CN100455512C - 电池级单水氢氧化锂的制备方法 - Google Patents
电池级单水氢氧化锂的制备方法 Download PDFInfo
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- CN100455512C CN100455512C CNB2007100510165A CN200710051016A CN100455512C CN 100455512 C CN100455512 C CN 100455512C CN B2007100510165 A CNB2007100510165 A CN B2007100510165A CN 200710051016 A CN200710051016 A CN 200710051016A CN 100455512 C CN100455512 C CN 100455512C
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- GLXDVVHUTZTUQK-UHFFFAOYSA-M lithium;hydroxide;hydrate Chemical compound [Li+].O.[OH-] GLXDVVHUTZTUQK-UHFFFAOYSA-M 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 title description 29
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 claims abstract description 137
- 239000000047 product Substances 0.000 claims abstract description 41
- 239000007788 liquid Substances 0.000 claims abstract description 29
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 27
- 239000007787 solid Substances 0.000 claims abstract description 25
- 239000012043 crude product Substances 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 238000001914 filtration Methods 0.000 claims abstract description 20
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 claims abstract description 15
- 238000001704 evaporation Methods 0.000 claims abstract description 14
- 238000001816 cooling Methods 0.000 claims abstract description 11
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000000706 filtrate Substances 0.000 claims abstract description 9
- 239000011734 sodium Substances 0.000 claims description 29
- 238000003756 stirring Methods 0.000 claims description 21
- 238000002360 preparation method Methods 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 238000000926 separation method Methods 0.000 claims description 16
- 230000008020 evaporation Effects 0.000 claims description 10
- 238000002425 crystallisation Methods 0.000 claims description 6
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 5
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 5
- 238000001291 vacuum drying Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 4
- 230000002000 scavenging effect Effects 0.000 claims description 4
- 210000002966 serum Anatomy 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229910001868 water Inorganic materials 0.000 abstract description 14
- 238000002386 leaching Methods 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 6
- 238000007670 refining Methods 0.000 abstract description 6
- 239000007832 Na2SO4 Substances 0.000 abstract 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 abstract 1
- PQVSTLUFSYVLTO-UHFFFAOYSA-N ethyl n-ethoxycarbonylcarbamate Chemical compound CCOC(=O)NC(=O)OCC PQVSTLUFSYVLTO-UHFFFAOYSA-N 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 229940040692 lithium hydroxide monohydrate Drugs 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 229910052938 sodium sulfate Inorganic materials 0.000 abstract 1
- 235000011152 sodium sulphate Nutrition 0.000 abstract 1
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 32
- 229910052744 lithium Inorganic materials 0.000 description 16
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 14
- 241001131796 Botaurus stellaris Species 0.000 description 11
- 238000001354 calcination Methods 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 238000005119 centrifugation Methods 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 description 6
- 229910001148 Al-Li alloy Inorganic materials 0.000 description 5
