BR112012014500A2 - método para aumentar o número de troca (ton) de um sistema de catalisador - Google Patents
método para aumentar o número de troca (ton) de um sistema de catalisadorInfo
- Publication number
- BR112012014500A2 BR112012014500A2 BR112012014500A BR112012014500A BR112012014500A2 BR 112012014500 A2 BR112012014500 A2 BR 112012014500A2 BR 112012014500 A BR112012014500 A BR 112012014500A BR 112012014500 A BR112012014500 A BR 112012014500A BR 112012014500 A2 BR112012014500 A2 BR 112012014500A2
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst system
- increasing
- atoms
- ton
- source
- Prior art date
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C47/00—Compounds having —CHO groups
- C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
- C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
- C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
''método para aumentar o número de troca (ton) de um sistema de catalisador''. um método para aumentar o ton de um sistema de catalisador para a monocarbonilação de compostos etilenicamente insaturados usando monóxido de carbono na presença de um co-reagente, outro que não a água ou uma fonte da mesma, tendo um átomo de hidrogênio móvel é descrito. o sistema de catalisador é obtenível pela combinação de: (a) um metal dos grupos (8,9) ou (10) ou um composto adequando do mesmo; (b) um ligante da fórmula geral (i) em que os grupos x^3^ e x^4^ independentemente representam radicais univalentes de até 30 átomos ou x^3^ e x^4^ juntos formam um radical bivalente de até 40 átomos e x^5^ tem até 400 átomos; q^1^ representa fósforo, arsênico ou antimônio; e c) opcionalmente, uma fonte de ânions. o método inclui a etapa de adicionar água ou uma fonte da mesma ao sistema de catalisador. o método é preferivelmente realizado na presença de um metal eletropositivo
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GBGB0921876.9A GB0921876D0 (en) | 2009-12-15 | 2009-12-15 | Improved carbonylation process |
PCT/GB2010/052093 WO2011073653A1 (en) | 2009-12-15 | 2010-12-15 | Improved carbonylation process |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112012014500A2 true BR112012014500A2 (pt) | 2016-08-16 |
Family
ID=41667109
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112012014500A BR112012014500A2 (pt) | 2009-12-15 | 2010-12-15 | método para aumentar o número de troca (ton) de um sistema de catalisador |
Country Status (15)
Country | Link |
---|---|
US (1) | US20120309613A1 (pt) |
EP (1) | EP2512670A1 (pt) |
JP (2) | JP2013513653A (pt) |
KR (1) | KR20120106974A (pt) |
CN (1) | CN102740972B (pt) |
AU (1) | AU2010332501B2 (pt) |
BR (1) | BR112012014500A2 (pt) |
CA (1) | CA2783586A1 (pt) |
EA (1) | EA024236B1 (pt) |
GB (1) | GB0921876D0 (pt) |
MX (1) | MX2012006967A (pt) |
SG (1) | SG181699A1 (pt) |
TW (1) | TWI508780B (pt) |
WO (1) | WO2011073653A1 (pt) |
ZA (1) | ZA201204316B (pt) |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
AR088124A1 (es) * | 2011-04-01 | 2014-05-14 | Dsm Ip Assets Bv | Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio |
GB201122054D0 (en) * | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
WO2013107902A1 (en) | 2012-01-20 | 2013-07-25 | Dsm Ip Assets B.V. | Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture |
CN114409541A (zh) * | 2020-10-28 | 2022-04-29 | 上海浦景化工技术股份有限公司 | 一种乙烯羰基化制丙酸酯类的系统 |
CN112480170B (zh) * | 2020-12-02 | 2023-03-14 | 中国海洋石油集团有限公司 | 一种双膦化合物、包含其的催化剂体系及其应用 |
Family Cites Families (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0055875B1 (en) | 1981-01-06 | 1986-08-20 | Shell Internationale Researchmaatschappij B.V. | Process for the carbonylation of olefins |
CA1231346A (en) | 1982-09-30 | 1988-01-12 | Eit Drent | Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst |
GB8531624D0 (en) | 1985-12-23 | 1986-02-05 | Shell Int Research | Carbonylation of ethylenically unsaturated compounds |
JPH0678269B2 (ja) * | 1986-01-09 | 1994-10-05 | 三菱化成株式会社 | オレフイン類のカルボニル化法 |
GB8605034D0 (en) | 1986-02-28 | 1986-04-09 | Shell Int Research | Carbonylation of compounds |
KR880007426A (ko) | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
GB8705699D0 (en) | 1987-03-11 | 1987-04-15 | Shell Int Research | Carbonylation of olefinically unsaturated compounds |
KR0144567B1 (ko) | 1989-03-03 | 1998-07-15 | 오노 알버어스 | 카르보닐화촉매시스템 |
CA2034971A1 (en) | 1990-02-05 | 1991-08-06 | Eit Drent | Carbonylation catalyst system |
FI91135C (fi) | 1990-03-19 | 1994-05-25 | Valmet Paper Machinery Inc | Menetelmä reikien poraamiseksi paperikoneen sylinterin vaippaan ja menetelmässä käytetty laitteisto |
CA2055628A1 (en) | 1990-12-03 | 1992-06-04 | Eit Drent | Carbonylation process and catalyst composition |
EP0495547B1 (en) | 1991-01-15 | 1996-04-24 | Shell Internationale Researchmaatschappij B.V. | Carbonylation of olefins |
