CN100360571C - α-烯烃聚合的液相法 - Google Patents

α-烯烃聚合的液相法 Download PDF

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Publication number
CN100360571C
CN100360571C CNB038141981A CN03814198A CN100360571C CN 100360571 C CN100360571 C CN 100360571C CN B038141981 A CNB038141981 A CN B038141981A CN 03814198 A CN03814198 A CN 03814198A CN 100360571 C CN100360571 C CN 100360571C
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CN
China
Prior art keywords
butene
deactivator
polymerization
polybutene
solution
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Expired - Fee Related
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CNB038141981A
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English (en)
Chinese (zh)
Other versions
CN1662565A (zh
Inventor
D·比加维
G·梅
N·阿里奇德菲内蒂
G·彭佐
G·维塔尔
M·科维兹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Basell Poliolefine Italia SRL
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Basell Poliolefine Italia SRL
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/42—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using short-stopping agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04—Monomers containing three or four carbon atoms
    • C08F110/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04—Monomers containing three or four carbon atoms
    • C08F10/08—Butenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/04—Polymerisation in solution
    • C08F2/06—Organic solvent
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/903—Monomer polymerized in presence of transition metal containing catalyst and hydrocarbon additive affecting polymer properties of catalyst activity

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CNB038141981A 2002-06-24 2003-06-17 α-烯烃聚合的液相法 Expired - Fee Related CN100360571C (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
EP02077543 2002-06-24
EP02077543.3 2002-06-24
US40819602P 2002-09-04 2002-09-04
US60/408,196 2002-09-04
PCT/EP2003/006348 WO2004000895A1 (en) 2002-06-24 2003-06-17 Liquid phase process for the polymerization of alpha-olefins

Publications (2)

Publication Number Publication Date
CN1662565A CN1662565A (zh) 2005-08-31
CN100360571C true CN100360571C (zh) 2008-01-09

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Family Applications (1)

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CNB038141981A Expired - Fee Related CN100360571C (zh) 2002-06-24 2003-06-17 α-烯烃聚合的液相法

Country Status (8)

Country Link
US (1) US7160964B2 (cg-RX-API-DMAC7.html)
EP (1) EP1515998B1 (cg-RX-API-DMAC7.html)
JP (1) JP4498925B2 (cg-RX-API-DMAC7.html)
KR (1) KR100992799B1 (cg-RX-API-DMAC7.html)
CN (1) CN100360571C (cg-RX-API-DMAC7.html)
AT (1) ATE509043T1 (cg-RX-API-DMAC7.html)
AU (1) AU2003246444A1 (cg-RX-API-DMAC7.html)
WO (1) WO2004000895A1 (cg-RX-API-DMAC7.html)

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RU2340634C2 (ru) 2003-06-12 2008-12-10 Базелль Полиолефин Италия С.Р.Л. Пост-обработка полимерных гранул
JP2007514026A (ja) * 2003-12-11 2007-05-31 バセル ポリオレフィン イタリア エス．アール．エル． オレフィンの重合のための液相法
RU2358988C2 (ru) * 2003-12-19 2009-06-20 Базелль Полиолефине Гмбх Способ (со)полимеризации этилена
WO2005058982A1 (en) * 2003-12-19 2005-06-30 Basell Polyolefine Gmbh Process for the (co)polymerization of ethylene
US8026311B2 (en) * 2005-03-25 2011-09-27 Braskem America, Inc. Process for production of propylene copolymers
RU2007145355A (ru) * 2005-06-07 2009-06-20 Базелль Полиолефин Италия С.Р.Л. (It) Полиолефиновые нанокомпозитные материалы
KR101298928B1 (ko) * 2005-07-27 2013-08-27 바셀 폴리올레핀 이탈리아 에스.알.엘 폴리올레핀 제조를 위한 중합 방법
US7446167B2 (en) 2006-04-13 2008-11-04 Fina Technology, Inc. Catalyst deactivation agents and methods for use of same
US20090326156A1 (en) * 2006-08-08 2009-12-31 Giampaolo Pellegatti Butene-1 copolymers
US10174137B2 (en) 2007-04-27 2019-01-08 Basell Poliolefine Italia S.R.I. Butene-1 terpolymers and process for their preparation
US7879958B2 (en) * 2007-08-07 2011-02-01 Bridgestone Corporation Polyhydroxy compounds as polymerization quenching agents
WO2009068365A2 (en) 2007-11-27 2009-06-04 Basell Poliolefine Italia S.R.L. Polyolefin nanocomposites materials
EP2072540A1 (en) * 2007-12-20 2009-06-24 Basell Poliolefine Italia S.r.l. Solution polymerization process for preparing polyolefins
KR101598643B1 (ko) 2008-03-14 2016-02-29 다이야니트릭스 가부시키가이샤 아크릴아마이드 수용액의 안정화 방법
KR101672225B1 (ko) * 2008-11-25 2016-11-03 바셀 폴리올레핀 이탈리아 에스.알.엘 올레핀 중합의 용액 방법
KR101123154B1 (ko) * 2008-12-03 2012-03-19 주식회사 엘지화학 전이금속 촉매의 비활성화제 및 이를 이용한 촉매의 비활성화 방법
SG11201402517SA (en) * 2011-12-22 2014-06-27 Exxonmobil Chem Patents Inc Methods and apparatus for deactivating a catalyst composition
WO2013183600A1 (ja) * 2012-06-04 2013-12-12 出光興産株式会社 粘接着剤組成物及びこれを用いた粘着テープ
CN105622813B (zh) * 2016-04-06 2018-01-26 辽宁方大工程设计有限公司 用于聚氯乙烯种子法糊树脂的生产装置及其生产工艺
US10450392B2 (en) 2016-07-29 2019-10-22 Exxonmobil Chemical Patents Inc. Polymerization processes using high molecular weight polyhydric quenching agents
CN110894249A (zh) * 2018-09-12 2020-03-20 中国石油化工股份有限公司 一种丁烯-1的均相聚合方法及装置
CN113056490B (zh) * 2019-01-18 2023-07-28 株式会社Lg化学 聚丁烯的分离方法
WO2021099106A1 (en) * 2019-11-18 2021-05-27 Basell Poliolefine Italia S.R.L. Continuous solution polymerization process
EP4263636A1 (en) 2020-12-16 2023-10-25 Basell Poliolefine Italia S.r.l. Flexible butene-1 copolymer for pipes
CN114316104B (zh) * 2022-01-07 2023-12-19 万华化学集团股份有限公司 一种烯烃聚合催化剂的减活化方法
CN115608276B (zh) * 2022-11-15 2025-11-21 国家能源集团宁夏煤业有限责任公司 连续生产聚α-烯烃的系统及方法
CN116655841B (zh) * 2023-06-06 2024-04-19 中国石油天然气股份有限公司 一种连续溶液聚合方法及系统
CN116715788B (zh) * 2023-08-09 2023-12-01 山东东方宏业化工有限公司 一种宽分子量分布的聚丁烯-1合成方法

