CA2276173A1 - Catalysts and processes for the polymerization of olefins - Google Patents
Catalysts and processes for the polymerization of olefins Download PDFInfo
- Publication number
- CA2276173A1 CA2276173A1 CA002276173A CA2276173A CA2276173A1 CA 2276173 A1 CA2276173 A1 CA 2276173A1 CA 002276173 A CA002276173 A CA 002276173A CA 2276173 A CA2276173 A CA 2276173A CA 2276173 A1 CA2276173 A1 CA 2276173A1
- Authority
- CA
- Canada
- Prior art keywords
- compound
- aluminium
- formula
- alkyl
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
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- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 74
- 239000003054 catalyst Substances 0.000 title claims abstract description 46
- 150000001336 alkenes Chemical class 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims description 44
- -1 cyclopentadienyl compound Chemical class 0.000 claims abstract description 104
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 49
- 150000001399 aluminium compounds Chemical class 0.000 claims abstract description 43
- 239000001257 hydrogen Substances 0.000 claims abstract description 26
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 26
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 25
- ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 claims abstract description 24
- 150000001875 compounds Chemical class 0.000 claims abstract description 21
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 19
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 19
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 229940077746 antacid containing aluminium compound Drugs 0.000 claims abstract description 10
- 125000002877 alkyl aryl group Chemical group 0.000 claims abstract description 9
- 125000004429 atom Chemical group 0.000 claims abstract description 8
- 229910052726 zirconium Inorganic materials 0.000 claims abstract description 8
- 229910052735 hafnium Inorganic materials 0.000 claims abstract description 6
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 6
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 claims abstract 10
- 125000001424 substituent group Chemical group 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 31
- 239000002904 solvent Substances 0.000 claims description 24
- 238000006243 chemical reaction Methods 0.000 claims description 23
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 claims description 23
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 22
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 22
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 21
- 239000005977 Ethylene Substances 0.000 claims description 21
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 18
- 239000004411 aluminium Substances 0.000 claims description 14
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- 229920006395 saturated elastomer Polymers 0.000 claims description 13
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 10
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 10
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 8
- 229920001198 elastomeric copolymer Polymers 0.000 claims description 8
- 229920001577 copolymer Polymers 0.000 claims description 7
- 150000004291 polyenes Chemical class 0.000 claims description 7
- HKVFGFGPRISDFM-UHFFFAOYSA-N tris(2,3,3-trimethylbutyl)alumane Chemical compound CC(C)(C)C(C)C[Al](CC(C)C(C)(C)C)CC(C)C(C)(C)C HKVFGFGPRISDFM-UHFFFAOYSA-N 0.000 claims description 7
- SSEXLBWMXFFGTD-UHFFFAOYSA-N tris(2,3-dimethylbutyl)alumane Chemical compound CC(C)C(C)C[Al](CC(C)C(C)C)CC(C)C(C)C SSEXLBWMXFFGTD-UHFFFAOYSA-N 0.000 claims description 7
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 claims description 6
