CN101309768B - 还原剂存在的情况下基于各向异性金属纳米颗粒合成催化剂的方法 - Google Patents

还原剂存在的情况下基于各向异性金属纳米颗粒合成催化剂的方法 Download PDF

Info

Publication number
CN101309768B
CN101309768B CN200680042364XA CN200680042364A CN101309768B CN 101309768 B CN101309768 B CN 101309768B CN 200680042364X A CN200680042364X A CN 200680042364XA CN 200680042364 A CN200680042364 A CN 200680042364A CN 101309768 B CN101309768 B CN 101309768B
Authority
CN
China
Prior art keywords
catalyst
metal
nanoparticles
reducing agent
anisotropic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN200680042364XA
Other languages
English (en)
Chinese (zh)
Other versions
CN101309768A (zh
Inventor
C·托马佐
D·尤兹奥
G·伯豪尔特
C·弗唐
B·哈布扎鲁
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of CN101309768A publication Critical patent/CN101309768A/zh
Application granted granted Critical
Publication of CN101309768B publication Critical patent/CN101309768B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • C01B3/505Membranes containing palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/42Platinum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/40Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
    • B01J23/44Palladium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • B01J35/393Metal or metal oxide crystallite size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45Nanoparticles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/0201Impregnation
    • B01J37/0211Impregnation using a colloidal suspension
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F1/00Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
    • B22F1/05Metallic powder characterised by the size or surface area of the particles
    • B22F1/054Nanosized particles
    • B22F1/0547Nanofibres or nanotubes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22FWORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
    • B22F9/00Making metallic powder or suspensions thereof
    • B22F9/16Making metallic powder or suspensions thereof using chemical processes
    • B22F9/18Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
    • B22F9/24Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B82NANOTECHNOLOGY
    • B82YSPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00Nanotechnology for materials or surface science, e.g. nanocomposites
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0026Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof of one single metal or a rare earth metal; Treatment thereof
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/32Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
    • C01B3/34Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
    • C01B3/38Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents using catalysts
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/501Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion
    • C01B3/503Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by diffusion characterised by the membrane
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/50Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
    • C01B3/56Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
    • C01B3/58Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction
    • C01B3/583Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids including a catalytic reaction the reaction being the selective oxidation of carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C10G2/331Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used containing group VIII-metals
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G25/00Refining of hydrocarbon oils in the absence of hydrogen, with solid sorbents
    • C10G25/003Specific sorbent material, not covered by C10G25/02 or C10G25/03
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/36Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C10G45/40Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used containing platinum group metals or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44Hydrogenation of the aromatic hydrocarbons
    • C10G45/46Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44Hydrogenation of the aromatic hydrocarbons
    • C10G45/46Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/48Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/44Hydrogenation of the aromatic hydrocarbons
    • C10G45/46Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used
    • C10G45/52Hydrogenation of the aromatic hydrocarbons characterised by the catalyst used containing platinum group metals or compounds thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2235/00Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties
    • B01J2235/30Scanning electron microscopy; Transmission electron microscopy
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391Physical properties of the active metal ingredient
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0405Purification by membrane separation
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0435Catalytic purification
    • C01B2203/044Selective oxidation of carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/04Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
    • C01B2203/0465Composition of the impurity
    • C01B2203/047Composition of the impurity the impurity being carbon monoxide
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/70Catalyst aspects
    • C10G2300/703Activation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Nanotechnology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
CN200680042364XA 2005-11-14 2006-11-14 还原剂存在的情况下基于各向异性金属纳米颗粒合成催化剂的方法 Expired - Fee Related CN101309768B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0511523 2005-11-14
FR0511523A FR2893262A1 (fr) 2005-11-14 2005-11-14 Procede de synthese en presence de reducteur d'un catalyseur a base de nanoparticules metalliques anisotropes.
PCT/FR2006/002512 WO2007057553A1 (fr) 2005-11-14 2006-11-14 Procede de synthese en presence de reducteur d'un catalyseur a base de nanoparticules metalliques anisotropes

Publications (2)

Publication Number Publication Date
CN101309768A CN101309768A (zh) 2008-11-19
CN101309768B true CN101309768B (zh) 2012-09-05

Family

ID=36592967

Family Applications (1)

