MX2012006967A - Proceso mejorado de carbonizacion. - Google Patents

Proceso mejorado de carbonizacion.

Info

Publication number
MX2012006967A
MX2012006967A MX2012006967A MX2012006967A MX2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A MX 2012006967 A MX2012006967 A MX 2012006967A
Authority
MX
Mexico
Prior art keywords
atoms
source
catalyst system
x3and
metal
Prior art date
Application number
MX2012006967A
Other languages
English (en)
Inventor
Graham Ronald Eastham
Philip Ian Richards
Original Assignee
Lucite Int Uk Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lucite Int Uk Ltd filed Critical Lucite Int Uk Ltd
Publication of MX2012006967A publication Critical patent/MX2012006967A/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00—Compounds having —CHO groups
    • C07C47/02—Saturated compounds having —CHO groups bound to acyclic carbon atoms or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C07C69/22—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety
    • C07C69/24—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen having three or more carbon atoms in the acid moiety esterified with monohydroxylic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/32—Addition reactions to C=C or C-C triple bonds
    • B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Se describe un método para incrementar el número de ciclos (TON) de un sistema de catalizadores para la monocarbonilación de compuestos etilénicamente insaturados con el uso de monóxido de carbono en presencia de un co-reactivo, aparte del agua o una fuente de la misma, que tiene un átomo de hidrógeno móvil. El sistema de catalizadores se obtiene al combinar: (a) un metal de grupo 8, 9 ó 10 o un compuesto adecuado del mismo; (b) un ligando de la fórmula general (I) (ver fórmula (I)) donde los grupos X3 y X4 representan por separado radicales univalentes de hasta 30 átomos o X3 y X4 forman juntos un radical bivalente de hasta 40 átomos y X5 tienen hasta 400 átomos; Q1 representa fósforo, arsénico o antimonio; y c) opcionalmente, una fuente de aniones.
MX2012006967A 2009-12-15 2010-12-15 Proceso mejorado de carbonizacion. MX2012006967A (es)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0921876.9A GB0921876D0 (en) 2009-12-15 2009-12-15 Improved carbonylation process
PCT/GB2010/052093 WO2011073653A1 (en) 2009-12-15 2010-12-15 Improved carbonylation process

Publications (1)

Publication Number Publication Date
MX2012006967A true MX2012006967A (es) 2012-07-17

Family

ID=41667109

Family Applications (1)

Application Number Title Priority Date Filing Date
MX2012006967A MX2012006967A (es) 2009-12-15 2010-12-15 Proceso mejorado de carbonizacion.

Country Status (15)

Country Link
US (1) US20120309613A1 (es)
EP (1) EP2512670A1 (es)
JP (2) JP2013513653A (es)
KR (1) KR20120106974A (es)
CN (1) CN102740972B (es)
AU (1) AU2010332501B2 (es)
BR (1) BR112012014500A2 (es)
CA (1) CA2783586A1 (es)
EA (1) EA024236B1 (es)
GB (1) GB0921876D0 (es)
MX (1) MX2012006967A (es)
SG (1) SG181699A1 (es)
TW (1) TWI508780B (es)
WO (1) WO2011073653A1 (es)
ZA (1) ZA201204316B (es)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
AR088124A1 (es) * 2011-04-01 2014-05-14 Dsm Ip Assets Bv Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio
GB201122054D0 (en) * 2011-12-21 2012-02-01 Lucite Int Uk Ltd A continuous process for the carbonylation of ethylene
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
CN114409541A (zh) * 2020-10-28 2022-04-29 上海浦景化工技术股份有限公司 一种乙烯羰基化制丙酸酯类的系统
CN112480170B (zh) * 2020-12-02 2023-03-14 中国海洋石油集团有限公司 一种双膦化合物、包含其的催化剂体系及其应用