- FCVHBUFELUXTLR-UHFFFAOYSA-N [Li].[AlH3] Chemical compound [Li].[AlH3] FCVHBUFELUXTLR-UHFFFAOYSA-N 0.000 description 5
- 239000011575 calcium Substances 0.000 description 5
- 238000005868 electrolysis reaction Methods 0.000 description 5
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 5
- 239000011777 magnesium Substances 0.000 description 5
- 238000001556 precipitation Methods 0.000 description 5
- 238000005265 energy consumption Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000004519 grease Substances 0.000 description 4
- PAZHGORSDKKUPI-UHFFFAOYSA-N lithium metasilicate Chemical compound [Li+].[Li+].[O-][Si]([O-])=O PAZHGORSDKKUPI-UHFFFAOYSA-N 0.000 description 4
- 229910052912 lithium silicate Inorganic materials 0.000 description 4
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 235000011116 calcium hydroxide Nutrition 0.000 description 3
- 238000009993 causticizing Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000012528 membrane Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000344 soap Substances 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 2
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 229910001424 calcium ion Inorganic materials 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- 229910001425 magnesium ion Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- -1 Monohydrate lithium hydroxide Chemical class 0.000 description 1
- 229910006069 SO3H Inorganic materials 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 239000003957 anion exchange resin Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- QYHKLBKLFBZGAI-UHFFFAOYSA-N boron magnesium Chemical compound [B].[Mg] QYHKLBKLFBZGAI-UHFFFAOYSA-N 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001718 carbodiimides Chemical class 0.000 description 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical compound OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003518 caustics Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- UQSQSQZYBQSBJZ-UHFFFAOYSA-N fluorosulfonic acid Chemical compound OS(F)(=O)=O UQSQSQZYBQSBJZ-UHFFFAOYSA-N 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011381 foam concrete Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003317 industrial substance Substances 0.000 description 1
- 239000003014 ion exchange membrane Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 229910001416 lithium ion Inorganic materials 0.000 description 1
- GCICAPWZNUIIDV-UHFFFAOYSA-N lithium magnesium Chemical compound [Li].[Mg] GCICAPWZNUIIDV-UHFFFAOYSA-N 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 230000001050 lubricating effect Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010010 raising Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000019155 vitamin A Nutrition 0.000 description 1
- 239000011719 vitamin A Substances 0.000 description 1
- 238000003809 water extraction Methods 0.000 description 1
Images
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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CNB2007100510165A CN100455512C (zh) | 2007-12-28 | 2007-12-28 | 电池级单水氢氧化锂的制备方法 |
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CNB2007100510165A CN100455512C (zh) | 2007-12-28 | 2007-12-28 | 电池级单水氢氧化锂的制备方法 |
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CN101214978A CN101214978A (zh) | 2008-07-09 |
CN100455512C true CN100455512C (zh) | 2009-01-28 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101830484A (zh) * | 2010-04-29 | 2010-09-15 | 合肥国轩高科动力能源有限公司 | 从液相法制备LiFePO4材料的废弃滤液中回收氢氧化锂的方法 |
