TW200600495A - Process for the carbonylation of ethylenically or acetylenically unsaturated compounds - Google Patents
Process for the carbonylation of ethylenically or acetylenically unsaturated compoundsInfo
- Publication number
- TW200600495A TW200600495A TW094105891A TW94105891A TW200600495A TW 200600495 A TW200600495 A TW 200600495A TW 094105891 A TW094105891 A TW 094105891A TW 94105891 A TW94105891 A TW 94105891A TW 200600495 A TW200600495 A TW 200600495A
- Authority
- TW
- Taiwan
- Prior art keywords
- carbonylation
- unsaturated compounds
- ethylenically
- acetylenically unsaturated
- jointly
- Prior art date
Links
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 230000006315 carbonylation Effects 0.000 title abstract 2
- 238000005810 carbonylation reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 abstract 2
- VURFVHCLMJOLKN-UHFFFAOYSA-N diphosphane Chemical compound PP VURFVHCLMJOLKN-UHFFFAOYSA-N 0.000 abstract 2
- -1 phosphino group Chemical group 0.000 abstract 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000000962 organic group Chemical group 0.000 abstract 1
- 229910052763 palladium Inorganic materials 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 239000011574 phosphorus Substances 0.000 abstract 1
- 229910052697 platinum Inorganic materials 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2409—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring with more than one complexing phosphine-P atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
- C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/36—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates
- C07C67/38—Preparation of carboxylic acid esters by reaction with carbon monoxide or formates by addition to an unsaturated carbon-to-carbon bond
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/655—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms
- C07F9/6552—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a six-membered ring
- C07F9/65522—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having oxygen atoms, with or without sulfur, selenium, or tellurium atoms, as the only ring hetero atoms the oxygen atom being part of a six-membered ring condensed with carbocyclic rings or carbocyclic ring systems
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
- C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
- B01J2231/32—Addition reactions to C=C or C-C triple bonds
- B01J2231/321—Hydroformylation, metalformylation, carbonylation or hydroaminomethylation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/824—Palladium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/828—Platinum
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
A process for the carbonylation of unsaturated compounds by contacting the unsaturated compound with carbon monoxide in the presence of a catalyst system comprising: (a) a source of palladium and/or platinum; and (c) an unsymmetrical bidentate diphosphine ligand of formula I, R1R2 > P1 - R3 - P2 < R4R5 (I) wherein P1 and P2 represent phosphorus atoms; R3 represents a divalent organic bridging group; and R1, R2, R4 and R5 each individually, or R1 and R2 jointly, and/or R4 and R5 jointly represent organic groups that are covalently linked to the phosphorus; and wherein R1, R2, R4 and R5 are chosen in such way, that the phosphino group R1R2 > P1 differs from the phosphino group P2 < R4R5.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP04251065 | 2004-02-26 | ||
PCT/EP2004/050794 WO2004103948A1 (en) | 2003-05-22 | 2004-05-13 | Process for the carbonylation of a conjugated diene |
EP04257283 | 2004-11-24 |
Publications (1)
Publication Number | Publication Date |
---|---|
TW200600495A true TW200600495A (en) | 2006-01-01 |
Family
ID=37432304
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW094105891A TW200600495A (en) | 2004-02-26 | 2005-02-25 | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds |
Country Status (7)
Country | Link |
---|---|
EP (1) | EP1735263A1 (en) |
JP (1) | JP2007524700A (en) |
KR (1) | KR20060129489A (en) |
BR (1) | BRPI0507918A (en) |
CA (1) | CA2557362A1 (en) |
TW (1) | TW200600495A (en) |
WO (1) | WO2005082830A1 (en) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1651587A1 (en) | 2003-07-03 | 2006-05-03 | Lucite International UK Limited | Process for the hydroformylation of ethylenically unsaturated compounds |
GB0403592D0 (en) | 2004-02-18 | 2004-03-24 | Lucite Int Uk Ltd | A catalyst system |
GB0411951D0 (en) | 2004-05-28 | 2004-06-30 | Lucite Int Uk Ltd | Carbonylation of ester |
GB0516556D0 (en) | 2005-08-12 | 2005-09-21 | Lucite Int Uk Ltd | Improved catalyst system |
EP1957198B1 (en) * | 2005-11-17 | 2018-08-22 | Lucite International UK Limited | Carbonylation of ethylenically unsaturated compounds |
GB0607494D0 (en) | 2006-04-13 | 2006-05-24 | Lucite Int Uk Ltd | Metal complexes |
MX2009005568A (en) | 2006-12-02 | 2009-06-05 | Lucite Int Uk Ltd | Novel carbonylation ligands and their use in the carbonylation of ethylenically unsaturated compounds. |
GB0812297D0 (en) | 2008-07-04 | 2008-08-13 | Lucite Int Uk Ltd | Novel carbonylation ligand sand thier use of in the carbonylation of ethylenically unsaturated compounds |
FR2950349B1 (en) * | 2009-09-18 | 2011-08-26 | Rhodia Operations | ORGANOPHOSPHORIC COMPOUNDS, CATALYTIC SYSTEMS COMPRISING THESE COMPOUNDS, AND HYDROCYANATION METHOD USING THESE CATALYTIC SYSTEMS |
