EA201070139A1 - Способ карбонилирования этиленненасыщенных соединений и каталитическая система - Google Patents

Способ карбонилирования этиленненасыщенных соединений и каталитическая система

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Publication number
EA201070139A1
EA201070139A1 EA201070139A EA201070139A EA201070139A1 EA 201070139 A1 EA201070139 A1 EA 201070139A1 EA 201070139 A EA201070139 A EA 201070139A EA 201070139 A EA201070139 A EA 201070139A EA 201070139 A1 EA201070139 A1 EA 201070139A1
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EA
Eurasian Patent Office
Prior art keywords
compound
carbonylation
compounds
reaction
disclosed
Prior art date
Application number
EA201070139A
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English (en)
Inventor
Грэхам Рональд Истхэм
Филип Ян Ричардс
Original Assignee
ЛУСАЙТ ИНТЕРНЕЙШНЛ Ю Кей ЛИМИТЕД
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Publication of EA201070139A1 publication Critical patent/EA201070139A1/ru

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
    • C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

Раскрыт способ карбонилирования этиленненасыщенного соединения, включающий стадию осуществления взаимодействия указанного соединения с оксидом углерода в присутствии сореагента, содержащего подвижный атом водорода, и каталитической системы. Каталитическую систему получают путем объединения: (а) металла группы 8, 9 или 10 или его подходящего соединения; (b) лиганда общей формулы (I) и (с) необязательно, источника анионов. Настоящее изобретение отличается тем, что каталитическая система включает соединение, способствующее протеканию реакции карбонилирования, включающее ароматическое кольцо или кольцевую систему, замещенную по меньшей мере одной гидроксильной группой, где pKa указанной гидроксильной группы при температуре 25°С больше чем 3,0 и меньше чем 9,1, причем из указанных соединений, способствующих протеканию реакции карбонилирования, исключен 3-хинолин. Раскрыты каталитические системы для применения с соединением, способствующим протеканию реакции, и раскрыты способ повышения эффективности каталитической системы для карбонилирования этиленненасыщенных соединений и способ повышения скорости карбонилирования этиленненасыщенных соединений, включающий стадию добавления в реакцию такого соединения.
EA201070139A 2007-07-13 2008-07-08 Способ карбонилирования этиленненасыщенных соединений и каталитическая система EA201070139A1 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GBGB0713624.5A GB0713624D0 (en) 2007-07-13 2007-07-13 Improved solvent for catalyst system
PCT/GB2008/050550 WO2009010782A1 (en) 2007-07-13 2008-07-08 A process for the carbonylation of an ethylenically unsaturated compound and a catalyst system

Publications (1)

Publication Number Publication Date
EA201070139A1 true EA201070139A1 (ru) 2010-10-29

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EA201070139A EA201070139A1 (ru) 2007-07-13 2008-07-08 Способ карбонилирования этиленненасыщенных соединений и каталитическая система

Country Status (13)

Country Link
US (1) US20100197958A1 (ru)
EP (1) EP2167232A1 (ru)
JP (1) JP2010533162A (ru)
KR (1) KR20100057607A (ru)
CN (1) CN101743062A (ru)
AU (1) AU2008277439A1 (ru)
BR (1) BRPI0814301A2 (ru)
CA (1) CA2691698A1 (ru)
EA (1) EA201070139A1 (ru)
GB (1) GB0713624D0 (ru)
TW (1) TW200909412A (ru)
WO (1) WO2009010782A1 (ru)
ZA (1) ZA201000105B (ru)

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KR101633325B1 (ko) 2005-11-17 2016-06-24 루사이트 인터내셔널 유케이 리미티드 에틸렌성 불포화 화합물의 카르보닐화
GB0607494D0 (en) 2006-04-13 2006-05-24 Lucite Int Uk Ltd Metal complexes
WO2008065448A1 (en) * 2006-12-02 2008-06-05 Lucite International Uk Limited Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds
GB0812297D0 (en) * 2008-07-04 2008-08-13 Lucite Int Uk Ltd Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds
GB0921876D0 (en) * 2009-12-15 2010-01-27 Lucite Int Uk Ltd Improved carbonylation process
GB201000078D0 (en) 2010-01-05 2010-02-17 Lucite Int Uk Ltd Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands
DE102010002809A1 (de) 2010-03-12 2011-11-17 Evonik Degussa Gmbh Verfahren zur Herstellung von linearen alpha,omega-Dicarbonsäurediestern
AR088124A1 (es) * 2011-04-01 2014-05-14 Dsm Ip Assets Bv Proceso para la preparacion de esteres de acido alcanoico en un proceso de carbonilacion utilizando ligandos de bifosfato bidentados de paladio
AR085717A1 (es) 2011-04-01 2013-10-23 Dsm Ip Assets Bv Proceso para producir acido adipico y diesteres del mismo en un proceso de carbonilacion utilizando ligandos bifosfato bidentados de paladio
WO2013107904A1 (en) * 2012-01-19 2013-07-25 Dsm Ip Assets B.V. Process to produce alkanoic acid esters in a carbonylation process using lewis acids as acid promotor
WO2013107902A1 (en) 2012-01-20 2013-07-25 Dsm Ip Assets B.V. Process for the separation of a dissolved catalyst system from an alkoxycarbonylation reaction mixture
WO2017135897A1 (en) * 2016-02-02 2017-08-10 Agency For Science, Technology And Research A catalyst for the carbonylation of alkenes
US20240083926A1 (en) * 2020-12-15 2024-03-14 Agency For Science, Technology And Research Phosphorus compounds and methods thereof

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BE793203A (fr) * 1971-12-27 1973-06-22 Monsanto Co Production d'acides carboxyliques
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KR880007426A (ko) * 1986-12-24 1988-08-27 오노 알버어스 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법
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CA2526348A1 (en) * 2003-05-22 2004-12-02 Shell Internationale Research Maatschappij B.V. Process for the carbonylation of a conjugated diene

Also Published As

Publication number Publication date
KR20100057607A (ko) 2010-05-31
BRPI0814301A2 (pt) 2015-02-03
TW200909412A (en) 2009-03-01
CN101743062A (zh) 2010-06-16
CA2691698A1 (en) 2009-01-22
AU2008277439A1 (en) 2009-01-22
ZA201000105B (en) 2010-09-29
US20100197958A1 (en) 2010-08-05
GB0713624D0 (en) 2007-08-22
JP2010533162A (ja) 2010-10-21
EP2167232A1 (en) 2010-03-31
WO2009010782A1 (en) 2009-01-22

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