CH625192A5 - - Google Patents
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- Publication number
- CH625192A5 CH625192A5 CH781376A CH781376A CH625192A5 CH 625192 A5 CH625192 A5 CH 625192A5 CH 781376 A CH781376 A CH 781376A CH 781376 A CH781376 A CH 781376A CH 625192 A5 CH625192 A5 CH 625192A5
- Authority
- CH
- Switzerland
- Prior art keywords
- carbon
- carbon dioxide
- molten salt
- gas
- reaction
- Prior art date
Links
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 170
- 239000007789 gas Substances 0.000 claims description 140
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 109
- 150000003839 salts Chemical class 0.000 claims description 97
- 238000006243 chemical reaction Methods 0.000 claims description 86
- 239000001569 carbon dioxide Substances 0.000 claims description 84
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 75
- 239000001301 oxygen Substances 0.000 claims description 75
- 229910052760 oxygen Inorganic materials 0.000 claims description 75
- 238000000034 method Methods 0.000 claims description 74
- 229910052799 carbon Inorganic materials 0.000 claims description 67
- 239000003245 coal Substances 0.000 claims description 67
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 66
- 230000008569 process Effects 0.000 claims description 49
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 48
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 40
- 230000015572 biosynthetic process Effects 0.000 claims description 38
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 35
- 239000003575 carbonaceous material Substances 0.000 claims description 32
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 30
- 238000003786 synthesis reaction Methods 0.000 claims description 26
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 25
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 24
- 229910052717 sulfur Inorganic materials 0.000 claims description 23
- 239000011593 sulfur Substances 0.000 claims description 23
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical class [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 14
- 229910052979 sodium sulfide Inorganic materials 0.000 claims description 13
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 claims description 13
- 239000007787 solid Substances 0.000 claims description 10
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 4
- 239000003077 lignite Substances 0.000 claims description 4
- 230000000717 retained effect Effects 0.000 claims description 4
- 239000000571 coke Substances 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 2
- 239000010779 crude oil Substances 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 239000000295 fuel oil Substances 0.000 claims description 2
- 239000003415 peat Substances 0.000 claims description 2
- 239000003208 petroleum Substances 0.000 claims description 2
- 230000001737 promoting effect Effects 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 claims 1
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 33
- 238000002485 combustion reaction Methods 0.000 description 32
- 238000012360 testing method Methods 0.000 description 27
- 238000002309 gasification Methods 0.000 description 25
- 239000000463 material Substances 0.000 description 23
- 239000000155 melt Substances 0.000 description 23
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 17
- 239000000047 product Substances 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 239000000446 fuel Substances 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000002956 ash Substances 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 8
- 239000000356 contaminant Substances 0.000 description 8
- 238000007254 oxidation reaction Methods 0.000 description 8
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 8
- 238000000926 separation method Methods 0.000 description 8
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 241000196324 Embryophyta Species 0.000 description 5
