MX2020000970A - Materiales forosos a partir de arquitecturas de copolímeros en bloque complejas. - Google Patents
Materiales forosos a partir de arquitecturas de copolímeros en bloque complejas.Info
- Publication number
- MX2020000970A MX2020000970A MX2020000970A MX2020000970A MX2020000970A MX 2020000970 A MX2020000970 A MX 2020000970A MX 2020000970 A MX2020000970 A MX 2020000970A MX 2020000970 A MX2020000970 A MX 2020000970A MX 2020000970 A MX2020000970 A MX 2020000970A
- Authority
- MX
- Mexico
- Prior art keywords
- block copolymer
- porous materials
- complex block
- complex
- copolymer architectures
- Prior art date
Links
- 229920001400 block copolymer Polymers 0.000 title abstract 4
- 239000011148 porous material Substances 0.000 title abstract 3
- 238000004132 cross linking Methods 0.000 abstract 1
- 238000001514 detection method Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
- B01D71/80—Block polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/02—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor characterised by their properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/26—Polyalkenes
- B01D71/261—Polyethylene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/28—Polymers of vinyl aromatic compounds
- B01D71/281—Polystyrene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/28—Polymers of vinyl aromatic compounds
- B01D71/283—Polyvinylpyridine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
- B01D71/06—Organic material
- B01D71/40—Polymers of unsaturated acids or derivatives thereof, e.g. salts, amides, imides, nitriles, anhydrides, esters
- B01D71/401—Polymers based on the polymerisation of acrylic acid, e.g. polyacrylate
- B01D71/4011—Polymethylmethacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/283—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum a discontinuous liquid phase emulsified in a continuous macromolecular phase
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/28—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum
- C08J9/286—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof by elimination of a liquid phase from a macromolecular composition or article, e.g. drying of coagulum the liquid phase being a solvent for the monomers but not for the resulting macromolecular composition, i.e. macroporous or macroreticular polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2325/00—Details relating to properties of membranes
- B01D2325/02—Details relating to pores or porosity of the membranes
- B01D2325/021—Pore shapes
- B01D2325/0212—Symmetric or isoporous membranes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/05—Elimination by evaporation or heat degradation of a liquid phase
- C08J2201/0502—Elimination by evaporation or heat degradation of a liquid phase the liquid phase being organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2201/00—Foams characterised by the foaming process
- C08J2201/04—Foams characterised by the foaming process characterised by the elimination of a liquid or solid component, e.g. precipitation, leaching out, evaporation
- C08J2201/054—Precipitating the polymer by adding a non-solvent or a different solvent
- C08J2201/0542—Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition
- C08J2201/0544—Precipitating the polymer by adding a non-solvent or a different solvent from an organic solvent-based polymer composition the non-solvent being aqueous
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/042—Nanopores, i.e. the average diameter being smaller than 0,1 micrometer
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2205/00—Foams characterised by their properties
- C08J2205/04—Foams characterised by their properties characterised by the foam pores
- C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2353/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2353/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2453/00—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers
- C08J2453/02—Characterised by the use of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Derivatives of such polymers of vinyl aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Filtering Materials (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
Materiales de copolímero en bloque poroso autoensamblados con una arquitectura compleja de copolímero en bloque, métodos de preparación, usos para la separación y detección, y dispositivos para usar como tales. Los materiales porosos contienen al menos uno de macroporos, mesoporos o microporos, al menos algunos de los cuales son isoporosos, e incluyen al menos un copolímero en bloque con al menos dos bloques químicamente distintos, que además comprende una arquitectura compleja tal como: múltiples monómeros distintos en o entre bloques, ramificaciones, reticulaciones o arquitecturas en anillo.
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201762536835P | 2017-07-25 | 2017-07-25 | |
US201762564669P | 2017-09-28 | 2017-09-28 | |
US201862625633P | 2018-02-02 | 2018-02-02 | |
PCT/US2018/043303 WO2019023135A1 (en) | 2017-07-25 | 2018-07-23 | POROUS MATERIALS FROM COMPLEX BLOCK COPOLYMER ARCHITECTURES |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2020000970A true MX2020000970A (es) | 2020-09-28 |
