CA2362044C - Fire resistant thermoplastic silicone vulcanizates - Google Patents
Fire resistant thermoplastic silicone vulcanizates Download PDFInfo
- Publication number
- CA2362044C CA2362044C CA002362044A CA2362044A CA2362044C CA 2362044 C CA2362044 C CA 2362044C CA 002362044 A CA002362044 A CA 002362044A CA 2362044 A CA2362044 A CA 2362044A CA 2362044 C CA2362044 C CA 2362044C
- Authority
- CA
- Canada
- Prior art keywords
- component
- weight
- polyorganosiloxane
- composition
- thermoplastic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001296 polysiloxane Polymers 0.000 title claims description 38
- 229920001169 thermoplastic Polymers 0.000 title claims description 33
- 239000004416 thermosoftening plastic Substances 0.000 title claims description 33
- 230000009970 fire resistant effect Effects 0.000 title description 2
- 239000000203 mixture Substances 0.000 claims abstract description 65
- 239000003054 catalyst Substances 0.000 claims abstract description 56
- 239000000378 calcium silicate Substances 0.000 claims abstract description 35
- 229910052918 calcium silicate Inorganic materials 0.000 claims abstract description 35
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 claims abstract description 35
- 229920005989 resin Polymers 0.000 claims abstract description 23
- 239000011347 resin Substances 0.000 claims abstract description 23
- 238000002156 mixing Methods 0.000 claims abstract description 21
- 150000003377 silicon compounds Chemical class 0.000 claims abstract description 14
- 229920002397 thermoplastic olefin Polymers 0.000 claims abstract description 13
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 9
- 238000006459 hydrosilylation reaction Methods 0.000 claims abstract description 9
- -1 polypropylene Polymers 0.000 claims description 37
- 238000000034 method Methods 0.000 claims description 29
- 239000004743 Polypropylene Substances 0.000 claims description 19
- 229920001155 polypropylene Polymers 0.000 claims description 19
- 230000005540 biological transmission Effects 0.000 claims description 11
- 229910052882 wollastonite Inorganic materials 0.000 claims description 11
- 239000010456 wollastonite Substances 0.000 claims description 10
- 238000000576 coating method Methods 0.000 claims description 9
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 8
- 229920000573 polyethylene Polymers 0.000 claims description 8
- 239000012763 reinforcing filler Substances 0.000 claims description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229920006342 thermoplastic vulcanizate Polymers 0.000 abstract description 12
- 230000004907 flux Effects 0.000 abstract description 11
- 229920000098 polyolefin Polymers 0.000 abstract description 10
- 239000000779 smoke Substances 0.000 abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 46
- 239000000463 material Substances 0.000 description 38
- 239000004971 Cross linker Substances 0.000 description 37
- 229920001577 copolymer Polymers 0.000 description 31
- 235000012241 calcium silicate Nutrition 0.000 description 27
- 238000012360 testing method Methods 0.000 description 24
- 229920000092 linear low density polyethylene Polymers 0.000 description 23
- 239000004707 linear low-density polyethylene Substances 0.000 description 23
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 22
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 22
- 239000004205 dimethyl polysiloxane Substances 0.000 description 20
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 15
- 229910052791 calcium Inorganic materials 0.000 description 15
- 239000011575 calcium Substances 0.000 description 15
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 15
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 15
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 239000000377 silicon dioxide Substances 0.000 description 15
