CA2087578C - Preparing catalyst for olefin polymerization - Google Patents

Preparing catalyst for olefin polymerization

Info

Publication number
CA2087578C
CA2087578C CA002087578A CA2087578A CA2087578C CA 2087578 C CA2087578 C CA 2087578C CA 002087578 A CA002087578 A CA 002087578A CA 2087578 A CA2087578 A CA 2087578A CA 2087578 C CA2087578 C CA 2087578C
Authority
CA
Canada
Prior art keywords
process according
chromium
catalyst system
compound
pyrrole
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA002087578A
Other languages
English (en)
French (fr)
Other versions
CA2087578A1 (en
Inventor
William Kevin Reagen
Jeffrey Willis Freeman
Brian Keith Conroy
Ted Matthew Pettijohn
Elizabeth Ann Benham
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Phillips Petroleum Co
Original Assignee
Phillips Petroleum Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=37075872&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA2087578(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Phillips Petroleum Co filed Critical Phillips Petroleum Co
Priority to CA002087578A priority Critical patent/CA2087578C/en
Priority to AU31932/93A priority patent/AU650808B1/en
Priority to DK93101111T priority patent/DK0608447T3/da
Priority to ES93101111T priority patent/ES2161699T5/es
Priority to AT93101111T priority patent/ATE207084T1/de
Priority to EP93101111A priority patent/EP0608447B2/en
Priority to DE69330943T priority patent/DE69330943T3/de
Priority to CZ199388A priority patent/CZ287405B6/cs
Priority to NO930340A priority patent/NO301172B1/no
Priority to JP01897293A priority patent/JP3188335B2/ja
Priority to SA93140175A priority patent/SA93140175B1/ar
Publication of CA2087578A1 publication Critical patent/CA2087578A1/en
Priority to CN94114811A priority patent/CN1064367C/zh
Publication of CA2087578C publication Critical patent/CA2087578C/en
Application granted granted Critical
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/30Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/10Polymerisation reactions involving at least dual use catalysts, e.g. for both oligomerisation and polymerisation
    • B01J2231/12Olefin polymerisation or copolymerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20Olefin oligomerisation or telomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Polymerization Catalysts (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Polyethers (AREA)
CA002087578A 1993-01-19 1993-01-19 Preparing catalyst for olefin polymerization Expired - Lifetime CA2087578C (en)

Priority Applications (12)

Application Number Priority Date Filing Date Title
CA002087578A CA2087578C (en) 1993-01-19 1993-01-19 Preparing catalyst for olefin polymerization
AU31932/93A AU650808B1 (en) 1993-01-19 1993-01-21 Preparing catalyst for olefin polymerization
DE69330943T DE69330943T3 (de) 1993-01-19 1993-01-26 Verfahren zur Herstellung eines Olefinpolymerisationskatalysator
ES93101111T ES2161699T5 (es) 1993-01-19 1993-01-26 Procedimiento para la preparacion de un catalizador para polimerizar olefinas.
AT93101111T ATE207084T1 (de) 1993-01-19 1993-01-26 Verfahren zur herstellung eines olefinpolymerisationskatalysator
EP93101111A EP0608447B2 (en) 1993-01-19 1993-01-26 Process for the preparation of a catalyst for olefin polymerization
DK93101111T DK0608447T3 (da) 1993-01-19 1993-01-26 Fremgangsmåde til fremstilling af en katalysator til olefinpolymerisation
CZ199388A CZ287405B6 (en) 1993-01-19 1993-01-27 Process for preparing catalyst system and use thereof
NO930340A NO301172B1 (no) 1993-01-19 1993-02-01 Fremstilling av et katalysatorsystem og anvendelse av dette ved trimerisering, oligomerisering eller polymerisering av olefiner
JP01897293A JP3188335B2 (ja) 1993-01-19 1993-02-05 触媒系の製造法及びオレフィンを三量体化、オリゴマー化及び/又は重合する方法
SA93140175A SA93140175B1 (ar) 1993-01-19 1993-09-13 تحضير عامل حفاز لبلمرة أوليفين olefin
CN94114811A CN1064367C (zh) 1993-01-19 1994-07-25 制备催化剂体系的方法

