CA1230795A - Borate solution soluble polyvinyl alcohol films - Google Patents
Borate solution soluble polyvinyl alcohol filmsInfo
- Publication number
- CA1230795A CA1230795A CA000414399A CA414399A CA1230795A CA 1230795 A CA1230795 A CA 1230795A CA 000414399 A CA000414399 A CA 000414399A CA 414399 A CA414399 A CA 414399A CA 1230795 A CA1230795 A CA 1230795A
- Authority
- CA
- Canada
- Prior art keywords
- polyvinyl alcohol
- borate
- film
- molecular weight
- set forth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000004372 Polyvinyl alcohol Substances 0.000 title claims abstract description 69
- 229920002451 polyvinyl alcohol Polymers 0.000 title claims abstract description 68
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 150000001875 compounds Chemical class 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 230000027455 binding Effects 0.000 claims abstract description 8
- 238000009739 binding Methods 0.000 claims abstract description 8
- 239000000243 solution Substances 0.000 claims description 26
- 239000000654 additive Substances 0.000 claims description 22
- 238000000034 method Methods 0.000 claims description 21
- 230000000996 additive effect Effects 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 10
- 239000004014 plasticizer Substances 0.000 claims description 7
- FBPFZTCFMRRESA-KVTDHHQDSA-N D-Mannitol Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-KVTDHHQDSA-N 0.000 claims description 6
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 claims description 6
- 229930195725 Mannitol Natural products 0.000 claims description 6
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 6
- 239000000594 mannitol Substances 0.000 claims description 6
- 235000010355 mannitol Nutrition 0.000 claims description 6
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 5
- 239000005715 Fructose Substances 0.000 claims description 5
- 229930091371 Fructose Natural products 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000000600 sorbitol Substances 0.000 claims description 5
- UNXHWFMMPAWVPI-QWWZWVQMSA-N D-Threitol Natural products OC[C@@H](O)[C@H](O)CO UNXHWFMMPAWVPI-QWWZWVQMSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 claims description 3
- LKDRXBCSQODPBY-AMVSKUEXSA-N L-(-)-Sorbose Chemical compound OCC1(O)OC[C@H](O)[C@@H](O)[C@@H]1O LKDRXBCSQODPBY-AMVSKUEXSA-N 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 claims description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 3
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims 6
- 229940068984 polyvinyl alcohol Drugs 0.000 claims 6
- 239000002904 solvent Substances 0.000 claims 2
- 101000583616 Homo sapiens Polyhomeotic-like protein 2 Proteins 0.000 claims 1
- 102100030903 Polyhomeotic-like protein 2 Human genes 0.000 claims 1
- 239000002253 acid Substances 0.000 abstract description 14
- 238000010494 dissociation reaction Methods 0.000 abstract description 3
- 230000005593 dissociations Effects 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 description 10
- 239000011347 resin Substances 0.000 description 9
- 229920005989 resin Polymers 0.000 description 9
- 239000002202 Polyethylene glycol Substances 0.000 description 7
- 229920001223 polyethylene glycol Polymers 0.000 description 7
- 239000011521 glass Substances 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 5
- 238000011156 evaluation Methods 0.000 description 5
- 229960002737 fructose Drugs 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 229920002125 Sokalan® Polymers 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000003599 detergent Substances 0.000 description 3
- 239000006185 dispersion Substances 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- 150000002440 hydroxy compounds Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229920000609 methyl cellulose Polymers 0.000 description 3