GB0921875D0 (en) | 2009-12-15 | 2010-01-27 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
US20120309613A1 (en) | 2009-12-15 | 2012-12-06 | Lucite International Uk Limited | Carbonylation process |
GB201000078D0 (en) | 2010-01-05 | 2010-02-17 | Lucite Int Uk Ltd | Process for the carbonylation of ethylenically unsaturated compounds, novel carbonylation ligands and catalyst systems incorporatng such ligands |
GB201122054D0 (en) | 2011-12-21 | 2012-02-01 | Lucite Int Uk Ltd | A continuous process for the carbonylation of ethylene |
KR20220011721A (en) * | 2019-05-27 | 2022-01-28 | 디에스엠 아이피 어셋츠 비.브이. | Selective hydrogenation of alkynes to alkenes in the presence of phosphorus compounds and organosulfur compounds |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR880007418A (en) * | 1986-12-10 | 1988-08-27 | 오노 알버어스 | Selective Carbonylation Process of Conjugated Diene and Catalyst System without Organic Nitrogen-Containing Hot Air |
US5495041A (en) * | 1995-02-22 | 1996-02-27 | Dsm N.W. | Process for the preparation of a pentenoate ester |
US6137012A (en) * | 1998-10-13 | 2000-10-24 | E. I. Du Pont De Nemours And Company | Phosphole and diphosphole ligands for catalysis |
MY127358A (en) * | 2000-03-14 | 2006-11-30 | Shell Int Research | Process for the carbonylation of ethylenically unsaturated compounds |
DE10106348A1 (en) * | 2001-02-09 | 2002-08-14 | Basf Ag | Compound suitable as a catalyst or for producing a catalyst system |
MXPA02001147A (en) * | 2001-03-19 | 2004-04-21 | Warner Lambert Co | Synthesis of non-c2-symmetric bisphosphine ligands as catalysts for asymmetric hydrogenation. |
DE10148712A1 (en) * | 2001-10-02 | 2003-04-17 | Basf Ag | New 2-phosphatricyclodecane diphosphine derivatives useful as components of palladium catalysts for carbonylating conjugated dienes |
-
2005
- 2005-02-25 BR BRPI0507918-7A patent/BRPI0507918A/en not_active Application Discontinuation
- 2005-02-25 KR KR1020067019391A patent/KR20060129489A/en not_active Application Discontinuation
- 2005-02-25 WO PCT/EP2005/050803 patent/WO2005082830A1/en not_active Application Discontinuation
- 2005-02-25 JP JP2007500222A patent/JP2007524700A/en not_active Withdrawn
- 2005-02-25 CA CA002557362A patent/CA2557362A1/en not_active Abandoned
- 2005-02-25 EP EP05716797A patent/EP1735263A1/en not_active Withdrawn
- 2005-02-25 TW TW094105891A patent/TW200600495A/en unknown
Also Published As
Publication number | Publication date |
---|---|
KR20060129489A (en) | 2006-12-15 |
JP2007524700A (en) | 2007-08-30 |
CA2557362A1 (en) | 2005-09-09 |
WO2005082830A1 (en) | 2005-09-09 |
BRPI0507918A (en) | 2007-07-10 |
EP1735263A1 (en) | 2006-12-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TW200600495A (en) | Process for the carbonylation of ethylenically or acetylenically unsaturated compounds | |
MY127358A (en) | Process for the carbonylation of ethylenically unsaturated compounds | |
MY127093A (en) | Bidentate ligands useful in catalyst systems | |
MY134758A (en) | Multidentate phosphite ligands, catalyst compositions made therefrom and catalytic processes employing such multidentate phosphite ligands | |
ATE49010T1 (en) | PROCESS FOR PRODUCTION OF POLYKETONES. | |
MY143572A (en) | A catalyst system | |
WO2008008927A3 (en) | Hydrocyanation of 2-pentenenitrile | |
NZ297842A (en) | carbonylation of ethylene; catalyst contains group VIII metal and a bidentate phosphine compound | |
EA200970528A1 (en) | NEW CARBONYLATION LIGANDS AND THEIR APPLICATION IN CARBONYLATION OF ETHYLENE-NONSATURATED COMPOUNDS | |
EA200801345A1 (en) | CARBONYLATION OF ETHYLENE-NONSATURATED COMPOUNDS | |
MY133839A (en) | Process for the carbonylation of pentenenitrile | |
ATE471209T1 (en) | STABILIZATION OF HYDROFORMYLATION CATALYSTS BASED ON PHOSPHORAMIDITE LIGANDS | |
EA201170142A1 (en) | METHOD OF CARBONYLATION OF ETHYLENE-NONSATURATED COMPOUNDS, NEW LIGANDS FOR CARBONYLATION AND CATALYTIC SYSTEMS CONTAINING SUCH LIGANDS | |
CA2476736A1 (en) | Process for the carbonylation of an ethylenically unsaturated compound and catalyst therefore | |
UA87561C2 (en) | Method for producing substituted biphenyls | |
MY117848A (en) | Process to prepare a terminal aldehyde | |
TW200505841A (en) | Process for the hydroformylation of ethylenically unsaturated compounds | |
WO2002042359A3 (en) | Phosphonite ligands, catalyst compositions and hydroformylation process utilizing same | |
MY127097A (en) | Process for the carbonylation of a conjugated diene | |
WO2004028689A3 (en) | Process for the hydroformylation of an ethylenically unsaturated compound using a bidentate diphosphine composition with a bridging group comprising sp2 hybridized carbon atoms bound to the phosphorous atoms | |
ATE370112T1 (en) | METHOD FOR CARBONYLATING CONJUGATED DIENES USING A PALLADIUM CATALYST SYSTEM | |
ATE265412T1 (en) | METHOD FOR CARBONYLATING AN ACETYLENIC UNSATURATED COMPOUND | |
DE60206521T2 (en) | BIDENTATE LIGANDS FOR THE CARBONYLATION OF UNSATURATED COMPOUNDS | |
WO2000014055A3 (en) | Method for producing cyanovaleric acid or esters thereof | |
WO2002064250A3 (en) | Process for the carbonylation of ethylenically unsaturated compounds, bidentate diphosphine composition used in this process and processes for preparation of this bidentate diphosphine composition |