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
CA002087578A CA2087578C (en) 1993-01-19 1993-01-19 Preparing catalyst for olefin polymerization
AU31932/93A AU650808B1 (en) 1993-01-19 1993-01-21 Preparing catalyst for olefin polymerization
EP93101111A EP0608447B2 (en) 1993-01-19 1993-01-26 Process for the preparation of a catalyst for olefin polymerization
CZ199388A CZ287405B6 (en) 1993-01-19 1993-01-27 Process for preparing catalyst system and use thereof
NO930340A NO301172B1 (no) 1993-01-19 1993-02-01 Fremstilling av et katalysatorsystem og anvendelse av dette ved trimerisering, oligomerisering eller polymerisering av olefiner
JP01897293A JP3188335B2 (ja) 1993-01-19 1993-02-05 触媒系の製造法及びオレフィンを三量体化、オリゴマー化及び/又は重合する方法
CN94114811A CN1064367C (zh) 1993-01-19 1994-07-25 制备催化剂体系的方法

Publications (2)

Publication Number Publication Date
CA2087578A1 CA2087578A1 (en) 1994-07-20
CA2087578C true CA2087578C (en) 1998-10-27

Family

ID=37075872

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002087578A Expired - Lifetime CA2087578C (en) 1993-01-19 1993-01-19 Preparing catalyst for olefin polymerization

Country Status (12)

Country Link
EP (1) EP0608447B2 (ja)
JP (1) JP3188335B2 (ja)
CN (1) CN1064367C (ja)
AT (1) ATE207084T1 (ja)
AU (1) AU650808B1 (ja)
CA (1) CA2087578C (ja)
CZ (1) CZ287405B6 (ja)
DE (1) DE69330943T3 (ja)
DK (1) DK0608447T3 (ja)
ES (1) ES2161699T5 (ja)
NO (1) NO301172B1 (ja)
SA (1) SA93140175B1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7982085B2 (en) 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US8003839B2 (en) 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
US8076524B2 (en) 2006-02-03 2011-12-13 Exxonmobil Chemical Patents Inc. Process for generating alpha olefin comonomers
US8404915B2 (en) 2006-08-30 2013-03-26 Exxonmobil Chemical Patents Inc. Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations

