CA2722549C - Cell for solid oxide fuel cell - Google Patents
Cell for solid oxide fuel cell Download PDFInfo
- Publication number
- CA2722549C CA2722549C CA2722549A CA2722549A CA2722549C CA 2722549 C CA2722549 C CA 2722549C CA 2722549 A CA2722549 A CA 2722549A CA 2722549 A CA2722549 A CA 2722549A CA 2722549 C CA2722549 C CA 2722549C
- Authority
- CA
- Canada
- Prior art keywords
- coating layer
- alloy
- air electrode
- oxide
- sofc cell
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 45
- 239000007787 solid Substances 0.000 title claims abstract description 24
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 278
- 239000000956 alloy Substances 0.000 claims abstract description 278
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 147
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 147
- 239000001301 oxygen Substances 0.000 claims abstract description 147
- 239000011247 coating layer Substances 0.000 claims description 339
- 238000005245 sintering Methods 0.000 claims description 107
- 229910044991 metal oxide Inorganic materials 0.000 claims description 102
- 150000004706 metal oxides Chemical class 0.000 claims description 102
- 229910052596 spinel Inorganic materials 0.000 claims description 66
- 239000011029 spinel Substances 0.000 claims description 66
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 231100000572 poisoning Toxicity 0.000 abstract description 68
- 230000000607 poisoning effect Effects 0.000 abstract description 68
- 230000003647 oxidation Effects 0.000 abstract description 31
- 238000007254 oxidation reaction Methods 0.000 abstract description 31
- 238000010494 dissociation reaction Methods 0.000 abstract 2
- 230000005593 dissociations Effects 0.000 abstract 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 238000009826 distribution Methods 0.000 description 145
- 238000012360 testing method Methods 0.000 description 93
- 238000000034 method Methods 0.000 description 73
- 238000011282 treatment Methods 0.000 description 72
- 238000004458 analytical method Methods 0.000 description 36
- 230000000694 effects Effects 0.000 description 36
- 230000001590 oxidative effect Effects 0.000 description 26
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 24
- 239000010410 layer Substances 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 24
- 238000007598 dipping method Methods 0.000 description 22
- 230000005012 migration Effects 0.000 description 18
- 238000013508 migration Methods 0.000 description 18
- 229910052751 metal Inorganic materials 0.000 description 17
- 239000002184 metal Substances 0.000 description 16
- 239000007800 oxidant agent Substances 0.000 description 16
- 238000010586 diagram Methods 0.000 description 15
- UPWOEMHINGJHOB-UHFFFAOYSA-N cobalt(III) oxide Inorganic materials O=[Co]O[Co]=O UPWOEMHINGJHOB-UHFFFAOYSA-N 0.000 description 14
- 239000003792 electrolyte Substances 0.000 description 14
- 238000011156 evaluation Methods 0.000 description 14
- 230000006866 deterioration Effects 0.000 description 13
- 239000000523 sample Substances 0.000 description 13
- 239000000463 material Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 230000015572 biosynthetic process Effects 0.000 description 9
- 238000006467 substitution reaction Methods 0.000 description 9
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 238000004544 sputter deposition Methods 0.000 description 8
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 7
- 230000000717 retained effect Effects 0.000 description 7
- 229910052712 strontium Inorganic materials 0.000 description 7
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 6
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 6
- IVMYJDGYRUAWML-UHFFFAOYSA-N cobalt(II) oxide Inorganic materials [Co]=O IVMYJDGYRUAWML-UHFFFAOYSA-N 0.000 description 6
- 238000010276 construction Methods 0.000 description 6
- 238000007772 electroless plating Methods 0.000 description 6
- 229910052746 lanthanum Inorganic materials 0.000 description 6
- 230000014759 maintenance of location Effects 0.000 description 6