Application Number Title Priority Date Filing Date
CN200680042364XA Expired - Fee Related CN101309768B (zh) 2005-11-14 2006-11-14 还原剂存在的情况下基于各向异性金属纳米颗粒合成催化剂的方法

Country Status (8)

Country Link
US (1) US8030242B2 (enExample)
EP (1) EP1951460B1 (enExample)
JP (1) JP5563221B2 (enExample)
CN (1) CN101309768B (enExample)
DE (1) DE602006019632D1 (enExample)
FR (1) FR2893262A1 (enExample)
WO (1) WO2007057553A1 (enExample)
ZA (1) ZA200803802B (enExample)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2914200B1 (fr) * 2007-03-30 2009-11-27 Inst Francais Du Petrole Procede de synthese de nanoparticules metalliques cubiques en presence de deux reducteurs
KR101127056B1 (ko) * 2008-09-25 2012-03-23 삼성전기주식회사 금속 씨앗을 이용한 금속 나노 입자의 제조 방법 및 금속씨앗을 함유하는 금속 나노 입자
JP5535501B2 (ja) * 2009-03-13 2014-07-02 アイシン精機株式会社 白金ナノ粒子の製造方法
SG174995A1 (en) * 2009-03-30 2011-11-28 Agency Science Tech & Res Nanostructured metals
GB201002677D0 (en) * 2010-02-17 2010-04-07 Johnson Matthey Plc Supported metal catalysts
US8450236B2 (en) * 2010-04-13 2013-05-28 Cristal Usa Inc. Supported precious metal catalysts via hydrothermal deposition
TWI403358B (zh) * 2010-12-29 2013-08-01 Univ Nat Taiwan 分散奈米金屬粒子之方法及所製備之黏土及奈米金屬粒子之組成物
CN102744416B (zh) * 2011-04-19 2013-12-25 同济大学 一种二十面体晶态纳米镍钴合金的制备方法
US9314849B2 (en) * 2012-02-28 2016-04-19 North Carolina State University Synthesis of nanostructures
JP2014055126A (ja) 2012-08-10 2014-03-27 Sumitomo Chemical Co Ltd フィッシャー・トロプシュ反応による炭素原子数2〜4のオレフィンの製造方法
EP3092072B1 (en) * 2014-01-07 2022-03-02 Fujian Institute Of Research On The Structure Of Matter, Chinese Academy Of Sciences A process for vapor-phase methanol carbonylation to methyl formate
US20160001370A1 (en) 2014-07-03 2016-01-07 Carestream Health, Inc. Reducing agents for silver morphology control
CN104400005B (zh) * 2014-12-16 2017-08-08 湖南科技大学 一种荧光金纳米簇的合成方法
US12060319B2 (en) 2017-11-14 2024-08-13 China Petroleum & Chemical Corporation Preparation process for Cu-based catalyst and use thereof
DK3483139T3 (da) * 2017-11-14 2023-06-26 China Petroleum & Chem Corp Cu-baseret katalysator, dens fremstillingsfremgangsmåde og anvendelse deraf
CN110899718B (zh) * 2018-09-14 2022-11-15 上海铁路通信有限公司 一种大粒径壳核结构钴颗粒的制备方法
CN111054386B (zh) * 2018-10-16 2023-04-07 中国石油化工股份有限公司 轻质烷烃脱氢反应的催化剂及其制备方法
TWI878260B (zh) * 2019-01-17 2025-04-01 荷蘭商蜆殼國際研究所 基於雙金屬奈米粒子之催化劑、其在選擇性氫化中之用途以及製造所述催化劑之方法
CN111205154B (zh) * 2020-03-04 2022-05-31 厦门市涛峯辉生物医药科技研发中心 一种提高生成1-丁烯产率和选择性的方法
KR102572333B1 (ko) * 2021-08-30 2023-08-29 한국에너지기술연구원 형상이 제어된 귀금속 담지 촉매의 제조 방법 및 이로부터 제조된 비등방성의 귀금속 담지 촉매
CN114178541A (zh) * 2021-10-18 2022-03-15 温州医科大学 一种内建lspr耦合的蛋黄蛋壳型金纳米结构制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3991512A (en) * 1973-11-16 1976-11-16 Victor Stanzel Company Model aircraft
US5147841A (en) * 1990-11-23 1992-09-15 The United States Of America As Represented By The United States Department Of Energy Method for the preparation of metal colloids in inverse micelles and product preferred by the method
CN1244446A (zh) * 1998-08-12 2000-02-16 法国石油公司 有机化合物转化反应中可使用的载体上的催化剂
US6074979A (en) * 1997-05-23 2000-06-13 Celanese Gmbh Polybetaine-stabilized, palladium-containing nanoparticles, a process for preparing them and also catalysts prepared from them for producing vinyl acetate
US6197720B1 (en) * 1997-12-02 2001-03-06 Basf Aktiengesellschaft Palladium clusters and their use as catalysts

