FR3112969B1 - Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1 - Google Patents

Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1 Download PDF

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Publication number
FR3112969B1
FR3112969B1 FR2008091A FR2008091A FR3112969B1 FR 3112969 B1 FR3112969 B1 FR 3112969B1 FR 2008091 A FR2008091 A FR 2008091A FR 2008091 A FR2008091 A FR 2008091A FR 3112969 B1 FR3112969 B1 FR 3112969B1
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France
Prior art keywords
ethylene
hexene
chromium
trimerization
composition based
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Active
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FR2008091A
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English (en)
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FR3112969A1 (fr
Inventor
Lionel Magna
Typhène Michel
Pierre-Alain Breuil
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IFP Energies Nouvelles IFPEN
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IFP Energies Nouvelles IFPEN
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Priority to FR2008091A priority Critical patent/FR3112969B1/fr
Priority to PCT/EP2021/069496 priority patent/WO2022023027A1/fr
Publication of FR3112969A1 publication Critical patent/FR3112969A1/fr
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
    • B01J31/2208—Oxygen, e.g. acetylacetonates
    • B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0204—Ethers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La présente invention concerne une nouvelle composition catalytique à base de chrome et son utilisation pour l’oligomérisation d’éthylène, en particulier pour la trimérisation sélective de l’éthylène en hexène-1.
FR2008091A 2020-07-30 2020-07-30 Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1 Active FR3112969B1 (fr)

Priority Applications (2)

Application Number Priority Date Filing Date Title
FR2008091A FR3112969B1 (fr) 2020-07-30 2020-07-30 Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1
PCT/EP2021/069496 WO2022023027A1 (fr) 2020-07-30 2021-07-13 Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l'ethylene en hexene-1

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR2008091 2020-07-30
FR2008091A FR3112969B1 (fr) 2020-07-30 2020-07-30 Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1

Publications (2)

Publication Number Publication Date
FR3112969A1 FR3112969A1 (fr) 2022-02-04
FR3112969B1 true FR3112969B1 (fr) 2022-08-05

Family

ID=74045548

Family Applications (1)

Application Number Title Priority Date Filing Date
FR2008091A Active FR3112969B1 (fr) 2020-07-30 2020-07-30 Nouvelle composition catalytique a base de chrome et procede associe pour la trimerisation de l’ethylene en hexene-1

Country Status (2)

Country Link
FR (1) FR3112969B1 (fr)
WO (1) WO2022023027A1 (fr)

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5198563A (en) 1989-08-10 1993-03-30 Phillips Petroleum Company Chromium compounds and uses thereof
US5438027A (en) 1991-12-13 1995-08-01 Phillips Petroleum Company Chromium compounds and uses thereof
CA2087578C (fr) 1993-01-19 1998-10-27 William Kevin Reagen Methode de preparation d'un catalyseur pour la polymerisation d'olefines
TW354300B (en) 1993-02-17 1999-03-11 Mitsubishi Chem Corp Process for producing <alpha>-olefin oligomers
TW279167B (fr) 1993-03-12 1996-06-21 Sumitomo Chemical Co
US5543375A (en) 1994-02-18 1996-08-06 Phillips Petroleum Company Olefin production
US20010053742A1 (en) 1998-12-18 2001-12-20 Ronald D. Knudsen Catalyst and processes for olefin trimerization
FR2802833B1 (fr) * 1999-12-24 2002-05-10 Inst Francais Du Petrole Composition catalytique et procede pour l'oligomerisation de l'ethylene, en particulier en hexene-1
US6455648B1 (en) 1999-12-29 2002-09-24 Chevron Phillips Chemical Company Lp Olefin production
AU2002306188A1 (en) * 2001-04-12 2002-10-28 Sasol Technology (Pty) Ltd Oligomerisation process and catalyst system
WO2003053891A1 (fr) * 2001-12-20 2003-07-03 Sasol Technology (Pty) Ltd. Trimerisation et oligomerisation d'olefines au moyen d'un catalyseur a base de chrome
CA2740217C (fr) * 2008-10-31 2017-03-28 Chevron Phillips Chemical Company Lp Systeme et methode de desactivation et d'etanchement d'un catalyseur d'oligomerisation
EP2684857A1 (fr) * 2012-07-10 2014-01-15 Saudi Basic Industries Corporation Procédé d'oligomérisation de l'éthylène
DK3237363T3 (da) * 2014-12-23 2019-06-24 Sibur Holding Public Joint Stock Co Fremgangsmåder til at fremstille oligomerer af en olefin

Also Published As

Publication number Publication date
WO2022023027A1 (fr) 2022-02-03
FR3112969A1 (fr) 2022-02-04

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