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US5193004A (en) * 1990-12-03 1993-03-09 The Trustees Of Columbia University In The City Of New York Systems and methods for coding even fields of interlaced video sequences
TW354300B (en) * 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
TW279167B (ja) * 1993-03-12 1996-06-21 Sumitomo Chemical Co
MY115177A (en) * 1994-06-21 2003-04-30 Mitsubishi Chem Corp Process for producing (alpha) -olefin oligomers
JP3613642B2 (ja) 1994-09-05 2005-01-26 住友化学株式会社 1−ヘキセンの製造方法
KR100414008B1 (ko) * 1995-03-02 2004-04-29 미쓰비시 가가꾸 가부시키가이샤 α-올레핀올리고머의제조방법
JPH0912627A (ja) * 1995-06-28 1997-01-14 Mitsubishi Chem Corp α−オレフィン低重合体の製造方法
JPH09143228A (ja) * 1995-11-22 1997-06-03 Sumitomo Chem Co Ltd エチレン−α−オレフィン共重合体の製造方法
US5859303A (en) * 1995-12-18 1999-01-12 Phillips Petroleum Company Olefin production
JP2007045837A (ja) * 1996-02-02 2007-02-22 Mitsubishi Chemicals Corp α−オレフィン低重合体の製造方法
JP3823429B2 (ja) * 1996-06-28 2006-09-20 住友化学株式会社 触媒系及びオレフィンの反応方法
DE50010401D1 (de) 1999-03-29 2005-06-30 Basell Polyolefine Gmbh Verfahren zur polymerisation von olefinen
DE19935592A1 (de) 1999-08-02 2001-02-08 Elenac Gmbh Imidochromverbindungen in Katalysatorsystemen für die Olefinpolymerisation
WO2002066405A1 (en) * 2001-02-22 2002-08-29 Stichting Dutch Polymer Institute Catalyst system for the trimerisation of olefins
WO2002066404A1 (en) * 2001-02-22 2002-08-29 Stichting Dutch Polymer Institute Catalyst system for the trimerisation of olefins
US20050187418A1 (en) 2004-02-19 2005-08-25 Small Brooke L. Olefin oligomerization
US7384886B2 (en) 2004-02-20 2008-06-10 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20050187098A1 (en) 2004-02-20 2005-08-25 Knudsen Ronald D. Methods of preparation of an olefin oligomerization catalyst
BRPI0507900B1 (pt) 2004-02-20 2014-12-16 Chevron Phillips Chemical Co Métodos de fabricação de um catalisador para uso em oligomerização de uma olefina
US9550841B2 (en) 2004-02-20 2017-01-24 Chevron Phillips Chemical Company Lp Methods of preparation of an olefin oligomerization catalyst
US20070043181A1 (en) 2005-08-19 2007-02-22 Knudsen Ronald D Methods of preparation of an olefin oligomerization catalyst
JP2006117642A (ja) * 2004-09-22 2006-05-11 Nippon Polyethylene Kk オレフィン低重合体ならびにオレフィン共重合体の製造方法
WO2008081644A1 (ja) * 2006-12-28 2008-07-10 Mitsubishi Chemical Corporation α-オレフィン低重合体の製造方法及びピロール化合物の保管方法
US8629280B2 (en) 2007-01-08 2014-01-14 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine ether catalysts
WO2008085658A1 (en) 2007-01-08 2008-07-17 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine thioether catalysts
US8138348B2 (en) 2007-01-08 2012-03-20 Exxonmobil Chemical Patents Inc. Methods for oligomerizing olefins with chromium pyridine mono-oxazoline catalysts
US7902415B2 (en) 2007-12-21 2011-03-08 Chevron Phillips Chemical Company Lp Processes for dimerizing or isomerizing olefins
BRPI0921636B1 (pt) * 2008-10-31 2021-09-21 Chevron Phillips Chemical Company Lp Composições de precursores de metal e diluentes olefínicos
US8471085B2 (en) 2008-10-31 2013-06-25 Chevron Phillips Chemical Company Lp Oligomerization catalyst system and process for oligomerizing olefins
CN102107146B (zh) 2009-12-29 2013-10-16 中国石油天然气股份有限公司 一种用于乙烯三聚合成己烯-1的催化剂及其应用
RU2430116C1 (ru) * 2010-01-29 2011-09-27 Закрытое Акционерное Общество "Сибур Холдинг" Способ полимеризации и сополимеризации олефиновых олигомеров
CN104926589A (zh) * 2010-03-26 2015-09-23 三菱化学株式会社 α-烯烃低聚物的制造方法
WO2012045426A1 (en) * 2010-10-07 2012-04-12 Saudi Basic Industries Corporation Process for polymerisation of ethylene
CN102464545A (zh) 2010-11-11 2012-05-23 中国石油天然气股份有限公司 一种乙烯齐聚制备1-辛烯的方法
CN102558107B (zh) * 2010-12-21 2015-04-29 中国石油化工股份有限公司 制备三(四氢呋喃)三卤化铬的方法及该方法在制备烯烃齐聚用催化剂中的应用
US9586872B2 (en) 2011-12-30 2017-03-07 Chevron Phillips Chemical Company Lp Olefin oligomerization methods
US9133079B2 (en) 2012-01-13 2015-09-15 Siluria Technologies, Inc. Process for separating hydrocarbon compounds
CA2874526C (en) 2012-05-24 2022-01-18 Siluria Technologies, Inc. Oxidative coupling of methane systems and methods
US9969660B2 (en) 2012-07-09 2018-05-15 Siluria Technologies, Inc. Natural gas processing and systems
WO2014089479A1 (en) 2012-12-07 2014-06-12 Siluria Technologies, Inc. Integrated processes and systems for conversion of methane to multiple higher hydrocarbon products
BR112015020451A2 (pt) 2013-02-27 2017-07-18 Mitsui Chemicals Inc catalisador para multimerização de olefina e método para produzir multímero de olefina na presença de um catalisador para multimerização de olefina
US10047020B2 (en) 2013-11-27 2018-08-14 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
WO2015105911A1 (en) 2014-01-08 2015-07-16 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
US10377682B2 (en) 2014-01-09 2019-08-13 Siluria Technologies, Inc. Reactors and systems for oxidative coupling of methane
US9701597B2 (en) 2014-01-09 2017-07-11 Siluria Technologies, Inc. Oxidative coupling of methane implementations for olefin production
US9175109B1 (en) 2014-05-20 2015-11-03 Chevron Phillips Chemical Company Lp Oligomerization processes and polymer compositions produced therefrom
US9505675B2 (en) 2015-02-09 2016-11-29 Chevron Phillips Chemical Company Lp Deactivation of a process by-product
US9334204B1 (en) 2015-03-17 2016-05-10 Siluria Technologies, Inc. Efficient oxidative coupling of methane processes and systems
US10793490B2 (en) 2015-03-17 2020-10-06 Lummus Technology Llc Oxidative coupling of methane methods and systems
US9328297B1 (en) 2015-06-16 2016-05-03 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
WO2016205411A2 (en) 2015-06-16 2016-12-22 Siluria Technologies, Inc. Ethylene-to-liquids systems and methods
WO2017010998A1 (en) 2015-07-14 2017-01-19 Chevron Phillips Chemical Company Lp Olefin compositions
US10513473B2 (en) 2015-09-18 2019-12-24 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
US10519077B2 (en) 2015-09-18 2019-12-31 Chevron Phillips Chemical Company Lp Ethylene oligomerization/trimerization/tetramerization reactor
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US9944573B2 (en) 2016-04-13 2018-04-17 Siluria Technologies, Inc. Oxidative coupling of methane for olefin production
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US20180169561A1 (en) 2016-12-19 2018-06-21 Siluria Technologies, Inc. Methods and systems for performing chemical separations
US10407358B2 (en) * 2017-03-14 2019-09-10 Saudi Arabian Oil Company Process for ethylene oligomerization to produce alpha-olefins
JP2020521811A (ja) 2017-05-23 2020-07-27 ラマス テクノロジー リミテッド ライアビリティ カンパニー メタン酸化カップリングプロセスの統合
KR20200051583A (ko) 2017-07-07 2020-05-13 루머스 테크놀로지 엘엘씨 메탄의 산화적 커플링를 위한 시스템 및 방법
CN110668908A (zh) * 2019-09-09 2020-01-10 天津科技大学 一种制备聚α-烯烃合成油的催化剂及方法
FR3113054B1 (fr) 2020-07-30 2022-11-04 Ifp Energies Now Procede d’oligomerisation d’ethylene comprenant la preparation in situ de la composition catalytique
FR3112969B1 (fr) 2020-07-30 2022-08-05 Ifp Energies Now Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1
CN115501914A (zh) * 2022-09-22 2022-12-23 中化泉州石化有限公司 一种含解聚剂的乙烯三聚催化剂及其应用