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3992512A (en) * 1971-06-16 1976-11-16 Prototech Company Finely particulated colloidal platinum compound and sol for producing the same, and method of preparation
DE3161354D1 (en) * 1980-03-24 1983-12-15 Ytkemiska Inst A liquid suspension of particles of a metal belonging to the platinum group, and a method for the manufacture of such a suspension
JPS5870837A (ja) * 1981-10-21 1983-04-27 Nissan Motor Co Ltd メタノール改質用触媒の製造方法
JPS63307208A (ja) * 1987-06-08 1988-12-14 Chiyoda Chem Eng & Constr Co Ltd 貴金属微粉末の製造方法
JPH06151133A (ja) * 1992-11-11 1994-05-31 Kanegafuchi Chem Ind Co Ltd 磁石粉末の製造方法
DE4443705A1 (de) * 1994-12-08 1996-06-13 Studiengesellschaft Kohle Mbh Verfahren zur Herstellung von tensidstabilisierten Mono- und Bimetallkolloiden der Gruppe VIII und Ib des Periodensystems als isolierbare und in hoher Konzentration wasserlösliche Precursor für Katalysatoren
DE19734974A1 (de) * 1997-08-13 1999-02-25 Hoechst Ag Verfahren zur Herstellung von porös geträgerten Metall-Nanopartikel-haltigen Katalysatoren, insbesondere für die Gasphasenoxidation von Ethylen und Essigsäure zu Vinylacetat
JP2002035586A (ja) * 2000-07-21 2002-02-05 Toyota Motor Corp 排気ガス浄化用触媒及びその製造方法
JP4683399B2 (ja) * 2001-02-20 2011-05-18 バンドー化学株式会社 金属コロイド液
US6746597B2 (en) * 2002-01-31 2004-06-08 Hydrocarbon Technologies, Inc. Supported noble metal nanometer catalyst particles containing controlled (111) crystal face exposure
DE10211701A1 (de) * 2002-03-16 2003-09-25 Studiengesellschaft Kohle Mbh Verfahren zur in situ Immobilisierung von wasserlöslichen nanodispergierten Metalloxid-Kolloiden
US6992039B2 (en) * 2003-03-13 2006-01-31 General Motors Corporation Method for making monodispersed noble metal nanoparticles supported on oxide substrates
KR100696463B1 (ko) * 2003-09-27 2007-03-19 삼성에스디아이 주식회사 고농도 탄소 담지 촉매, 그 제조방법, 상기 촉매를 이용한촉매전극 및 이를 이용한 연료전지
JP2005324084A (ja) * 2004-05-12 2005-11-24 Mitsubishi Rayon Co Ltd パラジウム含有触媒の製造方法およびパラジウム含有触媒並びにそれを用いたα,β−不飽和カルボン酸の製造方法
JP2006026471A (ja) * 2004-07-13 2006-02-02 Nissan Motor Co Ltd 燃料電池用電極触媒およびその製造方法
FR2874515B1 (fr) * 2004-08-26 2007-09-07 Inst Francais Du Petrole Catalyseur comportant des nanoparticules metalliques anisotropes supportees, methode de synthese et applications
FR2874514B1 (fr) * 2004-08-26 2007-08-17 Inst Francais Du Petrole Procede mettant en oeuvre des nanoparticules metalliques anisotropes non supportees
JP4655755B2 (ja) * 2005-05-18 2011-03-23 住友化学株式会社 過酸化水素の製造方法
JP2007009267A (ja) * 2005-06-29 2007-01-18 Kri Inc 貴金属コロイドの製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3991512A (en) * 1973-11-16 1976-11-16 Victor Stanzel Company Model aircraft
US5147841A (en) * 1990-11-23 1992-09-15 The United States Of America As Represented By The United States Department Of Energy Method for the preparation of metal colloids in inverse micelles and product preferred by the method
US6074979A (en) * 1997-05-23 2000-06-13 Celanese Gmbh Polybetaine-stabilized, palladium-containing nanoparticles, a process for preparing them and also catalysts prepared from them for producing vinyl acetate
US6197720B1 (en) * 1997-12-02 2001-03-06 Basf Aktiengesellschaft Palladium clusters and their use as catalysts
CN1244446A (zh) * 1998-08-12 2000-02-16 法国石油公司 有机化合物转化反应中可使用的载体上的催化剂