- 239000001923 methylcellulose Substances 0.000 description 3
- 235000010981 methylcellulose Nutrition 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- -1 borate ions Chemical class 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 238000003760 magnetic stirring Methods 0.000 description 2
- 239000004584 polyacrylic acid Substances 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- 239000004328 sodium tetraborate Substances 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 239000005711 Benzoic acid Substances 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 1
- XUJNEKJLAYXESH-REOHCLBHSA-N L-Cysteine Chemical compound SC[C@H](N)C(O)=O XUJNEKJLAYXESH-REOHCLBHSA-N 0.000 description 1
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 235000010233 benzoic acid Nutrition 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- XUJNEKJLAYXESH-UHFFFAOYSA-N cysteine Natural products SCC(N)C(O)=O XUJNEKJLAYXESH-UHFFFAOYSA-N 0.000 description 1
- 235000018417 cysteine Nutrition 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000002979 fabric softener Substances 0.000 description 1
- 235000013922 glutamic acid Nutrition 0.000 description 1
- 239000004220 glutamic acid Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910000403 monosodium phosphate Inorganic materials 0.000 description 1
- 235000019799 monosodium phosphate Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- IWZKICVEHNUQTL-UHFFFAOYSA-M potassium hydrogen phthalate Chemical compound [K+].OC(=O)C1=CC=CC=C1C([O-])=O IWZKICVEHNUQTL-UHFFFAOYSA-M 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
- C08J2329/02—Homopolymers or copolymers of unsaturated alcohols
- C08J2329/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
- Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000536542A CA1240231A (en) | 1981-11-10 | 1987-05-06 | Borate solution soluble polyvinyl alcohol films |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US31996681A | 1981-11-10 | 1981-11-10 | |
| US319,966 | 1981-11-10 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000536542A Division CA1240231A (en) | 1981-11-10 | 1987-05-06 | Borate solution soluble polyvinyl alcohol films |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1230795A true CA1230795A (en) | 1987-12-29 |
Family
ID=23244308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000414399A Expired CA1230795A (en) | 1981-11-10 | 1982-10-28 | Borate solution soluble polyvinyl alcohol films |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0079712B2 (en, 2012) |
| JP (1) | JPS5887145A (en, 2012) |
| AT (1) | ATE34999T1 (en, 2012) |
| AU (2) | AU565500B2 (en, 2012) |
| BR (1) | BR8206469A (en, 2012) |
| CA (1) | CA1230795A (en, 2012) |
| DE (1) | DE3278638D1 (en, 2012) |
| ES (1) | ES8401553A1 (en, 2012) |
| GR (1) | GR77732B (en, 2012) |
| MX (2) | MX165884B (en, 2012) |
Families Citing this family (35)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4743394A (en) * | 1984-03-23 | 1988-05-10 | Kaufmann Edward J | Concentrated non-phosphate detergent paste compositions |
| US5362413A (en) * | 1984-03-23 | 1994-11-08 | The Clorox Company | Low-temperature-effective detergent compositions and delivery systems therefor |
| DE3415880A1 (de) * | 1984-04-28 | 1985-10-31 | Henkel KGaA, 4000 Düsseldorf | Waschzusatz |
| DE3422055A1 (de) * | 1984-06-14 | 1985-12-19 | Henkel KGaA, 4000 Düsseldorf | Waschzusatz |
| JPS6157700A (ja) * | 1984-08-29 | 1986-03-24 | 花王株式会社 | 水溶性フイルムを用いた単位包装洗剤製品 |
| US4972017A (en) * | 1987-03-24 | 1990-11-20 | The Clorox Company | Rinse soluble polymer film composition for wash additives |
