CN101258168B - 在反应活性有机介质中的聚合物分散体,制备方法和用途 - Google Patents

在反应活性有机介质中的聚合物分散体,制备方法和用途 Download PDF

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Publication number
CN101258168B
CN101258168B CN2006800272211A CN200680027221A CN101258168B CN 101258168 B CN101258168 B CN 101258168B CN 2006800272211 A CN2006800272211 A CN 2006800272211A CN 200680027221 A CN200680027221 A CN 200680027221A CN 101258168 B CN101258168 B CN 101258168B
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China
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dispersion
group
polymer
preparation
vinyl
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Expired - Fee Related
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CN2006800272211A
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English (en)
Chinese (zh)
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CN101258168A (zh
Inventor
G·里斯
C·德莱特
K·哈里里
P·莫伊劳
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Saint Gobain Adfors SAS
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Saint Gobain Vetrotex France SA
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00Processes of treating or compounding macromolecular substances
    • C08J3/02Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/24Coatings containing organic materials
    • C03C25/26Macromolecular compounds or prepolymers
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C25/00Surface treatment of fibres or filaments made from glass, minerals or slags
    • C03C25/10Coating
    • C03C25/24Coatings containing organic materials
    • C03C25/26Macromolecular compounds or prepolymers
    • C03C25/28Macromolecular compounds or prepolymers obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/14Organic medium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/06Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials
    • C08J5/08Reinforcing macromolecular compounds with loose or coherent fibrous material using pretreated fibrous materials glass fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/003Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D151/00Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D151/08Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C09D151/085Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds on to polysiloxanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F218/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
    • C08F218/02Esters of monocarboxylic acids
    • C08F218/04Vinyl esters
    • C08F218/08Vinyl acetate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10Esters
    • C08F220/12Esters of monohydric alcohols or phenols
    • C08F220/16Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1808C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F226/00Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen
    • C08F226/06Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen by a heterocyclic ring containing nitrogen
    • C08F226/10N-Vinyl-pyrrolidone
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2962Silane, silicone or siloxane in coating
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/29Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
    • Y10T428/2913Rod, strand, filament or fiber
    • Y10T428/2933Coated or with bond, impregnation or core
    • Y10T428/2964Artificial fiber or filament

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Manufacturing & Machinery (AREA)
  • Dispersion Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Paints Or Removers (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Surface Treatment Of Glass Fibres Or Filaments (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Adhesives Or Adhesive Processes (AREA)
CN2006800272211A 2005-05-26 2006-05-24 在反应活性有机介质中的聚合物分散体,制备方法和用途 Expired - Fee Related CN101258168B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0551386A FR2886299B1 (fr) 2005-05-26 2005-05-26 Dispersion de polymere dans un milieu organique reactif, procede de preparation et utilisations
FR0551386 2005-05-26
PCT/FR2006/050478 WO2007003822A2 (fr) 2005-05-26 2006-05-24 Dispersion de polymere dans un milieu organique reactif, procede de preparation et utilisations

Publications (2)

Publication Number Publication Date
CN101258168A CN101258168A (zh) 2008-09-03
CN101258168B true CN101258168B (zh) 2013-02-06

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Country Status (14)

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US (1) US8349944B2 (enExample)
EP (1) EP1883655B1 (enExample)
JP (1) JP5249018B2 (enExample)
KR (1) KR101432823B1 (enExample)
CN (1) CN101258168B (enExample)
AT (1) ATE502056T1 (enExample)
BR (1) BRPI0611041A2 (enExample)
CA (1) CA2609765C (enExample)
DE (1) DE602006020718D1 (enExample)
FR (1) FR2886299B1 (enExample)
MX (1) MX2007014836A (enExample)
NO (1) NO20076406L (enExample)
RU (1) RU2414478C2 (enExample)
WO (1) WO2007003822A2 (enExample)

Families Citing this family (3)

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Publication number Priority date Publication date Assignee Title
FR2946352B1 (fr) * 2009-06-04 2012-11-09 Saint Gobain Isover Composition d'encollage pour laine minerale comprenant un saccharide, un acide organique polycarboxylique et un silicone reactif, et produits isolants obtenus
WO2011104547A2 (en) 2010-02-23 2011-09-01 Artemis Intelligent Power Limited Fluid-working machine valve timing
CN109836545A (zh) * 2019-02-01 2019-06-04 涌奇材料技术(上海)有限公司 一种表面改性有机硅微米球的制备方法及其应用

Citations (4)

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US4810763A (en) * 1987-12-23 1989-03-07 Avery International Corporation Suspension polymerization in an organic medium
US4885350A (en) * 1984-07-06 1989-12-05 Ricoh Company, Ltd. Method of producing polymer particles having narrow particle size distribution
EP0933343A1 (en) * 1998-01-29 1999-08-04 Dow Corning Corporation Method for producing sized, coated ceramic fibers
CN1416434A (zh) * 2000-03-08 2003-05-07 巴斯福股份公司 聚合物的制备

