CH639230A5 - Method for producing an electrically conductive polymer formulation - Google Patents
Method for producing an electrically conductive polymer formulation Download PDFInfo
- Publication number
- CH639230A5 CH639230A5 CH1261775A CH1261775A CH639230A5 CH 639230 A5 CH639230 A5 CH 639230A5 CH 1261775 A CH1261775 A CH 1261775A CH 1261775 A CH1261775 A CH 1261775A CH 639230 A5 CH639230 A5 CH 639230A5
- Authority
- CH
- Switzerland
- Prior art keywords
- temperature
- resistance
- polymer
- copolymer
- formulation
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims description 78
- 238000009472 formulation Methods 0.000 title claims description 57
- 238000004519 manufacturing process Methods 0.000 title description 5
- 229920001940 conductive polymer Polymers 0.000 title description 2
- 239000000463 material Substances 0.000 claims description 64
- -1 polypropylene Polymers 0.000 claims description 57
- 238000002844 melting Methods 0.000 claims description 45
- 230000008018 melting Effects 0.000 claims description 45
- 229920000642 polymer Polymers 0.000 claims description 44
- 238000010438 heat treatment Methods 0.000 claims description 43
- 229920001971 elastomer Polymers 0.000 claims description 35
- 239000004743 Polypropylene Substances 0.000 claims description 32
- 229920001155 polypropylene Polymers 0.000 claims description 32
- 229920001169 thermoplastic Polymers 0.000 claims description 26
- 238000000034 method Methods 0.000 claims description 25
- 239000006229 carbon black Substances 0.000 claims description 21
- 239000004698 Polyethylene Substances 0.000 claims description 18
- 229920000573 polyethylene Polymers 0.000 claims description 18
- 229920001577 copolymer Polymers 0.000 claims description 16
- 239000002245 particle Substances 0.000 claims description 16
- 239000012815 thermoplastic material Substances 0.000 claims description 16
- 229920001400 block copolymer Polymers 0.000 claims description 14
- 239000000806 elastomer Substances 0.000 claims description 14
- 229920000578 graft copolymer Polymers 0.000 claims description 13
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 11
- 239000004793 Polystyrene Substances 0.000 claims description 9
- 229920002223 polystyrene Polymers 0.000 claims description 9
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 8
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 8
- 230000009477 glass transition Effects 0.000 claims description 8
- 229920002681 hypalon Polymers 0.000 claims description 8
- 230000007704 transition Effects 0.000 claims description 8
- 239000002033 PVDF binder Substances 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 7
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 7
- 238000002360 preparation method Methods 0.000 claims description 6
- 229920000098 polyolefin Polymers 0.000 claims description 4
- 229920006037 cross link polymer Polymers 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 230000008569 process Effects 0.000 claims description 2
- 239000002861 polymer material Substances 0.000 claims 1
- 239000005060 rubber Substances 0.000 description 21
- 239000004416 thermosoftening plastic Substances 0.000 description 19
- 230000007423 decrease Effects 0.000 description 12
- 239000002243 precursor Substances 0.000 description 12
- 229920006235 chlorinated polyethylene elastomer Polymers 0.000 description 8
- 239000011231 conductive filler Substances 0.000 description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- 229910052799 carbon Inorganic materials 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 229920000874 polytetramethylene terephthalate Polymers 0.000 description 6
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 5
- 239000004071 soot Substances 0.000 description 5
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005977 Ethylene Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- 229920006370 Kynar Polymers 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 239000002178 crystalline material Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 229920000339 Marlex Polymers 0.000 description 2
- 241000276498 Pollachius virens Species 0.000 description 2
- 229910002113 barium titanate Inorganic materials 0.000 description 2
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- 239000013536 elastomeric material Substances 0.000 description 2
