CN100343286C - 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法 - Google Patents

在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法 Download PDF

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Publication number
CN100343286C
CN100343286C CNB018158609A CN01815860A CN100343286C CN 100343286 C CN100343286 C CN 100343286C CN B018158609 A CNB018158609 A CN B018158609A CN 01815860 A CN01815860 A CN 01815860A CN 100343286 C CN100343286 C CN 100343286C
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CN1458937A (zh
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M·德斯塔拉克
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Rhodia Chimie SAS
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00Chemical modification by after-treatment
    • C08F8/34Introducing sulfur atoms or sulfur-containing groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/38Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
CNB018158609A 2000-09-18 2001-09-11 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法 Expired - Fee Related CN100343286C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0011877A FR2814168B1 (fr) 2000-09-18 2000-09-18 Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee en presence d'un compose disulfure
FR00/11877 2000-09-18

Publications (2)

Publication Number Publication Date
CN1458937A CN1458937A (zh) 2003-11-26
CN100343286C true CN100343286C (zh) 2007-10-17

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CNB018158609A Expired - Fee Related CN100343286C (zh) 2000-09-18 2001-09-11 在二硫化物化合物存在下,通过可控自由基聚合合成嵌段聚合物的方法

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US (1) US6916884B2 (enExample)
EP (1) EP1319027B1 (enExample)
JP (1) JP2004509181A (enExample)
KR (1) KR20030032031A (enExample)
CN (1) CN100343286C (enExample)
AT (1) ATE320451T1 (enExample)
AU (2) AU9000901A (enExample)
BR (1) BR0113941A (enExample)
CA (1) CA2422593A1 (enExample)
CZ (1) CZ2003751A3 (enExample)
DE (1) DE60118007T2 (enExample)
FR (1) FR2814168B1 (enExample)
HU (1) HUP0303387A3 (enExample)
MX (1) MXPA03002318A (enExample)
NO (1) NO20031231L (enExample)
PL (1) PL361423A1 (enExample)
SK (1) SK3112003A3 (enExample)
WO (1) WO2002022688A2 (enExample)
ZA (1) ZA200301563B (enExample)

Families Citing this family (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2794463B1 (fr) 1999-06-04 2005-02-25 Rhodia Chimie Sa Procede de synthese de polymeres par polymerisation radicalaire controlee a l'aide de xanthates halogenes
EP1483362B2 (en) * 2002-02-11 2012-12-26 Rhodia Chimie Dishwashing detergent composition comprising a block copolymer
FR2842814B1 (fr) 2002-07-26 2004-10-22 Coatex Sas Procede de polymerisation radicalaire controlee de l'acide acrylique et de ses sels, les polymeres obtenus, et leurs applications.
NL1025250C2 (nl) * 2004-01-15 2005-07-18 Univ Eindhoven Tech Multi- en bi-functionele dithiocarboxylaatverbindingen, monofunctionele alkoxycarbonyldithiocarbamaatverbinding, een werkwijze voor de bereiding van alkoxycarbonyldithiocarbamaatverbindingen evenals een werkwijze voor het door middel van radicaalpolymerisatie bereiden van multiblok-copolymeren.
US7279446B2 (en) 2004-11-15 2007-10-09 Rhodia Inc. Viscoelastic surfactant fluids having enhanced shear recovery, rheology and stability performance
DE602006006825D1 (de) * 2006-08-17 2009-06-25 Rhodia Operations Blockcopolymere, Verfahren zu deren Herstellung und ihre Verwendung in Emulsionen
JP5408435B2 (ja) 2007-09-12 2014-02-05 日産化学工業株式会社 ハイパーブランチポリマーの製造方法
WO2010101252A1 (ja) * 2009-03-06 2010-09-10 日産化学工業株式会社 ハイパーブランチポリマーの製造方法
WO2011007862A1 (ja) * 2009-07-16 2011-01-20 ダイキン工業株式会社 含フッ素ブロック共重合体の製造方法
US20170172142A1 (en) 2015-12-10 2017-06-22 Adama Makhteshim Ltd. Polyelectrolyte-layer forming block copolymers and compositions and uses thereof
WO2017103635A1 (en) 2015-12-16 2017-06-22 Rhodia Poliamida E Especialidades Ltda Emulsifier system for explosive emulsions
WO2017218735A1 (en) * 2016-06-15 2017-12-21 Rhodia Operations High performance surfactant fee latexes for improved water resistance
US20180072909A1 (en) * 2016-09-09 2018-03-15 Rhodia Operations Self-thickening latex for waterborne systems and related methods
AR114185A1 (es) 2018-01-23 2020-07-29 Adama Makhteshim Ltd Síntesis de 5-cloro-2-[(3,4,4-trifluoro-3-buten-1-il)tio]-tiazol
WO2020173725A1 (en) 2019-02-28 2020-09-03 Rhodia Operations Compositions for high stabilization of emulsions
WO2020182919A1 (en) 2019-03-12 2020-09-17 Rhodia Operations Stabilized friction reducer emulsions
FR3095447B1 (fr) 2019-04-26 2021-12-24 Michelin & Cie Bandage pour roue de véhicule transportable manuellement
CN110357992A (zh) * 2019-07-09 2019-10-22 复旦大学 一种超高分子量含氟聚合物的制备方法
FR3111636B1 (fr) 2020-06-18 2022-08-26 Michelin & Cie Composition élastomérique comprenant un composé phénolique et un composé de la famille des oses
FR3113905B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
FR3113906B1 (fr) 2020-09-04 2022-08-05 Michelin & Cie Composition de caoutchouc a base d’elastomere dienique fortement sature
WO2023210671A1 (ja) * 2022-04-26 2023-11-02 京セラ株式会社 共重合体、高分子膜、測定用装置および測定用担体