- 239000000654 additive Substances 0.000 description 13
- 229920002725 thermoplastic elastomer Polymers 0.000 description 13
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 13
- 229920001971 elastomer Polymers 0.000 description 12
- 238000009472 formulation Methods 0.000 description 12
- 239000000945 filler Substances 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- 239000005977 Ethylene Substances 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 239000003063 flame retardant Substances 0.000 description 7
- 229920001519 homopolymer Polymers 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 229910052697 platinum Inorganic materials 0.000 description 7
- 230000008569 process Effects 0.000 description 7
- 229920002554 vinyl polymer Polymers 0.000 description 7
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 6
- 150000001336 alkenes Chemical class 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 6
- 238000009413 insulation Methods 0.000 description 6
- 229920000642 polymer Polymers 0.000 description 6
- 239000005060 rubber Substances 0.000 description 6
- 229920005992 thermoplastic resin Polymers 0.000 description 6
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 229920002313 fluoropolymer Polymers 0.000 description 5
- 239000004811 fluoropolymer Substances 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- 229910052710 silicon Inorganic materials 0.000 description 5
- 239000010703 silicon Substances 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- 239000004215 Carbon black (E152) Substances 0.000 description 4
- 229920002943 EPDM rubber Polymers 0.000 description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 4
- 125000004122 cyclic group Chemical group 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000000155 melt Substances 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 125000000962 organic group Chemical group 0.000 description 4
- 125000005375 organosiloxane group Chemical group 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 230000003014 reinforcing effect Effects 0.000 description 4
- 238000013341 scale-up Methods 0.000 description 4
- 229920005573 silicon-containing polymer Polymers 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000015556 catabolic process Effects 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000006731 degradation reaction Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 150000008282 halocarbons Chemical group 0.000 description 3
- 150000004678 hydrides Chemical class 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 150000003057 platinum Chemical class 0.000 description 3
- CLSUSRZJUQMOHH-UHFFFAOYSA-L platinum dichloride Chemical compound Cl[Pt]Cl CLSUSRZJUQMOHH-UHFFFAOYSA-L 0.000 description 3
- 229920005672 polyolefin resin Polymers 0.000 description 3
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 3
- 229920002050 silicone resin Polymers 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004716 Ethylene/acrylic acid copolymer Substances 0.000 description 2
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 208000014117 bile duct papillary neoplasm Diseases 0.000 description 2
- FSIJKGMIQTVTNP-UHFFFAOYSA-N bis(ethenyl)-methyl-trimethylsilyloxysilane Chemical compound C[Si](C)(C)O[Si](C)(C=C)C=C FSIJKGMIQTVTNP-UHFFFAOYSA-N 0.000 description 2
- 229920001400 block copolymer Polymers 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 2
- QHZOMAXECYYXGP-UHFFFAOYSA-N ethene;prop-2-enoic acid Chemical compound C=C.OC(=O)C=C QHZOMAXECYYXGP-UHFFFAOYSA-N 0.000 description 2
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 230000009477 glass transition Effects 0.000 description 2
- 125000006038 hexenyl group Chemical group 0.000 description 2
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 229910052909 inorganic silicate Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 239000004800 polyvinyl chloride Substances 0.000 description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 2
