CA2403755C - Polymer mixture comprising an amorphous polyolefin containing cycloaliphatic olefins - Google Patents
Polymer mixture comprising an amorphous polyolefin containing cycloaliphatic olefins Download PDFInfo
- Publication number
- CA2403755C CA2403755C CA2403755A CA2403755A CA2403755C CA 2403755 C CA2403755 C CA 2403755C CA 2403755 A CA2403755 A CA 2403755A CA 2403755 A CA2403755 A CA 2403755A CA 2403755 C CA2403755 C CA 2403755C
- Authority
- CA
- Canada
- Prior art keywords
- polymer mixture
- cycloolefin copolymer
- polymer
- cycloolefin
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920002959 polymer blend Polymers 0.000 title claims abstract description 33
- 229920000098 polyolefin Polymers 0.000 title claims abstract description 15
- 150000001336 alkenes Chemical class 0.000 title claims description 6
- 239000000203 mixture Substances 0.000 claims abstract description 19
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims abstract description 18
- 239000004033 plastic Substances 0.000 claims abstract description 6
- 229920003023 plastic Polymers 0.000 claims abstract description 6
- 238000001125 extrusion Methods 0.000 claims abstract description 5
- 238000001746 injection moulding Methods 0.000 claims abstract description 4
- 238000010102 injection blow moulding Methods 0.000 claims abstract description 3
- 229920001577 copolymer Polymers 0.000 claims description 39
- 230000009477 glass transition Effects 0.000 claims description 27
- -1 acyclic olefins Chemical class 0.000 claims description 26
- 229920000642 polymer Polymers 0.000 claims description 15
- 229920001897 terpolymer Polymers 0.000 claims description 11
- 239000005977 Ethylene Substances 0.000 claims description 10
- 229920001038 ethylene copolymer Polymers 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 6
- SFFFIHNOEGSAIH-UHFFFAOYSA-N bicyclo[2.2.1]hept-2-ene;ethene Chemical group C=C.C1C2CCC1C=C2 SFFFIHNOEGSAIH-UHFFFAOYSA-N 0.000 claims description 5
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 4
- 229920006395 saturated elastomer Polymers 0.000 claims description 4
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 claims description 3
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 claims description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 125000004122 cyclic group Chemical group 0.000 claims description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 150000003254 radicals Chemical class 0.000 claims description 2
- XBFJAVXCNXDMBH-UHFFFAOYSA-N tetracyclo[6.2.1.1(3,6).0(2,7)]dodec-4-ene Chemical compound C1C(C23)C=CC1C3C1CC2CC1 XBFJAVXCNXDMBH-UHFFFAOYSA-N 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims 2
- VPGLGRNSAYHXPY-UHFFFAOYSA-L zirconium(2+);dichloride Chemical compound Cl[Zr]Cl VPGLGRNSAYHXPY-UHFFFAOYSA-L 0.000 description 29
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 9
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 7
- 239000003054 catalyst Substances 0.000 description 6
- WKBPZYKAUNRMKP-UHFFFAOYSA-N 1-[2-(2,4-dichlorophenyl)pentyl]1,2,4-triazole Chemical compound C=1C=C(Cl)C=C(Cl)C=1C(CCC)CN1C=NC=N1 WKBPZYKAUNRMKP-UHFFFAOYSA-N 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- 150000003623 transition metal compounds Chemical class 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 229920002633 Kraton (polymer) Polymers 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- MPJLHVOQWLKMRN-UHFFFAOYSA-L C[SiH](C)[Zr](Cl)(Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 Chemical compound C[SiH](C)[Zr](Cl)(Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 MPJLHVOQWLKMRN-UHFFFAOYSA-L 0.000 description 1
