CN101146845A - 具有改进的熔融性能和结晶性能的聚酯的制备方法 - Google Patents
具有改进的熔融性能和结晶性能的聚酯的制备方法 Download PDFInfo
- Publication number
- CN101146845A CN101146845A CNA2006800092670A CN200680009267A CN101146845A CN 101146845 A CN101146845 A CN 101146845A CN A2006800092670 A CNA2006800092670 A CN A2006800092670A CN 200680009267 A CN200680009267 A CN 200680009267A CN 101146845 A CN101146845 A CN 101146845A
- Authority
- CN
- China
- Prior art keywords
- polyester
- aforementioned
- moles
- gram
- molecular weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000728 polyester Polymers 0.000 title claims abstract description 105
- 238000002844 melting Methods 0.000 title claims abstract description 27
- 230000008018 melting Effects 0.000 title claims abstract description 27
- 238000002425 crystallisation Methods 0.000 title claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 title abstract description 7
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 43
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims abstract description 34
- 239000007790 solid phase Substances 0.000 claims abstract description 24
- 239000002245 particle Substances 0.000 claims abstract description 21
- 238000005886 esterification reaction Methods 0.000 claims abstract description 19
- 238000005809 transesterification reaction Methods 0.000 claims abstract description 12
- 239000003054 catalyst Substances 0.000 claims abstract description 10
- 238000007669 thermal treatment Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims description 53
- -1 polyethylene terephthalate Polymers 0.000 claims description 27
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 26
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 25
- 230000008569 process Effects 0.000 claims description 20
- 239000011572 manganese Substances 0.000 claims description 19
- 239000008188 pellet Substances 0.000 claims description 19
- 230000032050 esterification Effects 0.000 claims description 18
- 229910001868 water Inorganic materials 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 16
- 230000008025 crystallization Effects 0.000 claims description 10
- 239000000463 material Substances 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 8
- 238000010438 heat treatment Methods 0.000 claims description 7
- 230000000630 rising effect Effects 0.000 claims description 7
- 229910052787 antimony Inorganic materials 0.000 claims description 6
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 6
- 239000013078 crystal Substances 0.000 claims description 6
- 239000011261 inert gas Substances 0.000 claims description 6
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 4
- 238000006482 condensation reaction Methods 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000012298 atmosphere Substances 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052732 germanium Inorganic materials 0.000 claims description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 claims description 2
- 229910000765 intermetallic Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims 1
- 238000007711 solidification Methods 0.000 abstract 1
- 230000008023 solidification Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 21
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 10
- 238000001816 cooling Methods 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 7
- 150000002009 diols Chemical class 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 239000000178 monomer Substances 0.000 description 7
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 5
- 239000007788 liquid Substances 0.000 description 5
- 238000012545 processing Methods 0.000 description 5