Also Published As

Publication number Publication date
EP1951460A1 (fr) 2008-08-06
FR2893262A1 (fr) 2007-05-18
JP5563221B2 (ja) 2014-07-30
CN101309768A (zh) 2008-11-19
US8030242B2 (en) 2011-10-04
ZA200803802B (en) 2009-02-25
US20090226357A1 (en) 2009-09-10
DE602006019632D1 (de) 2011-02-24
JP2009515693A (ja) 2009-04-16
WO2007057553A1 (fr) 2007-05-24
EP1951460B1 (fr) 2011-01-12

Similar Documents

Publication Publication Date Title
CN101309768B (zh) 还原剂存在的情况下基于各向异性金属纳米颗粒合成催化剂的方法
CN101646491B (zh) 在两种还原剂存在下合成立方金属纳米颗粒的方法
Al-Fatesh et al. Reforming of methane: Effects of active metals, supports, and promoters
CN102762296B (zh) 用于催化co和h2合成碳氢化合物的催化剂及其制备方法
RU2292238C2 (ru) Катализатор для процесса фишера-тропша (варианты) и способ его получения
CN1130265C (zh) 有机化合物转化反应中可使用的载体上的催化剂
CA2833079C (en) Catalysts
JP7353297B2 (ja) 芳香族化合物を水素化するために用いるニッケル-銅系バイメタリック触媒の調製方法
CN107921427A (zh) 甲烷干重整反应、用于甲烷干重整反应的含镍和铈的核壳结构的催化剂及其制备
CA2594019A1 (en) Reforming nanocatalysts and method of making and using such catalysts
KR102472412B1 (ko) 액상유기수소운반체 탈수소화용 촉매 및 이의 제조방법
US20230059034A1 (en) Method of preparing the water-gas shift catalyst, catalyst, use and process to reduce the content of carbon monoxide
KR102408100B1 (ko) 메탄의 건식 개질 반응용 2차원 니켈 실리케이트 분자체 촉매의 제조방법 및 이에 따라 제조된 메탄의 건식 개질 반응용 2차원 니켈 실리케이트 분자체 촉매
JP2009515693A5 (enExample)
CN101160376A (zh) 重整纳米催化剂以及制备和使用这类催化剂的方法
Lu et al. Copper-based catalysts for selective hydrogenation of acetylene derived from Cu (OH) 2
CN101020137A (zh) 一种合成气制重质烃催化剂及其制备方法
GB2611859A (en) Method of preparing the water-gas shift catalyst, catalyst, use and process to reduce the content of carbon monoxide
WO2008047676A1 (fr) Procédé de fabrication d'un gaz contenant de l'hydrogène
AU2021440561B2 (en) Platinum-loaded alumina catalyst, method of producing same, and method of dehydrogenating hydrogenated aromatic using the catalyst
US20080096986A1 (en) Method for synthesizing a catalyst based on anisotropic metallic nanoparticles by a micellar means
WO2019016765A1 (en) THERMOCATALYTIC PROCESS FOR GENERATING HYDROGEN AND CARBON MONOXIDE FROM HYDROCARBONS
US20220355282A1 (en) Porous material composite comprising alloy nanoparticles, composite catalyst comprising same, and manufacturing method therefor
CA2803331A1 (en) Platinum-free monometallic and bimetallic nanoparticles as ring-opening catalysts
KR20110117301A (ko) 나노미터 크기의 구리계 촉매 제조 방법

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120905

CF01 Termination of patent right due to non-payment of annual fee