- 238000003763 carbonization Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 4
- 150000008041 alkali metal carbonates Chemical class 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 238000002474 experimental method Methods 0.000 description 4
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 229910000027 potassium carbonate Inorganic materials 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 238000006722 reduction reaction Methods 0.000 description 4
- 230000008929 regeneration Effects 0.000 description 4
- 238000011069 regeneration method Methods 0.000 description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000002609 medium Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 150000003464 sulfur compounds Chemical class 0.000 description 3
- -1 B. sodium carbonate Chemical class 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 238000007036 catalytic synthesis reaction Methods 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 229910001882 dioxygen Inorganic materials 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 230000020169 heat generation Effects 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000197 pyrolysis Methods 0.000 description 2
- 239000011833 salt mixture Substances 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000003476 subbituminous coal Substances 0.000 description 2
- 150000004763 sulfides Chemical class 0.000 description 2
- XTQHKBHJIVJGKJ-UHFFFAOYSA-N sulfur monoxide Chemical class S=O XTQHKBHJIVJGKJ-UHFFFAOYSA-N 0.000 description 2
- 229910052815 sulfur oxide Inorganic materials 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000019738 Limestone Nutrition 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- 239000007868 Raney catalyst Substances 0.000 description 1
- 229910000564 Raney nickel Inorganic materials 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 241000982035 Sparattosyce Species 0.000 description 1
- WVYYHSKIGBEZCQ-UHFFFAOYSA-N [O-2].[O-2].[Cr+3].[Fe+2] Chemical compound [O-2].[O-2].[Cr+3].[Fe+2] WVYYHSKIGBEZCQ-UHFFFAOYSA-N 0.000 description 1
- 230000002745 absorbent Effects 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001339 alkali metal compounds Chemical class 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 1
- 239000003830 anthracite Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000002802 bituminous coal Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- XXLDWSKFRBJLMX-UHFFFAOYSA-N carbon dioxide;carbon monoxide Chemical compound O=[C].O=C=O XXLDWSKFRBJLMX-UHFFFAOYSA-N 0.000 description 1
- NPGILLWFJVZZPP-UHFFFAOYSA-N carbon dioxide;lead Chemical compound [Pb].O=C=O NPGILLWFJVZZPP-UHFFFAOYSA-N 0.000 description 1
- UBAZGMLMVVQSCD-UHFFFAOYSA-N carbon dioxide;molecular oxygen Chemical compound O=O.O=C=O UBAZGMLMVVQSCD-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- DQIPXGFHRRCVHY-UHFFFAOYSA-N chromium zinc Chemical compound [Cr].[Zn] DQIPXGFHRRCVHY-UHFFFAOYSA-N 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- YXSIKEMDQWEQTO-UHFFFAOYSA-N copper zinc chromium(3+) oxygen(2-) Chemical compound [O-2].[Zn+2].[Cr+3].[Cu+2] YXSIKEMDQWEQTO-UHFFFAOYSA-N 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 238000004868 gas analysis Methods 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- 229910000358 iron sulfate Inorganic materials 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000009666 routine test Methods 0.000 description 1
- 238000005029 sieve analysis Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 125000000101 thioether group Chemical group 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/57—Gasification using molten salts or metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/78—High-pressure apparatus
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/72—Other features
- C10J3/82—Gas withdrawal means