- GNRSAWUEBMWBQH-UHFFFAOYSA-N nickel(II) oxide Inorganic materials [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- KZEVSDGEBAJOTK-UHFFFAOYSA-N 1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-2-[5-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]ethanone Chemical compound N1N=NC=2CN(CCC=21)C(CC=1OC(=NN=1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)=O KZEVSDGEBAJOTK-UHFFFAOYSA-N 0.000 description 5
- HMUNWXXNJPVALC-UHFFFAOYSA-N 1-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)N1CCN(CC1)C(CN1CC2=C(CC1)NN=N2)=O HMUNWXXNJPVALC-UHFFFAOYSA-N 0.000 description 5
- LDXJRKWFNNFDSA-UHFFFAOYSA-N 2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]ethanone Chemical compound C1CN(CC2=NNN=C21)CC(=O)N3CCN(CC3)C4=CN=C(N=C4)NCC5=CC(=CC=C5)OC(F)(F)F LDXJRKWFNNFDSA-UHFFFAOYSA-N 0.000 description 5
- SXAMGRAIZSSWIH-UHFFFAOYSA-N 2-[3-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,2,4-oxadiazol-5-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NOC(=N1)CC(=O)N1CC2=C(CC1)NN=N2 SXAMGRAIZSSWIH-UHFFFAOYSA-N 0.000 description 5
- 229910007564 Zn—Co Inorganic materials 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- YJLUBHOZZTYQIP-UHFFFAOYSA-N 2-[5-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]-1,3,4-oxadiazol-2-yl]-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethanone Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C1=NN=C(O1)CC(=O)N1CC2=C(CC1)NN=N2 YJLUBHOZZTYQIP-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- GEYXPJBPASPPLI-UHFFFAOYSA-N manganese(III) oxide Inorganic materials O=[Mn]O[Mn]=O GEYXPJBPASPPLI-UHFFFAOYSA-N 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 238000005191 phase separation Methods 0.000 description 3
- 229910000859 α-Fe Inorganic materials 0.000 description 3
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- 229910017060 Fe Cr Inorganic materials 0.000 description 2
- 229910002544 Fe-Cr Inorganic materials 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- AHKZTVQIVOEVFO-UHFFFAOYSA-N oxide(2-) Chemical compound [O-2] AHKZTVQIVOEVFO-UHFFFAOYSA-N 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 238000009877 rendering Methods 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910018487 Ni—Cr Inorganic materials 0.000 description 1
- 229910001308 Zinc ferrite Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 229910001566 austenite Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000011195 cermet Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- GNMQOUGYKPVJRR-UHFFFAOYSA-N nickel(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Ni+3].[Ni+3] GNMQOUGYKPVJRR-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010421 standard material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0258—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the configuration of channels, e.g. by the flow field of the reactant or coolant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0215—Glass; Ceramic materials
- H01M8/0217—Complex oxides, optionally doped, of the type AMO3, A being an alkaline earth metal or rare earth metal and M being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0204—Non-porous and characterised by the material
- H01M8/0223—Composites
- H01M8/0228—Composites in the form of layered or coated products
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/0273—Sealing or supporting means around electrodes, matrices or membranes with sealing or supporting means in the form of a frame
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1231—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0297—Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- Materials Engineering (AREA)
- Ceramic Engineering (AREA)
- Fuel Cell (AREA)
- Compounds Of Iron (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Inert Electrodes (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2008114315 | 2008-04-24 | ||
| JP2008-114315 | 2008-04-24 | ||
| JP2008195189 | 2008-07-29 | ||
| JP2008-195189 | 2008-07-29 | ||
| JP2008-267607 | 2008-10-16 | ||
| JP2008267607 | 2008-10-16 | ||
| PCT/JP2009/058079 WO2009131180A1 (ja) | 2008-04-24 | 2009-04-23 | 固体酸化物形燃料電池用セル |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2722549A1 CA2722549A1 (en) | 2009-10-29 |
| CA2722549C true CA2722549C (en) | 2016-10-04 |
Family
ID=41216909