- 102000007336 epsin Human genes 0.000 description 2
- 108010032643 epsin Proteins 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000013021 overheating Methods 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920000260 silastic Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000005496 tempering Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 229920001567 vinyl ester resin Polymers 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- SYJPAKDNFZLSMV-HYXAFXHYSA-N (Z)-2-methylpropanal oxime Chemical compound CC(C)\C=N/O SYJPAKDNFZLSMV-HYXAFXHYSA-N 0.000 description 1
- RNQBCZCPNUHWLV-UHFFFAOYSA-N 1,8-dioxacyclotetradecane-2,7-dione Chemical compound O=C1CCCCC(=O)OCCCCCCO1 RNQBCZCPNUHWLV-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 1
- 206010012289 Dementia Diseases 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- 229920002633 Kraton (polymer) Polymers 0.000 description 1
- 241001082241 Lythrum hyssopifolia Species 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 240000007930 Oxalis acetosella Species 0.000 description 1
- 235000008098 Oxalis acetosella Nutrition 0.000 description 1
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 239000004433 Thermoplastic polyurethane Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000012661 block copolymerization Methods 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 235000010980 cellulose Nutrition 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000010382 chemical cross-linking Methods 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 229920003244 diene elastomer Polymers 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 230000005489 elastic deformation Effects 0.000 description 1
- 229920001198 elastomeric copolymer Polymers 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 125000002573 ethenylidene group Chemical group [*]=C=C([H])[H] 0.000 description 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical compound FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000002654 heat shrinkable material Substances 0.000 description 1
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical group FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000005865 ionizing radiation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002239 polyacrylonitrile Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001748 polybutylene Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- REQCZEXYDRLIBE-UHFFFAOYSA-N procainamide Chemical compound CCN(CC)CCNC(=O)C1=CC=C(N)C=C1 REQCZEXYDRLIBE-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000005641 tunneling Effects 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 229920001959 vinylidene polymer Polymers 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01C—RESISTORS
- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/02—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient
- H01C7/027—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material having positive temperature coefficient consisting of conducting or semi-conducting material dispersed in a non-conductive organic material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
- H01B1/20—Conductive material dispersed in non-conductive organic material
- H01B1/24—Conductive material dispersed in non-conductive organic material the conductive material comprising carbon-silicon compounds, carbon or silicon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Dispersion Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Medicinal Chemistry (AREA)
- Ceramic Engineering (AREA)
- Electromagnetism (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Conductive Materials (AREA)
- Thermistors And Varistors (AREA)
- Resistance Heating (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US51003574A | 1974-09-27 | 1974-09-27 | |
US60163975A | 1975-08-04 | 1975-08-04 |
Publications (1)
Publication Number | Publication Date |
---|---|
CH639230A5 true CH639230A5 (en) | 1983-10-31 |
Family
ID=27056755
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CH1261775A CH639230A5 (en) | 1974-09-27 | 1975-09-29 | Method for producing an electrically conductive polymer formulation |
Country Status (12)
Families Citing this family (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4017715A (en) * | 1975-08-04 | 1977-04-12 | Raychem Corporation | Temperature overshoot heater |