- C10J3/84—Gas withdrawal means with means for removing dust or tar from the gas
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/02—Processes for making hydrogen or synthesis gas
- C01B2203/0283—Processes for making hydrogen or synthesis gas containing a CO-shift step, i.e. a water gas shift step
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0415—Purification by absorption in liquids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0475—Composition of the impurity the impurity being carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/80—Aspect of integrated processes for the production of hydrogen or synthesis gas not covered by groups C01B2203/02 - C01B2203/1695
- C01B2203/84—Energy production
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/093—Coal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0943—Coke
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0956—Air or oxygen enriched air
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0969—Carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0973—Water
- C10J2300/0976—Water as steam
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0983—Additives
- C10J2300/0986—Catalysts
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
- C10J2300/1656—Conversion of synthesis gas to chemicals
- C10J2300/1662—Conversion of synthesis gas to chemicals to methane
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/16—Integration of gasification processes with another plant or parts within the plant
- C10J2300/1671—Integration of gasification processes with another plant or parts within the plant with the production of electricity
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
- C10J2300/1815—Recycle loops, e.g. gas, solids, heating medium, water for carbon dioxide
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1846—Partial oxidation, i.e. injection of air or oxygen only
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Carbon And Carbon Compounds (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/588,563 US4017271A (en) | 1975-06-19 | 1975-06-19 | Process for production of synthesis gas |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH625192A5 true CH625192A5 (ko) | 1981-09-15 |
Family
ID=24354355
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH781376A CH625192A5 (ko) | 1975-06-19 | 1976-06-18 |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US4017271A (ko) |
| JP (1) | JPS6041116B2 (ko) |
| AU (1) | AU498375B2 (ko) |
| BE (1) | BE842934A (ko) |
| CA (1) | CA1079972A (ko) |
| CH (1) | CH625192A5 (ko) |
| DE (1) | DE2626520A1 (ko) |
| FR (1) | FR2316319A2 (ko) |
| GB (1) | GB1556448A (ko) |
| IT (1) | IT1064101B (ko) |
| NL (1) | NL7606391A (ko) |
| SE (1) | SE422077B (ko) |
Families Citing this family (51)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4455153A (en) * | 1978-05-05 | 1984-06-19 | Jakahi Douglas Y | Apparatus for storing solar energy in synthetic fuels |
| US4206251A (en) * | 1978-06-01 | 1980-06-03 | Hughes Aircraft Company | Method for diffusing metals into substrates |
| US4246255A (en) * | 1979-04-02 | 1981-01-20 | Rockwell International Corporation | Disposal of PCB |
| US4338096A (en) * | 1980-10-06 | 1982-07-06 | Cosden Technology, Inc. | Method and apparatus for controlling the flow of molten reaction media |
| US4395975A (en) * | 1982-01-22 | 1983-08-02 | Ashworth Robert A | Method for desulfurization and oxidation of carbonaceous fuels |
| US4423702A (en) | 1982-01-22 | 1984-01-03 | Ashworth Robert A | Method for desulfurization, denitrifaction, and oxidation of carbonaceous fuels |
| US4476683A (en) * | 1982-12-20 | 1984-10-16 | General Electric Company | Energy efficient multi-stage water gas shift reaction |
| DE3334687A1 (de) * | 1983-09-24 | 1985-04-18 | Klöckner-Humboldt-Deutz AG, 5000 Köln | Verfahren und vorrichtung zur herstellung eines aus wasserstoff und kohlenmonoxid bestehenden synthesegases |
