160145A (en) | 1998-10-23 | 2000-12-12 | Albemarle Corporation | Transition metal compounds having conjugate aluminoxate anions and their use as catalyst components |
| US6492292B2 (en) | 1998-10-23 | 2002-12-10 | Albemarle Corporation | Gelatinous compositions formed from hydroxyaluminoxane, solid compositions formed therefrom, and the use of such compositions as catalyst components |
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| WO2000031091A1 (de) | 1998-11-25 | 2000-06-02 | Basell Polypropylen Gmbh | Verfahren zur herstellung von monoaryloxy-ansa-metallocenen |
| GB9906296D0 (en) | 1999-03-18 | 1999-05-12 | Bp Chem Int Ltd | Polymerisation catalysts |
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| GC0000291A (en) * | 2000-06-30 | 2006-11-01 | Shell Int Research | Ligands and catalyst systems thereof for ethylene oligomerisation to linear alpha olefins |
| US7037988B2 (en) * | 2000-10-03 | 2006-05-02 | Shell Oil Company | Process for the co-oligomerisation of ethylene and alpha olefins |
| CN1139574C (zh) * | 2001-01-21 | 2004-02-25 | 中国科学院上海有机化学研究所 | 卤代苯基吡啶基双亚胺后过渡金属配合物、合成方法及用途 |
| US6900153B2 (en) | 2001-03-28 | 2005-05-31 | E.I. Du Pont De Nemours And Company | Supported olefin polymerization catalysts |
| BR0212317A (pt) * | 2001-09-14 | 2004-09-21 | Basell Polyolefine Gmbh | Processo para a polimerização de olefinas na presença de um sistema de catalisador, uso do mesmo, e, polìmero |
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| EP1403288A1 (en) | 2002-09-27 | 2004-03-31 | ATOFINA Research | Dual site catalyst system comprising a hafnocene component for the production of bimodal polyolefins |
| DE10317395A1 (de) | 2003-04-15 | 2004-11-04 | Basell Polyolefine Gmbh | Katalysatorsysteme vom Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung |
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| US7674910B2 (en) | 2004-04-08 | 2010-03-09 | Basell Polyolefine Gmbh | Process for preparing diimine compounds |
| DE102004020524A1 (de) | 2004-04-26 | 2005-11-10 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung zu dessen Herstellung |
| CN100372609C (zh) | 2005-04-22 | 2008-03-05 | 中国科学院化学研究所 | 一种用于乙烯齐聚和聚合的催化剂及制备方法和用途 |
| BRPI0617253A2 (pt) | 2005-10-14 | 2016-04-19 | Basell Polyolefine Gmbh | sistemas catalisadores híbridos suportados sobre halogeneto de magnésio |
| DE102006001959A1 (de) | 2006-01-13 | 2007-07-19 | Basell Polyolefine Gmbh | Verfahren zur Herstellung von unsymmetrischen Bis(imino)verbindungen |
| US7795411B2 (en) * | 2006-10-05 | 2010-09-14 | Fred Hutchinson Cancer Research Center | Vectors for expressing in vivo biotinylated recombinant proteins |
| RU2009136679A (ru) | 2007-03-06 | 2011-04-20 | Базелль Полиолефине Гмбх (De) | Комплексы железа и их применение в способах полимеризации |
| DE102007017903A1 (de) | 2007-04-13 | 2008-10-16 | Basell Polyolefine Gmbh | Polyethylen und Katalysatorzusammensetzung und Verfahren zu dessen Herstellung |
| US20100234548A1 (en) | 2007-12-21 | 2010-09-16 | Basell Polyolefine Gmbh | Phenanthroline-comprising complexes |
-
2006
- 2006-01-13 DE DE102006001959A patent/DE102006001959A1/de not_active Withdrawn
-
2007
- 2007-01-08 WO PCT/EP2007/000096 patent/WO2007080081A2/en not_active Ceased
- 2007-01-08 EP EP07702617.7A patent/EP1971577B1/en active Active
- 2007-01-08 JP JP2008549819A patent/JP5165587B2/ja active Active
- 2007-01-08 AU AU2007204447A patent/AU2007204447A1/en not_active Abandoned
- 2007-01-08 KR KR1020087016982A patent/KR101373915B1/ko active Active
- 2007-01-08 BR BRPI0706486A patent/BRPI0706486C8/pt active IP Right Grant
- 2007-01-08 RU RU2008133220/04A patent/RU2434854C2/ru active
- 2007-01-08 CN CN200780003011.3A patent/CN101370778B/zh active Active
- 2007-01-08 US US12/087,554 patent/US8252875B2/en active Active
-
2008
- 2008-07-09 ZA ZA200805967A patent/ZA200805967B/xx unknown
Also Published As
| Publication number | Publication date |
|---|---|
| RU2008133220A (ru) | 2010-02-20 |
| CN101370778A (zh) | 2009-02-18 |
| KR20080083316A (ko) | 2008-09-17 |
| US20090054609A1 (en) | 2009-02-26 |
| EP1971577A2 (en) | 2008-09-24 |
| ZA200805967B (en) | 2009-04-29 |
| KR101373915B1 (ko) | 2014-03-14 |
| JP2009523146A (ja) | 2009-06-18 |
| BRPI0706486A2 (pt) | 2011-03-29 |
| EP1971577B1 (en) | 2014-11-26 |
| US8252875B2 (en) | 2012-08-28 |
| RU2434854C2 (ru) | 2011-11-27 |
| BRPI0706486B1 (pt) | 2019-03-19 |
| JP5165587B2 (ja) | 2013-03-21 |
| AU2007204447A1 (en) | 2007-07-19 |
| DE102006001959A1 (de) | 2007-07-19 |
| CN101370778B (zh) | 2014-10-22 |
| WO2007080081A2 (en) | 2007-07-19 |
| WO2007080081A3 (en) | 2007-08-30 |
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