CA2888512C - Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems and methods - Google Patents
Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems and methods Download PDFInfo
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- CA2888512C CA2888512C CA2888512A CA2888512A CA2888512C CA 2888512 C CA2888512 C CA 2888512C CA 2888512 A CA2888512 A CA 2888512A CA 2888512 A CA2888512 A CA 2888512A CA 2888512 C CA2888512 C CA 2888512C
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- molecular sieve
- small pore
- pore molecular
- ring small
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- IQDXNHZDRQHKEF-UHFFFAOYSA-N dialuminum;dicalcium;dioxido(oxo)silane Chemical compound [Al+3].[Al+3].[Ca+2].[Ca+2].[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O.[O-][Si]([O-])=O IQDXNHZDRQHKEF-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 229910052730 francium Inorganic materials 0.000 description 1
- KLMCZVJOEAUDNE-UHFFFAOYSA-N francium atom Chemical compound [Fr] KLMCZVJOEAUDNE-UHFFFAOYSA-N 0.000 description 1
- 229910021485 fumed silica Inorganic materials 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910001411 inorganic cation Inorganic materials 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 150000002603 lanthanum Chemical class 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- CSJDCSCTVDEHRN-UHFFFAOYSA-N methane;molecular oxygen Chemical compound C.O=O CSJDCSCTVDEHRN-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- QEFYFXOXNSNQGX-UHFFFAOYSA-N neodymium atom Chemical compound [Nd] QEFYFXOXNSNQGX-UHFFFAOYSA-N 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000006259 organic additive Substances 0.000 description 1
- 238000010979 pH adjustment Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 229910052670 petalite Inorganic materials 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- AABBHSMFGKYLKE-SNAWJCMRSA-N propan-2-yl (e)-but-2-enoate Chemical compound C\C=C\C(=O)OC(C)C AABBHSMFGKYLKE-SNAWJCMRSA-N 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910052851 sillimanite Inorganic materials 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 229910052642 spodumene Inorganic materials 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 229910052645 tectosilicate Inorganic materials 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052649 zeolite group Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
- 238000013316 zoning Methods 0.000 description 1
Classifications
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- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
- B01D53/9404—Removing only nitrogen compounds
- B01D53/9409—Nitrogen oxides
- B01D53/9413—Processes characterised by a specific catalyst
- B01D53/9418—Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/80—Mixtures of different zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
- B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/723—CHA-type, e.g. Chabazite, LZ-218
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
- B01J29/76—Iron group metals or copper
- B01J29/763—CHA-type, e.g. Chabazite, LZ-218
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/83—Aluminophosphates [APO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/82—Phosphates
- B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
- B01J29/85—Silicoaluminophosphates [SAPO compounds]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/024—Multiple impregnation or coating
- B01J37/0246—Coatings comprising a zeolite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/204—Alkaline earth metals
- B01D2255/2042—Barium
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
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- B01D2255/207—Transition metals
- B01D2255/20738—Iron
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/20—Metals or compounds thereof
- B01D2255/207—Transition metals
- B01D2255/20761—Copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2255/00—Catalysts
- B01D2255/50—Zeolites
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Crystallography & Structural Chemistry (AREA)
- Biomedical Technology (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Analytical Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Exhaust Gas After Treatment (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Applications Claiming Priority (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261716073P | 2012-10-19 | 2012-10-19 | |
| US61/716,073 | 2012-10-19 | ||
| US14/055,953 | 2013-10-17 | ||
| US14/055,953 US9242238B2 (en) | 2012-10-19 | 2013-10-17 | Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems, and methods |
| PCT/US2013/065492 WO2014062944A1 (en) | 2012-10-19 | 2013-10-17 | Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems and methods |
