CH631417A5 - Verfahren zur kontinuierlichen herstellung von phosphin. - Google Patents
Verfahren zur kontinuierlichen herstellung von phosphin. Download PDFInfo
- Publication number
- CH631417A5 CH631417A5 CH641177A CH641177A CH631417A5 CH 631417 A5 CH631417 A5 CH 631417A5 CH 641177 A CH641177 A CH 641177A CH 641177 A CH641177 A CH 641177A CH 631417 A5 CH631417 A5 CH 631417A5
- Authority
- CH
- Switzerland
- Prior art keywords
- phosphorus
- reaction
- phosphine
- hydroxide solution
- alcohol
- Prior art date
Links
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Chemical compound P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 title claims description 79
- 229910000073 phosphorus hydride Inorganic materials 0.000 title claims description 50
- 238000000034 method Methods 0.000 title claims description 22
- 238000010924 continuous production Methods 0.000 title claims 2
- 238000006243 chemical reaction Methods 0.000 claims description 44
- 239000007789 gas Substances 0.000 claims description 32
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 29
- 229910052698 phosphorus Inorganic materials 0.000 claims description 28
- 239000011574 phosphorus Substances 0.000 claims description 27
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- 229910001854 alkali hydroxide Inorganic materials 0.000 claims description 13
- 239000000203 mixture Substances 0.000 claims description 12
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 8
- 239000007791 liquid phase Substances 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 230000001476 alcoholic effect Effects 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000000376 reactant Substances 0.000 claims description 3
- 230000007717 exclusion Effects 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims description 2
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 53
- 239000000243 solution Substances 0.000 description 25
- 150000003839 salts Chemical class 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 239000012071 phase Substances 0.000 description 3
- ACVYVLVWPXVTIT-UHFFFAOYSA-M phosphinate Chemical compound [O-][PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-M 0.000 description 3
- 238000010926 purge Methods 0.000 description 3
- 239000012266 salt solution Substances 0.000 description 3
- 229910001379 sodium hypophosphite Inorganic materials 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- KWSLGOVYXMQPPX-UHFFFAOYSA-N 5-[3-(trifluoromethyl)phenyl]-2h-tetrazole Chemical compound FC(F)(F)C1=CC=CC(C2=NNN=N2)=C1 KWSLGOVYXMQPPX-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000012495 reaction gas Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- NCPXQVVMIXIKTN-UHFFFAOYSA-N trisodium;phosphite Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])[O-] NCPXQVVMIXIKTN-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- AMQJEAYHLZJPGS-UHFFFAOYSA-N N-Pentanol Chemical compound CCCCCO AMQJEAYHLZJPGS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- ZRRLFMPOAYZELW-UHFFFAOYSA-N disodium;hydrogen phosphite Chemical compound [Na+].[Na+].OP([O-])[O-] ZRRLFMPOAYZELW-UHFFFAOYSA-N 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 238000005191 phase separation Methods 0.000 description 1
- 229910001392 phosphorus oxide Inorganic materials 0.000 description 1
- 238000004886 process control Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002792 vascular Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/06—Hydrogen phosphides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE2632316A DE2632316C3 (de) | 1976-07-17 | 1976-07-17 | Verfahren zur kontinuierlichen Herstellung von Phosphin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH631417A5 true CH631417A5 (de) | 1982-08-13 |
Family
ID=5983317
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH641177A CH631417A5 (de) | 1976-07-17 | 1977-05-24 | Verfahren zur kontinuierlichen herstellung von phosphin. |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4143121A (enExample) |
| BE (1) | BE856843A (enExample) |
| CA (1) | CA1083777A (enExample) |
| CH (1) | CH631417A5 (enExample) |
| DD (1) | DD131009A5 (enExample) |
| DE (1) | DE2632316C3 (enExample) |
| DK (1) | DK146925C (enExample) |
| ES (1) | ES460465A1 (enExample) |
| FR (1) | FR2358359A1 (enExample) |
| GB (1) | GB1535711A (enExample) |
| IT (1) | IT1079733B (enExample) |
| NL (1) | NL182634C (enExample) |
| SE (1) | SE7708204L (enExample) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2840147A1 (de) * | 1978-09-15 | 1980-03-27 | Hoechst Ag | Verfahren zur kontinuierlichen herstellung von phosphan |
| US6685904B1 (en) * | 1998-04-16 | 2004-02-03 | Occicdental Chemical Corporation | Process for making phosphorus halides and oxyhalides |
| CN111453708B (zh) * | 2020-05-21 | 2024-07-23 | 天津中科拓新科技有限公司 | 一种电子级磷烷的合成与精制方法及装置 |
| CN114620695B (zh) * | 2022-02-23 | 2023-07-07 | 沧州华宇特种气体科技有限公司 | 一种制备磷化氢的系统及其制备方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH322981A (fr) * | 1956-09-10 | 1957-07-15 | Fonte Electr S A | Procédé pour la préparation d'hypophosphites. |
| US2977192A (en) * | 1958-08-26 | 1961-03-28 | Fmc Corp | Process for the production of phosphine and sodium hypophosphite |
| DE2125587C3 (de) * | 1971-05-24 | 1974-08-15 | Knapsack Ag, 5033 Huerth-Knapsack | Verfahren zur Herstellung von Hypophosphiten |
| DE2549084C3 (de) * | 1975-11-03 | 1981-04-30 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung von Phosphin |
-
1976
- 1976-07-17 DE DE2632316A patent/DE2632316C3/de not_active Expired
-
1977
- 1977-05-24 CH CH641177A patent/CH631417A5/de not_active IP Right Cessation
- 1977-06-20 NL NLAANVRAGE7706777,A patent/NL182634C/xx not_active IP Right Cessation
- 1977-07-01 IT IT50081/77A patent/IT1079733B/it active
- 1977-07-04 GB GB27882/77A patent/GB1535711A/en not_active Expired
- 1977-07-06 ES ES460465A patent/ES460465A1/es not_active Expired
- 1977-07-13 FR FR7721767A patent/FR2358359A1/fr active Granted
- 1977-07-13 US US05/815,161 patent/US4143121A/en not_active Expired - Lifetime
- 1977-07-14 SE SE7708204A patent/SE7708204L/xx unknown
- 1977-07-15 CA CA282,811A patent/CA1083777A/en not_active Expired
- 1977-07-15 DK DK322277A patent/DK146925C/da not_active IP Right Cessation
- 1977-07-15 BE BE179367A patent/BE856843A/xx not_active IP Right Cessation
- 1977-07-15 DD DD7700200097A patent/DD131009A5/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| NL7706777A (nl) | 1978-01-19 |
| IT1079733B (it) | 1985-05-13 |
| DK322277A (da) | 1978-01-18 |
| NL182634B (nl) | 1987-11-16 |
| FR2358359B1 (enExample) | 1982-02-26 |
| GB1535711A (en) | 1978-12-13 |
| DE2632316A1 (de) | 1978-01-19 |
| DK146925B (da) | 1984-02-13 |
| US4143121A (en) | 1979-03-06 |
| DE2632316C3 (de) | 1981-12-24 |
| DK146925C (da) | 1984-07-23 |
| DD131009A5 (de) | 1978-05-24 |
| FR2358359A1 (fr) | 1978-02-10 |
| SE7708204L (sv) | 1978-01-18 |
| CA1083777A (en) | 1980-08-19 |
| BE856843A (fr) | 1978-01-16 |
| DE2632316B2 (de) | 1981-02-05 |
| ES460465A1 (es) | 1978-05-01 |
| NL182634C (nl) | 1988-04-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased | ||
| PL | Patent ceased |