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 2
- 229920001730 Moisture cure polyurethane Polymers 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 229920001707 polybutylene terephthalate Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- 229920001634 Copolyester Polymers 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000007084 catalytic combustion reaction Methods 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 229940117389 dichlorobenzene Drugs 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 230000005593 dissociations Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/16—Dicarboxylic acids and dihydroxy compounds
- C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
- C08G63/181—Acids containing aromatic rings
- C08G63/183—Terephthalic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/80—Solid-state polycondensation
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Description
实施例1 | 对比例1 | |
Mn起始[g/mol] | 4715 | 4795 |
EGN | 424 | 417 |
CCOOH起始[mol/t] | 166 | 121 |
%COOH起始 | 39.1 | 29.0 |
T/t SSP[℃/h] | 225/28.5 | 225/24.5 |
Mn最终[g/mol] | 22675 | 23810 |
CCOOH最终[mol/t] | 72.2 | 46.9 |
酯化百分比(E/(E+T)) | 55.8% | 44.5% |
DSC熔点[℃] | 259.4 | 64.1 |
DSC熔融热[J/g] | 68.7 | 69.5 |
DSC第二次行程结晶峰[℃] | 172.5 | 169.0 |
DSC第二次行程熔点[℃] | 255.3 | 254.4 |
实施例2 | 实施例3 | 对比例2 | |
Mn起始[g/mol] | 4955 | 4795 | 3245 |
EGN | 404 | 417 | 616 |
CCOOH起始[mol/t] | 161 | 121 | 46.2 |
%COOH起始 | 39.9 | 29.0 | 7.5 |
T/t SSP [℃/h] | 215/28 | 215/28 | 215/28 |
Mn最终[g/mol] | 17832 | 19023 | 12548 |
CCOOH最终[mol/t] | 42.1 | 26.4 | 14.1 |
酯化比例(E/(E+T)) | 85% | 60.6% | 14% |
DSC熔点[℃] | 253.2 | 254.6 | 257.1 |
DSC熔融焓[J/g] | 70.2 | 72.8 | 76.1 |
DSC第二次行程结晶峰[℃] | 164.2 | 159.2 | 149.9 |
Claims (22)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE200510014071 DE102005014071A1 (de) | 2005-03-23 | 2005-03-23 | Herstellung eines Polyesters mit verbesserten Aufschmelzeigenschaften und Kristallisationseigenschaften |
DE102005014071.8 | 2005-03-23 | ||
PCT/CH2006/000043 WO2006099755A1 (de) | 2005-03-23 | 2006-01-19 | Verfahren zur herstellung eines polyesters mit verbesserten aufschmelzeigenschaften und kristallisationseigenschaften |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101146845A true CN101146845A (zh) | 2008-03-19 |
CN101146845B CN101146845B (zh) | 2011-03-30 |
Family
ID=35953958
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2006800092670A Expired - Fee Related CN101146845B (zh) | 2005-03-23 | 2006-01-19 | 具有改进的熔融性能和结晶性能的聚酯的制备方法 |
Country Status (16)
Country | Link |
---|---|
US (1) | US9133303B2 (zh) |
EP (1) | EP1861450B1 (zh) |
KR (1) | KR101229581B1 (zh) |
CN (1) | CN101146845B (zh) |
AR (1) | AR053142A1 (zh) |
BR (1) | BRPI0614010B1 (zh) |
DE (1) | DE102005014071A1 (zh) |
EA (1) | EA012301B1 (zh) |
ES (1) | ES2626978T3 (zh) |
LT (1) | LT1861450T (zh) |
MX (1) | MX2007011175A (zh) |
PL (1) | PL1861450T3 (zh) |
TW (1) | TWI431037B (zh) |
UA (1) | UA90713C2 (zh) |
WO (1) | WO2006099755A1 (zh) |
ZA (1) | ZA200707540B (zh) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI743034B (zh) * | 2015-04-14 | 2021-10-21 | 德商伍德伊文達菲瑟有限公司 | 用於從可結晶熱塑性材料顆粒中結晶和分離低分子成分之方法及其裝置 |
CN114773796A (zh) * | 2021-01-22 | 2022-07-22 | Skc株式会社 | 聚酯膜、其制备方法及使用其用于再生聚对苯二甲酸乙二醇酯容器的方法 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
RU2454245C2 (ru) | 2006-12-26 | 2012-06-27 | Сентро Де Инмунология Молекулар | Фармацевтические композиции, способные вызывать апоптоз опухолевых клеток, для диагностики и лечения в-клеточной хронической лимфоцитарной лейкемии |
DE102009009957A1 (de) * | 2009-02-23 | 2010-08-26 | Bühler AG | Verfahren zur Herstellung von Polyesterpartikeln bei hohem Durchsatz in einer Linie |