Publications (2)
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| CA2888512A1 CA2888512A1 (en) | 2014-04-24 |
| CA2888512C true CA2888512C (en) | 2020-09-22 |
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| CA2888512A Active CA2888512C (en) | 2012-10-19 | 2013-10-17 | Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems and methods |
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| CN (1) | CN104736243A (enExample) |
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| WO (1) | WO2014062944A1 (enExample) |
| ZA (1) | ZA201503449B (enExample) |
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| DK2150328T5 (da) * | 2007-04-26 | 2015-06-29 | Johnson Matthey Plc | SCR-fremgangsmåde og system med Cu/SAPO-34 zeolitkatalysator |
| BR112014018506A8 (pt) * | 2012-01-31 | 2017-07-11 | Johnson Matthey Plc | Composição de catalisador, método para tratar nox, e, artigo catalítico |
| EP2908947B1 (en) * | 2012-10-19 | 2021-09-29 | BASF Corporation | Mixed metal 8-ring small pore molecular sieve catalytic articles and methods |
| KR102227793B1 (ko) * | 2013-08-30 | 2021-03-15 | 존슨 맛쎄이 퍼블릭 리미티드 컴파니 | NOx를 함유하는 배기가스를 처리하기 위한 제올라이트 블렌드 촉매 |
| JP6513652B2 (ja) * | 2013-10-31 | 2019-05-15 | ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ | Ａｅｉゼオライトの合成 |
| GB2522527B (en) * | 2013-12-02 | 2018-01-24 | Johnson Matthey Plc | Mixed template synthesis of high silica Cu-CHA |
| US11266981B2 (en) * | 2013-12-02 | 2022-03-08 | Johnson Matthey Public Limited Company | Mixed template synthesis of low silica CHA zeolite |
| CN107107043A (zh) * | 2014-10-07 | 2017-08-29 | 庄信万丰股份有限公司 | 用于处理废气的分子筛催化剂 |
| CN107107044B (zh) * | 2014-10-30 | 2021-10-01 | 巴斯夫公司 | 混合的金属大晶体分子筛催化剂组合物、催化制品、系统和方法 |
| GB2559432B (en) * | 2014-11-14 | 2021-01-13 | Johnson Matthey Plc | AFX zeolite |
| GB2540832B (en) * | 2015-02-20 | 2019-04-17 | Johnson Matthey Plc | Bi-metal molecular sieve catalysts |
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| WO2016149606A1 (en) * | 2015-03-19 | 2016-09-22 | Basf Corporation | Filter catalyzed with scr catalyst, systems and methods |
| WO2017023766A1 (en) * | 2015-08-03 | 2017-02-09 | Cummins Emission Solutions Inc. | Sensor configuration for aftertreatment system including scr on filter |
| EP3344384B1 (en) * | 2015-09-04 | 2025-03-26 | BASF Mobile Emissions Catalysts LLC | Integrated scr and ammonia oxidation catalyst systems |
| CN105439171B (zh) * | 2015-12-22 | 2021-05-11 | 天津众智科技有限公司 | 以碳酸酯为合成促进剂制备sapo-34分子筛的方法及其应用 |
| JP6779498B2 (ja) * | 2016-01-22 | 2020-11-04 | 国立大学法人広島大学 | スズを含有するゼオライトおよびその製造方法 |
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| JP6925350B2 (ja) * | 2016-02-03 | 2021-08-25 | ビーエーエスエフ コーポレーション | 銅および鉄共交換チャバザイト触媒 |
| KR20180114238A (ko) * | 2016-03-08 | 2018-10-17 | 바스프 코포레이션 | 감소된 n2o 배출을 나타내는 이온-교환된 분자체 촉매 |
| CN107233932A (zh) | 2016-03-29 | 2017-10-10 | 巴斯夫公司 | 用于scr催化剂的脱硫方法 |
| EP3442687A1 (de) * | 2016-04-13 | 2019-02-20 | Umicore AG & Co. KG | Partikelfilter mit scr-aktiver beschichtung |
| CN105772065B (zh) * | 2016-04-13 | 2018-01-30 | 贵州大学 | 一种改性zsm‑5分子筛催化剂及其制备方法 |
| CN105688981B (zh) * | 2016-04-13 | 2018-02-09 | 贵州大学 | 一种改性sapo‑34分子筛催化剂的制备方法 |
| CN105772063B (zh) * | 2016-04-13 | 2018-01-30 | 贵州大学 | 一种改性zsm‑5分子筛催化剂及其制备方法 |
| CN105854931B (zh) * | 2016-04-13 | 2018-01-30 | 贵州大学 | 一种改性sapo‑34分子筛催化剂的制备方法 |
| KR20180127514A (ko) * | 2016-04-13 | 2018-11-28 | 우미코레 아게 운트 코 카게 | Scr-활성 코팅을 갖는 촉매 |
| WO2018015930A1 (en) * | 2016-07-22 | 2018-01-25 | Johnson Matthey Public Limited Company | Exhaust gas catalyst and catalyst binders for filter substrates |
| CA3032554A1 (en) * | 2016-08-05 | 2018-02-08 | Basf Corporation | Selective catalytic reduction articles and systems having high nox conversion and low n2o formation |
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| CN110114130B (zh) | 2016-12-05 | 2022-10-14 | 巴斯夫公司 | 用于氧化NO、氧化烃类、氧化NH3和选择性催化还原NOx的四功能催化剂 |
| CN110621402B (zh) | 2017-03-20 | 2023-04-14 | 巴斯夫公司 | 选择性催化还原制品和系统 |
| JP2020515766A (ja) | 2017-04-04 | 2020-05-28 | ビーエーエスエフ コーポレーション | 統合された排出制御システム |
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| US9242238B2 (en) | 2016-01-26 |
| MX2015004812A (es) | 2016-03-11 |
| KR20150074094A (ko) | 2015-07-01 |
| EP2908947A4 (en) | 2016-07-06 |
| JP2016500562A (ja) | 2016-01-14 |
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| RU2015118443A (ru) | 2016-12-10 |
| EP2908947B1 (en) | 2021-09-29 |
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| US20150086456A1 (en) | 2015-03-26 |
| US20140112853A1 (en) | 2014-04-24 |
| EP2908947A1 (en) | 2015-08-26 |
| BR112015008645A2 (enExample) | 2017-08-22 |
| US9486792B2 (en) | 2016-11-08 |
| CN104736243A (zh) | 2015-06-24 |
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