Family Cites Families (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0055875B1 (en) 1981-01-06 1986-08-20 Shell Internationale Researchmaatschappij B.V. Process for the carbonylation of olefins
CA1231346A (en) 1982-09-30 1988-01-12 Eit Drent Process for the carbonylation of olefinically unsaturated compounds with a palladium catalyst
GB8531624D0 (en) 1985-12-23 1986-02-05 Shell Int Research Carbonylation of ethylenically unsaturated compounds
JPH0678269B2 (ja) * 1986-01-09 1994-10-05 三菱化成株式会社 オレフイン類のカルボニル化法
GB8605034D0 (en) 1986-02-28 1986-04-09 Shell Int Research Carbonylation of compounds
KR880007426A (ko) 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
GB8705699D0 (en) 1987-03-11 1987-04-15 Shell Int Research Carbonylation of olefinically unsaturated compounds
KR0144567B1 (ko) 1989-03-03 1998-07-15 오노 알버어스 카르보닐화촉매시스템
CA2034971A1 (en) 1990-02-05 1991-08-06 Eit Drent Carbonylation catalyst system
FI91135C (fi) 1990-03-19 1994-05-25 Valmet Paper Machinery Inc Menetelmä reikien poraamiseksi paperikoneen sylinterin vaippaan ja menetelmässä käytetty laitteisto
CA2055628A1 (en) 1990-12-03 1992-06-04 Eit Drent Carbonylation process and catalyst composition
ES2077337T3 (es) 1991-01-15 1995-11-16 Shell Int Research Procedimiento para la carbonilacion de olefinas.
DE69210054T2 (de) 1991-01-15 1996-12-12 Shell Int Research Carbonylierung von Olefinen
EP0499329B1 (en) 1991-02-15 1994-05-04 Shell Internationale Researchmaatschappij B.V. Carbonylation catalyst system
GB9425911D0 (en) 1994-12-22 1995-02-22 Ici Plc Process for the carbonylation of olefins and catalyst system for use therein
US5618983A (en) * 1995-08-25 1997-04-08 E. I. Du Pont De Nemours And Company Hydroformylation process
GB9705699D0 (en) * 1997-03-19 1997-05-07 Ici Plc Process for the carbonylation of ethylene
US6156934A (en) 1997-03-26 2000-12-05 Shell Oil Company Diphosphines
TW524801B (en) 1999-03-22 2003-03-21 Shell Int Research Process for the carbonylation of conjugated dienes
MY127358A (en) 2000-03-14 2006-11-30 Shell Int Research Process for the carbonylation of ethylenically unsaturated compounds
DE10048874A1 (de) 2000-09-29 2002-04-11 Basf Ag Katalysatorsystem und Verfahren zur Carbonylierung
DE10228293A1 (de) 2001-07-28 2003-02-13 Basf Ag Verfahren zur Herstellung von Dialkylketonen
CA2476736C (en) 2002-02-19 2012-06-05 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore
CN1681591B (zh) 2002-09-12 2012-04-18 卢西特国际英国有限公司 催化剂体系
WO2004103948A1 (en) 2003-05-22 2004-12-02 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of a conjugated diene
JP2007516197A (ja) * 2003-07-03 2007-06-21 ルーサイト インターナショナル ユーケー リミテッド エチレン性不飽和化合物のヒドロホルミル化方法
US7084291B2 (en) * 2003-10-15 2006-08-01 General Electric Company Water resistant catalyst for the production of diaryl carbonates via the direct carbonylation of phenolic compounds
KR20060129489A (ko) 2004-02-26 2006-12-15 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 에틸렌계 또는 아세틸렌계 불포화 화합물의 카르보닐화방법
GB0516556D0 (en) * 2005-08-12 2005-09-21 Lucite Int Uk Ltd Improved catalyst system
CA2671409C (en) * 2006-12-02 2016-07-26 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0625518D0 (en) * 2006-12-21 2007-01-31 Lucite Int Uk Ltd Carbonylation of conjugated dienes
GB0713624D0 (en) * 2007-07-13 2007-08-22 Lucite Int Uk Ltd Improved solvent for catalyst system
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process

Also Published As

Publication number Publication date
CN102740972B (zh) 2015-02-11
JP2015214551A (ja) 2015-12-03
AU2010332501A1 (en) 2012-07-26
KR20120106974A (ko) 2012-09-27
SG181699A1 (en) 2012-07-30
WO2011073653A1 (en) 2011-06-23
US20120309613A1 (en) 2012-12-06
EA201290514A1 (ru) 2013-01-30
GB0921876D0 (en) 2010-01-27
AU2010332501A2 (en) 2012-08-02
CA2783586A1 (en) 2011-06-23
ZA201204316B (en) 2013-02-27
BR112012014500A2 (pt) 2016-08-16
EP2512670A1 (en) 2012-10-24
AU2010332501B2 (en) 2014-10-30
TW201143889A (en) 2011-12-16
TWI508780B (zh) 2015-11-21
CN102740972A (zh) 2012-10-17
EA024236B1 (ru) 2016-08-31
JP2013513653A (ja) 2013-04-22

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