DE69204691T2 (de) | 1991-01-15 | 1996-04-11 | Shell Int Research | Verfahren zur Karbonylierung von Olefin. |
ES2054519T3 (es) | 1991-02-15 | 1994-08-01 | Shell Int Research | Sistema de catalizador de carbonilacion. |
GB9425911D0 (en) | 1994-12-22 | 1995-02-22 | Ici Plc | Process for the carbonylation of olefins and catalyst system for use therein |
US5618983A (en) * | 1995-08-25 | 1997-04-08 | E. I. Du Pont De Nemours And Company | Hydroformylation process |
GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
US6156934A (en) | 1997-03-26 | 2000-12-05 | Shell Oil Company | Diphosphines |
TW524801B (en) | 1999-03-22 | 2003-03-21 | Shell Int Research | Process for the carbonylation of conjugated dienes |
MY127358A (en) | 2000-03-14 | 2006-11-30 | Shell Int Research | Process for the carbonylation of ethylenically unsaturated compounds |
DE10048874A1 (de) | 2000-09-29 | 2002-04-11 | Basf Ag | Katalysatorsystem und Verfahren zur Carbonylierung |
DE10228293A1 (de) | 2001-07-28 | 2003-02-13 | Basf Ag | Verfahren zur Herstellung von Dialkylketonen |
WO2003070370A1 (en) | 2002-02-19 | 2003-08-28 | Shell Internationale Research Maatschappij B.V. | Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore |
KR100924521B1 (ko) | 2002-09-12 | 2009-11-02 | 루싸이트 인터내셔날 유케이 리미티드 | 촉매 시스템 |
KR20060015274A (ko) | 2003-05-22 | 2006-02-16 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 공액 디엔의 카르보닐화 방법 |
WO2005003070A1 (en) * | 2003-07-03 | 2005-01-13 | Lucite International Uk Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
US7084291B2 (en) * | 2003-10-15 | 2006-08-01 | General Electric Company | Water resistant catalyst for the production of diaryl carbonates via the direct carbonylation of phenolic compounds |
EP1735263A1 (en) | 2004-02-26 | 2006-12-27 | Shell Internationale Researchmaatschappij B.V. | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds |
GB0516556D0 (en) * | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
CA2671409C (en) * | 2006-12-02 | 2016-07-26 | Lucite International Uk Limited | Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds |
GB0625518D0 (en) * | 2006-12-21 | 2007-01-31 | Lucite Int Uk Ltd | Carbonylation of conjugated dienes |
GB0713624D0 (en) * | 2007-07-13 | 2007-08-22 | Lucite Int Uk Ltd | Improved solvent for catalyst system |
US20120309613A1 (en) * | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
-
2009
- 2009-12-15 US US13/516,176 patent/US20120309613A1/en not_active Abandoned
- 2009-12-15 GB GBGB0921876.9A patent/GB0921876D0/en not_active Ceased
-
2010
- 2010-12-15 SG SG2012043840A patent/SG181699A1/en unknown
- 2010-12-15 CA CA2783586A patent/CA2783586A1/en not_active Abandoned
- 2010-12-15 WO PCT/GB2010/052093 patent/WO2011073653A1/en active Application Filing
- 2010-12-15 MX MX2012006967A patent/MX2012006967A/es not_active Application Discontinuation
- 2010-12-15 CN CN201080062848.7A patent/CN102740972B/zh not_active Expired - Fee Related
- 2010-12-15 KR KR1020127018429A patent/KR20120106974A/ko not_active Application Discontinuation
- 2010-12-15 TW TW099144089A patent/TWI508780B/zh not_active IP Right Cessation
- 2010-12-15 BR BR112012014500A patent/BR112012014500A2/pt not_active IP Right Cessation
- 2010-12-15 JP JP2012543906A patent/JP2013513653A/ja active Pending
- 2010-12-15 EA EA201290514A patent/EA024236B1/ru not_active IP Right Cessation
- 2010-12-15 AU AU2010332501A patent/AU2010332501B2/en not_active Ceased
- 2010-12-15 EP EP10795448A patent/EP2512670A1/en not_active Withdrawn
-
2012
- 2012-06-12 ZA ZA2012/04316A patent/ZA201204316B/en unknown
-
2015
- 2015-06-03 JP JP2015113273A patent/JP2015214551A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
GB0921876D0 (en) | 2010-01-27 |
TWI508780B (zh) | 2015-11-21 |
JP2015214551A (ja) | 2015-12-03 |
EA201290514A1 (ru) | 2013-01-30 |
CN102740972A (zh) | 2012-10-17 |
JP2013513653A (ja) | 2013-04-22 |
SG181699A1 (en) | 2012-07-30 |
ZA201204316B (en) | 2013-02-27 |
AU2010332501A2 (en) | 2012-08-02 |
EP2512670A1 (en) | 2012-10-24 |
TW201143889A (en) | 2011-12-16 |
AU2010332501A1 (en) | 2012-07-26 |
CN102740972B (zh) | 2015-02-11 |
EA024236B1 (ru) | 2016-08-31 |
WO2011073653A1 (en) | 2011-06-23 |
AU2010332501B2 (en) | 2014-10-30 |
US20120309613A1 (en) | 2012-12-06 |
KR20120106974A (ko) | 2012-09-27 |
MX2012006967A (es) | 2012-07-17 |
CA2783586A1 (en) | 2011-06-23 |
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Legal Events
Date | Code | Title | Description |
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B08F | Application fees: application dismissed [chapter 8.6 patent gazette] | ||
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] | ||
B350 | Update of information on the portal [chapter 15.35 patent gazette] |