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 claims description 6
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Natural products C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 claims description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 125000003454 indenyl group Chemical group C1(C=CC2=CC=CC=C12)* 0.000 claims description 6
- XCYXOPOHMFRQSM-UHFFFAOYSA-N tris[2-(4-methylcyclohex-3-en-1-yl)propyl]alumane Chemical compound C1CC(C)=CCC1C(C)C[Al](CC(C)C1CC=C(C)CC1)CC(C)C1CCC(C)=CC1 XCYXOPOHMFRQSM-UHFFFAOYSA-N 0.000 claims description 6
- 150000001993 dienes Chemical class 0.000 claims description 5
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 4
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 claims description 4
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 claims description 4
- 229910007161 Si(CH3)3 Chemical group 0.000 claims description 3
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 claims description 3
- 239000000460 chlorine Substances 0.000 claims description 3
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 3
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 2
- AZWXAPCAJCYGIA-UHFFFAOYSA-N bis(2-methylpropyl)alumane Chemical compound CC(C)C[AlH]CC(C)C AZWXAPCAJCYGIA-UHFFFAOYSA-N 0.000 claims description 2
- 229910052801 chlorine Inorganic materials 0.000 claims description 2
- 230000000295 complement effect Effects 0.000 claims description 2
- 150000001925 cycloalkenes Chemical class 0.000 claims description 2
- SIPUZPBQZHNSDW-UHFFFAOYSA-N diisobutylaluminium hydride Substances CC(C)C[Al]CC(C)C SIPUZPBQZHNSDW-UHFFFAOYSA-N 0.000 claims description 2
- 230000007717 exclusion Effects 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 125000002097 pentamethylcyclopentadienyl group Chemical group 0.000 claims description 2
- 125000006527 (C1-C5) alkyl group Chemical group 0.000 claims 4
- 125000000041 C6-C10 aryl group Chemical group 0.000 claims 2
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 claims 1
- 125000006736 (C6-C20) aryl group Chemical group 0.000 claims 1
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims 1
- 125000003342 alkenyl group Chemical group 0.000 abstract description 13
- 125000003118 aryl group Chemical group 0.000 abstract description 10
- 230000000694 effects Effects 0.000 abstract description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 70
- 229920000642 polymer Polymers 0.000 description 27
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 26
- ZMZGFLUUZLELNE-UHFFFAOYSA-N 2,3,5-triiodobenzoic acid Chemical compound OC(=O)C1=CC(I)=CC(I)=C1I ZMZGFLUUZLELNE-UHFFFAOYSA-N 0.000 description 25
- 125000000217 alkyl group Chemical group 0.000 description 25
- 239000000243 solution Substances 0.000 description 21
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 20
- 235000011089 carbon dioxide Nutrition 0.000 description 20
- 238000010992 reflux Methods 0.000 description 19
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 18
- 238000005481 NMR spectroscopy Methods 0.000 description 16
- 239000000047 product Substances 0.000 description 15
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 9
- 239000007983 Tris buffer Substances 0.000 description 8
- CPOFMOWDMVWCLF-UHFFFAOYSA-N methyl(oxo)alumane Chemical compound C[Al]=O CPOFMOWDMVWCLF-UHFFFAOYSA-N 0.000 description 8
- NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 7
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 6
- JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 230000011514 reflex Effects 0.000 description 6
