CN101080829A - 锰干电池负极锌材料的制造方法 - Google Patents
锰干电池负极锌材料的制造方法 Download PDFInfo
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- CN101080829A CN101080829A CNA2005800429302A CN200580042930A CN101080829A CN 101080829 A CN101080829 A CN 101080829A CN A2005800429302 A CNA2005800429302 A CN A2005800429302A CN 200580042930 A CN200580042930 A CN 200580042930A CN 101080829 A CN101080829 A CN 101080829A
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- China
- Prior art keywords
- zinc
- negative electrode
- dry cell
- manufacturing
- formed body
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 0 CCC1C2(CC*(C)C3)C3C1C2 Chemical compound CCC1C2(CC*(C)C3)C3C1C2 0.000 description 1
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-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C18/00—Alloys based on zinc
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/06—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars
- B22D11/0602—Continuous casting of metals, i.e. casting in indefinite lengths into moulds with travelling walls, e.g. with rolls, plates, belts, caterpillars formed by a casting wheel and belt, e.g. Properzi-process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/1206—Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22F—CHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
- C22F1/00—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
- C22F1/16—Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of other metals or alloys based thereon
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
- H01M4/08—Processes of manufacture
- H01M4/12—Processes of manufacture of consumable metal or alloy electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/244—Zinc electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/42—Alloys based on zinc
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Metallurgy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Continuous Casting (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Primary Cells (AREA)
Abstract
Description
添加元素(质量%) | 腐蚀减量(mg) | 寿命相对值 | |
参照例 | Pb 0.3 | 4.8 | 100 |
比较例1 | Bi 0.05 | 10.3 | 95 |
实施例1 | Bi 0.1 | 3.7 | 101 |
实施例2 | Bi 0.3 | 2.1 | 101 |
实施例3 | Bi 0.5 | 1.4 | 101 |
实施例4 | Bi 0.7 | 1.2 | 102 |
比较例2 | Bi 1.0 | 1.2 | 96 |
实施例5 | Bi 0.3Mg 0.0003 | 2.0 | 100 |
实施例6 | Bi 0.3Mg 0.0005 | 2.1 | 101 |
实施例7 | Bi 0.3Mg 0.01 | 2.1 | 101 |
实施例8 | Bi 0.3Mg 0.05 | 2.2 | 100 |
实施例9 | Bi 0.3Mg 0.07 | 2.8 | 98 |
Bi添加量(Mg添加量) | 铸造机出口锌板的折断发生率(%) | 铸造机出口锌板的结晶状态(针状结晶发生率)(%) | 压延后锌板的龟裂状况(优、良、可、不可) | |
比较例3 | 0.05 | 0 | 9 | 可 |
实施例10 | 0.1 | 0 | 6 | 良 |
实施例11 | 0.3 | 0 | 4 | 优 |
实施例12 | 0.5 | 0 | 5 | 优 |
实施例13 | 0.7 | 0 | 7 | 良 |
比较例4 | 1.0 | 10 | 17 | 不可 |
实施例14 | 0.3(0.005) | 0 | 4 | 优 |
实施例15 | 0.3(0.05) | 0 | 5 | 优 |
锭模内熔融锌合金的温度(℃) | 铸造机出口锌板的折断发生率(%) | 铸造机出口锌板的结晶状态(针状结晶发生率)(%) | 压延后锌板的龟裂状况(优、良、可、不可) | |
实施例16 | 300 | 0 | 12 | 可 |
实施例17 | 400 | 0 | 9 | 良 |
实施例18 | 500 | 0 | 4 | 优 |
实施例19 | 600 | 0 | 8 | 良 |
实施例20 | 700 | 0 | 10 | 可 |
冷却水温度(℃) | 铸造机出口锌板的折断发生率(%) | 铸造机出口锌板的结晶状态(针状结晶发生率)(%) | 压延后锌板的龟裂状况(优、良、可、不可) | |
实施例21 | 10 | 0 | 7 | 良 |
实施例22 | 20 | 0 | 3 | 优 |
实施例23 | 30 | 0 | 4 | 优 |
实施例24 | 40 | 0 | 8 | 良 |
实施例25 | 50 | 0 | 12 | 可 |
