CA3008827C - Selectively permeable graphene oxide membrane - Google Patents
Selectively permeable graphene oxide membrane Download PDFInfo
- Publication number
- CA3008827C CA3008827C CA3008827A CA3008827A CA3008827C CA 3008827 C CA3008827 C CA 3008827C CA 3008827 A CA3008827 A CA 3008827A CA 3008827 A CA3008827 A CA 3008827A CA 3008827 C CA3008827 C CA 3008827C
- Authority
- CA
- Canada
- Prior art keywords
- graphene oxide
- selectively permeable
- oxide membrane
- water
- permeable graphene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000012528 membrane Substances 0.000 title abstract 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract 4
- 229910021389 graphene Inorganic materials 0.000 title abstract 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 3
- 238000000034 method Methods 0.000 abstract 2
- 230000035699 permeability Effects 0.000 abstract 2
- 239000000463 material Substances 0.000 abstract 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/44—Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0002—Organic membrane manufacture
- B01D67/0006—Organic membrane manufacture by chemical reactions
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0041—Inorganic membrane manufacture by agglomeration of particles in the dry state
- B01D67/00416—Inorganic membrane manufacture by agglomeration of particles in the dry state by deposition by filtration through a support or base layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0039—Inorganic membrane manufacture
- B01D67/0044—Inorganic membrane manufacture by chemical reaction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
- B01D67/00791—Different components in separate layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0079—Manufacture of membranes comprising organic and inorganic components
- B01D67/00793—Dispersing a component, e.g. as particles or powder, in another component
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
- B01D67/0081—After-treatment of organic or inorganic membranes
- B01D67/0083—Thermal after-treatment
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/08—Hollow fibre membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/10—Supported membranes; Membrane supports
- B01D69/107—Organic support material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1213—Laminated layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1214—Chemically bonded layers, e.g. cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/1216—Three or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
- B01D69/1251—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction by interfacial polymerisation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/14—Dynamic membranes
- B01D69/141—Heterogeneous membranes, e.g. containing dispersed material; Mixed matrix membranes
- B01D69/148—Organic/inorganic mixed matrix membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/021—Carbon
- B01D71/0211—Graphene or derivates thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/02—Inorganic material
- B01D71/024—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/38—Polyalkenylalcohols; Polyalkenylesters; Polyalkenylethers; Polyalkenylaldehydes; Polyalkenylketones; Polyalkenylacetals; Polyalkenylketals
- B01D71/381—Polyvinylalcohol
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2323/00—Details relating to membrane preparation
- B01D2323/30—Cross-linking
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/04—Characteristic thickness
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/36—Hydrophilic membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
- B01D61/025—Reverse osmosis; Hyperfiltration