- 239000008096 xylene Substances 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000012230 colorless oil Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- URLKBWYHVLBVBO-UHFFFAOYSA-N Para-Xylene Chemical group CC1=CC=C(C)C=C1 URLKBWYHVLBVBO-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 230000003197 catalytic effect Effects 0.000 description 4
- 239000012634 fragment Substances 0.000 description 4
- 150000004678 hydrides Chemical class 0.000 description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 description 4
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 4
- 238000010926 purge Methods 0.000 description 4
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 3
- 239000000356 contaminant Substances 0.000 description 3
- 229920000092 linear low density polyethylene Polymers 0.000 description 3
- 239000004707 linear low-density polyethylene Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- VGONMIOMLRCRSS-UHFFFAOYSA-N tris(2,3-dimethylhexyl)alumane Chemical compound CCCC(C)C(C)C[Al](CC(C)C(C)CCC)CC(C)C(C)CCC VGONMIOMLRCRSS-UHFFFAOYSA-N 0.000 description 3
- BENYMJNPVWYYES-UHFFFAOYSA-N tris(2,3-dimethylpentyl)alumane Chemical compound CCC(C)C(C)C[Al](CC(C)C(C)CC)CC(C)C(C)CC BENYMJNPVWYYES-UHFFFAOYSA-N 0.000 description 3
- FEJNOSHLGDRZDX-UHFFFAOYSA-N tris(2-ethyl-3-methylbutyl)alumane Chemical compound CCC(C(C)C)C[Al](CC(CC)C(C)C)CC(CC)C(C)C FEJNOSHLGDRZDX-UHFFFAOYSA-N 0.000 description 3
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 2
- FUDNBFMOXDUIIE-UHFFFAOYSA-N 3,7-dimethylocta-1,6-diene Chemical compound C=CC(C)CCC=C(C)C FUDNBFMOXDUIIE-UHFFFAOYSA-N 0.000 description 2
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 2
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000005234 alkyl aluminium group Chemical group 0.000 description 2
- 229910000091 aluminium hydride Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- IDASTKMEQGPVRR-UHFFFAOYSA-N cyclopenta-1,3-diene;zirconium(2+) Chemical class [Zr+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 IDASTKMEQGPVRR-UHFFFAOYSA-N 0.000 description 2
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- GEAWFZNTIFJMHR-UHFFFAOYSA-N hepta-1,6-diene Chemical compound C=CCCCC=C GEAWFZNTIFJMHR-UHFFFAOYSA-N 0.000 description 2
- PYGSKMBEVAICCR-UHFFFAOYSA-N hexa-1,5-diene Chemical compound C=CCCC=C PYGSKMBEVAICCR-UHFFFAOYSA-N 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 235000021110 pickles Nutrition 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 229910052723 transition metal Inorganic materials 0.000 description 2
- 150000003624 transition metals Chemical class 0.000 description 2
- UVCGXEXDZCCTFF-UHFFFAOYSA-N tris(2,4-dimethylheptyl)alumane Chemical compound CCCC(C)CC(C)C[Al](CC(C)CC(C)CCC)CC(C)CC(C)CCC UVCGXEXDZCCTFF-UHFFFAOYSA-N 0.000 description 2
- JAFSWBPCWFKGBY-UHFFFAOYSA-N tris(2-ethyl-3-methylpentyl)alumane Chemical compound CCC(C)C(CC)C[Al](CC(CC)C(C)CC)CC(CC)C(C)CC JAFSWBPCWFKGBY-UHFFFAOYSA-N 0.000 description 2
- AMPVHNIRJXJXEN-UHFFFAOYSA-N tris(3-ethyl-2-methylpentyl)alumane Chemical compound CCC(CC)C(C)C[Al](CC(C)C(CC)CC)CC(C)C(CC)CC AMPVHNIRJXJXEN-UHFFFAOYSA-N 0.000 description 2
- VIDMRZMJMLMHSP-UHFFFAOYSA-N tris(3-methyl-2-propan-2-ylbutyl)alumane Chemical compound CC(C)C(C(C)C)C[Al](CC(C(C)C)C(C)C)CC(C(C)C)C(C)C VIDMRZMJMLMHSP-UHFFFAOYSA-N 0.000 description 2
- XMGQYMWWDOXHJM-JTQLQIEISA-N (+)-α-limonene Chemical compound CC(=C)[C@@H]1CCC(C)=CC1 XMGQYMWWDOXHJM-JTQLQIEISA-N 0.000 description 1
- VYXHVRARDIDEHS-QGTKBVGQSA-N (1z,5z)-cycloocta-1,5-diene Chemical compound C\1C\C=C/CC\C=C/1 VYXHVRARDIDEHS-QGTKBVGQSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- UHWUPRFSWYYSEB-UHFFFAOYSA-N 1-[bis(2-trimethylsilylpropyl)alumanyl]propan-2-yl-trimethylsilane Chemical compound C[Si](C)(C)C(C)C[Al](CC(C)[Si](C)(C)C)CC(C)[Si](C)(C)C UHWUPRFSWYYSEB-UHFFFAOYSA-N 0.000 description 1