FI64482C (fi) * | 1974-09-27 | 1983-11-10 | Raychem Corp | Vaermeaoterhaemtbar anordning och anordning av densamma foer en kabelskarv |
FR2320678A1 (fr) * | 1975-08-04 | 1977-03-04 | Raychem Corp | Objet auto-chauffant muni d'electrodes en tissu |
US4095044A (en) * | 1976-10-26 | 1978-06-13 | Raychem Corporation | Multiple cable adapter and splice case including the same |
EP0001307A1 (en) * | 1977-09-19 | 1979-04-04 | Shell Internationale Researchmaatschappij B.V. | A semi-conductive composition and an electric wire or cable coated with such a composition |
JPS5835536B2 (ja) * | 1978-05-22 | 1983-08-03 | 大日本インキ化学工業株式会社 | 樹脂組成物 |
FR2440104A1 (fr) * | 1978-10-27 | 1980-05-23 | Raychem Sa Nv | Raccords thermoretractables notamment pour cables, procede pour leur mise en oeuvre et ensemble les comportant |
JPS5784586A (en) * | 1980-11-13 | 1982-05-26 | Hitachi Cable | Self-temperature controllable heater |
JPS5917935B2 (ja) * | 1981-08-25 | 1984-04-24 | 住友電気工業株式会社 | 熱収縮チユ−ブ |
DE3245589A1 (de) * | 1982-12-09 | 1984-06-14 | Hoechst Ag, 6230 Frankfurt | Unvernetzbare, elektrisch leitfaehige formmassen auf der basis von thermoplastischen kunststoffen und russ |
JPS59214103A (ja) * | 1983-05-19 | 1984-12-04 | 株式会社フジクラ | 電磁波吸収材用混和物 |
JPS60188439A (ja) * | 1984-03-09 | 1985-09-25 | Meidensha Electric Mfg Co Ltd | 導電性複合材料 |
US4724417A (en) * | 1985-03-14 | 1988-02-09 | Raychem Corporation | Electrical devices comprising cross-linked conductive polymers |
JPS6265401A (ja) * | 1985-09-18 | 1987-03-24 | 安田 繁之 | 感熱電気抵抗組成物における定常発熱温度の調整方法 |
DE3635286A1 (de) * | 1986-10-16 | 1988-04-21 | Lentia Gmbh | Flaechenheizelement und verfahren zu dessen herstellung |
JPH028258A (ja) * | 1988-06-28 | 1990-01-11 | Matsushita Electric Ind Co Ltd | 自己温度制御発熱体組成物 |
CN1086929A (zh) * | 1992-09-04 | 1994-05-18 | 单一检索有限公司 | 挠性塑料电极及其制造方法 |
JP3684867B2 (ja) * | 1998-10-07 | 2005-08-17 | Nok株式会社 | Ptc組成物および面状発熱体 |
DE10021803B4 (de) * | 2000-05-04 | 2006-06-22 | Franz Koppe | Heizmatte und Verfahren zur Herstellung sowie Verwendung derselben |
WO2020218141A1 (ja) * | 2019-04-23 | 2020-10-29 | 株式会社クラレ | 熱可塑性液晶ポリマーフィルム、積層体、および成形体、ならびにそれらの製造方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3243753A (en) * | 1962-11-13 | 1966-03-29 | Kohler Fred | Resistance element |
US3591526A (en) * | 1968-01-25 | 1971-07-06 | Polyelectric Corp | Method of manufacturing a temperature sensitive,electrical resistor material |
US3793716A (en) * | 1972-09-08 | 1974-02-26 | Raychem Corp | Method of making self limiting heat elements |
US3849333A (en) * | 1972-09-26 | 1974-11-19 | Union Carbide Corp | Semi-conducting polymer system comprising a copolymer of ethylene-ethylarcralate or vinyl acetate,ethylene-propylene-termonomer and carbon black |
US3823217A (en) * | 1973-01-18 | 1974-07-09 | Raychem Corp | Resistivity variance reduction |
-
1975
- 1975-09-26 IT IT27705/75A patent/IT1042912B/it active
- 1975-09-26 FR FR7529585A patent/FR2286169A1/fr active Granted
- 1975-09-26 SE SE7510846A patent/SE412976B/xx unknown
- 1975-09-26 NL NL7511394A patent/NL7511394A/xx not_active Application Discontinuation
- 1975-09-26 JP JP50116270A patent/JPS5160236A/ja active Granted
- 1975-09-26 AU AU85230/75A patent/AU504687B2/en not_active Expired
- 1975-09-26 CA CA236,456A patent/CA1074096A/en not_active Expired
- 1975-09-26 GB GB39518/75A patent/GB1528622A/en not_active Expired
- 1975-09-26 BR BR7506262*A patent/BR7506262A/pt unknown
- 1975-09-26 ES ES441299A patent/ES441299A1/es not_active Expired
- 1975-09-29 DE DE2543346A patent/DE2543346C2/de not_active Expired
- 1975-09-29 CH CH1261775A patent/CH639230A5/de not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
JPS6135223B2 (enrdf_load_stackoverflow) | 1986-08-12 |
DE2543346A1 (de) | 1976-04-15 |
SE7510846L (sv) | 1976-03-29 |
JPS5160236A (en) | 1976-05-26 |
GB1528622A (en) | 1978-10-18 |
SE412976B (sv) | 1980-03-24 |
CA1074096A (en) | 1980-03-25 |
BR7506262A (pt) | 1976-08-03 |
FR2286169B1 (enrdf_load_stackoverflow) | 1979-05-04 |
NL7511394A (nl) | 1976-03-30 |
AU504687B2 (en) | 1979-10-25 |
DE2543346C2 (de) | 1985-09-12 |
AU8523075A (en) | 1977-03-31 |
IT1042912B (it) | 1980-01-30 |
ES441299A1 (es) | 1977-07-01 |
FR2286169A1 (fr) | 1976-04-23 |
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