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/56—Polyamides, e.g. polyester-amides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/124—Water desalination
- Y02A20/131—Reverse-osmosis
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Dispersion Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Carbon And Carbon Compounds (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562268835P | 2015-12-17 | 2015-12-17 | |
| US62/268,835 | 2015-12-17 | ||
| US201662339589P | 2016-05-20 | 2016-05-20 | |
| US62/339,589 | 2016-05-20 | ||
| PCT/US2016/066992 WO2017106540A1 (en) | 2015-12-17 | 2016-12-15 | Selectively permeable graphene oxide membrane |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3008827A1 CA3008827A1 (en) | 2017-06-22 |
| CA3008827C true CA3008827C (en) | 2021-05-18 |
Family
ID=57750636
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3008827A Active CA3008827C (en) | 2015-12-17 | 2016-12-15 | Selectively permeable graphene oxide membrane |
Country Status (9)
| Country | Link |
|---|---|
| US (2) | US10442709B2 (enExample) |
| EP (2) | EP3389836B1 (enExample) |
| JP (1) | JP6750017B2 (enExample) |
| KR (1) | KR102108667B1 (enExample) |
| CN (1) | CN109219479B (enExample) |
| CA (1) | CA3008827C (enExample) |
| ES (1) | ES2788169T3 (enExample) |
| TW (1) | TWI725090B (enExample) |
| WO (1) | WO2017106540A1 (enExample) |
Families Citing this family (46)
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| US9902141B2 (en) | 2014-03-14 | 2018-02-27 | University Of Maryland | Layer-by-layer assembly of graphene oxide membranes via electrostatic interaction and eludication of water and solute transport mechanisms |
| US10442709B2 (en) * | 2015-12-17 | 2019-10-15 | Nitto Denko Corporation | Selectively permeable graphene oxide membrane |
| CA3022311A1 (en) | 2016-05-11 | 2017-11-16 | Massachusetts Institute Of Technology | Graphene oxide membranes and related methods |
| WO2018067269A1 (en) * | 2016-10-03 | 2018-04-12 | Nitto Denko Corporation | Graphene oxide anti-microbial element |
| CN110573240B (zh) * | 2017-03-01 | 2022-11-22 | 日东电工株式会社 | 选择性渗透的氧化石墨烯膜 |
| CN109224888A (zh) * | 2017-07-10 | 2019-01-18 | 浙江工业大学 | 一种氧化石墨烯框架改性聚酰胺反渗透膜及其应用 |
| JP2020529311A (ja) * | 2017-08-04 | 2020-10-08 | 日東電工株式会社 | 選択透過性酸化グラフェン膜 |
| CN107555566B (zh) * | 2017-08-31 | 2020-11-24 | 华南理工大学 | 磺化石墨烯与阳离子聚丙烯酰胺乳液协同处理重金属污染水的方法 |
| CN111727082A (zh) * | 2017-12-21 | 2020-09-29 | 日东电工株式会社 | 氧化石墨烯膜的保护性涂层 |
| CN208078031U (zh) * | 2017-12-29 | 2018-11-09 | 云谷(固安)科技有限公司 | 封装结构及包括封装结构的显示装置 |
| US20210060522A1 (en) * | 2018-01-08 | 2021-03-04 | Virginia Commonwealth University | Graphene-based materials for the efficient removal of pollutants from water |
| CN108097059A (zh) * | 2018-01-15 | 2018-06-01 | 哈尔滨工业大学 | 一种利用二硫化钼建立水通道增强聚酰胺反渗透膜水通量的改性方法 |
| US11607652B2 (en) | 2018-02-07 | 2023-03-21 | National University Corporation Kobe University | Composite separation membrane |
| US11420164B2 (en) * | 2018-03-01 | 2022-08-23 | King Fahd University Of Petroleum And Minerals | Method of deionizing saline water with a diffusion barrier |
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| CN112261988A (zh) * | 2018-06-08 | 2021-01-22 | 日东电工株式会社 | 选择性渗透的氧化石墨烯膜 |
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| CN109277003B (zh) * | 2018-09-22 | 2021-10-15 | 浙江工业大学 | 一种石墨烯超滤膜及其制备方法 |
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| JP2022513287A (ja) * | 2018-12-17 | 2022-02-07 | 日東電工株式会社 | 選択透過性高分子膜 |
| CN111715078B (zh) * | 2019-03-20 | 2022-05-24 | 暨南大学 | 一种具有固定层间距的三明治氧化石墨烯中空纤维膜及其制备方法与应用 |
| CN111715082A (zh) * | 2019-03-21 | 2020-09-29 | 南京林业大学 | 一种高效的超亲油纳米纤维膜的简易制备方法及纳米纤维膜 |
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| JP7572972B2 (ja) * | 2019-05-15 | 2024-10-24 | ヴィア セパレイションズ,インコーポレイテッド | 耐久性のある酸化グラフェン膜 |