- HOEFIGOFJSMARD-UHFFFAOYSA-N 1-methylcycloocta-1,5-diene Chemical compound CC1=CCCC=CCC1 HOEFIGOFJSMARD-UHFFFAOYSA-N 0.000 description 1
- KYSNRMGJOYWQQR-UHFFFAOYSA-N 11-methyldodeca-1,10-diene Chemical compound CC(C)=CCCCCCCCC=C KYSNRMGJOYWQQR-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- SLQMKNPIYMOEGB-UHFFFAOYSA-N 2-methylhexa-1,5-diene Chemical compound CC(=C)CCC=C SLQMKNPIYMOEGB-UHFFFAOYSA-N 0.000 description 1
- 125000005916 2-methylpentyl group Chemical group 0.000 description 1
- FSWNZCWHTXTQBY-UHFFFAOYSA-N 4,6-dimethylhept-1-ene Chemical compound CC(C)CC(C)CC=C FSWNZCWHTXTQBY-UHFFFAOYSA-N 0.000 description 1
- NFDXGVFXQUFNQW-UHFFFAOYSA-N 4-[bis(aziridin-1-yl)phosphoryl]morpholine Chemical compound C1CN1P(N1CCOCC1)(=O)N1CC1 NFDXGVFXQUFNQW-UHFFFAOYSA-N 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- OJOWICOBYCXEKR-UHFFFAOYSA-N 5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CC)CC1C=C2 OJOWICOBYCXEKR-UHFFFAOYSA-N 0.000 description 1
- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 description 1
- KUFDSEQTHICIIF-UHFFFAOYSA-N 6-methylhepta-1,5-diene Chemical compound CC(C)=CCCC=C KUFDSEQTHICIIF-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 235000002918 Fraxinus excelsior Nutrition 0.000 description 1
- 101150065592 NME2 gene Proteins 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- KVOZXXSUSRZIKD-UHFFFAOYSA-N Prop-2-enylcyclohexane Chemical compound C=CCC1CCCCC1 KVOZXXSUSRZIKD-UHFFFAOYSA-N 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- 238000007068 beta-elimination reaction Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 1
- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000001282 iso-butane Substances 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 125000002950 monocyclic group Chemical group 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000002899 organoaluminium compounds Chemical class 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 150000003254 radicals Chemical group 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000001149 thermolysis Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- RXTYCDSTJDDMRJ-UHFFFAOYSA-N tris(2,3,3-trimethylpentyl)alumane Chemical compound CCC(C)(C)C(C)C[Al](CC(C)C(C)(C)CC)CC(C)C(C)(C)CC RXTYCDSTJDDMRJ-UHFFFAOYSA-N 0.000 description 1
- WRZKUDJYHWOMSC-UHFFFAOYSA-N tris(2,3-diethylpentyl)alumane Chemical compound CCC(CC)C(CC)C[Al](CC(CC)C(CC)CC)CC(CC)C(CC)CC WRZKUDJYHWOMSC-UHFFFAOYSA-N 0.000 description 1
- IBAAQZWRANCYLH-UHFFFAOYSA-N tris(2,3-dimethyl-3-phenylbutyl)alumane Chemical compound C=1C=CC=CC=1C(C)(C)C(C)C[Al](CC(C)C(C)(C)C=1C=CC=CC=1)CC(C)C(C)(C)C1=CC=CC=C1 IBAAQZWRANCYLH-UHFFFAOYSA-N 0.000 description 1
- WUGMXCQCNQHHDC-UHFFFAOYSA-N tris(2,3-dimethylheptyl)alumane Chemical compound CCCCC(C)C(C)C[Al](CC(C)C(C)CCCC)CC(C)C(C)CCCC WUGMXCQCNQHHDC-UHFFFAOYSA-N 0.000 description 1
- JZYDMTLGWBVVIU-UHFFFAOYSA-N tris(2,5-dimethylhexyl)alumane Chemical compound CC(C)CCC(C)C[Al](CC(C)CCC(C)C)CC(C)CCC(C)C JZYDMTLGWBVVIU-UHFFFAOYSA-N 0.000 description 1
- IDEILWZYRDEEGQ-UHFFFAOYSA-N tris(2-ethyl-3,3-dimethylpentyl)alumane Chemical compound CCC(C)(C)C(CC)C[Al](CC(CC)C(C)(C)CC)CC(CC)C(C)(C)CC IDEILWZYRDEEGQ-UHFFFAOYSA-N 0.000 description 1
- SHYOGCVYLVUSDK-UHFFFAOYSA-N tris(2-ethyl-3-phenylbutyl)alumane Chemical compound C=1C=CC=CC=1C(C)C(CC)C[Al](CC(CC)C(C)C=1C=CC=CC=1)CC(CC)C(C)C1=CC=CC=C1 SHYOGCVYLVUSDK-UHFFFAOYSA-N 0.000 description 1
- ZMFQGYOUXPHLOA-UHFFFAOYSA-N tris(2-methyl-3-phenylbutyl)alumane Chemical compound C=1C=CC=CC=1C(C)C(C)C[Al](CC(C)C(C)C=1C=CC=CC=1)CC(C)C(C)C1=CC=CC=C1 ZMFQGYOUXPHLOA-UHFFFAOYSA-N 0.000 description 1