锌板插入压延机时的温度(℃) | 铸造机出口锌板的折断发生率(%) | 铸造机出口锌板的结晶状态(针状结晶发生率)(%) | 压延后锌板的龟裂状况(优、良、可、不可) | |
实施例26 | 85 | 0 | 10 | 可 |
实施例27 | 100 | 0 | 7 | 良 |
实施例28 | 150 | 0 | 3 | 优 |
实施例29 | 190 | 0 | 8 | 良 |
实施例30 | 202 | 0 | 12 | 可 |
实施例31 | 1904次压延 | 0 | 7 | 优 |
实施例32 | 1906次压延 | 0 | 8 | 良 |
实施例33 | 1907次压延 | 0 | 9 | 可 |
在铸造机出口的带状成形体的厚度(mm) | 铸造机圆盘直径(cm) | 铸造机出口带状成形体的折断发生率(%) | 铸造机出口锌板的结晶状态(针状结晶发生率)(%) | 压延后锌板的龟裂状况(优、良、可、不可) | |
实施例34 | 1 | 18 | 0 | 11 | 可 |
实施例35 | 1 | 25 | 0 | 7 | 良 |
实施例36 | 1 | 50 | 0 | 4 | 优 |
实施例37 | 1 | 100 | 0 | 8 | 良 |
实施例38 | 1 | 200 | 0 | 9 | 良 |
实施例39 | 10 | 18 | 15 | 14 | 可 |
实施例40 | 10 | 50 | 0 | 6 | 优 |
实施例41 | 10 | 100 | 0 | 5 | 优 |
实施例42 | 10 | 200 | 0 | 8 | 良 |
实施例43 | 10 | 220 | 0 | 13 | 可 |
实施例44 | 30 | 18 | 10 | 14 | 可 |
实施例45 | 30 | 50 | 0 | 9 | 良 |
实施例46 | 30 | 100 | 0 | 5 | 优 |
实施例47 | 30 | 200 | 0 | 8 | 良 |
实施例48 | 30 | 220 | 0 | 12 | 可 |
冷却水温度(℃) | 锌板投入压延机时的温度(℃) | 铸造机出口锌板的结晶状态(针状结晶发生率)(%) | 压延后锌板的横断面的平均粒径(μm)200μm以上的面积比(%) | 压延后锌板的龟裂状况(优、良、可、不可) | |
实施例49 | 20 | 88 | 9 | 78μm(22%) | 可 |
实施例50 | 25 | 100 | 7 | 76μm(9%) | 良 |
实施例51 | 30 | 120 | 5 | 72μm(8%) | 优 |
实施例52 | 40 | 140 | 4 | 50μm(4%) | 优 |
实施例53 | 40 | 160 | 8 | 69μm(7%) | 优 |
实施例54 | 45 | 190 | 9 | 70μm(10%) | 良 |
实施例55 | 50 | 218 | 12 | 90μm(28%) | 可 |
Claims (13)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2004301215 | 2004-10-15 | ||
JP301215/2004 | 2004-10-15 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101080829A true CN101080829A (zh) | 2007-11-28 |
CN100530775C CN100530775C (zh) | 2009-08-19 |
Family
ID=36148159
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2005800429302A Active CN100530775C (zh) | 2004-10-15 | 2005-06-06 | 锰干电池负极锌材料的制造方法 |
Country Status (8)
Country | Link |
---|---|
US (1) | US7874346B2 (zh) |
EP (1) | EP1808917B1 (zh) |
JP (1) | JP5072363B2 (zh) |
KR (1) | KR100929283B1 (zh) |
CN (1) | CN100530775C (zh) |
HK (1) | HK1110152A1 (zh) |
PL (1) | PL1808917T3 (zh) |
WO (1) | WO2006040857A1 (zh) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110756778A (zh) * | 2019-11-04 | 2020-02-07 | 武汉深蓝自动化设备股份有限公司 | 一种铅酸蓄电池板栅连续铸造装置 |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5091408B2 (ja) * | 2003-11-07 | 2012-12-05 | 東芝ホームアプライアンス株式会社 | 電池用負極活物質材料、電池用負極缶、電池用負極亜鉛板、マンガン乾電池、及びその製造方法 |
JP5091409B2 (ja) * | 2003-12-25 | 2012-12-05 | 東芝ホームアプライアンス株式会社 | 電池用負極缶、およびこれを用いたマンガン乾電池 |
CN101383410A (zh) * | 2003-12-25 | 2009-03-11 | 东芝电池株式会社 | 锰干电池 |
KR101500643B1 (ko) * | 2007-05-10 | 2015-03-10 | 재단법인 포항산업과학연구원 | 연속 성형 장치 및 연속 성형 방법 |
CN103480811B (zh) * | 2013-10-12 | 2015-07-01 | 武汉钢铁(集团)公司 | 急冷制带的设备及工艺 |
EP3624963B1 (de) | 2017-05-19 | 2021-08-25 | IQ Power Licensing AG | Vorrichtung zum giessen von elektrodenträgern für blei-säure-batterien |
CN112840053B (zh) * | 2018-10-03 | 2022-08-09 | 三井金属矿业株式会社 | 锌箔、使用了其的一次电池用负极活性物质材料和锌箔的制造方法 |
EP4130313A4 (en) | 2020-03-27 | 2023-09-27 | Mitsui Mining & Smelting Co., Ltd. | ZINC SHEET, ACTIVE MATERIAL FOR BATTERY NEGATIVE ELECTRODE USING SUCH SHEET AND METHOD FOR PRODUCING ZINC SHEET |
CN112371847A (zh) * | 2020-10-23 | 2021-02-19 | 昆山智盛精密铸造有限公司 | 一种高散热性合金笔记本电脑壳体成型模具及生产方法 |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4397247A (en) * | 1980-01-03 | 1983-08-09 | Lemelson Jerome H | Molding system and article |