- 125000005372 silanol group Chemical group 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 2
- 125000006850 spacer group Chemical group 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- 125000000094 2-phenylethyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241001391944 Commicarpus scandens Species 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical group F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
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- 239000004965 Silica aerogel Substances 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 231100000230 acceptable toxicity Toxicity 0.000 description 1
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- RREGISFBPQOLTM-UHFFFAOYSA-N alumane;trihydrate Chemical compound O.O.O.[AlH3] RREGISFBPQOLTM-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229940058344 antitrematodals organophosphorous compound Drugs 0.000 description 1
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- 125000003710 aryl alkyl group Chemical group 0.000 description 1
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- 230000008033 biological extinction Effects 0.000 description 1
- 125000004369 butenyl group Chemical group C(=CCC)* 0.000 description 1
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- 239000000919 ceramic Substances 0.000 description 1
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- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
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- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 125000000582 cycloheptyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000003493 decenyl group Chemical group [H]C([*])=C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- IJKVHSBPTUYDLN-UHFFFAOYSA-N dihydroxy(oxo)silane Chemical compound O[Si](O)=O IJKVHSBPTUYDLN-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
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- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
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- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
- 125000002255 pentenyl group Chemical group C(=CCCC)* 0.000 description 1
- 125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
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- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052990 silicon hydride Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- FBEIPJNQGITEBL-UHFFFAOYSA-J tetrachloroplatinum Chemical compound Cl[Pt](Cl)(Cl)Cl FBEIPJNQGITEBL-UHFFFAOYSA-J 0.000 description 1
- 239000012815 thermoplastic material Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 125000000725 trifluoropropyl group Chemical group [H]C([H])(*)C([H])([H])C(F)(F)F 0.000 description 1
- 150000004684 trihydrates Chemical class 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/20—Polysiloxanes containing silicon bound to unsaturated aliphatic groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Communication Cables (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Inorganic Insulating Materials (AREA)
- Organic Insulating Materials (AREA)
- Insulated Conductors (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US24303999A | 1999-02-02 | 1999-02-02 | |
| US09/243,039 | 1999-02-02 | ||
| PCT/US2000/002417 WO2000046291A1 (en) | 1999-02-02 | 2000-01-31 | Fire resistant thermoplastic silicone vulcanizates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2362044A1 CA2362044A1 (en) | 2000-08-10 |
| CA2362044C true CA2362044C (en) | 2008-09-23 |
Family
ID=22917123
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002362044A Expired - Fee Related CA2362044C (en) | 1999-02-02 | 2000-01-31 | Fire resistant thermoplastic silicone vulcanizates |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6433049B1 (enExample) |