- JHKHTIUZAWUYBF-UHFFFAOYSA-N tris(2-methyl-3-propylhexyl)alumane Chemical compound CCCC(CCC)C(C)C[Al](CC(C)C(CCC)CCC)CC(C)C(CCC)CCC JHKHTIUZAWUYBF-UHFFFAOYSA-N 0.000 description 1
- NEKKHOCWHFUARF-UHFFFAOYSA-N tris(2-propan-2-ylpentyl)alumane Chemical compound CCCC(C(C)C)C[Al](CC(CCC)C(C)C)CC(CCC)C(C)C NEKKHOCWHFUARF-UHFFFAOYSA-N 0.000 description 1
- YEGQCMGIQOIQNF-UHFFFAOYSA-N tris(3,3-dimethyl-2-propan-2-ylbutyl)alumane Chemical compound CC(C)C(C(C)(C)C)C[Al](CC(C(C)C)C(C)(C)C)CC(C(C)C)C(C)(C)C YEGQCMGIQOIQNF-UHFFFAOYSA-N 0.000 description 1
- NWZXKGHKCZTEHC-UHFFFAOYSA-N tris(3-ethyl-2-methylheptyl)alumane Chemical compound CCCCC(CC)C(C)C[Al](CC(C)C(CC)CCCC)CC(C)C(CC)CCCC NWZXKGHKCZTEHC-UHFFFAOYSA-N 0.000 description 1
- PZHDFOMROGHRBA-UHFFFAOYSA-N tris(3-ethyl-2-methylhexyl)alumane Chemical compound CCCC(CC)C(C)C[Al](CC(C)C(CC)CCC)CC(C)C(CC)CCC PZHDFOMROGHRBA-UHFFFAOYSA-N 0.000 description 1
- MLDSMTVYPPIXMZ-UHFFFAOYSA-N tris(4-methylpentyl)alumane Chemical compound CC(C)CCC[Al](CCCC(C)C)CCCC(C)C MLDSMTVYPPIXMZ-UHFFFAOYSA-N 0.000 description 1
- AETKXSGBGBBCGA-UHFFFAOYSA-N tris[3-methyl-2-(2-methylpropyl)pentyl]alumane Chemical compound CCC(C)C(CC(C)C)C[Al](CC(CC(C)C)C(C)CC)CC(CC(C)C)C(C)CC AETKXSGBGBBCGA-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/02—Ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP97203332 | 1997-10-29 | ||
| EP97203332.8 | 1997-10-29 | ||
| PCT/EP1998/006732 WO1999021899A1 (en) | 1997-10-29 | 1998-10-23 | Catalysts and processes for the polymerization of olefins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2276173A1 true CA2276173A1 (en) | 1999-05-06 |
Family
ID=8228869
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002276173A Abandoned CA2276173A1 (en) | 1997-10-29 | 1998-10-23 | Catalysts and processes for the polymerization of olefins |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US6559252B1 (https=) |
| EP (1) | EP0948549B1 (https=) |
| JP (1) | JP4383549B2 (https=) |
| KR (1) | KR20000069756A (https=) |
| CN (1) | CN1116314C (https=) |
| AR (1) | AR017401A1 (https=) |
| AU (1) | AU1031899A (https=) |
| BR (1) | BR9806724A (https=) |
| CA (1) | CA2276173A1 (https=) |
| DE (1) | DE69815657T2 (https=) |
| ES (1) | ES2201544T3 (https=) |
| HU (1) | HUP0001325A3 (https=) |
| ID (1) | ID22020A (https=) |
| IL (1) | IL130479A0 (https=) |
| MY (1) | MY133201A (https=) |
| NO (1) | NO993205L (https=) |
| PL (1) | PL334339A1 (https=) |
| WO (1) | WO1999021899A1 (https=) |
| ZA (1) | ZA989696B (https=) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2000001738A2 (en) | 1998-07-02 | 2000-01-13 | Montell Technology Company Bv | Process for the preparation of substantially amorphous alpha-olefin polymers, compositions containing them and process for the preparation of bridged ligand |
| ES2197714T3 (es) | 1998-11-18 | 2004-01-01 | Basell Polyolefine Gmbh | Metalocenos de eslabon metileno como componentes cataliticos de la polimerizacion de olefinas. |
| WO2000035974A1 (en) | 1998-12-15 | 2000-06-22 | Basell Technology Company B.V. | Catalyst system for olefin polymerization |
| ATE252605T1 (de) | 1999-03-09 | 2003-11-15 | Basell Polyolefine Gmbh | Mehrstufiges verfahren zur (co)polymersation von olefinen |
| US6774253B1 (en) | 1999-06-04 | 2004-08-10 | Basell Polyolefine Gmbh | Process for the preparation of titanium complexes |
| EP1102773B1 (en) | 1999-06-07 | 2003-04-02 | Basell Polyolefine GmbH | Preparation of transition-metal-alkyl-complexes carrying a bidentate, dianionic ligand |
| BR0014616A (pt) | 1999-09-22 | 2002-06-18 | Basell Technology Co Bv | Sistema catalìtico e processo para a polimerização de olefinas |