| US4801636A (en) * | 1987-03-24 | 1989-01-31 | The Clorox Company | Rinse soluble polymer film composition for wash additives |
| US4747976A (en) * | 1987-05-14 | 1988-05-31 | The Clorox Company | PVA films with nonhydrolyzable anionic comonomers for packaging detergents |
| US4885105A (en) * | 1987-05-14 | 1989-12-05 | The Clorox Company | Films from PVA modified with nonhydrolyzable anionic comonomers |
| GB8909253D0 (en) * | 1989-04-24 | 1989-06-07 | Unilever Plc | Packaged liquid cleaning product |
| FR2649403B1 (fr) * | 1989-07-05 | 1991-10-25 | Lenigen Norbert | Film d'alcool polyvinylique ayant des caracteristiques ameliorees de solubilite |
| GB2244220B (en) * | 1990-05-01 | 1994-10-12 | Courtaulds Films & Packaging | Packaging materials |
| ES2073302T3 (es) * | 1991-05-14 | 1995-08-01 | Ecolab Inc | Concentrado quimico en dos partes. |
| EP0524823B1 (en) * | 1991-07-26 | 1999-10-06 | Kureha Chemical Industry Co., Ltd. | A resin composition and food packaging materials formed therefrom |
| JP3561572B2 (ja) * | 1996-04-03 | 2004-09-02 | 信越ポリマー株式会社 | ポリビニルアルコール系樹脂組成物 |
| JP3609898B2 (ja) * | 1996-06-03 | 2005-01-12 | 株式会社クラレ | 薬剤包装用水溶性フィルム |
| JPH10324785A (ja) * | 1997-05-27 | 1998-12-08 | Kuraray Co Ltd | ビニルアルコール系重合体組成物 |
| DE69925712T2 (de) * | 1998-07-23 | 2006-03-23 | Kao Corporation | Wäscheartikel in tuchform |
| GB9906169D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
| GB9906176D0 (en) * | 1999-03-17 | 1999-05-12 | Unilever Plc | Process for producing a water soluble package |
| GB9906171D0 (en) | 1999-03-17 | 1999-05-12 | Unilever Plc | A process for producing a water soluble package |
| EP1272606A1 (en) | 2000-04-14 | 2003-01-08 | Unilever N.V. | Water soluble package and liquid contents thereof |
| AU2001270503B2 (en) | 2000-05-15 | 2004-04-01 | Unilever Plc | Liquid detergent composition |
| US6492312B1 (en) | 2001-03-16 | 2002-12-10 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Water soluble sachet with a dishwashing enhancing particle |
| GB0222964D0 (en) | 2002-10-03 | 2002-11-13 | Unilever Plc | Polymeric film for water soluble package |
| JP4056859B2 (ja) * | 2002-11-11 | 2008-03-05 | 日本合成化学工業株式会社 | 水溶性フィルム |
| WO2017043507A1 (ja) * | 2015-09-11 | 2017-03-16 | 日本合成化学工業株式会社 | 水溶性フィルムおよびそれを用いた薬剤包装体、並びに水溶性フィルムの製造方法 |
| PL3443030T3 (pl) | 2016-04-13 | 2022-10-10 | Monosol, Llc | Folia rozpuszczalna w wodzie, opakowania z folią oraz sposoby jej wytwarzania i stosowania |
| JP7133475B2 (ja) | 2016-06-13 | 2022-09-08 | モノソル リミテッド ライアビリティ カンパニー | 異なるフィルムの組み合わせから作製された水溶性単位用量物品 |
| US10899518B2 (en) | 2016-06-13 | 2021-01-26 | Monosol, Llc | Water-soluble packets |
| JP7059205B2 (ja) | 2016-06-13 | 2022-04-25 | モノソル リミテッド ライアビリティ カンパニー | 水溶性の密封強度を改善するための第１のフィルムおよび第２のフィルムの使用 |
| US10611988B2 (en) | 2017-03-16 | 2020-04-07 | The Procter & Gamble Company | Methods for making encapsulate-containing product compositions |
| US10385296B2 (en) | 2017-03-16 | 2019-08-20 | The Procter & Gamble Company | Methods for making encapsulate-containing product compositions |
| US10385297B2 (en) | 2017-03-16 | 2019-08-20 | The Procter & Gamble Company | Methods for making encapsulate-containing product compositions |
| JP7107970B2 (ja) * | 2017-05-31 | 2022-07-27 | ローム アンド ハース カンパニー | 自立型分散剤フィルム |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB927963A (en) * | 1961-01-06 | 1963-06-06 | Kurashiki Rayon Kk | Method of preventing water-soluble films of polyvinyl alcohol derivatives from adhering and non-sticky films made thereby |
| US3220991A (en) * | 1962-03-28 | 1965-11-30 | Monsanto Co | Heat stabilization of polyvinyl alcohol with aliphatic polycarboxylic acid |
| AU508381B2 (en) * | 1974-01-03 | 1980-03-20 | E. X. Dupont De Nemours and Company | Water soluble films |