- SVHPGKHHBXQFLQ-UHFFFAOYSA-L Cl[Zr](Cl)(C1C=CC=C1)(C1c2ccccc2-c2ccccc12)=C(c1ccccc1)c1ccccc1 Chemical compound Cl[Zr](Cl)(C1C=CC=C1)(C1c2ccccc2-c2ccccc12)=C(c1ccccc1)c1ccccc1 SVHPGKHHBXQFLQ-UHFFFAOYSA-L 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- HCYNNFRJVSZIHW-UHFFFAOYSA-N O=C(C1=CC=CC=C1)[Zr](C1C=CC=C1)(C1C2=CC=CC=C2C=C1)C(C1=CC=CC=C1)=O.Cl.Cl Chemical compound O=C(C1=CC=CC=C1)[Zr](C1C=CC=C1)(C1C2=CC=CC=C2C=C1)C(C1=CC=CC=C1)=O.Cl.Cl HCYNNFRJVSZIHW-UHFFFAOYSA-N 0.000 description 1
- 241000765083 Ondina Species 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- LBKBUQUIRJQWLH-UHFFFAOYSA-L [Cl-].[Cl-].C1(=CC=CC=C1)CC=[Zr+2](C1C=CC=C1)C1C2=CC=CC=C2C=2C=CC=CC1=2 Chemical compound [Cl-].[Cl-].C1(=CC=CC=C1)CC=[Zr+2](C1C=CC=C1)C1C2=CC=CC=C2C=2C=CC=CC1=2 LBKBUQUIRJQWLH-UHFFFAOYSA-L 0.000 description 1
- YCIQPHTUFUTPAN-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](C1C2=CC=CC=C2C=C1)[SiH2]CC1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](C1C2=CC=CC=C2C=C1)[SiH2]CC1=CC=CC=C1 YCIQPHTUFUTPAN-UHFFFAOYSA-L 0.000 description 1
- BWUKAWLFMALYIV-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Hf+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 BWUKAWLFMALYIV-UHFFFAOYSA-L 0.000 description 1
- NWBSMOHZFZYBLB-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](=C(C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](=C(C)C)C1C2=CC=CC=C2C=C1 NWBSMOHZFZYBLB-UHFFFAOYSA-L 0.000 description 1
- XVMVAJPMNDQYLF-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH2]C=CC1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH2]C=CC1=CC=CC=C1 XVMVAJPMNDQYLF-UHFFFAOYSA-L 0.000 description 1
- IIYQHRJOJALMSW-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH2]CC1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH2]CC1=CC=CC=C1 IIYQHRJOJALMSW-UHFFFAOYSA-L 0.000 description 1
- DHOIFLAXQKMNNF-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2](C1C2=CC=CC=C2C=C1)[SiH](C=1C=CC=CC=1)C1=CC=CC=C1 DHOIFLAXQKMNNF-UHFFFAOYSA-L 0.000 description 1
- DPXFROCZZRXAGW-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([GeH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([GeH](C)C)C1C2=CC=CC=C2C=C1 DPXFROCZZRXAGW-UHFFFAOYSA-L 0.000 description 1
- FJMJPZLXUXRLLD-UHFFFAOYSA-L [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 Chemical compound [Cl-].[Cl-].C1=CC2=CC=CC=C2C1[Zr+2]([SiH](C)C)C1C2=CC=CC=C2C=C1 FJMJPZLXUXRLLD-UHFFFAOYSA-L 0.000 description 1
- DIDTVPPGXZOJGG-UHFFFAOYSA-L [Cl-].[Cl-].C1C[SiH](C1)[Zr++](C1C=Cc2ccccc12)C1C=Cc2ccccc12 Chemical compound [Cl-].[Cl-].C1C[SiH](C1)[Zr++](C1C=Cc2ccccc12)C1C=Cc2ccccc12 DIDTVPPGXZOJGG-UHFFFAOYSA-L 0.000 description 1
- OKPFRHMGNFRBIW-UHFFFAOYSA-L [SiH](c1ccccc1)c1ccccc1.Cl[Zr](Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 Chemical compound [SiH](c1ccccc1)c1ccccc1.Cl[Zr](Cl)(C1C=CC=C1)C1c2ccccc2-c2ccccc12 OKPFRHMGNFRBIW-UHFFFAOYSA-L 0.000 description 1
- 150000005674 acyclic monoalkenes Chemical class 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical class OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 125000003368 amide group Chemical group 0.000 description 1