DE102014110337A1 (de) * | 2014-07-22 | 2016-01-28 | Technip Zimmer Gmbh | Verfahren und Anlage zur Herstellung von PET-Granulat |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2559290B2 (de) * | 1975-12-31 | 1979-08-02 | Davy International Ag, 6000 Frankfurt | Verfahren zur kontinuierlichen Herstellung von hochmolekularem PoIyäthylenterephthalat |
DD139129A1 (de) * | 1978-10-12 | 1979-12-12 | Eckehart Schaaf | Verfahren zur herstellung hochmolekularer polyester durch festphasennachpolykondensation |
DE4131362A1 (de) * | 1991-09-20 | 1993-03-25 | Zimmer Ag | Verfahren zur herstellung statistischer copolyester |
US5540868A (en) * | 1995-01-20 | 1996-07-30 | E. I. Du Pont De Nemours And Company | Process for pellet formation from amorphous polyester |
US5830982A (en) * | 1995-01-20 | 1998-11-03 | E. I. Du Pont De Nemours And Company | Production of poly (ethylene terephthalate) |
KR100443389B1 (ko) * | 1995-12-14 | 2004-11-16 | 이.아이,듀우판드네모아앤드캄파니 | 폴리에스테르 예비중합체의 제조 방법 |
US6762235B2 (en) | 2001-04-24 | 2004-07-13 | Mitsubishi Engineering-Plastics Corporation | Polybutylene terephthalate resin and compositions and molded articles comprising the resin |
DE10158312A1 (de) | 2001-11-28 | 2003-06-18 | Zimmer Ag | Verfahren zur Herstellung von Polyester- oder Copolyester-Prepolymer |
DE102004014590A1 (de) | 2004-03-23 | 2005-10-20 | Buehler Ag | Teilkristallines Polyethylenterephthalat |
-
2005
- 2005-03-23 DE DE200510014071 patent/DE102005014071A1/de not_active Withdrawn
-
2006
- 2006-01-19 UA UAA200711698A patent/UA90713C2/ru unknown
- 2006-01-19 PL PL06700533T patent/PL1861450T3/pl unknown
- 2006-01-19 ES ES06700533.0T patent/ES2626978T3/es active Active
- 2006-01-19 EP EP06700533.0A patent/EP1861450B1/de active Active
- 2006-01-19 KR KR1020077023083A patent/KR101229581B1/ko active IP Right Grant
- 2006-01-19 US US11/886,818 patent/US9133303B2/en not_active Expired - Fee Related
- 2006-01-19 CN CN2006800092670A patent/CN101146845B/zh not_active Expired - Fee Related
- 2006-01-19 BR BRPI0614010-6A patent/BRPI0614010B1/pt not_active IP Right Cessation
- 2006-01-19 MX MX2007011175A patent/MX2007011175A/es active IP Right Grant
- 2006-01-19 EA EA200702051A patent/EA012301B1/ru not_active IP Right Cessation
- 2006-01-19 WO PCT/CH2006/000043 patent/WO2006099755A1/de active Application Filing
- 2006-01-19 LT LTEP06700533.0T patent/LT1861450T/lt unknown
- 2006-02-22 AR ARP060100647 patent/AR053142A1/es active IP Right Grant
- 2006-02-24 TW TW95106193A patent/TWI431037B/zh not_active IP Right Cessation
-
2007
- 2007-08-28 ZA ZA200707540A patent/ZA200707540B/xx unknown
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
TWI743034B (zh) * | 2015-04-14 | 2021-10-21 | 德商伍德伊文達菲瑟有限公司 | 用於從可結晶熱塑性材料顆粒中結晶和分離低分子成分之方法及其裝置 |
CN114773796A (zh) * | 2021-01-22 | 2022-07-22 | Skc株式会社 | 聚酯膜、其制备方法及使用其用于再生聚对苯二甲酸乙二醇酯容器的方法 |
Also Published As
Publication number | Publication date |
---|---|
EA012301B1 (ru) | 2009-08-28 |
BRPI0614010B1 (pt) | 2018-05-15 |
EA200702051A1 (ru) | 2008-02-28 |
AR053142A1 (es) | 2007-04-25 |
EP1861450B1 (de) | 2017-03-01 |
ZA200707540B (en) | 2008-09-25 |
WO2006099755A1 (de) | 2006-09-28 |
CN101146845B (zh) | 2011-03-30 |
LT1861450T (lt) | 2017-05-25 |
US20090082541A1 (en) | 2009-03-26 |
KR101229581B1 (ko) | 2013-02-04 |
UA90713C2 (en) | 2010-05-25 |
TWI431037B (zh) | 2014-03-21 |
US9133303B2 (en) | 2015-09-15 |
KR20070121725A (ko) | 2007-12-27 |
EP1861450A1 (de) | 2007-12-05 |
MX2007011175A (es) | 2007-11-07 |
TW200640986A (en) | 2006-12-01 |
DE102005014071A1 (de) | 2006-09-28 |
BRPI0614010A2 (pt) | 2011-03-01 |
PL1861450T3 (pl) | 2017-08-31 |
ES2626978T3 (es) | 2017-07-26 |
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