| US6444833B1 (en) | 1999-12-15 | 2002-09-03 | Basell Technology Company Bv | Metallocene compounds, process for their preparation and their use in catalytic systems for the polymerization of olefins |
| EP1157046B1 (en) | 1999-12-28 | 2005-12-07 | Basell Polyolefine GmbH | Process for the preparation of ethylene polymers |
| DE60029464T2 (de) | 1999-12-28 | 2007-07-26 | Basell Polyolefine Gmbh | Verfahren zur herstellung von ethylen polymeren |
| JP4358470B2 (ja) | 1999-12-28 | 2009-11-04 | バセル テクノロジー カンパニー ビー．ブイ． | メタロセン化合物、リガンド、触媒、ポリマーの製造方法及びプロピレンホモポリマー |
| ES2239665T3 (es) | 2000-01-18 | 2005-10-01 | Basell Polyolefine Gmbh | Procedimiento para producir polimeros aa base de propileno, substancialmente amorfos. |
| US6710006B2 (en) * | 2000-02-09 | 2004-03-23 | Shell Oil Company | Non-symmetrical ligands and catalyst systems thereof for ethylene oligomerization to linear alpha olefins |
| DE60103702T2 (de) | 2000-02-24 | 2005-06-23 | Basell Polyolefine Gmbh | Organometallische Verbindungen die als Cokatalysator bei der Polymerisation von Olefinen verwendet ist |
| DE60108062T2 (de) | 2000-05-24 | 2005-06-02 | Basell Polyolefine Gmbh | Propylenpolymere und verfahren zur ihrer herstellung |
| US6673869B2 (en) | 2000-07-27 | 2004-01-06 | Basell Poliolefine Italia S.P.A. | Transparent elastomeric thermoplastic polyolefin compositions |
| EP1392740B1 (en) | 2000-09-25 | 2008-08-20 | Basell Polyolefine GmbH | Process for the preparation of ethylene polymers with a bis-amido titanium compound |
| US7037988B2 (en) * | 2000-10-03 | 2006-05-02 | Shell Oil Company | Process for the co-oligomerisation of ethylene and alpha olefins |
| DE60135311D1 (de) | 2000-12-22 | 2008-09-25 | Basell Polyolefine Gmbh | Katalysatorkomponente fur die polymerisation von olefinen |
| JP2004516365A (ja) | 2000-12-22 | 2004-06-03 | バセル ポリオレフィン イタリア エス．ピー．エー． | 多孔性ポリマーの製造方法およびそれから得られるポリマー |
| US7417006B2 (en) | 2001-05-21 | 2008-08-26 | Basell Polyolefine Gmbh | Catalyst system for the polymerization of olefins |
| JP4332029B2 (ja) | 2001-06-12 | 2009-09-16 | バーゼル・ポリオレフィン・ゲーエムベーハー | １−ブテンの重合方法 |
| WO2002100908A1 (en) * | 2001-06-12 | 2002-12-19 | Basell Polyolefine Gmbh | Process for the polymerization of 1-butene |
| WO2003000706A1 (en) | 2001-06-22 | 2003-01-03 | Basell Polyolefine Gmbh | Metallocenes, use in catalyst systems for producing olefin polymers |
| EP1406969A1 (en) | 2001-07-17 | 2004-04-14 | Basell Polyolefine GmbH | Multistep process for the (co)polymerization of olefins |
| CN1255419C (zh) * | 2001-08-01 | 2006-05-10 | 国际壳牌研究有限公司 | 乙烯低聚生产直链α烯烃用配位体及其催化剂体系 |
| DE60218059T2 (de) | 2001-11-12 | 2007-08-30 | Basell Polyolefine Gmbh | Verfahren zur polymerisation von 1-buten und 1-buten polymeren |
| US7022793B2 (en) | 2001-11-27 | 2006-04-04 | Basell Polyolefine Gmbh | Process for the treatment of polymer compositions |
| US7141637B2 (en) | 2001-11-30 | 2006-11-28 | Basell Polyolefine Gmbh | Metallocene compounds and process for the preparation of propylene polymers |
| JP2005517773A (ja) * | 2002-02-25 | 2005-06-16 | バセル ポリオレフィン ジーエムビーエイチ | エチレンの共重合方法 |
| AU2003242663A1 (en) * | 2002-06-26 | 2004-01-19 | Basell Poliolefine Italia S.P.A. | Impact-resistant polyolefin compositions |
| RU2308470C2 (ru) * | 2002-06-26 | 2007-10-20 | Базелль Полиолефин Италия С.П.А. | Ударопрочные полиолефиновые композиции |
| CN100532400C (zh) | 2002-07-09 | 2009-08-26 | 巴塞尔聚烯烃股份有限公司 | 用于烯烃聚合的催化剂体系 |
| DE60329691D1 (de) | 2002-09-06 | 2009-11-26 | Basell Polyolefine Gmbh | Verfahren zur copolymerisation von ethylen |
| WO2004037415A2 (en) * | 2002-09-25 | 2004-05-06 | Shell Internationale Research Maatschappij B.V. | Catalyst systems for ethylene oligomerisation to linear alpha olefins |
| US7569647B2 (en) | 2002-10-10 | 2009-08-04 | Basell Polyolefine Gmbh | Process for the copolymerization of ethylene |