Citations (5)

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Publication number Priority date Publication date Assignee Title
DE1645282A1 (de) * 1964-06-15 1970-07-16 Mobil Oil Corp Verfahren zum Abtrennen eines Polymerisats eines 1-Olefins mit 4 bis 10 Kohlenstoffatomen aus einer Loesung in seinem fluessigen 1-Olefinmonomer
EP0172961A1 (en) * 1984-08-30 1986-03-05 Mitsui Petrochemical Industries, Ltd. 1-Butene polymer and its use
EP0225099A2 (en) * 1985-11-15 1987-06-10 Chisso Corporation Process for continuously producing a propylene-ethylene block copolymer
CN87106011A (zh) * 1986-09-08 1988-07-06 埃尔·帕索产品公司 生产稳定无腐蚀性的无定形聚α-烯烃的工艺方法
CN1157000A (zh) * 1994-03-25 1997-08-13 埃克森化学专利公司 不相容的聚合催化剂之间的转换方法

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US3356666A (en) 1963-08-27 1967-12-05 Allied Chem Process of polymerizing butene-1
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
JPS5922910A (ja) * 1982-07-29 1984-02-06 Sumitomo Chem Co Ltd エチレン重合体またはエチレン共重合体の製造方法
JPS6153307A (ja) * 1984-08-23 1986-03-17 Chisso Corp α−オレフインの連続スラリ−重合法
JPS61159404A (ja) * 1985-01-07 1986-07-19 Mitsui Toatsu Chem Inc ポリオレフインの精製方法
US4634744A (en) * 1985-01-09 1987-01-06 Chemplex Company Method of catalyst deactivation
JPS61166802A (ja) * 1985-01-18 1986-07-28 Mitsui Toatsu Chem Inc 希釈剤の回収方法
US5118757A (en) * 1990-03-26 1992-06-02 Shell Oil Company Polymer production
JPH06128302A (ja) * 1992-10-19 1994-05-10 Idemitsu Petrochem Co Ltd オレフィン系重合体の製造方法
JPH1171421A (ja) * 1997-07-03 1999-03-16 Sumitomo Chem Co Ltd オレフィン重合用固体触媒成分、オレフィン重合用触媒、及びオレフィン系重合体の製造方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE1645282A1 (de) * 1964-06-15 1970-07-16 Mobil Oil Corp Verfahren zum Abtrennen eines Polymerisats eines 1-Olefins mit 4 bis 10 Kohlenstoffatomen aus einer Loesung in seinem fluessigen 1-Olefinmonomer
EP0172961A1 (en) * 1984-08-30 1986-03-05 Mitsui Petrochemical Industries, Ltd. 1-Butene polymer and its use
EP0225099A2 (en) * 1985-11-15 1987-06-10 Chisso Corporation Process for continuously producing a propylene-ethylene block copolymer
CN87106011A (zh) * 1986-09-08 1988-07-06 埃尔·帕索产品公司 生产稳定无腐蚀性的无定形聚α-烯烃的工艺方法
CN1157000A (zh) * 1994-03-25 1997-08-13 埃克森化学专利公司 不相容的聚合催化剂之间的转换方法

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Publication number Publication date
KR20050016627A (ko) 2005-02-21
JP4498925B2 (ja) 2010-07-07
JP2005530914A (ja) 2005-10-13
WO2004000895A1 (en) 2003-12-31
ATE509043T1 (de) 2011-05-15
EP1515998B1 (en) 2011-05-11
AU2003246444A1 (en) 2004-01-06
KR100992799B1 (ko) 2010-11-08
EP1515998A1 (en) 2005-03-23
US7160964B2 (en) 2007-01-09
US20050250917A1 (en) 2005-11-10
CN1662565A (zh) 2005-08-31

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Termination date: 20130617