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2722549A Active CA2722549C (en) | 2008-04-24 | 2009-04-23 | Cell for solid oxide fuel cell |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8865373B2 (da) |
| EP (1) | EP2276094B1 (da) |
| JP (1) | JP4659136B2 (da) |
| KR (1) | KR101553270B1 (da) |
| CA (1) | CA2722549C (da) |
| DK (1) | DK2276094T3 (da) |
| WO (1) | WO2009131180A1 (da) |
Families Citing this family (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8163434B2 (en) * | 2008-08-28 | 2012-04-24 | General Electric Company | Barrier coatings for interconnects; related devices, and methods of forming |
| JP4866955B2 (ja) * | 2009-11-09 | 2012-02-01 | 日本碍子株式会社 | 接合体 |
| JP5451469B2 (ja) * | 2010-03-15 | 2014-03-26 | 大阪瓦斯株式会社 | 燃料電池用インターコネクタの製造方法 |
| CN102108552B (zh) * | 2010-11-15 | 2013-05-01 | 复旦大学 | 一种NiCo2O4纳米晶体薄膜的制备方法及其在制备半导体光电器件的应用 |
| JP5572146B2 (ja) * | 2011-03-22 | 2014-08-13 | 大阪瓦斯株式会社 | 保護膜形成方法、セル接続部材および固体酸化物形燃料電池用セル |
| EP2693545B1 (en) | 2011-03-30 | 2015-12-09 | Murata Manufacturing Co., Ltd. | Fuel cell |
| WO2012132893A1 (ja) * | 2011-03-30 | 2012-10-04 | 株式会社村田製作所 | 燃料電池 |
| JP5904880B2 (ja) * | 2011-06-03 | 2016-04-20 | 大阪瓦斯株式会社 | 固体酸化物型燃料電池および固体酸化物型燃料電池の製造方法 |
| JP5726023B2 (ja) * | 2011-08-31 | 2015-05-27 | 京セラ株式会社 | 固体酸化物形燃料電池セル、セルスタック装置、燃料電池モジュールおよび燃料電池装置 |
| US9070932B2 (en) | 2011-10-11 | 2015-06-30 | Massachusetts Institute Of Technology | Carbon electrodes |
| JP2013118178A (ja) * | 2011-10-31 | 2013-06-13 | Osaka Gas Co Ltd | 固体酸化物形燃料電池 |
| JP2013118177A (ja) * | 2011-10-31 | 2013-06-13 | Osaka Gas Co Ltd | 固体酸化物形燃料電池 |
| WO2013090601A2 (en) | 2011-12-16 | 2013-06-20 | Massachusetts Institute Of Technology | Compact nanoparticles for biological applications |
| JP5832405B2 (ja) * | 2012-09-24 | 2015-12-16 | 大阪瓦斯株式会社 | 保護膜形成方法、セル接続部材の製造方法および固体酸化物型燃料電池用セルの製造方法 |
| JP5943821B2 (ja) * | 2012-12-05 | 2016-07-05 | 大阪瓦斯株式会社 | セル間接続部材の製造方法および固体酸化物型燃料電池の製造方法 |
| JP2014199801A (ja) | 2012-12-28 | 2014-10-23 | 株式会社半導体エネルギー研究所 | 非水系二次電池およびセパレータ |
| CN105359321A (zh) * | 2013-03-15 | 2016-02-24 | Lg燃料电池系统股份有限公司 | 用于捕获铬而配置的燃料电池系统 |
| CN103184451B (zh) * | 2013-03-28 | 2015-08-05 | 常州大学 | 一种抗氧化导电尖晶石涂层的制备工艺 |
| JP5522870B1 (ja) | 2013-04-12 | 2014-06-18 | 日本碍子株式会社 | 燃料電池セル |
| KR101392684B1 (ko) * | 2013-05-13 | 2014-05-27 | 한국과학기술원 | 인터코넥트 코팅 기반 금속지지체 고체산화물 연료전지 제작방법 및 이에 의하여 제조된 고체산화물 연료전지 |
| US9559384B2 (en) | 2013-05-15 | 2017-01-31 | Semiconductor Energy Laboratory Co., Ltd. | Secondary battery and method for restoring capacity of secondary battery |
| CN103579638B (zh) * | 2013-11-11 | 2016-04-27 | 上海中聚佳华电池科技有限公司 | 锂空气电池的空气电极催化剂及其制备方法 |
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| JPS57202089A (en) * | 1981-06-05 | 1982-12-10 | Matsushita Electric Ind Co Ltd | Sheathed heater |
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| CN1397016A (zh) * | 2000-01-28 | 2003-02-12 | 催化电极有限公司 | 一氧化碳检测器 |
| JP2004259643A (ja) | 2003-02-27 | 2004-09-16 | Sanyo Electric Co Ltd | 固体酸化物燃料電池 |
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| JP2006032183A (ja) * | 2004-07-20 | 2006-02-02 | Nissan Motor Co Ltd | 電気伝導性材料及びこれを用いた固体酸化物形燃料電池。 |
| DE102005015755A1 (de) | 2005-04-06 | 2006-10-12 | Forschungszentrum Jülich GmbH | Verfahren zur Herstellung einer Chromverdampfungsschutzschicht für chromoxidbildende Metallsubstrate |
| JP2007016297A (ja) * | 2005-07-11 | 2007-01-25 | Hitachi Metals Ltd | 固体酸化物型燃料電池セパレータ用鋼 |
| US20070122304A1 (en) | 2005-11-28 | 2007-05-31 | Ramasesha Sheela K | Alloys for intermediate temperature applications, methods for maufacturing thereof and articles comprising the same |
| EP1976045B1 (en) | 2006-01-17 | 2016-11-16 | Osaka Gas Company Limited | Cell for solid oxide fuel cell and process for producing the same |
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| EP2276094A1 (en) | 2011-01-19 |
| US20110287341A1 (en) | 2011-11-24 |
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| KR20110020781A (ko) | 2011-03-03 |
| JP4659136B2 (ja) | 2011-03-30 |
| CA2722549A1 (en) | 2009-10-29 |
| EP2276094B1 (en) | 2014-04-16 |
| DK2276094T3 (da) | 2014-05-12 |
| EP2276094A4 (en) | 2012-04-11 |
| WO2009131180A1 (ja) | 2009-10-29 |
| KR101553270B1 (ko) | 2015-09-15 |
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