CH437776A - Stabilisator für gegebenenfalls andere Kunstharze enthaltende Vinylchloridhomo- oder mischpolymerisatharze und Verwendung desselben - Google Patents
Stabilisator für gegebenenfalls andere Kunstharze enthaltende Vinylchloridhomo- oder mischpolymerisatharze und Verwendung desselbenInfo
- Publication number
- CH437776A CH437776A CH302761A CH302761A CH437776A CH 437776 A CH437776 A CH 437776A CH 302761 A CH302761 A CH 302761A CH 302761 A CH302761 A CH 302761A CH 437776 A CH437776 A CH 437776A
- Authority
- CH
- Switzerland
- Prior art keywords
- stabilizer
- black black
- parts
- salts
- sorbitol
- Prior art date
Links
- 239000003381 stabilizer Substances 0.000 title claims description 74
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 title claims description 18
- 229920001519 homopolymer Polymers 0.000 title claims description 10
- 229920003002 synthetic resin Polymers 0.000 title claims description 5
- 239000000057 synthetic resin Substances 0.000 title claims description 5
- 229920006026 co-polymeric resin Polymers 0.000 title claims description 4
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 59
- 239000000194 fatty acid Substances 0.000 claims description 59
- 229930195729 fatty acid Natural products 0.000 claims description 59
- 150000004665 fatty acids Chemical class 0.000 claims description 57
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 45
- 239000000600 sorbitol Substances 0.000 claims description 45
- 239000003760 tallow Substances 0.000 claims description 37
- 239000000203 mixture Substances 0.000 claims description 35
- 150000003751 zinc Chemical class 0.000 claims description 28
- 159000000007 calcium salts Chemical class 0.000 claims description 21
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 18
- 150000003839 salts Chemical class 0.000 claims description 18
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 16
- 239000004301 calcium benzoate Substances 0.000 claims description 12
- 235000010237 calcium benzoate Nutrition 0.000 claims description 12
- HZQXCUSDXIKLGS-UHFFFAOYSA-L calcium;dibenzoate;trihydrate Chemical compound O.O.O.[Ca+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 HZQXCUSDXIKLGS-UHFFFAOYSA-L 0.000 claims description 12
- 239000011701 zinc Substances 0.000 claims description 10
- 239000011575 calcium Substances 0.000 claims description 7
- 229920001577 copolymer Polymers 0.000 claims description 7
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 230000006866 deterioration Effects 0.000 claims description 3
- 235000019483 Peanut oil Nutrition 0.000 claims description 2
- 235000013969 calcium salts of fatty acid Nutrition 0.000 claims description 2
- 239000000312 peanut oil Substances 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical class CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 claims 1
- 239000010513 hydrogenated corn oil Substances 0.000 claims 1
- 239000010514 hydrogenated cottonseed oil Substances 0.000 claims 1
- 229920005989 resin Polymers 0.000 description 27
- 239000011347 resin Substances 0.000 description 27
- 238000010438 heat treatment Methods 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 238000002845 discoloration Methods 0.000 description 12
- 229920000915 polyvinyl chloride Polymers 0.000 description 12
- 239000004800 polyvinyl chloride Substances 0.000 description 12
- 239000011342 resin composition Substances 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 10
- 230000006641 stabilisation Effects 0.000 description 10
- 238000011105 stabilization Methods 0.000 description 10
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical class [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 10
- 229920006385 Geon Polymers 0.000 description 7
- 239000013068 control sample Substances 0.000 description 6
- 210000002374 sebum Anatomy 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- -1 alkyl tin Chemical compound 0.000 description 4