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5254198A (en) * 1988-06-20 1993-10-19 Kuraray Co., Ltd. Method of bonding a metal or alloy utilizing a polymerizable thiocarboxylic acid or a derivative thereof
WO1998058974A1 (fr) * 1997-06-23 1998-12-30 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
WO1999035178A1 (fr) * 1997-12-31 1999-07-15 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithioesters
CN1228787A (zh) * 1996-07-10 1999-09-15 纳幕尔杜邦公司 具有活性特征的聚合作用

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE156600C (enExample)
DE2756128A1 (de) * 1977-12-16 1979-06-21 Gerhard Kappes Klappstuhl
DE2756218C2 (de) * 1977-12-16 1983-03-10 Denki Kagaku Kogyo K.K., Tokyo Verfahren zur Herstellung eines bei Raumtemperatur mit einer Aminverbindung härtbaren in Toluol löslichen, flüssigen Copolymeren
FR2442863A1 (fr) * 1978-11-07 1980-06-27 Distugil Procede de preparation de polychloroprene modifie au soufre
DD156600A5 (de) * 1981-02-25 1982-09-08 Karin Wendler Verfahren zur herstellung fluessiger polymerer mit reaktiven endgruppen
JPH0676516B2 (ja) * 1985-11-28 1994-09-28 旭化成工業株式会社 タイヤトレツド用のゴム組成物
DE3608556A1 (de) * 1986-03-14 1987-10-01 Akzo Gmbh Telechele polymere
JPS6426672A (en) * 1987-04-01 1989-01-27 Yokohama Rubber Co Ltd Ultraviolet-curing type resin composition
JPH0753846B2 (ja) * 1988-06-20 1995-06-07 株式会社クラレ 含イオウ接着剤
JP2765137B2 (ja) * 1988-12-15 1998-06-11 ジェイエスアール株式会社 紙塗被組成物用の共重合体ラテックスおよび紙塗被組成物
JPH04198303A (ja) * 1990-11-27 1992-07-17 Sanyo Chem Ind Ltd 重合開始剤および重合方法
JPH0649131A (ja) * 1992-07-30 1994-02-22 Nippon Shokubai Co Ltd 高酸価(メタ)アクリル系重合体の製造方法
FR2755969B1 (fr) * 1996-11-20 1998-12-24 Atochem Elf Sa Polymerisation en presence d'un radical libre stable et d'un iniferter
CA2309279C (en) * 1997-12-18 2009-07-14 E.I. Du Pont De Nemours And Company Polymerization process with living characteristics and polymers made therefrom
WO1999035177A1 (fr) * 1997-12-31 1999-07-15 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithiocarbamates
FR2802209B1 (fr) * 1999-12-10 2002-03-01 Rhodia Chimie Sa Latex a chimie de surface modifiee et poudres redispersables , leur obtention et leurs utilisations

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5254198A (en) * 1988-06-20 1993-10-19 Kuraray Co., Ltd. Method of bonding a metal or alloy utilizing a polymerizable thiocarboxylic acid or a derivative thereof
CN1228787A (zh) * 1996-07-10 1999-09-15 纳幕尔杜邦公司 具有活性特征的聚合作用
WO1998058974A1 (fr) * 1997-06-23 1998-12-30 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee
WO1999035178A1 (fr) * 1997-12-31 1999-07-15 Rhodia Chimie Procede de synthese de polymeres a blocs par polymerisation radicalaire controlee a partir de composes dithioesters

Also Published As

Publication number Publication date
BR0113941A (pt) 2003-07-22
DE60118007T2 (de) 2006-11-02
AU9000901A (en) 2002-03-26
AU2001290009B2 (en) 2005-05-12
US20030187165A1 (en) 2003-10-02
HUP0303387A3 (en) 2005-03-29
US6916884B2 (en) 2005-07-12
CZ2003751A3 (cs) 2003-06-18
DE60118007D1 (de) 2006-05-11
ZA200301563B (en) 2004-03-01
KR20030032031A (ko) 2003-04-23
MXPA03002318A (es) 2003-06-24
EP1319027B1 (fr) 2006-03-15
WO2002022688A2 (fr) 2002-03-21
PL361423A1 (en) 2004-10-04
HUP0303387A2 (hu) 2004-01-28
SK3112003A3 (en) 2003-09-11
JP2004509181A (ja) 2004-03-25
FR2814168A1 (fr) 2002-03-22
FR2814168B1 (fr) 2006-11-17
ATE320451T1 (de) 2006-04-15
CN1458937A (zh) 2003-11-26
CA2422593A1 (fr) 2002-03-21
NO20031231L (no) 2003-05-19
EP1319027A2 (fr) 2003-06-18
NO20031231D0 (no) 2003-03-17
WO2002022688A3 (fr) 2002-06-20

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