| JPS61183827U (ko) * | 1985-05-09 | 1986-11-17 | ||
| JPH0420614A (ja) * | 1990-05-12 | 1992-01-24 | Nisshoku Corp | 植生袋 |
| US5177304A (en) * | 1990-07-24 | 1993-01-05 | Molten Metal Technology, Inc. | Method and system for forming carbon dioxide from carbon-containing materials in a molten bath of immiscible metals |
| DE69427692T2 (de) * | 1993-04-06 | 2002-05-02 | Ausmelt Ltd | Schmelzen von kohlenstoffhaltigem material |
| AU6530694A (en) * | 1993-04-08 | 1994-11-08 | Shell Oil Company | Method of reducing halides in synthesis gas |
| WO1995016010A1 (en) * | 1993-12-07 | 1995-06-15 | Ashland Oil, Inc. | Improved molten metal decomposition apparatus and process |
| US5615626A (en) * | 1994-10-05 | 1997-04-01 | Ausmelt Limited | Processing of municipal and other wastes |
| DE19722059A1 (de) * | 1997-05-27 | 1998-12-03 | Boehlke Eckard | Verfahren und Vorrichtung zur Gewinnung Wasserstoff und Kohlenmonoxid enthaltender Gase |
| NL1008832C2 (nl) | 1998-04-07 | 1999-10-08 | Univ Delft Tech | Werkwijze voor het omzetten van een koolstofomvattend materiaal, een werkwijze voor het bedrijven van een brandstofcel en een werkwijze voor het bedrijven van een brandstofcelstapel. |
| CA2368496C (en) | 2000-02-29 | 2012-02-14 | Mitsubishi Heavy Industries, Ltd. | Biomass gasification furnace and methanol synthesis system making use of gas produced through biomass gasification |
| US20020020112A1 (en) * | 2000-07-25 | 2002-02-21 | Scotlund Stivers | Process and apparatus for manufacturing fuel gas and liquid fuels from trash, other waste materials and solid fuels |
| DK1303629T3 (da) * | 2000-07-25 | 2006-10-30 | Emmaus Foundation Inc | Fremgangsmåde til forögelse af ethanolproduktion fra mikrobiel fermetering |
| US20020020363A1 (en) * | 2000-07-25 | 2002-02-21 | Scotlund Stivers | Pressure relief system |
| CN100427383C (zh) * | 2004-10-12 | 2008-10-22 | 昆明理工大学 | 熔融盐中用晶格氧催化氧化天然气制氢的方法 |
| US20130213280A9 (en) * | 2005-04-18 | 2013-08-22 | Klaus S. Lackner | Methods and systems for reducing carbon dioxide emissions |
| US20070225382A1 (en) * | 2005-10-14 | 2007-09-27 | Van Den Berg Robert E | Method for producing synthesis gas or a hydrocarbon product |
| US20080141591A1 (en) * | 2006-12-19 | 2008-06-19 | Simulent Inc. | Gasification of sulfur-containing carbonaceous fuels |
| DE102007002056B4 (de) * | 2007-01-13 | 2008-09-11 | Forschungszentrum Karlsruhe Gmbh | Verfahren und Vorrichtung zur Umsetzung von Biomasse in gasförmige Produkte |
| FI122786B (fi) * | 2007-07-20 | 2012-06-29 | Upm Kymmene Oyj | Synteettisten hiilivetyketjujen valmistuksessa syntyvän hiilidioksidin käyttö |
| US20090074656A1 (en) * | 2007-09-18 | 2009-03-19 | Calvin Billings | Process for production of hydrogen from coal and other fossil fuels |
| US20090173081A1 (en) * | 2008-01-07 | 2009-07-09 | Paul Steven Wallace | Method and apparatus to facilitate substitute natural gas production |
| US8528343B2 (en) * | 2008-01-07 | 2013-09-10 | General Electric Company | Method and apparatus to facilitate substitute natural gas production |
| US20090173080A1 (en) * | 2008-01-07 | 2009-07-09 | Paul Steven Wallace | Method and apparatus to facilitate substitute natural gas production |
| US8592190B2 (en) * | 2009-06-11 | 2013-11-26 | Ineos Bio Limited | Methods for sequestering carbon dioxide into alcohols via gasification fermentation |
| BRPI0913850B1 (pt) * | 2008-06-20 | 2020-01-21 | Ineos Bio Sa | método de produção de álcool |
| US8580001B2 (en) * | 2008-08-21 | 2013-11-12 | General Electric Company | Method and apparatus for assembling gasification reactor injection devices |
| WO2010062879A2 (en) * | 2008-11-26 | 2010-06-03 | Good Earth Power Corporation | Enhanced product gas and power evolution from carbonaceous materials via gasification |
| EP2382283A2 (en) * | 2008-12-30 | 2011-11-02 | Shell Oil Company | Method and system for supplying synthesis gas |