| US7589160B2 (en) | 2002-12-04 | 2009-09-15 | Basell Polyolefine Gmbh | Process for preparing 1-butene polymers |
| DE60329523D1 (de) | 2002-12-04 | 2009-11-12 | Basell Polyolefine Gmbh | 1-Buten-Copolymere und Herstellungsverfahren dafür |
| KR101060985B1 (ko) * | 2003-05-12 | 2011-08-31 | 바젤 폴리올레핀 게엠베하 | 1-부텐의 중합 방법 |
| CN101163723B (zh) | 2003-07-04 | 2010-12-22 | 巴塞尔聚烯烃股份有限公司 | 烯烃聚合方法 |
| US20050014983A1 (en) * | 2003-07-07 | 2005-01-20 | De Boer Eric Johannes Maria | Process for producing linear alpha olefins |
| ATE418567T1 (de) | 2003-12-22 | 2009-01-15 | Basell Polyolefine Gmbh | Metallocenverbindungen |
| EP1735355B1 (en) | 2004-03-12 | 2010-09-29 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
| BRPI0508155A (pt) | 2004-03-12 | 2007-08-07 | Basell Polyolefine Gmbh | sistema catalìtico para a polimerização de olefinas |
| EP1723184A1 (en) | 2004-03-12 | 2006-11-22 | Basell Polyolefine GmbH | Process for polymerizing 1-hexene or higher alpha-olefins |
| CA2560564C (en) | 2004-03-24 | 2013-07-09 | Shell Internationale Research Maatschappij B.V. | Transition metal complexes |
| JP4897670B2 (ja) * | 2004-05-04 | 2012-03-14 | バーゼル・ポリオレフィン・ゲーエムベーハー | アタクチック１−ブテンポリマー類の製造方法 |
| AR049714A1 (es) * | 2004-07-13 | 2006-08-30 | Shell Int Research | Proceso de preparacion de alfa olefinas lineales |
| WO2006005648A1 (en) | 2004-07-13 | 2006-01-19 | Basell Polyolefine Gmbh | Metallocene compounds, ligands used in their preparation, preparation of 1-butene polymers and 1-butene polymers therefrom |
| EP1769009A1 (en) | 2004-07-22 | 2007-04-04 | Basell Polyolefine GmbH | Process for producing fractionable 1-butene polymers |
| CA2573975A1 (en) | 2004-07-22 | 2006-01-26 | Basell Polyolefine Gmbh | 1-butene polymers composition |
| RU2007118505A (ru) * | 2004-10-18 | 2008-11-27 | Базелль Полиолефин Италия С.Р.Л. (It) | (со)полимеры бутена-1 с низкой изотактичностью |
| ATE501183T1 (de) * | 2004-10-21 | 2011-03-15 | Basell Polyolefine Gmbh | 1-buten-polymer und herstellungsverfahren dafür |
| EP1655314A1 (en) * | 2004-11-09 | 2006-05-10 | Basell Polyolefine GmbH | Process for the preparation of 1-butene/propylene copolymers |
| EP1814922A1 (en) * | 2004-11-22 | 2007-08-08 | Basell Polyolefine GmbH | Propylene based terpolymers |
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| EP1879959B1 (en) | 2005-05-11 | 2011-07-06 | Basell Poliolefine Italia S.r.l. | Polymerization process for preparing polyolefin blends |
| US8051611B2 (en) * | 2005-06-24 | 2011-11-08 | Dryvit Systems, Inc. | Exterior insulation and finish system and method and tool for installing same |
| EP1902062B1 (en) * | 2005-06-30 | 2012-06-13 | Basell Polyolefine GmbH | Metallocene compounds |
| ATE469928T1 (de) * | 2005-10-21 | 2010-06-15 | Basell Polyolefine Gmbh | Statistische polypropylencopolymere mit hohen schmelzflussraten für spritzguss- und schmelzblasanwendungen |
| CN101291986B (zh) * | 2005-10-21 | 2011-12-14 | 巴塞尔聚烯烃股份有限公司 | 用于注射模塑的聚丙烯 |
| EP1940889B1 (en) * | 2005-10-21 | 2010-06-02 | Basell Polyolefine GmbH | Propylene polymers |
| US20090017710A1 (en) * | 2006-02-02 | 2009-01-15 | Basell Polyolefine Gmbh | Propylene Melt Blown Resins, Propylene Melt Blown Resin Fibers and Non-Woven Fabric Made From the Same, and Methods of Making the Same |
| US8343602B2 (en) * | 2006-02-23 | 2013-01-01 | Basell Poliolefine Italia, s.r.l. | Propylene polymers for injection molding applications |
| JP2009530341A (ja) * | 2006-03-17 | 2009-08-27 | バーゼル・ポリオレフィン・ゲーエムベーハー | メタロセン化合物類 |
| WO2007116034A1 (en) * | 2006-04-12 | 2007-10-18 | Basell Polyolefine Gmbh | Metallocene compounds |