Family
ID=65039794
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2020000970A MX2020000970A (es) | 2017-07-25 | 2018-07-23 | Materiales forosos a partir de arquitecturas de copolímeros en bloque complejas. |
Country Status (9)
Country | Link |
---|---|
US (1) | US20200238227A1 (es) |
EP (1) | EP3658262A4 (es) |
JP (1) | JP2020528952A (es) |
KR (1) | KR102640611B1 (es) |
CN (1) | CN111032200A (es) |
CA (1) | CA3071140A1 (es) |
MX (1) | MX2020000970A (es) |
SG (1) | SG11202000664YA (es) |
WO (1) | WO2019023135A1 (es) |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP3636696A1 (en) | 2011-05-04 | 2020-04-15 | Cornell University | Multiblock copolymer films, methods of making same and uses thereof |
KR102308085B1 (ko) | 2016-04-28 | 2021-10-06 | 테라포어 테크놀로지스, 인코포레이티드 | 정전기적 분리를 위한 대전된 이소포러스 재료 |
CN110475602B (zh) | 2016-11-17 | 2022-05-03 | 特拉波雷技术有限公司 | 含有高分子量亲水性添加剂的均孔自组装嵌段共聚物膜及其制备方法 |
SG11201907674WA (en) | 2017-02-22 | 2019-09-27 | Terapore Tech Inc | Ligand bound mbp membranes, uses and method of manufacturing |
US11572424B2 (en) * | 2017-05-12 | 2023-02-07 | Terapore Technologies, Inc. | Chemically resistant fluorinated multiblock polymer structures, methods of manufacturing and use |
MX2020003098A (es) | 2017-09-19 | 2020-07-28 | Terapore Tech Inc | Estructura entrelazada isoporosa de copolimero de bloques quimicamente resistente. |
WO2019178045A1 (en) * | 2018-03-12 | 2019-09-19 | Terapore Technologies, Inc. | Isoporous mesoporous asymmetric block copolymer materials with macrovoids and method of making the same |
CN112074339A (zh) * | 2018-04-04 | 2020-12-11 | 特拉波雷技术有限公司 | 包封颗粒分馏装置和系统以及该装置和系统的使用方法 |
US20210370237A1 (en) * | 2018-10-05 | 2021-12-02 | Terapore Technologies, Inc. | Method of filtering liquids or gases for electronics production |
FR3097689B1 (fr) * | 2019-06-19 | 2021-06-25 | Commissariat Energie Atomique | Procédé de formation d’une couche microporeuse électroconductrice hydrophobe utile à titre de couche de diffusion de gaz |
TW202116823A (zh) * | 2019-06-24 | 2021-05-01 | 英商弗萊克英納寶有限公司 | 藉由調整機械性能而改良介電質的應力反應與附著行為 |
US20220283116A1 (en) * | 2019-08-03 | 2022-09-08 | King Abdullah University Of Science And Technology | Device for detecting analytes in a sample, and methods of use thereof |
CN112090288A (zh) * | 2020-08-05 | 2020-12-18 | 杭州晟聚环保科技有限公司 | 一种两亲性砜类聚合物及共混膜的制备方法 |
US20240181398A1 (en) | 2021-03-19 | 2024-06-06 | Global Life Sciences Solutions Operations Uk Ltd. | Viral filter and method of viral filtration |
CN113144911B (zh) * | 2021-04-12 | 2022-04-29 | 浙江工业大学 | 含羟基嵌段共聚物及耐污染耐酸碱溶胀多孔膜的制备方法 |
CN117384385B (zh) * | 2023-12-13 | 2024-03-22 | 天津工业大学 | 一种具有非线型嵌段结构的聚砜基嵌段共聚物及其合成方法与应用 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7151120B2 (en) * | 2001-10-17 | 2006-12-19 | The Regents Of The University Of Michigan | Degradable porous materials with high surface areas |
EP2533884A1 (en) * | 2010-02-11 | 2012-12-19 | King Abdullah University Of Science And Technology | Self-assembled block copolymer membrane |
EP3636696A1 (en) * | 2011-05-04 | 2020-04-15 | Cornell University | Multiblock copolymer films, methods of making same and uses thereof |
JP6330230B2 (ja) * | 2013-03-11 | 2018-05-30 | ユニヴァーシティー オブ ノートル ダム デュ ラック | マルチブロックコポリマー及び使用方法 |
WO2015048244A1 (en) * | 2013-09-25 | 2015-04-02 | Cornell University | Multiblock copolymer films with inorganic nanoparticles, methods of making same, and uses thereof |
FR3014876B1 (fr) * | 2013-12-13 | 2017-03-31 | Arkema France | Procede de realisation d'un film de copolymere a blocs sur un substrat |
DE102014213027A1 (de) * | 2014-07-04 | 2016-01-07 | Helmholtz-Zentrum Geesthacht Zentrum für Material- und Küstenforschung GmbH | Verfahren zur Herstellung einer Membran mit isoporöser trennaktiver Schicht mit einstellbarer Porengröße, Membran, Filtrationsmodul und Verwendung |
US11021630B2 (en) * | 2014-12-30 | 2021-06-01 | Rohm And Haas Electronic Materials Llc | Copolymer formulation for directed self assembly, methods of manufacture thereof and articles comprising the same |
CN110475602B (zh) * | 2016-11-17 | 2022-05-03 | 特拉波雷技术有限公司 | 含有高分子量亲水性添加剂的均孔自组装嵌段共聚物膜及其制备方法 |
-
2018
- 2018-07-23 EP EP18837375.7A patent/EP3658262A4/en not_active Withdrawn
- 2018-07-23 KR KR1020207005342A patent/KR102640611B1/ko active IP Right Grant
- 2018-07-23 SG SG11202000664YA patent/SG11202000664YA/en unknown
- 2018-07-23 CN CN201880055509.2A patent/CN111032200A/zh active Pending
- 2018-07-23 US US16/633,508 patent/US20200238227A1/en not_active Abandoned
- 2018-07-23 JP JP2020503958A patent/JP2020528952A/ja active Pending
- 2018-07-23 CA CA3071140A patent/CA3071140A1/en active Pending
- 2018-07-23 MX MX2020000970A patent/MX2020000970A/es unknown
- 2018-07-23 WO PCT/US2018/043303 patent/WO2019023135A1/en unknown
Also Published As
Publication number | Publication date |
---|---|
US20200238227A1 (en) | 2020-07-30 |
JP2020528952A (ja) | 2020-10-01 |
WO2019023135A1 (en) | 2019-01-31 |
CA3071140A1 (en) | 2019-01-31 |
KR102640611B1 (ko) | 2024-02-27 |
EP3658262A4 (en) | 2021-04-07 |
SG11202000664YA (en) | 2020-02-27 |
EP3658262A1 (en) | 2020-06-03 |
CN111032200A (zh) | 2020-04-17 |
KR20200054170A (ko) | 2020-05-19 |
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