| US8309049B2 (en) * | 2009-10-19 | 2012-11-13 | Battelle Energy Alliance, Llc | Molten metal reactor and method of forming hydrogen, carbon monoxide and carbon dioxide using the molten alkaline metal reactor |
| US8999021B2 (en) * | 2010-04-13 | 2015-04-07 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| US8585789B2 (en) * | 2010-04-13 | 2013-11-19 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| US8580152B2 (en) | 2010-04-13 | 2013-11-12 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| KR20120064030A (ko) * | 2010-12-08 | 2012-06-18 | 에스케이이노베이션 주식회사 | 이산화탄소의 배출이 저감된 가스화 방법 |
| US20120255301A1 (en) | 2011-04-06 | 2012-10-11 | Bell Peter S | System for generating power from a syngas fermentation process |
| US8685281B2 (en) * | 2011-07-21 | 2014-04-01 | Battelle Energy Alliance Llc | System and process for the production of syngas and fuel gasses |
| US9216401B2 (en) | 2011-07-21 | 2015-12-22 | Battelle Energy Alliance Llc | Bell column downtube, reactors utilizing same and related methods |
| US20140026485A1 (en) * | 2012-07-25 | 2014-01-30 | Co2Fuel, Llc | Single Layer Gas Processing |
| US20150104862A1 (en) * | 2013-10-10 | 2015-04-16 | Ineos Usa Llc | Methods for gasification of carbonaceous materials |
| US9714391B2 (en) * | 2014-08-14 | 2017-07-25 | Johnny D. Combs | Waste to fuel system |
| CN108650888B (zh) * | 2015-12-14 | 2020-11-06 | 气体产品与化学公司 | 气化工艺和馈送系统 |
| US10364398B2 (en) * | 2016-08-30 | 2019-07-30 | Thermochem Recovery International, Inc. | Method of producing product gas from multiple carbonaceous feedstock streams mixed with a reduced-pressure mixing gas |
| GB2585643A (en) * | 2019-07-08 | 2021-01-20 | Lfeog Ltd | Methods and systems for gasification of hydrocarbonaceous feedstocks |
| CN112831351B (zh) * | 2020-12-30 | 2021-12-28 | 西安交通大学 | 一种原位资源化利用电厂高温二氧化碳的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3533739A (en) * | 1968-04-01 | 1970-10-13 | Black Sivalls & Bryson Inc | Combustion of sulfur-bearing carbonaceous fuel |
| US3692506A (en) * | 1970-02-13 | 1972-09-19 | Total Energy Corp | High btu gas content from coal |
| JPS526703B1 (ko) * | 1970-10-01 | 1977-02-24 | ||
| US3758673A (en) * | 1971-03-18 | 1973-09-11 | Exxon Research Engineering Co | Process for the production of a carbon monoxide containing gas |
| US3890113A (en) * | 1973-06-25 | 1975-06-17 | Texaco Inc | Production of methane |
| US3916617A (en) * | 1974-03-29 | 1975-11-04 | Rockwell International Corp | Process for production of low BTU gas |
-
1975
- 1975-06-19 US US05/588,563 patent/US4017271A/en not_active Expired - Lifetime
-
1976
- 1976-05-19 AU AU14091/76A patent/AU498375B2/en not_active Expired
- 1976-05-20 CA CA252,943A patent/CA1079972A/en not_active Expired
- 1976-06-10 GB GB24105/76A patent/GB1556448A/en not_active Expired
- 1976-06-14 BE BE167904A patent/BE842934A/xx not_active IP Right Cessation
- 1976-06-14 DE DE19762626520 patent/DE2626520A1/de not_active Withdrawn
- 1976-06-14 NL NL7606391A patent/NL7606391A/xx not_active Application Discontinuation
- 1976-06-16 IT IT49986/76A patent/IT1064101B/it active
- 1976-06-16 SE SE7606864A patent/SE422077B/xx unknown
- 1976-06-18 CH CH781376A patent/CH625192A5/de not_active IP Right Cessation
- 1976-06-18 FR FR7618621A patent/FR2316319A2/fr active Granted
- 1976-06-18 JP JP51072076A patent/JPS6041116B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| GB1556448A (en) | 1979-11-21 |
| FR2316319A2 (fr) | 1977-01-28 |
| SE422077B (sv) | 1982-02-15 |
| AU498375B2 (en) | 1979-03-08 |
| FR2316319B2 (ko) | 1981-12-04 |
| CA1079972A (en) | 1980-06-24 |
| SE7606864L (sv) | 1976-12-20 |
| IT1064101B (it) | 1985-02-18 |
| US4017271A (en) | 1977-04-12 |
| JPS522892A (en) | 1977-01-10 |
| JPS6041116B2 (ja) | 1985-09-13 |
| DE2626520A1 (de) | 1976-12-23 |
| NL7606391A (nl) | 1976-12-21 |
| BE842934A (fr) | 1976-12-14 |
| AU1409176A (en) | 1977-11-24 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PL | Patent ceased |