| EP3969158A1 (en) | 2019-05-15 | 2022-03-23 | Via Separations, Inc. | Filtration apparatus containing graphene oxide membrane |
| CN114144253A (zh) * | 2019-06-12 | 2022-03-04 | 新南创新私人有限公司 | 过滤膜以及其生产方法 |
| CN113924268B (zh) | 2019-06-13 | 2024-03-08 | 2599218 安大略公司 | 用于制造石墨烯膜的设备、方法和系统 |
| US11058997B2 (en) | 2019-08-16 | 2021-07-13 | 2599218 Ontario Inc. | Graphene membrane and method for making graphene membrane |
| US11167250B1 (en) * | 2019-09-19 | 2021-11-09 | National Technology & Engineering Solutions Of Sandia, Llc | Filtration membranes |
| PL4041430T3 (pl) * | 2019-10-11 | 2025-04-14 | Corewater Technologies Inc. | Kompozytowy materiał filtracyjny wielokrotnego użytku oraz sposoby jego wytwarzania i wykorzystania do usuwania i niszczenia zanieczyszczeń cząsteczkowych z wody |
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| GB201320564D0 (en) * | 2013-11-21 | 2014-01-08 | Univ Manchester | Water Purification |
| CN103768960B (zh) | 2014-01-06 | 2016-02-10 | 北京化工大学 | 一种石墨烯基膜的制备方法及其在油水分离中的应用 |
| CN106102884B (zh) * | 2014-03-12 | 2020-11-17 | 汉阳大学校产学协力团 | 包含氧化石墨烯涂层的复合膜、包含其的多孔聚合物支撑体及其制备方法 |
| US9902141B2 (en) * | 2014-03-14 | 2018-02-27 | University Of Maryland | Layer-by-layer assembly of graphene oxide membranes via electrostatic interaction and eludication of water and solute transport mechanisms |
| WO2015142938A1 (en) * | 2014-03-17 | 2015-09-24 | Washington University | Composite nanostructures having a crumpled graphene oxide shell |
| US20150344666A1 (en) | 2014-05-29 | 2015-12-03 | Reagents Of The University Of Minnesota | Laminates Comprising Oligomer-Grafted Nanofillers and Advanced Composite Materials |
| US10456754B2 (en) * | 2014-08-08 | 2019-10-29 | University Of Southern California | High performance membranes for water reclamation using polymeric and nanomaterials |
| CN107530642B (zh) * | 2015-04-20 | 2021-05-07 | 义安理工学院 | 官能化单层石墨烯基薄膜复合材料及其制造方法 |
| GB201510761D0 (en) * | 2015-06-18 | 2015-08-05 | Imp Innovations Ltd | 2-dimensional carbon material |
| US10442709B2 (en) * | 2015-12-17 | 2019-10-15 | Nitto Denko Corporation | Selectively permeable graphene oxide membrane |
-
2016
- 2016-12-15 US US15/380,797 patent/US10442709B2/en active Active
- 2016-12-15 CN CN201680082039.XA patent/CN109219479B/zh not_active Expired - Fee Related
- 2016-12-15 WO PCT/US2016/066992 patent/WO2017106540A1/en not_active Ceased
- 2016-12-15 CA CA3008827A patent/CA3008827C/en active Active
- 2016-12-15 ES ES16822865T patent/ES2788169T3/es active Active
- 2016-12-15 EP EP16822865.8A patent/EP3389836B1/en active Active
- 2016-12-15 EP EP20152970.8A patent/EP3677330A1/en not_active Withdrawn
- 2016-12-15 JP JP2018531602A patent/JP6750017B2/ja not_active Expired - Fee Related
- 2016-12-15 KR KR1020187020569A patent/KR102108667B1/ko not_active Expired - Fee Related
- 2016-12-16 TW TW105141782A patent/TWI725090B/zh not_active IP Right Cessation
-
2019
- 2019-08-29 US US16/556,021 patent/US20200017377A1/en not_active Abandoned
Also Published As
| Publication number | Publication date |
|---|---|
| CN109219479B (zh) | 2022-01-04 |
| KR102108667B1 (ko) | 2020-05-07 |
| US20170174537A1 (en) | 2017-06-22 |
| EP3389836B1 (en) | 2020-03-04 |
| US10442709B2 (en) | 2019-10-15 |
| JP2019500212A (ja) | 2019-01-10 |
| TWI725090B (zh) | 2021-04-21 |
| KR20180095048A (ko) | 2018-08-24 |
| CN109219479A (zh) | 2019-01-15 |
| CA3008827A1 (en) | 2017-06-22 |
| TW201739699A (zh) | 2017-11-16 |
| ES2788169T3 (es) | 2020-10-20 |
| WO2017106540A1 (en) | 2017-06-22 |
| JP6750017B2 (ja) | 2020-09-02 |
| US20200017377A1 (en) | 2020-01-16 |
| EP3389836A1 (en) | 2018-10-24 |
| EP3677330A1 (en) | 2020-07-08 |
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