DE602004008299D1 - Verfahren zur carbonylierung von konjugierten dienen mit einem palladium-katalysatorsystem - Google Patents
Verfahren zur carbonylierung von konjugierten dienen mit einem palladium-katalysatorsystemInfo
- Publication number
- DE602004008299D1 DE602004008299D1 DE602004008299T DE602004008299T DE602004008299D1 DE 602004008299 D1 DE602004008299 D1 DE 602004008299D1 DE 602004008299 T DE602004008299 T DE 602004008299T DE 602004008299 T DE602004008299 T DE 602004008299T DE 602004008299 D1 DE602004008299 D1 DE 602004008299D1
- Authority
- DE
- Germany
- Prior art keywords
- aliphatic
- ligand
- catalyst system
- source
- carbon atoms
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000034 method Methods 0.000 title abstract 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 4
- 229910052763 palladium Inorganic materials 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 abstract 6
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 abstract 4
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 229910052698 phosphorus Inorganic materials 0.000 abstract 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 abstract 2
- 150000001450 anions Chemical class 0.000 abstract 2
- 229910052799 carbon Inorganic materials 0.000 abstract 2
- -1 palladium cations Chemical class 0.000 abstract 2
- 125000004437 phosphorous atom Chemical group 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 230000006315 carbonylation Effects 0.000 abstract 1
- 238000005810 carbonylation reaction Methods 0.000 abstract 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 238000010924 continuous production Methods 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- ZOUWOGOTHLRRLS-UHFFFAOYSA-N palladium;phosphane Chemical compound P.[Pd] ZOUWOGOTHLRRLS-UHFFFAOYSA-N 0.000 abstract 1
- 150000003017 phosphorus Chemical group 0.000 abstract 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03077340 | 2003-07-25 | ||
| EP03077340 | 2003-07-25 | ||
| PCT/EP2004/007059 WO2005014520A1 (en) | 2003-07-25 | 2004-06-28 | Process for the carbonylation of conjugated dienes using a palladium catalyst system |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE602004008299D1 true DE602004008299D1 (de) | 2007-09-27 |
| DE602004008299T2 DE602004008299T2 (de) | 2008-05-08 |
Family
ID=34130224
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE602004008299T Expired - Lifetime DE602004008299T2 (de) | 2003-07-25 | 2004-06-28 | Verfahren zur carbonylierung von konjugierten dienen mit einem palladium-katalysatorsystem |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7820849B2 (de) |
| EP (1) | EP1656336B1 (de) |
| KR (1) | KR101143206B1 (de) |
| CN (1) | CN100417635C (de) |
| AT (1) | ATE370112T1 (de) |
| DE (1) | DE602004008299T2 (de) |
| MY (1) | MY138563A (de) |
| TW (1) | TWI352081B (de) |
| WO (1) | WO2005014520A1 (de) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20140028072A (ko) | 2011-05-13 | 2014-03-07 | 노보머, 인코포레이티드 | 촉매적 카르보닐화 촉매 및 방법 |
| EP2922813B1 (de) * | 2012-11-23 | 2016-10-12 | Firmenich SA | Hydrocarbonylation oder methoxycarbonylation von 1,3-dien-derivaten mit palladium-komplex |
| US10858329B2 (en) | 2014-05-05 | 2020-12-08 | Novomer, Inc. | Catalyst recycle methods |
| US10597294B2 (en) | 2014-05-30 | 2020-03-24 | Novomer, Inc. | Integrated methods for chemical synthesis |
| CN106714966B (zh) | 2014-07-25 | 2021-02-02 | 诺沃梅尔公司 | 金属络合物的合成及其用途 |
| MA41513A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de distillation pour la production d'acide acrylique |
| MA41514A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédés intégrés de synthèse chimique |
| AU2016218996A1 (en) * | 2015-02-13 | 2017-08-24 | Novomer, Inc. | Continuous carbonylation processes |
| MA41510A (fr) | 2015-02-13 | 2017-12-19 | Novomer Inc | Procédé de production d'acide acrylique |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR880007426A (ko) * | 1986-12-24 | 1988-08-27 | 오노 알버어스 | 팔라듐 촉매를 사용한 올레핀형 불포화 화합물의 카르보닐화 방법 |
| US5304674A (en) * | 1992-06-29 | 1994-04-19 | Shell Oil Company | Preparation of alkanedioic derivatives |
| US5495041A (en) * | 1995-02-22 | 1996-02-27 | Dsm N.W. | Process for the preparation of a pentenoate ester |
| GB9705699D0 (en) * | 1997-03-19 | 1997-05-07 | Ici Plc | Process for the carbonylation of ethylene |
| US6489506B2 (en) * | 1997-03-19 | 2002-12-03 | Lucite International Uk Limited | Process for the palladium and phosphine ligand catalyzed carbonylation of ethylene |
| TW524801B (en) * | 1999-03-22 | 2003-03-21 | Shell Int Research | Process for the carbonylation of conjugated dienes |