WO2019220004A1 (en) | 2018-05-18 | 2019-11-21 | Outotec (Finland) Oy | Method for recovering lithium hydroxide |
WO2021094647A1 (en) | 2019-11-15 | 2021-05-20 | Outotec (Finland) Oy | Arrangement and method for recovering lithium hydroxide |
WO2024089394A1 (en) * | 2022-10-27 | 2024-05-02 | Research By British Lithium Ltd | Production of battery grade chemicals |
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CN102020294B (zh) * | 2010-12-23 | 2012-04-25 | 雅安华汇锂业科技材料有限公司 | 无尘级单水氢氧化锂及其制备方法 |
CN102659144B (zh) * | 2012-04-26 | 2014-02-12 | 雅安华汇锂业科技材料有限公司 | 高纯级单水氢氧化锂的制备方法 |
CN102786069B (zh) * | 2012-09-07 | 2014-02-12 | 雅安华汇锂业科技材料有限公司 | 无尘级单水氢氧化锂的制备方法 |
CN103408041B (zh) * | 2013-08-22 | 2015-08-05 | 四川国理锂材料有限公司 | 碳酸锂的生产工艺 |
MX2017005919A (es) * | 2014-11-05 | 2017-08-03 | Reed Advanced Mat Pty Ltd | Produccion de hidroxido de litio. |
CN104944447B (zh) * | 2015-06-25 | 2017-01-25 | 江苏容汇通用锂业股份有限公司 | 一种电池级一水氢氧化锂的制备方法 |
JP7030049B2 (ja) * | 2015-08-27 | 2022-03-04 | ネマスカ リチウム インコーポレーテッド | リチウム含有材料を処理するための方法 |
CN105819472A (zh) * | 2016-03-09 | 2016-08-03 | 江苏容汇通用锂业股份有限公司 | 一种用硫酸锂溶液生产高纯度电池级碳酸锂的方法 |
CN106348318B (zh) * | 2016-10-28 | 2017-08-08 | 荆门市格林美新材料有限公司 | 氧化锂制备自动化系统 |
CN106629787B (zh) * | 2016-12-20 | 2018-09-18 | 阿坝中晟锂业有限公司 | 一种电池级氢氧化锂的制备方法 |
CN110407237B (zh) * | 2018-04-26 | 2022-01-25 | 天齐锂业股份有限公司 | 联合制备电动汽车级碳酸锂和单水氢氧化锂的方法 |
CN110407235B (zh) * | 2018-04-26 | 2022-01-25 | 天齐锂业股份有限公司 | 电动汽车级单水氢氧化锂的制备方法 |
CN109442870B (zh) * | 2018-10-25 | 2020-11-03 | 江西赣锋锂业股份有限公司 | 一种干燥单水氢氧化锂的方法 |
CN109761251A (zh) * | 2019-04-11 | 2019-05-17 | 天齐锂业资源循环技术研发(江苏)有限公司 | 一种利用废旧锂离子电池制备氢氧化锂的方法 |
CN111874925A (zh) * | 2019-07-10 | 2020-11-03 | 成都市真璞科技有限公司 | 从锂盐副产品中回收锂的方法 |
CN110330041B (zh) * | 2019-07-22 | 2022-06-14 | 重庆锦弘新材料技术工程有限公司 | 一种低品级碳酸锂的高值化利用方法 |
CN112110462B (zh) * | 2020-08-31 | 2023-05-12 | 荆门市格林美新材料有限公司 | 一种用连续冷冻溶析结晶方式生产电池级氢氧化锂的方法 |
CN112456518B (zh) * | 2020-12-11 | 2022-04-29 | 武汉工程大学 | 一种含钠锂卤水的钠锂分离与浓缩的方法 |
CN112645361A (zh) * | 2020-12-23 | 2021-04-13 | 广西天源新能源材料有限公司 | 一种用锂辉石和锂聚合物生产单水氢氧化锂的工艺 |
CN114590829A (zh) * | 2022-03-25 | 2022-06-07 | 郑州中科新兴产业技术研究院 | 一种含铝锂固废资源化回收利用方法 |
CN114538480A (zh) * | 2022-03-25 | 2022-05-27 | 江西九岭锂业股份有限公司 | 一种微粉电池级单水氢氧化锂的工艺方法 |
CN115676857A (zh) * | 2022-12-19 | 2023-02-03 | 唐山润达纳米高新钙业有限公司 | 一种联合生产锂电池原材料、碳酸钙和硫酸钙的方法 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1486931A (zh) * | 2002-09-30 | 2004-04-07 | 南通泛亚锂业有限公司 | 一水氢氧化锂生产工艺 |
-
2007
- 2007-12-28 CN CNB2007100510165A patent/CN100455512C/zh active Active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1486931A (zh) * | 2002-09-30 | 2004-04-07 | 南通泛亚锂业有限公司 | 一水氢氧化锂生产工艺 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101830484A (zh) * | 2010-04-29 | 2010-09-15 | 合肥国轩高科动力能源有限公司 | 从液相法制备LiFePO4材料的废弃滤液中回收氢氧化锂的方法 |
WO2019220004A1 (en) | 2018-05-18 | 2019-11-21 | Outotec (Finland) Oy | Method for recovering lithium hydroxide |
US11292725B2 (en) | 2018-05-18 | 2022-04-05 | Metso Outotec Finland Oy | Method for recovering lithium hydroxide |
WO2021094647A1 (en) | 2019-11-15 | 2021-05-20 | Outotec (Finland) Oy | Arrangement and method for recovering lithium hydroxide |
WO2024089394A1 (en) * | 2022-10-27 | 2024-05-02 | Research By British Lithium Ltd | Production of battery grade chemicals |
Also Published As
Publication number | Publication date |
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CN101214978A (zh) | 2008-07-09 |
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