CH202757A - Process for the preparation of an oxazine of the anthraquinone series. - Google Patents

Process for the preparation of an oxazine of the anthraquinone series.

Info

Publication number
CH202757A
CH202757A CH202757DA CH202757A CH 202757 A CH202757 A CH 202757A CH 202757D A CH202757D A CH 202757DA CH 202757 A CH202757 A CH 202757A
Authority
CH
Switzerland
Prior art keywords
acid
oxazine
preparation
condensation
copper chloride
Prior art date
Application number
Other languages
German (de)
Inventor
Aktiengesellsc Farbenindustrie
Original Assignee
Ig Farbenindustrie Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ig Farbenindustrie Ag filed Critical Ig Farbenindustrie Ag
Publication of CH202757A publication Critical patent/CH202757A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
    • C09B5/00—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings
    • C09B5/24—Dyes with an anthracene nucleus condensed with one or more heterocyclic rings with or without carbocyclic rings the heterocyclic rings being only condensed with an anthraquinone nucleus in 1-2 or 2-3 position
    • C09B5/44—Azines of the anthracene series
    • C09B5/60—Thiazines; Oxazines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Coloring (AREA)

Description

  

  Verfahren zur Darstellung eines     Oxazins    der     Anthrachinonreihe.       Gegenstand des vorliegenden Zusatzpa  tentes ist ein Verfahren zur Darstellung eines       Oxazins    der     Anthrachinonreihe,    welches da  durch gekennzeichnet ist,     dass    man     1-jodan-          thrachinon-2-sulfosaures    Kalium mit<B>3.</B> 4.<B>5.</B>     6-          Tetrachlor-2-aminophenol    in Gegenwart eines  säurebindenden Mittels kondensiert.  



  <I>Beispiel:</I>       23Gewichtsteilel-jodanthrachinon-2.Sulfo-          saures    Kalium,<B>19</B>     Gewichtsteile        3.4.5.6-          Tetraehlor-2-amiiiophenol        (95-prozentig),   <B>15</B>  Gewichtsteile Soda     ealciniert,   <B>15</B> Gewichts  teile     Natriumbicarbonat    und<B>1</B>     Gewiebtsteil          Kupferchlorür    werden in 400     Gewiebtsteilen     Wasser<B>3</B> Stunden bei 40-500     C    gerührt.

    Man gibt das Reaktionsgemisch in etwa 4000  Gewichtsteile beissen Wassers, saugt ab und  wäscht mit heissem Wasser nach. Zur wei  teren Reinigung kocht man das     Antbrachinon-          tetrachloroxazin    mit verdünnter Salzsäure aus,  wäscht neutral, trocknet und kristallisiert aus    etwa<B>1000</B>     Volumteilen    Nitrobenzol um. Man  erhält lange     dunkelviolettbraune,    glänzende  Nadeln, welche sieh in konzentrierter Schwe  felsäure     init    grüner Farbe lösen und aus braun  roter     Küpe    auf Baumwolle blaustichig rote  Farbtöne ergeben.



  Process for the preparation of an oxazine of the anthraquinone series. The subject matter of the present additional patent is a process for the preparation of an oxazine of the anthraquinone series, which is characterized in that 1-iodanethrachinone-2-sulfonic acid potassium with <B> 3. </B> 4. <B> 5. </B> 6-tetrachloro-2-aminophenol condensed in the presence of an acid-binding agent.



  <I> Example: </I> 23 parts by weight iodanthraquinone-2.Sulfo-acid potassium, <B> 19 </B> parts by weight 3.4.5.6-tetrachloro-2-amiiiophenol (95 percent), <B> 15 </ B> parts by weight of soda soda, <B> 15 </B> parts by weight of sodium bicarbonate and <B> 1 </B> part by weight of copper chloride are stirred in 400 parts by weight of water at 40-500 ° C. for 3 hours.

    The reaction mixture is poured into about 4000 parts by weight of hot water, filtered off with suction and washed with hot water. For further cleaning, the antbrachinon tetrachloroxazine is boiled out with dilute hydrochloric acid, washed neutral, dried and recrystallized from about <B> 1000 </B> parts by volume of nitrobenzene. Long, dark purple-brown, shiny needles are obtained which dissolve in concentrated sulfuric acid with a green color and give blue-tinged red hues from a brown-red vat on cotton.

