EA201290514A1 - Улучшенный способ карбонилирования - Google Patents

Улучшенный способ карбонилирования

Info

Publication number
EA201290514A1
EA201290514A1 EA201290514A EA201290514A EA201290514A1 EA 201290514 A1 EA201290514 A1 EA 201290514A1 EA 201290514 A EA201290514 A EA 201290514A EA 201290514 A EA201290514 A EA 201290514A EA 201290514 A1 EA201290514 A1 EA 201290514A1
Authority
EA
Eurasian Patent Office
Prior art keywords
atoms
source
catalyst system
groups
carbonylate
Prior art date
Application number
EA201290514A
Other languages
English (en)
Other versions
EA024236B1 (ru
Inventor
Грэхам Рональд Истхэм
Филип Ян Ричардс
Original Assignee
ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД filed Critical ЛУСАЙТ ИНТЕРНЭШНЛ ЮКей ЛИМИТЕД
Publication of EA201290514A1 publication Critical patent/EA201290514A1/ru
Publication of EA024236B1 publication Critical patent/EA024236B1/ru

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Описывается способ увеличения значения TON системы катализатора монокарбонилирования этиленненасыщенных соединений при использовании монооксида углерода в присутствии сореагента, отличного от воды или ее источника и содержащего подвижный атом водорода. Система катализатора может быть получена в результате объединения: (а) металла из групп (8), (9) или (10) или его подходящего для использования соединения; (b) лиганда, описывающегося общей формулой (I), где группы Xи Xнезависимо представляют собой одновалентные радикалы, содержащие до 30 атомов, или Xи Xсовместно образуют двухвалентный радикал, содержащий до 40 атомов, а Xсодержит до 400 атомов; Qпредставляет собой атом фосфора, мышьяка или сурьмы; и с) необязательно источника анионов. Способ включает стадию добавления к системе катализатора воды или ее источника. Способ предпочтительно реализуют в присутствии электроположительного металла.
EA201290514A 2009-12-15 2010-12-15 Улучшенный способ карбонилирования EA024236B1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0921876.9A GB0921876D0 (en) 2009-12-15 2009-12-15 Improved carbonylation process
PCT/GB2010/052093 WO2011073653A1 (en) 2009-12-15 2010-12-15 Improved carbonylation process

Publications (2)

Publication Number Publication Date
EA201290514A1 true EA201290514A1 (ru) 2013-01-30
EA024236B1 EA024236B1 (ru) 2016-08-31

Family

ID=41667109

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201290514A EA024236B1 (ru) 2009-12-15 2010-12-15 Улучшенный способ карбонилирования

Country Status (15)

Country Link
US (1) US20120309613A1 (ru)
EP (1) EP2512670A1 (ru)
JP (2) JP2013513653A (ru)
KR (1) KR20120106974A (ru)
CN (1) CN102740972B (ru)
AU (1) AU2010332501B2 (ru)
BR (1) BR112012014500A2 (ru)
CA (1) CA2783586A1 (ru)
EA (1) EA024236B1 (ru)
GB (1) GB0921876D0 (ru)
MX (1) MX2012006967A (ru)
SG (1) SG181699A1 (ru)
TW (1) TWI508780B (ru)
WO (1) WO2011073653A1 (ru)
ZA (1) ZA201204316B (ru)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
AR088124A1 (es) * 2011-04-01 2014-05-14 Dsm Ip Assets Bv Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
CN114409541A (zh) * 2020-10-28 2022-04-29 上海浦景化工技术股份有限公司 一种乙烯羰基化制丙酸酯类的系统
CN112480170B (zh) * 2020-12-02 2023-03-14 中国海洋石油集团有限公司 一种双膦化合物、包含其的催化剂体系及其应用

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3175174D1 (en) 1981-01-06 1986-09-25 Shell Int Research Process for the carbonylation of olefins
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
GB8531624D0 (en) 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
JPH0678269B2 (ja) * 1986-01-09 1994-10-05 三菱化成株式会社 オレフイン類のカルボニル化法
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
KR880007426A (ko) 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
US5158921A (en) 1989-03-03 1992-10-27 Shell Oil Company Carbonylation catalyst and process
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
FI91135C (fi) 1990-03-19 1994-05-25 Valmet Paper Machinery Inc Menetelmä reikien poraamiseksi paperikoneen sylinterin vaippaan ja menetelmässä käytetty laitteisto
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
EP0495547B1 (en) 1991-01-15 1996-04-24 Shell Internationale Researchmaatschappij B.V. Carbonylation of olefins
DE69204691T2 (de) 1991-01-15 1996-04-11 Shell Int Research Verfahren zur Karbonylierung von Olefin.
KR100230139B1 (ko) 1991-02-15 1999-11-15 오노 알버어스 카르보닐화 촉매 시스템
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US5618983A (en) * 1995-08-25 1997-04-08 E. I. Du Pont De Nemours And Company Hydroformylation process
GB9705699D0 (en) * 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
TW524801B (en) 1999-03-22 2003-03-21 Shell Int Research Process for the carbonylation of conjugated dienes
MY127358A (en) 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10228293A1 (de) 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
CA2476736C (en) 2002-02-19 2012-06-05 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
ES2429871T3 (es) 2002-09-12 2013-11-18 Lucite International Uk Limited Un sistema catalizador que comprende un ligando de 1,2-bis-(fosfin)metaloceno
CA2526348A1 (en) 2003-05-22 2004-12-02 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of a conjugated diene
JP2007516197A (ja) * 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
US7084291B2 (en) * 2003-10-15 2006-08-01 General Electric Company Water resistant catalyst for the production of diaryl carbonates via the direct carbonylation of phenolic compounds
WO2005082830A1 (en) 2004-02-26 2005-09-09 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of ethylenically or acetylenically unsaturated compounds
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
WO2008065448A1 (en) * 2006-12-02 2008-06-05 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
GB0713624D0 (en) * 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process

Also Published As

Publication number Publication date
GB0921876D0 (en) 2010-01-27
ZA201204316B (en) 2013-02-27
EP2512670A1 (en) 2012-10-24
SG181699A1 (en) 2012-07-30
AU2010332501B2 (en) 2014-10-30
MX2012006967A (es) 2012-07-17
WO2011073653A1 (en) 2011-06-23
CN102740972A (zh) 2012-10-17
AU2010332501A1 (en) 2012-07-26
EA024236B1 (ru) 2016-08-31
US20120309613A1 (en) 2012-12-06
AU2010332501A2 (en) 2012-08-02
KR20120106974A (ko) 2012-09-27
CA2783586A1 (en) 2011-06-23
CN102740972B (zh) 2015-02-11
BR112012014500A2 (pt) 2016-08-16
JP2013513653A (ja) 2013-04-22
TW201143889A (en) 2011-12-16
JP2015214551A (ja) 2015-12-03
TWI508780B (zh) 2015-11-21

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Legal Events

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MM4A Lapse of a eurasian patent due to non-payment of renewal fees within the time limit in the following designated state(s)

Designated state(s): AM AZ BY KZ KG MD TJ TM RU