| EP (1) | EP1153079B1 (enExample) |
| JP (1) | JP4717218B2 (enExample) |
| KR (1) | KR20010101947A (enExample) |
| CN (1) | CN1134498C (enExample) |
| AT (1) | ATE274557T1 (enExample) |
| AU (1) | AU3218900A (enExample) |
| CA (1) | CA2362044C (enExample) |
| DE (1) | DE60013252T2 (enExample) |
| MX (1) | MXPA01007766A (enExample) |
| TW (1) | TW526230B (enExample) |
| WO (1) | WO2000046291A1 (enExample) |
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| TW538482B (en) * | 1999-04-26 | 2003-06-21 | Shinetsu Chemical Co | Semiconductor encapsulating epoxy resin composition and semiconductor device |
| JP4987184B2 (ja) * | 2000-11-10 | 2012-07-25 | 東レ・ダウコーニング株式会社 | ポリオレフィン系樹脂組成物およびその製造方法 |
| US6479580B1 (en) * | 2001-04-30 | 2002-11-12 | Dow Corning Corporation | Polyolefin thermoplastic silicone elastomers employing radical cure |
| JP4012807B2 (ja) * | 2002-03-19 | 2007-11-21 | 株式会社フジクラ | 難燃性光ファイバコードおよび製造方法 |
| US7104822B2 (en) * | 2002-05-16 | 2006-09-12 | Homac Mfg. Company | Electrical connector including silicone elastomeric material and associated methods |
| US6830475B2 (en) * | 2002-05-16 | 2004-12-14 | Homac Mfg. Company | Electrical connector with visual seating indicator and associated methods |
| US7104823B2 (en) * | 2002-05-16 | 2006-09-12 | Homac Mfg. Company | Enhanced separable connector with thermoplastic member and related methods |
| US6796820B2 (en) * | 2002-05-16 | 2004-09-28 | Homac Mfg. Company | Electrical connector including cold shrink core and thermoplastic elastomer material and associated methods |
| US6811418B2 (en) * | 2002-05-16 | 2004-11-02 | Homac Mfg. Company | Electrical connector with anti-flashover configuration and associated methods |
| US6790063B2 (en) | 2002-05-16 | 2004-09-14 | Homac Mfg. Company | Electrical connector including split shield monitor point and associated methods |
| US6905356B2 (en) * | 2002-05-16 | 2005-06-14 | Homac Mfg. Company | Electrical connector including thermoplastic elastomer material and associated methods |
| AU2002952136A0 (en) * | 2002-10-17 | 2002-10-31 | Polymers Australia Pty Limited | "Modified Polymeric Compositions" |
| CN1298809C (zh) | 2002-08-01 | 2007-02-07 | 陶瓷聚合体有限公司 | 耐火硅氧烷聚合物组合物 |
| US7026399B2 (en) | 2002-09-27 | 2006-04-11 | Taylor Made Golf Company, Inc. | Golf ball incorporating a polymer network comprising silicone |
| AU2003271422C1 (en) * | 2002-10-17 | 2010-02-18 | Olex Australia Pty Ltd | Fire resistant polymeric compositions |
| TWI322176B (en) * | 2002-10-17 | 2010-03-21 | Polymers Australia Pty Ltd | Fire resistant compositions |
| CA2420319C (en) * | 2003-02-27 | 2007-11-27 | Csl Silicones Inc. | Method for protecting surfaces from effects of fire |
| US20050148706A1 (en) * | 2003-02-28 | 2005-07-07 | Csl Silicones Inc. | Method for protecting surfaces from effects of fire |
| EP1699866A2 (en) * | 2003-12-15 | 2006-09-13 | Dow Corning Corporation | Fluorocarbon elastomer silicone vulcanizates |
| EP1709105A1 (en) * | 2003-12-15 | 2006-10-11 | Dow Corning Corporation | Fluoroplastic silicone vulcanizates |
| JPWO2005066263A1 (ja) * | 2003-12-26 | 2008-04-17 | Jsr株式会社 | 熱可塑性エラストマー組成物およびその成形品 |
| EP1733002B1 (en) * | 2004-03-31 | 2012-06-06 | Olex Australia Pty Limited | Ceramifying composition for fire protection |
| US20050229563A1 (en) * | 2004-04-19 | 2005-10-20 | Holzmann Mark V | Filter element |
| US7468334B2 (en) * | 2004-10-04 | 2008-12-23 | Highland Industries, Inc. | Silicone vulcanizate coated fabric |
| EP2161305B1 (en) * | 2004-10-14 | 2012-07-11 | Asahi Kasei Chemicals Corporation | Resin composition |
| US7828870B1 (en) | 2004-11-24 | 2010-11-09 | Cummins Filtration Ip, Inc. | Filter assembly with cost effective seal |
| US7413588B2 (en) * | 2004-11-24 | 2008-08-19 | Fleetguard, Inc. | High efficiency, low restriction, cost effective filter |