| EP1332124A1 (de) * | 2000-09-27 | 2003-08-06 | Dsm N.V. | Verfahren zur carbonylierung von konjugierten diene |
-
2004
- 2004-06-28 US US10/565,773 patent/US7820849B2/en not_active Expired - Fee Related
- 2004-06-28 CN CNB2004800216212A patent/CN100417635C/zh not_active Expired - Fee Related
- 2004-06-28 WO PCT/EP2004/007059 patent/WO2005014520A1/en active IP Right Grant
- 2004-06-28 DE DE602004008299T patent/DE602004008299T2/de not_active Expired - Lifetime
- 2004-06-28 EP EP04740443A patent/EP1656336B1/de not_active Expired - Lifetime
- 2004-06-28 AT AT04740443T patent/ATE370112T1/de not_active IP Right Cessation
- 2004-06-28 KR KR1020067001646A patent/KR101143206B1/ko not_active IP Right Cessation
- 2004-07-20 MY MYPI20042896A patent/MY138563A/en unknown
- 2004-07-23 TW TW093122142A patent/TWI352081B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| TWI352081B (en) | 2011-11-11 |
| WO2005014520A1 (en) | 2005-02-17 |
| ATE370112T1 (de) | 2007-09-15 |
| EP1656336A1 (de) | 2006-05-17 |
| EP1656336B1 (de) | 2007-08-15 |
| DE602004008299T2 (de) | 2008-05-08 |
| CN100417635C (zh) | 2008-09-10 |
| KR20060041282A (ko) | 2006-05-11 |
| CN1829679A (zh) | 2006-09-06 |
| TW200512176A (en) | 2005-04-01 |
| KR101143206B1 (ko) | 2012-05-18 |
| MY138563A (en) | 2009-06-30 |
| US7820849B2 (en) | 2010-10-26 |
| US20070155984A1 (en) | 2007-07-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Fernández-Alvarez et al. | Homogeneous catalytic reduction of CO 2 with hydrosilanes | |
| Mote et al. | Hydrogen‐Bonding‐Assisted Supramolecular Metal Catalysis | |
| Rout et al. | Recent advances in transition-metal-mediated Csp2-B and Csp2-P cross-coupling reactions | |
| DE60103255D1 (de) | Verfahren zum carbonylieren von pentennitril | |
| DE60103254D1 (de) | Verfahren zum carbonylieren von aethylenisch ungesättigten verbindungen | |
| Higuchi et al. | Tunable ligand effects on ruthenium catalyst activity for selectively preparing imines or amides by dehydrogenative coupling reactions of alcohols and amines | |
| Yang et al. | Palladium catalyzed asymmetric hydrophosphination of α, β-and α, β, γ, δ-unsaturated malonate esters–efficient control of reactivity, stereo-and regio-selectivity | |
| Li et al. | Rh-catalyzed regio-and enantioselective allylic phosphinylation | |
| Kostas et al. | A palladium complex with a new hemilabile amino-and sulfur-containing phosphinite ligand as an efficient catalyst for the Heck reaction of aryl bromides with styrene. The effect of the amino group | |
| Chen et al. | Acetonitrile-dependent oxyphosphorylation: A mild one-pot synthesis of β-ketophosphonates from alkenyl acids or alkenes | |
| TW200600495A (en) | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds | |
| ATE320438T1 (de) | Bisphosphit-ligande für carbonylierungsverfahren | |
| DE602004008299D1 (de) | Verfahren zur carbonylierung von konjugierten dienen mit einem palladium-katalysatorsystem | |
| CN101343289A (zh) | 一种合成有机膦酸酯衍生物的方法 | |
| Jumde et al. | Deoxycholic acid derived monophosphites as chiral ligands in the asymmetric Suzuki–Miyaura cross-coupling | |
| Tato et al. | Rhodium-catalyzed conjugate addition of arylindium reagents to α, β-unsaturated carbonyl compounds | |
| Margarita et al. | Transition‐Metal‐Catalyzed Regioselective Asymmetric Mono‐Hydrogenation of Dienes and Polyenes | |
| Nirmala et al. | Ruthenium (II) complexes incorporating salicylaldiminato-functionalized N-heterocyclic carbene ligands as efficient and versatile catalysts for hydration of organonitriles | |
| AU2003299066A1 (en) | Process for the hydroformylation of an ethylenically unsaturated compound using a bidentate diphosphine composition with a bridging group comprising sp2 hybridized carbon atoms bound to the phosphorous atoms | |
| MY127097A (en) | Process for the carbonylation of a conjugated diene | |
| Shi et al. | Chiral C1-symmetric diaminothiophosphoramide–Cu (I) catalyzed asymmetric addition of diethylzinc to N-sulfonylimines | |
| Takaki et al. | Hydrophosphination of alkynes and related reactions catalyzed by rare-earth amides | |
| Gladiali et al. | Asymmetric allylic alkylation catalyzed by Pd (II)-complexes with (S)-BINPO, a hemilabile axially chiral P, O-heterodonor inducer | |
| Brahmachari | Microwave-assisted Hirao reaction: Recent developments | |
| Kim et al. | Asymmetric synthesis of chiral tertiary borylated phosphonates by copper-catalyzed conjugate borylation |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| 8364 | No opposition during term of opposition |