- 229920006125 amorphous polymer Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000004600 biostabiliser Substances 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 150000001925 cycloalkenes Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- IVTQDRJBWSBJQM-UHFFFAOYSA-L dichlorozirconium;indene Chemical compound C1=CC2=CC=CC=C2C1[Zr](Cl)(Cl)C1C2=CC=CC=C2C=C1 IVTQDRJBWSBJQM-UHFFFAOYSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000006078 metal deactivator Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920005787 opaque polymer Polymers 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 125000003808 silyl group Chemical group [H][Si]([H])([H])[*] 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003608 titanium Chemical class 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
- C08G61/02—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes
- C08G61/04—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms
- C08G61/06—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds
- C08G61/08—Macromolecular compounds containing only carbon atoms in the main chain of the macromolecule, e.g. polyxylylenes only aliphatic carbon atoms prepared by ring-opening of carbocyclic compounds of carbocyclic compounds containing one or more carbon-to-carbon double bonds in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2365/00—Characterised by the use of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Shaping By String And By Release Of Stress In Plastics And The Like (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10009646A DE10009646A1 (de) | 2000-03-01 | 2000-03-01 | Neues Polymergemisch |
| DE10009646.8 | 2000-03-01 | ||
| PCT/EP2001/002012 WO2001064786A1 (de) | 2000-03-01 | 2001-02-22 | Polymergemisch enthaltend ein amorphes polyolefin enthaltend cycloaliphatische olefinen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2403755A1 CA2403755A1 (en) | 2001-09-07 |
| CA2403755C true CA2403755C (en) | 2011-08-09 |
Family
ID=7632904
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2403755A Expired - Lifetime CA2403755C (en) | 2000-03-01 | 2001-02-22 | Polymer mixture comprising an amorphous polyolefin containing cycloaliphatic olefins |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US6767966B2 (https=) |
| EP (1) | EP1268661B1 (https=) |
| JP (1) | JP2003531923A (https=) |
| AT (1) | ATE438687T1 (https=) |
| CA (1) | CA2403755C (https=) |
| DE (2) | DE10009646A1 (https=) |
| ES (1) | ES2331462T3 (https=) |
| WO (1) | WO2001064786A1 (https=) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE20104426U1 (de) * | 2001-03-14 | 2001-05-23 | Trioliet Mullos B.V., Oldenzaal | Silage-Schneidzange |
| GB2386122A (en) * | 2002-03-06 | 2003-09-10 | Reckitt Benckiser Nv | Improvements in or relating to packaging |
| DE60333181D1 (de) * | 2002-04-15 | 2010-08-12 | Dsm Ip Assets Bv | Ür |
| AU2003263983B2 (en) * | 2002-08-05 | 2008-05-08 | Cryovac, Inc. | High free shrink, high modulus, low shrink tension film with elastic recovery |
| DE10236502B4 (de) * | 2002-08-09 | 2004-10-14 | Nordenia Deutschland Gronau Gmbh | Siegelfähige Folie für Aufreißverpackungen |
| DE10242730A1 (de) * | 2002-09-13 | 2004-03-25 | Ticona Gmbh | Thermoformbare Folie mit hoher Wärmeformbeständigkeit und Wasserdampfbarriere |
| DE102004014585A1 (de) * | 2004-03-23 | 2005-10-13 | Basf Ag | Blends aus Styrol-Butadien-Blockcopolymeren |