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 235000011187 glycerol Nutrition 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 231100000331 toxic Toxicity 0.000 description 4
- 230000002588 toxic effect Effects 0.000 description 4
- 229920012485 Plasticized Polyvinyl chloride Polymers 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 238000004806 packaging method and process Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 229910002056 binary alloy Inorganic materials 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 235000020075 ouzo Nutrition 0.000 description 2
- 230000002688 persistence Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 239000004709 Chlorinated polyethylene Substances 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 235000005687 corn oil Nutrition 0.000 description 1
- 239000002285 corn oil Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000009969 flowable effect Effects 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
- C08K5/053—Polyhydroxylic alcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/05—Alcohols; Metal alcoholates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15058A US3003998A (en) | 1960-03-15 | 1960-03-15 | Polyvinyl chloride resin compositions for use in food packaging |
| US15059A US3003999A (en) | 1960-03-15 | 1960-03-15 | Stabilized polyvinyl compositions for use in food packaging |
| US15060A US3004000A (en) | 1960-03-15 | 1960-03-15 | Polyvinyl chloride resin compositions stabilized for use in food packaging |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH437776A true CH437776A (de) | 1967-06-15 |
Family
ID=27360253
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH302761A CH437776A (de) | 1960-03-15 | 1961-03-14 | Stabilisator für gegebenenfalls andere Kunstharze enthaltende Vinylchloridhomo- oder mischpolymerisatharze und Verwendung desselben |
| CH302861A CH408414A (de) | 1960-03-15 | 1961-03-14 | Stabilisator und Verwendung desselben |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH302861A CH408414A (de) | 1960-03-15 | 1961-03-14 | Stabilisator und Verwendung desselben |
Country Status (5)
| Country | Link |
|---|---|
| CH (2) | CH437776A (enrdf_load_stackoverflow) |
| DE (3) | DE1241106B (enrdf_load_stackoverflow) |
| ES (1) | ES265400A1 (enrdf_load_stackoverflow) |
| GB (3) | GB918362A (enrdf_load_stackoverflow) |
| NL (3) | NL262419A (enrdf_load_stackoverflow) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1398281A (en) * | 1972-03-03 | 1975-06-18 | Akzo Nv | Additives for resins |
| FR2356674A1 (fr) * | 1976-06-28 | 1978-01-27 | Rhone Poulenc Ind | Compositions stabilisees a base de polymere de chlorure de vinyle |
| US4269743A (en) * | 1979-06-04 | 1981-05-26 | Dart Industries Inc. | Low toxicity vinyl halide stabilizer compositions |
| JP3077173B2 (ja) * | 1990-07-09 | 2000-08-14 | 住友化学工業株式会社 | 表面艶消し製品 |
-
0
- NL NL262420D patent/NL262420A/xx unknown
- DE DENDAT1240658D patent/DE1240658C2/de not_active Expired
- NL NL129754D patent/NL129754C/xx active
- NL NL262419D patent/NL262419A/xx unknown
- DE DENDAT1251522D patent/DE1251522B/de active Pending
-
1961
- 1961-03-04 ES ES0265400A patent/ES265400A1/es not_active Expired
- 1961-03-13 GB GB9113/61A patent/GB918362A/en not_active Expired
- 1961-03-13 GB GB9115/61A patent/GB918364A/en not_active Expired
- 1961-03-13 GB GB9114/61A patent/GB918363A/en not_active Expired
- 1961-03-13 DE DEA36963A patent/DE1241106B/de active Pending
- 1961-03-14 CH CH302761A patent/CH437776A/de unknown
- 1961-03-14 CH CH302861A patent/CH408414A/de unknown
Also Published As
| Publication number | Publication date |
|---|---|
| GB918362A (en) | 1963-02-13 |
| DE1241106B (de) | 1967-05-24 |
| GB918364A (en) | 1963-02-13 |
| NL262420A (enrdf_load_stackoverflow) | |
| DE1240658C2 (de) | 1975-06-12 |
| CH408414A (de) | 1966-02-28 |
| GB918363A (en) | 1963-02-13 |
| NL129754C (enrdf_load_stackoverflow) | |
| ES265400A1 (es) | 1961-09-01 |
| DE1251522B (de) | 1967-10-05 |
| NL262419A (enrdf_load_stackoverflow) |
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