| US7674857B2 (en) * | 2005-11-18 | 2010-03-09 | Momentive Performance Materials Inc. | Room temperature-cured siloxane sealant compositions of reduced gas permeability |
| US9181486B2 (en) | 2006-05-25 | 2015-11-10 | Aspen Aerogels, Inc. | Aerogel compositions with enhanced performance |
| EP1862496B1 (en) * | 2006-05-31 | 2013-01-23 | Borealis Technology Oy | Flame retardant polyethylene composition comprising polypropylene |
| US20080058460A1 (en) * | 2006-09-05 | 2008-03-06 | Dow Corning Corporation | Silicone hot melt additive for thermoplastics |
| US7932342B2 (en) * | 2008-01-16 | 2011-04-26 | International Business Machines Corporation | Method to improve wettability by reducing liquid polymer macromolecule mobility through forming polymer blend system |
| CN101236807B (zh) * | 2008-01-21 | 2010-08-25 | 深圳琦富瑞电子有限公司 | 一种耐高温硅橡胶无卤电线电缆或套管的制作方法 |
| FR2931160A1 (fr) * | 2008-05-16 | 2009-11-20 | Multibase Sa | Nouvel elastomere thermoplastique, adapte a la fabrication de conduits flexibles pour le transport de liquides |
| US7977283B2 (en) | 2008-06-27 | 2011-07-12 | Baker Hughes Incorporated | Method of minimizing or reducing salt deposits by use of a fluid containing a fructan and derivatives thereof |
| CN101429340B (zh) * | 2008-11-19 | 2011-04-20 | 合肥工业大学 | 一种硅橡胶聚烯烃合金材料 |
| CN101921432A (zh) * | 2010-09-29 | 2010-12-22 | 东莞市柏百顺石油化工有限公司 | 一种低烟、无卤、阻燃聚丙烯电缆料及其制备方法 |
| JP5575712B2 (ja) * | 2011-08-01 | 2014-08-20 | 理研ビタミン株式会社 | ポリプロピレン系樹脂組成物並びに該組成物を含有するポリオレフィン系樹脂組成物及びその成形品 |
| WO2013101938A1 (en) * | 2011-12-27 | 2013-07-04 | Dow Corning Corporation | Organopolysiloxanes including silicon-bonded trialkylsilyl-substituted organic groups |
| BR112014026595B1 (pt) * | 2012-05-07 | 2024-03-12 | Becton Dickinson France | Revestimento e composição lubrificante para recipiente médico,recipiente parcialmente revestido com o dito revestimento lubrificante,processo para a produção de um recipiente médico e uso de uma mistura de silicone à base de vinil e silicone à base de acrilato como um componente de silicone reativo em uma composição lubrificante |
| WO2013169485A1 (en) * | 2012-05-10 | 2013-11-14 | Exxonmobil Chemical Patents Inc. | Compositions and methods for making them |
| FR2996617B1 (fr) * | 2012-10-08 | 2014-12-26 | Hutchinson | Courroie de transmission de puissance avec film thermoplastique comprenant un elastomere silicone. |
| CN102924793B (zh) * | 2012-11-22 | 2014-03-12 | 深圳市森日有机硅材料有限公司 | 一种硅氧烷改性的热塑性材料及其制备方法 |
| EP2879135A1 (en) * | 2013-11-28 | 2015-06-03 | Nexans | Fire resistant compositions |
| BR112016017939A2 (pt) | 2014-02-07 | 2017-10-17 | Gen Cable Technologies Corp | métodos para formar cabos com coberturas aprimoradas |
| CN104109388B (zh) * | 2014-07-31 | 2016-05-25 | 江苏省交通规划设计院股份有限公司 | 一种高长径比针状硅灰石填充改性双组份道路灌缝胶 |
| CN104151694B (zh) * | 2014-08-29 | 2017-08-01 | 上海至正道化高分子材料股份有限公司 | 一种耐电弧闪络adss光缆护套料 |
| JP6434143B2 (ja) | 2014-11-21 | 2018-12-05 | マルチベース・エスア | 熱可塑性シリコーンエラストマー |
| US10222547B2 (en) | 2015-11-30 | 2019-03-05 | Corning Incorporated | Flame-retardant optical fiber coating |
| CN105315673A (zh) * | 2015-12-08 | 2016-02-10 | 苏州市享乐惠信息科技有限公司 | 一种高绝缘硅胶板 |
| JP6656045B2 (ja) * | 2016-03-29 | 2020-03-04 | 信越化学工業株式会社 | 担持白金触媒を含有する樹脂組成物、及びそれを用いた熱硬化性オルガノポリシロキサン組成物ならびにその硬化方法 |
| CN109195649B (zh) | 2016-05-27 | 2021-04-06 | 艾斯曲尔医疗公司 | 致动机构 |
| CN109310903A (zh) * | 2016-06-16 | 2019-02-05 | 阿丘克环保方案私人有限公司 | 用于火灾灭火剂的组合物 |
| US10167396B2 (en) * | 2017-05-03 | 2019-01-01 | Corning Incorporated | Low smoke fire-resistant optical ribbon |
| EP4103650B1 (de) * | 2020-02-10 | 2023-08-02 | Wacker Chemie AG | Siliconkautschukzusammensetzungen und deren vulkanisate für den einsatz in trinkwasseranwendungen |
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| US4387176A (en) | 1982-02-04 | 1983-06-07 | General Electric Company | Silicone flame retardants for plastics |