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AT346071B (de) * 1976-11-17 1978-10-25 Vianova Kunstharz Ag Verfahren zur herstellung von nichtwaesserigen polymerdispersionen mit selektiv in sich vernetzten teilchen
GB8721712D0 (en) * 1987-09-15 1987-10-21 Bp Chem Int Ltd Polymer polyols
US4824816A (en) * 1987-09-21 1989-04-25 Exxon Research & Engineering Company Method for producing stabilized zeolite catalysts
JP2825308B2 (ja) * 1990-03-07 1998-11-18 株式会社リコー 非水系樹脂分散液の製造方法
JPH04142327A (ja) * 1990-10-04 1992-05-15 Mitsui Petrochem Ind Ltd イミド系樹脂組成物
JPH04363305A (ja) * 1991-06-10 1992-12-16 Mitsui Toatsu Chem Inc ポリマーポリオールおよびその製造方法
RU2028985C1 (ru) * 1992-02-06 1995-02-20 Государственный научно-исследовательский институт стекла Замасливатель для стеклянного волокна
RU2028986C1 (ru) * 1992-06-10 1995-02-20 Акционерное общество открытого типа - Научно-производственное объединение "Стеклопластик" Состав для обработки стеклянного волокна
FR2727972B1 (fr) * 1994-12-13 1997-01-31 Vetrotex France Sa Composition d'ensimage pour fils de verre, procede utilisant cette composition et produits resultants
FR2743362B1 (fr) * 1996-01-05 1998-02-06 Vetrotex France Sa Composition d'ensimage pour fils de verre, procede utilisant cette composition et produits resultants
US6121378A (en) * 1997-08-21 2000-09-19 Mitsui Chemicals, Inc. Thermosetting powder paint composition
EP1040165B1 (en) * 1997-12-18 2002-06-12 Tremco Incorporated A polysiloxane having a copolymer dispersed therein and sealants containing the same
DE10131326A1 (de) * 2001-06-28 2003-01-16 Bosch Gmbh Robert Einsatzwerkzeug für Schleifmaschinen
FR2833002B1 (fr) * 2001-12-05 2004-07-23 Saint Gobain Vetrotex Composition d'ensimage pour fils de verre, fils de verre ainsi obtenus et composites comprenant lesdit fils
FR2839968B1 (fr) * 2002-05-22 2005-02-11 Saint Gobain Vetrotex Composition d'ensimage anhydre a base de polyurethane pour fils de verre, fils de verre obtenus et composites comprenant lesdits fils
DE10226931A1 (de) * 2002-06-17 2003-12-24 Bayer Ag Polyurethan-Polyharnstoff Dispersionen
JP4078138B2 (ja) * 2002-07-10 2008-04-23 株式会社神戸製鋼所 防汚性、易洗浄性を有する光硬化性樹脂コーティング組成物、および硬化塗装膜
JP2006031871A (ja) * 2004-07-20 2006-02-02 Toshiba Corp 半導体記憶装置
US20070081954A1 (en) * 2005-10-06 2007-04-12 Nathalie Mougin Dispersion of polymer particles, composition comprising it and cosmetic treatment method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4885350A (en) * 1984-07-06 1989-12-05 Ricoh Company, Ltd. Method of producing polymer particles having narrow particle size distribution
US4810763A (en) * 1987-12-23 1989-03-07 Avery International Corporation Suspension polymerization in an organic medium
EP0933343A1 (en) * 1998-01-29 1999-08-04 Dow Corning Corporation Method for producing sized, coated ceramic fibers
CN1416434A (zh) * 2000-03-08 2003-05-07 巴斯福股份公司 聚合物的制备

Also Published As

Publication number Publication date
EP1883655A2 (fr) 2008-02-06
ATE502056T1 (de) 2011-04-15
FR2886299A1 (fr) 2006-12-01
WO2007003822A3 (fr) 2007-02-22
DE602006020718D1 (de) 2011-04-28
BRPI0611041A2 (pt) 2010-12-07
NO20076406L (no) 2008-02-12
MX2007014836A (es) 2008-02-15
FR2886299B1 (fr) 2010-08-20
KR101432823B1 (ko) 2014-08-26
JP2008545830A (ja) 2008-12-18
CN101258168A (zh) 2008-09-03
CA2609765C (fr) 2014-07-08
RU2007148921A (ru) 2009-07-10
JP5249018B2 (ja) 2013-07-31
WO2007003822A2 (fr) 2007-01-11
KR20080021048A (ko) 2008-03-06
RU2414478C2 (ru) 2011-03-20
US20090214864A1 (en) 2009-08-27
CA2609765A1 (fr) 2007-01-11
EP1883655B1 (fr) 2011-03-16
US8349944B2 (en) 2013-01-08

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