US5002475A (en) * | 1988-10-04 | 1991-03-26 | Intellex Corporation | Reaction injection molding apparatus |
JPH05318037A (ja) | 1992-05-15 | 1993-12-03 | Mitsui Kinzoku Kyushu Kiko Kk | 連続鋳造裁断プラント装置 |
JP3651852B2 (ja) * | 1992-07-01 | 2005-05-25 | 東芝電池株式会社 | マンガン乾電池 |
JP2612138B2 (ja) | 1992-12-22 | 1997-05-21 | 富士電気化学株式会社 | 電池の負極亜鉛缶 |
JP3105115B2 (ja) | 1993-07-30 | 2000-10-30 | 東芝電池株式会社 | マンガン乾電池 |
JP2918446B2 (ja) * | 1994-04-27 | 1999-07-12 | 富士電気化学株式会社 | 電池の負極亜鉛缶 |
EP0899038B1 (en) * | 1997-08-28 | 2003-09-24 | General Motors Corporation | Process for lost foam casting of aluminium with coated pattern |
JP2000058045A (ja) * | 1998-08-10 | 2000-02-25 | Toshiba Battery Co Ltd | マンガン乾電池 |
GB9913675D0 (en) * | 1999-06-11 | 1999-08-11 | Ever Ready Ltd | Method of preparing zinc alloy foil |
US20040087754A1 (en) * | 2002-10-31 | 2004-05-06 | Paul Foley | Polyurethane compounds and articles prepared therefrom |
JP5091408B2 (ja) | 2003-11-07 | 2012-12-05 | 東芝ホームアプライアンス株式会社 | 電池用負極活物質材料、電池用負極缶、電池用負極亜鉛板、マンガン乾電池、及びその製造方法 |
CN101383410A (zh) | 2003-12-25 | 2009-03-11 | 东芝电池株式会社 | 锰干电池 |
JP5091409B2 (ja) | 2003-12-25 | 2012-12-05 | 東芝ホームアプライアンス株式会社 | 電池用負極缶、およびこれを用いたマンガン乾電池 |
-
2005
- 2005-06-06 CN CNB2005800429302A patent/CN100530775C/zh active Active
- 2005-06-06 US US11/577,267 patent/US7874346B2/en not_active Expired - Fee Related
- 2005-06-06 JP JP2006540827A patent/JP5072363B2/ja not_active Expired - Fee Related
- 2005-06-06 PL PL05751594.2T patent/PL1808917T3/pl unknown
- 2005-06-06 WO PCT/JP2005/010378 patent/WO2006040857A1/ja active Application Filing
- 2005-06-06 EP EP05751594.2A patent/EP1808917B1/en active Active
- 2005-06-06 KR KR1020077010012A patent/KR100929283B1/ko active IP Right Grant
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2008
- 2008-04-23 HK HK08104508.9A patent/HK1110152A1/xx not_active IP Right Cessation
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110756778A (zh) * | 2019-11-04 | 2020-02-07 | 武汉深蓝自动化设备股份有限公司 | 一种铅酸蓄电池板栅连续铸造装置 |
Also Published As
Publication number | Publication date |
---|---|
HK1110152A1 (en) | 2008-07-04 |
EP1808917A4 (en) | 2008-01-16 |
US20080029189A1 (en) | 2008-02-07 |
KR20070083911A (ko) | 2007-08-24 |
KR100929283B1 (ko) | 2009-11-27 |
EP1808917B1 (en) | 2016-03-30 |
EP1808917A1 (en) | 2007-07-18 |
PL1808917T3 (pl) | 2016-09-30 |
WO2006040857A1 (ja) | 2006-04-20 |
JP5072363B2 (ja) | 2012-11-14 |
JPWO2006040857A1 (ja) | 2008-05-15 |
US7874346B2 (en) | 2011-01-25 |
CN100530775C (zh) | 2009-08-19 |
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Effective date of registration: 20160825 Address after: Tokyo, Japan Patentee after: TOSHIBA LIFESTYLE PRODUCTS & SERVICES Corp. Address before: Tokyo, Japan Patentee before: TOSHIBA LIFESTYLE PRODUCTS & SERVICES Corp. Patentee before: Toshiba Corp. Effective date of registration: 20160825 Address after: Tokyo, Japan Patentee after: TOSHIBA LIFESTYLE PRODUCTS & SERVICES Corp. Patentee after: Toshiba Corp. Address before: Tokyo, Japan Patentee before: TOSHIBA LIFESTYLE PRODUCTS & SERVICES Corp. Patentee before: Toshiba Home Appliances Holdings Corp. Patentee before: Toshiba Corp. |