| US7258930B2 (en) * | 2004-04-28 | 2007-08-21 | Cryovac, Inc. | Oxygen scavenging film with cyclic olefin copolymer |
| JP2006083266A (ja) * | 2004-09-15 | 2006-03-30 | Teijin Ltd | 光学用フィルム |
| DE102004051102A1 (de) * | 2004-10-19 | 2006-04-27 | Basf Ag | Verfahren zur Herstellung von Polyurethan-Hartschaumstoffen |
| US20070141366A1 (en) * | 2005-12-21 | 2007-06-21 | Janet Rivett | Multilayer film with hot tack property |
| US7501219B2 (en) * | 2005-12-23 | 2009-03-10 | Eastman Kodak Company | Thermal receiver |
| WO2008018951A1 (en) * | 2006-08-04 | 2008-02-14 | Exxonmobil Chemical Patents Inc. | Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers, and fillers |
| US20080033112A1 (en) * | 2006-08-04 | 2008-02-07 | Squire Kevin R | Polymer compositions comprising cyclic olefin copolymers and polyolefin modifiers |
| US8148472B1 (en) | 2006-08-04 | 2012-04-03 | Exxonmobil Research And Engineering Company | Polymer compositions comprising cyclic olefin polymers, polyolefin modifiers and non-functionalized plasticizers |
| US20080070142A1 (en) * | 2006-09-20 | 2008-03-20 | Fuji Xerox Co., Ltd. | Toner for electrostatic charge development, and developer for electrostatic charge development using the same, developer cartridge for electrostatic charge development and image forming apparatus |
| WO2008050525A1 (en) * | 2006-09-29 | 2008-05-02 | Konica Minolta Opto, Inc. | Retardation film |
| US8519056B2 (en) * | 2007-06-01 | 2013-08-27 | Exxonmobil Chemical Patents Inc. | Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins |
| EP2253669B1 (en) * | 2009-05-20 | 2016-02-24 | Teknologian tutkimuskeskus VTT Oy | PPO composition as bonding base for electronic components, and method |
| EP2562821A1 (en) * | 2010-04-22 | 2013-02-27 | Daicel Corporation | Optical semiconductor protective material, precursor for same, and method for manufacturing optical semiconductor protective material |
| US9868313B2 (en) | 2012-12-28 | 2018-01-16 | Avery Dennison Corporation | Topcoat compositions, coated substrates, and related methods |
| CA2917301C (en) * | 2013-07-02 | 2021-12-14 | Hoang T. Pham | Heat activated shrink films |
| DE23202633T1 (de) | 2015-12-29 | 2025-05-08 | Adapa Flexibles Denmark Slagelse A/S | Verfahren zur bereitstellung eines extrem chemikalienbeständigen films, film und daraus erhältliches laminat |
| DK3513965T3 (da) | 2018-08-08 | 2022-07-25 | Danapak Flexibles As | Forbedrede film og laminater til anvendelse i pakning af reaktive forbindelser |
| CN114867602A (zh) | 2020-01-06 | 2022-08-05 | 因夫聚丙烯有限责任公司 | 包括阻隔层的聚合物基底 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE237070C (https=) | ||||
| DE109224C (https=) | ||||
| US4614778A (en) | 1984-02-03 | 1986-09-30 | Hirokazu Kajiura | Random copolymer |
| US5003019A (en) * | 1987-03-02 | 1991-03-26 | Mitsui Petrochemical Industries, Ltd. | Cyclo-olefinic random copolymer, olefinic random copolymer, and process for producing cyclo-olefinic random copolymers |
| EP0317262B1 (en) | 1987-11-17 | 1996-01-31 | Japan Synthetic Rubber Co., Ltd. | Transparent resin material |
| US6027677A (en) * | 1988-08-08 | 2000-02-22 | Chronopol, Inc. | Films containing poly(hydroxy acid)s |
| DE3922546A1 (de) | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
| JPH03106962A (ja) | 1989-09-20 | 1991-05-07 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂組成物 |