| US4500688A (en) | 1982-04-20 | 1985-02-19 | Petrarch Systems Inc. | Curable silicone containing compositions and methods of making same |
| JPS59105042A (ja) * | 1982-12-07 | 1984-06-18 | Showa Denko Kk | プロピレン系重合体組成物 |
| US4695602A (en) * | 1985-02-28 | 1987-09-22 | Lnp Corporation | Fiber reinforced thermoplastics containing silicone interpenetrating polymer networks |
| GB8806497D0 (en) | 1988-03-18 | 1988-04-20 | Mortile Acoustic Ind Ltd | Non-toxic fire retardant thermoplastic material |
| JPH02189340A (ja) * | 1989-01-17 | 1990-07-25 | Hitachi Cable Ltd | 熱硬化性重合体ブレンド物の製造方法 |
| JPH02242839A (ja) * | 1989-03-15 | 1990-09-27 | Hitachi Cable Ltd | 熱硬化性重合体ブレンド物の製造方法 |
| US5091453A (en) | 1989-04-21 | 1992-02-25 | Bp Chemicals Limited | Flame retardant polymer composition |
| US5104920A (en) | 1989-06-14 | 1992-04-14 | Union Carbide Chemicals & Plastics Technology Corporation | Flame retardant compositions |
| JPH0788027B2 (ja) * | 1989-10-26 | 1995-09-27 | ポリプラスチックス株式会社 | 回路形成用２色成形品 |
| JP3057818B2 (ja) * | 1991-06-12 | 2000-07-04 | ジェイエスアール株式会社 | 熱可塑性エラストマー組成物 |
| CA2092444A1 (en) | 1992-05-08 | 1993-11-09 | William M. Bunting | Use of polyphenylene ether resins to improve the flame retardancy of high molecular weight silicones |
| US5391594A (en) | 1992-06-29 | 1995-02-21 | Dow Corning Corporation | Method for imparting fire retardancy to organic resins |
| US5508323A (en) | 1992-06-29 | 1996-04-16 | Dow Corning Corporation | Method for imparting fire retardancy to organic resins |
| EP0699717A3 (en) * | 1994-08-30 | 1997-01-02 | Dow Corning | Organopolysiloxane compositions curable into products having good adhesiveness and reduced flammability |
| US5648426A (en) * | 1995-05-05 | 1997-07-15 | Huls America Inc. | Composition and method for impact modification of thermoplastics |
| CA2322196C (en) * | 1998-03-03 | 2008-07-29 | Dow Corning Corporation | Thermoplastic silicone elastomers |
| US6153691A (en) * | 1998-10-07 | 2000-11-28 | Dow Corning Corporation | Thermoplastic silicone vulcanizates prepared by condensation cure |
| US6080489A (en) * | 1999-01-04 | 2000-06-27 | Dow Corning Corporation | Thermoplastic polymers modified with siloxane blends |
-
2000
- 2000-01-19 TW TW089100816A patent/TW526230B/zh not_active IP Right Cessation
- 2000-01-31 CA CA002362044A patent/CA2362044C/en not_active Expired - Fee Related
- 2000-01-31 CN CNB008034176A patent/CN1134498C/zh not_active Expired - Lifetime
- 2000-01-31 WO PCT/US2000/002417 patent/WO2000046291A1/en not_active Ceased
- 2000-01-31 EP EP00910031A patent/EP1153079B1/en not_active Expired - Lifetime
- 2000-01-31 AU AU32189/00A patent/AU3218900A/en not_active Abandoned
- 2000-01-31 AT AT00910031T patent/ATE274557T1/de not_active IP Right Cessation
- 2000-01-31 JP JP2000597358A patent/JP4717218B2/ja not_active Expired - Fee Related
- 2000-01-31 MX MXPA01007766A patent/MXPA01007766A/es active IP Right Grant
- 2000-01-31 KR KR1020017009765A patent/KR20010101947A/ko not_active Withdrawn
- 2000-01-31 DE DE60013252T patent/DE60013252T2/de not_active Expired - Lifetime
-
2001
- 2001-06-13 US US09/880,480 patent/US6433049B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| DE60013252D1 (de) | 2004-09-30 |
| MXPA01007766A (es) | 2002-04-24 |
| WO2000046291A1 (en) | 2000-08-10 |
| CA2362044A1 (en) | 2000-08-10 |
| TW526230B (en) | 2003-04-01 |
| CN1134498C (zh) | 2004-01-14 |
| US6433049B1 (en) | 2002-08-13 |
| US20020055567A1 (en) | 2002-05-09 |
| ATE274557T1 (de) | 2004-09-15 |
| JP2002536485A (ja) | 2002-10-29 |
| DE60013252T2 (de) | 2005-09-01 |
| AU3218900A (en) | 2000-08-25 |
| EP1153079B1 (en) | 2004-08-25 |
| EP1153079A1 (en) | 2001-11-14 |
| JP4717218B2 (ja) | 2011-07-06 |
| CN1339047A (zh) | 2002-03-06 |
| KR20010101947A (ko) | 2001-11-15 |
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Legal Events
| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20170131 |