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7982085B2 (en) 2006-02-03 2011-07-19 Exxonmobil Chemical Patents Inc. In-line process for generating comonomer
US8003839B2 (en) 2006-02-03 2011-08-23 Exxonmobil Chemical Patents Inc. Process for generating linear apha olefin comonomers
US8076524B2 (en) 2006-02-03 2011-12-13 Exxonmobil Chemical Patents Inc. Process for generating alpha olefin comonomers
US8404915B2 (en) 2006-08-30 2013-03-26 Exxonmobil Chemical Patents Inc. Phosphine ligand-metal compositions, complexes, and catalysts for ethylene trimerizations

Also Published As

Publication number Publication date
ES2161699T5 (es) 2007-11-01
EP0608447B2 (en) 2007-03-14
DK0608447T3 (da) 2002-02-11
CA2087578A1 (en) 1994-07-20
ATE207084T1 (de) 2001-11-15
DE69330943T2 (de) 2002-04-11
JP3188335B2 (ja) 2001-07-16
CZ8893A3 (en) 1994-08-17
AU650808B1 (en) 1994-06-30
CN1115766A (zh) 1996-01-31
JPH06239920A (ja) 1994-08-30
CN1064367C (zh) 2001-04-11
NO930340L (no) 1994-08-02
DE69330943D1 (de) 2001-11-22
NO301172B1 (no) 1997-09-22
SA93140175B1 (ar) 2006-07-30
DE69330943T3 (de) 2007-10-18
CZ287405B6 (en) 2000-11-15
EP0608447A1 (en) 1994-08-03
EP0608447B1 (en) 2001-10-17
ES2161699T3 (es) 2001-12-16
NO930340D0 (no) 1993-02-01

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