| EP2010580B1 (en) * | 2006-04-21 | 2016-07-13 | Basell Polyolefine GmbH | Process for the preparation of ethylene copolymers |
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Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT1237398B (it) | 1989-01-31 | 1993-06-01 | Ausimont Srl | Catalizzatori per la polimerizzazione di olefine. |
| DE3922546A1 (de) | 1989-07-08 | 1991-01-17 | Hoechst Ag | Verfahren zur herstellung von cycloolefinpolymeren |
| EP0501370B1 (de) | 1991-02-27 | 1998-11-25 | Ticona GmbH | Verfahren zur Herstellung von Cycloolefin(co)polymeren mit enger Molekulargewichtsverteilung |
| IL106042A (en) | 1992-06-18 | 1999-05-09 | Montell Technology Company Bv | Catalysts for the polymerization of olefins obtained from organometallic cyclopentadienyl compounds alumino-organic compounds and water and process for the preparation of an ethylene homo- and copolymer |
| DE4325824A1 (de) * | 1993-07-31 | 1995-02-02 | Basf Ag | Verfahren zur Herstellung von Homopolymerisaten des Ethylens oder Copolymerisaten des Ethylens |
| IT1271406B (it) * | 1993-09-13 | 1997-05-28 | Spherilene Srl | Procedimento per la preparazione di polimeri dell'etilene e prodotti ottenuti |
| IT1273661B (it) | 1994-07-20 | 1997-07-09 | Spherilene Srl | Catalizzatori per la polimerizzazione delle olefine |
| US6476163B2 (en) * | 1997-10-29 | 2002-11-05 | Basell Technology Company Bv | Catalysts for the polymerization of olefins and process for the preparation thereof |
-
1997
- 1997-10-29 US US09/331,917 patent/US6559252B1/en not_active Expired - Fee Related
-
1998
- 1998-10-23 PL PL98334339A patent/PL334339A1/xx not_active Application Discontinuation
- 1998-10-23 ZA ZA989696A patent/ZA989696B/xx unknown
- 1998-10-23 DE DE69815657T patent/DE69815657T2/de not_active Expired - Lifetime
- 1998-10-23 JP JP52322899A patent/JP4383549B2/ja not_active Expired - Lifetime
- 1998-10-23 CN CN98802759A patent/CN1116314C/zh not_active Expired - Fee Related
- 1998-10-23 IL IL13047998A patent/IL130479A0/xx unknown
- 1998-10-23 ID IDW990616A patent/ID22020A/id unknown
- 1998-10-23 KR KR1019997005892A patent/KR20000069756A/ko not_active Withdrawn
- 1998-10-23 AU AU10318/99A patent/AU1031899A/en not_active Abandoned
- 1998-10-23 BR BR9806724-9A patent/BR9806724A/pt not_active Application Discontinuation
- 1998-10-23 ES ES98952738T patent/ES2201544T3/es not_active Expired - Lifetime
- 1998-10-23 EP EP98952738A patent/EP0948549B1/en not_active Expired - Lifetime
- 1998-10-23 CA CA002276173A patent/CA2276173A1/en not_active Abandoned
- 1998-10-23 HU HU0001325A patent/HUP0001325A3/hu unknown
- 1998-10-23 WO PCT/EP1998/006732 patent/WO1999021899A1/en not_active Ceased
- 1998-10-28 MY MYPI98004911A patent/MY133201A/en unknown
- 1998-10-29 AR ARP980105418A patent/AR017401A1/es unknown
-
1999
- 1999-06-28 NO NO993205A patent/NO993205L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA989696B (en) | 1999-04-29 |
| EP0948549B1 (en) | 2003-06-18 |
| IL130479A0 (en) | 2000-06-01 |
| WO1999021899A1 (en) | 1999-05-06 |
| CN1248270A (zh) | 2000-03-22 |
| CN1116314C (zh) | 2003-07-30 |
| KR20000069756A (ko) | 2000-11-25 |
| DE69815657T2 (de) | 2004-04-29 |
| HUP0001325A2 (hu) | 2000-08-28 |
| EP0948549A2 (en) | 1999-10-13 |
| ID22020A (id) | 1999-08-26 |
| MY133201A (en) | 2007-10-31 |
| JP4383549B2 (ja) | 2009-12-16 |
| US6559252B1 (en) | 2003-05-06 |
| NO993205D0 (no) | 1999-06-28 |
| ES2201544T3 (es) | 2004-03-16 |
| DE69815657D1 (de) | 2003-07-24 |
| HUP0001325A3 (en) | 2002-02-28 |
| NO993205L (no) | 1999-06-28 |
| AR017401A1 (es) | 2001-09-05 |
| BR9806724A (pt) | 2000-04-04 |
| JP2001507401A (ja) | 2001-06-05 |
| AU1031899A (en) | 1999-05-17 |
| PL334339A1 (en) | 2000-02-28 |
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