| JPH0420553A (ja) * | 1990-05-15 | 1992-01-24 | Mitsui Petrochem Ind Ltd | 環状オレフィン系樹脂組成物およびその用途 |
| US5371158A (en) * | 1990-07-05 | 1994-12-06 | Hoechst Aktiengesellschaft | Bulk polymerization using specific metallocene catalysts for the preparation of cycloolefin polymers |
| TW227005B (https=) * | 1990-11-14 | 1994-07-21 | Hoechst Ag | |
| ATE223440T1 (de) * | 1991-03-09 | 2002-09-15 | Basell Polyolefine Gmbh | Metallocen und katalysator |
| JPH0551512A (ja) | 1991-08-23 | 1993-03-02 | Mitsui Petrochem Ind Ltd | ポリオレフイン系樹脂組成物 |
| JPH06228380A (ja) * | 1993-01-29 | 1994-08-16 | Mitsui Petrochem Ind Ltd | 環状オレフィン系重合体組成物 |
| BR9408143A (pt) * | 1993-11-26 | 1997-08-12 | Eastman Chem Co | Filme termo-contrátil polímero processo para a preparação de filme e concentrado de poliéster/plastificante que é usado para preparar o filme |
| DE4425408A1 (de) * | 1994-07-13 | 1996-01-18 | Hoechst Ag | Cycloolefinpolymere |
| DE4425409A1 (de) * | 1994-07-13 | 1996-01-18 | Hoechst Ag | Cycloolefinpolymere |
| EP0744285B1 (en) | 1995-05-24 | 1999-12-15 | Cryovac, Inc. | Multilayer oxygen barrier packaging film |
| US6294616B1 (en) * | 1995-05-25 | 2001-09-25 | B. F. Goodrich Company | Blends and alloys of polycyclic polymers |
| JP3577387B2 (ja) * | 1996-04-11 | 2004-10-13 | 三菱樹脂株式会社 | 熱収縮性環状オレフイン系重合体チユーブ |
| US5824398A (en) * | 1996-06-24 | 1998-10-20 | Eastman Chemical Company | Plasticized polyester for shrink film applications |
| CA2207673A1 (en) | 1996-06-25 | 1997-12-25 | Silvano Iaboni | Heat shrinkable packaging film with improved hot slip properties |
| DE19633641A1 (de) | 1996-08-21 | 1998-02-26 | Hoechst Ag | Elastomere Cycloolefincopolymere |
| JP4437232B2 (ja) * | 1997-06-13 | 2010-03-24 | ティコナ ゲゼルシャフト ミット ベシュレンクテル ハフツング | エレクトレット |
| US6232407B1 (en) | 1998-06-10 | 2001-05-15 | Teijin Limited | Process for producing hydrogenated α-olefin-dicyclopentadiene copolymer, method for molding the same and optical material |
| EP0965614B1 (de) * | 1998-06-16 | 2006-03-15 | Ticona GmbH | Schlagzähe Cycloolefin-Copolymer-Legierung |
| JP2000017088A (ja) * | 1998-07-01 | 2000-01-18 | Mitsui Chemicals Inc | 易打ち抜き開封性包装材料 |
| JP3936489B2 (ja) * | 1999-04-16 | 2007-06-27 | 積水化学工業株式会社 | ノルボルネン系位相差補償フィルム |
-
2000
- 2000-03-01 DE DE10009646A patent/DE10009646A1/de not_active Withdrawn
-
2001
- 2001-02-22 ES ES01915287T patent/ES2331462T3/es not_active Expired - Lifetime
- 2001-02-22 CA CA2403755A patent/CA2403755C/en not_active Expired - Lifetime
- 2001-02-22 WO PCT/EP2001/002012 patent/WO2001064786A1/de not_active Ceased
- 2001-02-22 AT AT01915287T patent/ATE438687T1/de not_active IP Right Cessation
- 2001-02-22 JP JP2001564277A patent/JP2003531923A/ja active Pending
- 2001-02-22 DE DE50115023T patent/DE50115023D1/de not_active Expired - Lifetime
- 2001-02-22 EP EP01915287A patent/EP1268661B1/de not_active Expired - Lifetime
- 2001-02-22 US US10/220,377 patent/US6767966B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| WO2001064786A1 (de) | 2001-09-07 |
| EP1268661A1 (de) | 2003-01-02 |
| US20030166781A1 (en) | 2003-09-04 |
| ATE438687T1 (de) | 2009-08-15 |
| JP2003531923A (ja) | 2003-10-28 |
| CA2403755A1 (en) | 2001-09-07 |
| EP1268661B1 (de) | 2009-08-05 |
| ES2331462T3 (es) | 2010-01-05 |
| DE50115023D1 (de) | 2009-09-17 |
| US6767966B2 (en) | 2004-07-27 |
| DE10009646A1 (de) | 2001-09-13 |
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