CN104736243A - 混合金属8环小孔分子筛催化剂组合物、催化制品、体系和方法 - Google Patents

混合金属8环小孔分子筛催化剂组合物、催化制品、体系和方法 Download PDF

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Publication number
CN104736243A
CN104736243A CN201380054335.5A CN201380054335A CN104736243A CN 104736243 A CN104736243 A CN 104736243A CN 201380054335 A CN201380054335 A CN 201380054335A CN 104736243 A CN104736243 A CN 104736243A
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China
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promoted
molecular sieve
ring small
pore molecular
copper
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CN201380054335.5A
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Chinese (zh)
Inventor
J·L·莫纳汉
P·伯克
M·J·布林
B·斯拉夫斯基
M·娜加塔
万能康之
E·基姆
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BASF Corp
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BASF Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80Mixtures of different zeolites
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/723CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/83Aluminophosphates [APO compounds]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85Silicoaluminophosphates [SAPO compounds]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0246Coatings comprising a zeolite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/204Alkaline earth metals
    • B01D2255/2042Barium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20738Iron
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20761Copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/50Zeolites

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biomedical Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Exhaust Gas After Treatment (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CN201380054335.5A 2012-10-19 2013-10-17 混合金属8环小孔分子筛催化剂组合物、催化制品、体系和方法 Pending CN104736243A (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
US201261716073P 2012-10-19 2012-10-19
US61/716,073 2012-10-19
US14/055,953 2013-10-17
US14/055,953 US9242238B2 (en) 2012-10-19 2013-10-17 Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems, and methods
PCT/US2013/065492 WO2014062944A1 (en) 2012-10-19 2013-10-17 Mixed metal 8-ring small pore molecular sieve catalyst compositions, catalytic articles, systems and methods

Publications (1)

Publication Number Publication Date
CN104736243A true CN104736243A (zh) 2015-06-24

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US (2) US9242238B2 (enExample)
EP (1) EP2908947B1 (enExample)
JP (1) JP6469578B2 (enExample)
KR (1) KR102186666B1 (enExample)
CN (1) CN104736243A (enExample)
BR (1) BR112015008645B1 (enExample)
CA (1) CA2888512C (enExample)
MX (1) MX387698B (enExample)
MY (1) MY169112A (enExample)
RU (1) RU2717953C2 (enExample)
WO (1) WO2014062944A1 (enExample)
ZA (1) ZA201503449B (enExample)

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CN107949436A (zh) * 2015-09-04 2018-04-20 巴斯夫欧洲公司 集成的scr和氨氧化催化剂体系
CN109790039A (zh) * 2016-08-05 2019-05-21 巴斯夫公司 选择性催化还原制品和系统
CN109843432A (zh) * 2016-08-05 2019-06-04 巴斯夫公司 选择性催化还原制品和系统
CN111646483A (zh) * 2020-06-12 2020-09-11 浙江浙能技术研究院有限公司 一种Ru-SSZ-13分子筛及其制备方法
CN116139919A (zh) * 2021-11-22 2023-05-23 上海歌地催化剂有限公司 一种scr催化剂及其制备方法

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BR112014018506A8 (pt) * 2012-01-31 2017-07-11 Johnson Matthey Plc Composição de catalisador, método para tratar nox, e, artigo catalítico
EP2908947B1 (en) * 2012-10-19 2021-09-29 BASF Corporation Mixed metal 8-ring small pore molecular sieve catalytic articles and methods
KR102227793B1 (ko) * 2013-08-30 2021-03-15 존슨 맛쎄이 퍼블릭 리미티드 컴파니 NOx를 함유하는 배기가스를 처리하기 위한 제올라이트 블렌드 촉매
JP6513652B2 (ja) * 2013-10-31 2019-05-15 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーJohnson Matthey Public Limited Company Aeiゼオライトの合成
GB2522527B (en) * 2013-12-02 2018-01-24 Johnson Matthey Plc Mixed template synthesis of high silica Cu-CHA
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CN107107043A (zh) * 2014-10-07 2017-08-29 庄信万丰股份有限公司 用于处理废气的分子筛催化剂
CN107107044B (zh) * 2014-10-30 2021-10-01 巴斯夫公司 混合的金属大晶体分子筛催化剂组合物、催化制品、系统和方法
GB2559432B (en) * 2014-11-14 2021-01-13 Johnson Matthey Plc AFX zeolite
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JP6779498B2 (ja) * 2016-01-22 2020-11-04 国立大学法人広島大学 スズを含有するゼオライトおよびその製造方法
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CN105772063B (zh) * 2016-04-13 2018-01-30 贵州大学 一种改性zsm‑5分子筛催化剂及其制备方法
CN105854931B (zh) * 2016-04-13 2018-01-30 贵州大学 一种改性sapo‑34分子筛催化剂的制备方法
KR20180127514A (ko) * 2016-04-13 2018-11-28 우미코레 아게 운트 코 카게 Scr-활성 코팅을 갖는 촉매
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US11278874B2 (en) * 2018-11-30 2022-03-22 Johnson Matthey Public Limited Company Enhanced introduction of extra-framework metal into aluminosilicate zeolites
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KR20230098620A (ko) * 2020-10-30 2023-07-04 바스프 코포레이션 향상된 고온 전환 및 감소된 n2o 생성을 위한 촉매
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CN107949436A (zh) * 2015-09-04 2018-04-20 巴斯夫欧洲公司 集成的scr和氨氧化催化剂体系
CN109790039A (zh) * 2016-08-05 2019-05-21 巴斯夫公司 选择性催化还原制品和系统
CN109843432A (zh) * 2016-08-05 2019-06-04 巴斯夫公司 选择性催化还原制品和系统
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CN109790039B (zh) * 2016-08-05 2023-08-04 巴斯夫公司 选择性催化还原制品和系统
CN111646483A (zh) * 2020-06-12 2020-09-11 浙江浙能技术研究院有限公司 一种Ru-SSZ-13分子筛及其制备方法
CN116139919A (zh) * 2021-11-22 2023-05-23 上海歌地催化剂有限公司 一种scr催化剂及其制备方法

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