Claims (1)

PATENTANSPRUCH: Verfahren zur Darstellung eines Oxazins der Anthrachinonreibe, dadurüh gekennzeich net, dass man 1-jodantbrachinon-2-sulfosaures Kalium mit 3.4.5.6-Tetrachloi--2-amino- phenol. in Gegenwart einps säurebindenden Mittels kondensiert. Der so erhaltene Farbstoff bildet dunkel- violettbraune glänzende Nadeln, welche sich in konzentrierter Schwefelsäure mit grüner Farbe lösen und aus braunroter Nüpe Baum wolle blaustichig rot färben. PATENT CLAIM: A method for the preparation of an oxazine from the anthraquinone grater, which is characterized by the fact that 1-iodantbrachinon-2-sulfonic acid potassium is mixed with 3.4.5.6-tetrachloi-2-aminophenol. condensed in the presence of an acid-binding agent. The dye thus obtained forms dark violet-brown shiny needles, which dissolve in concentrated sulfuric acid with a green color and turn a reddish brown nipple of tree wool with a bluish red color. UNTERANSPRÜCHE: <B>1.</B> Verfahren nach Patentanspruch, dadurch gekennzeichnet, dass man als säurebindende Mittel wasserfreies Natriumcarbonat und Natriumbiearbonat verwendet. 2.Verfahren nach Patentanspruch, dadurch gekennzeichnet, dass man die Kondensation in Clegenwart vor) Kupferchlorür durch führt. SUBClaims: <B> 1. </B> Method according to patent claim, characterized in that anhydrous sodium carbonate and sodium carbonate are used as acid-binding agents. 2. The method according to claim, characterized in that the condensation is carried out in Clegenwart before) copper chloride. 3.Verfahren nach Patentanspruch, dadurch gekennzeichnet, dass man die Kondensation durch Erwärmen der Reaktionskomponen ten während<B>3</B> Stunden auf 40-4511C in Gegenwart von wasserfreier Soda, Natrium- bicarbonat, Kupferehlorüt, und Wasser be wirkt. 3. The method according to claim, characterized in that the condensation is effected by heating the reaction components for <B> 3 </B> hours to 40-4511C in the presence of anhydrous soda, sodium bicarbonate, copper chloride, and water.
CH202757D 1936-06-27 1937-06-18 Process for the preparation of an oxazine of the anthraquinone series. CH202757A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE202757X 1936-06-27
CH199191T 1938-08-15

Publications (1)

Publication Number Publication Date
CH202757A true CH202757A (en) 1939-01-31

Family

ID=25723234

Family Applications (1)

Application Number Title Priority Date Filing Date
CH202757D CH202757A (en) 1936-06-27 1937-06-18 Process for the preparation of an oxazine of the anthraquinone series.

Country Status (1)

Country Link
CH (1) CH202757A (en)

Similar Documents

Publication Publication Date Title
CH202757A (en) Process for the preparation of an oxazine of the anthraquinone series.
CH222472A (en) Process for the production of a nitrogen-containing condensation product.
AT126120B (en) Process for the preparation of vat dyes of the perylene series.
CH188225A (en) Process for the production of a vat dye of the anthraquinone series.
CH211036A (en) Process for the preparation of a phenanthrene derivative.
CH195556A (en) Process for the preparation of a pyrene derivative.
CH202760A (en) Process for the preparation of an oxazine of the anthraquinone series.
CH185588A (en) Process for the preparation of an acidic dye of the anthraquinone series.
CH100389A (en) Process for the preparation of a dye.
CH195859A (en) Process for the production of a vat dye.
CH179682A (en) Process for the production of a new vat dye.
CH216320A (en) Process for the production of an acidic wool dye.
CH196353A (en) Process for the preparation of a pyrene derivative.
CH104012A (en) Process for the preparation of a condensation product of the anthraquinone series which can be used as dye and dye intermediate.
CH100390A (en) Process for the preparation of a dye.
CH216598A (en) Process for the production of a vat dye.
CH191570A (en) Process for the production of a new anthraquinone vat dye.
CH195860A (en) Process for the production of a vat dye.
CH162466A (en) Process for the preparation of an acylamino compound.
CH211850A (en) Process for the preparation of a phenanthrene derivative.
CH222464A (en) Process for the production of a nitrogen-containing condensation product.
CH100400A (en) Process for the preparation of a condensation product of the anthraquinone series which can be used as dye and dye intermediate.
CH141317A (en) Process for the preparation of a brown vat dye.
CH216319A (en) Process for the production of an acidic wool dye.
CH134106A (en) Process for the preparation of a new nitrogen-containing vat dye.