| US4082678A (en) * | 1976-11-10 | 1978-04-04 | The Procter & Gamble Company | Fabric conditioning articles and process |
| DE2919886A1 (de) * | 1978-05-18 | 1979-11-22 | Unilease S A | Verfahren zur reinhaltung von verschmutzungsgefaehrdeten innen- und aussenoberflaechen |
| MX151028A (es) * | 1978-11-17 | 1984-09-11 | Unilever Nv | Mejoras en bolsa insoluble pero permeable al agua que tiene una capa protectora dispersable o soluble en agua,que contiene una composicion detergente en particulas |
-
1982
- 1982-10-28 CA CA000414399A patent/CA1230795A/en not_active Expired
- 1982-10-29 DE DE8282305772T patent/DE3278638D1/de not_active Expired
- 1982-10-29 AT AT82305772T patent/ATE34999T1/de not_active IP Right Cessation
- 1982-10-29 EP EP82305772A patent/EP0079712B2/en not_active Expired - Lifetime
- 1982-11-05 AU AU90215/82A patent/AU565500B2/en not_active Ceased
- 1982-11-09 BR BR8206469A patent/BR8206469A/pt not_active IP Right Cessation
- 1982-11-09 MX MX195102A patent/MX165884B/es unknown
- 1982-11-09 ES ES517586A patent/ES8401553A1/es not_active Expired
- 1982-11-09 JP JP57195410A patent/JPS5887145A/ja active Granted
- 1982-11-10 GR GR69776A patent/GR77732B/el unknown
-
1987
- 1987-01-19 AU AU67679/87A patent/AU597328B2/en not_active Ceased
-
1992
- 1992-11-03 MX MX9206308A patent/MX9206308A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| BR8206469A (pt) | 1983-09-27 |
| EP0079712B1 (en) | 1988-06-08 |
| ATE34999T1 (de) | 1988-06-15 |
| EP0079712B2 (en) | 1993-10-06 |
| GR77732B (en, 2012) | 1984-09-25 |
| JPH0370760B2 (en, 2012) | 1991-11-08 |
| JPS5887145A (ja) | 1983-05-24 |
| MX165884B (es) | 1992-12-07 |
| AU597328B2 (en) | 1990-05-31 |
| AU9021582A (en) | 1983-05-19 |
| MX9206308A (es) | 1994-05-31 |
| DE3278638D1 (en) | 1988-07-14 |
| ES517586A0 (es) | 1983-12-16 |
| EP0079712A1 (en) | 1983-05-25 |
| AU6767987A (en) | 1987-06-25 |
| AU565500B2 (en) | 1987-09-17 |
| ES8401553A1 (es) | 1983-12-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1230795A (en) | Borate solution soluble polyvinyl alcohol films | |
| US4626372A (en) | Borate solution soluble polyvinyl alcohol films | |
| US4828744A (en) | Borate solution soluble polyvinyl alcohol films | |
| US4608187A (en) | Rubber toughened polyvinyl alcohol film compositions | |
| DE3885507T2 (de) | Folien aus mit nicht hydrolysierbaren anionischen Comonomeren modifizierten PVA,die Additive enthalten. | |
| US3186869A (en) | Coated film for laundry package | |
| US4972017A (en) | Rinse soluble polymer film composition for wash additives | |
| EP0284334A2 (en) | Rinse soluble polymer film composition for wash additives | |
| CN100360590C (zh) | 包装非液体产品用的加有淀粉的聚乙烯醇共聚物膜及其制备方法 | |
| Saito | Salt effect on polymer solutions | |
| NZ335308A (en) | Detergent composition containing a granulated percarbonate | |
| PT95491A (pt) | Processo para a preparacao de uma composicao de limpeza liquida, espessada, estavel, contendo agente branqueador | |
| CN110343580A (zh) | 一种高含水量的单位剂量洗涤剂制品 | |
| JPH0374498A (ja) | チキソトロピー水性液状洗浄組成物、該組成物の製造方法及び汚れた食器の洗浄方法 | |
| CA1240231A (en) | Borate solution soluble polyvinyl alcohol films | |
| NO843789L (no) | Fylt termoplastmateriale. | |
| DE60314646T2 (de) | Gelförmiges textilwasch- und/oder vorbehandelungsmittel, das sich nach der abgab | |
| US4164478A (en) | Process for improving granular detergents | |
| KR890004443B1 (ko) | 수용성 고분자 중합체의 이분산성(易分散性) 조성물 | |
| JPS6197348A (ja) | 耐湿、防湿性に優れた水溶性フイルム | |
| JPH06262028A (ja) | 除湿剤組成物 | |
| HUE028946T2 (en) | Halogen-resistant composition | |
| US3257348A (en) | Polyvinyl alcohol composition with phosphate esters of ethoxylated alkyl phenols and polyoxyethylene aryl ether | |
| WO2022081503A1 (en) | Laundry detergent composition | |
| US5599473A (en) | Nitrogen-free rinse cycle fabric softeners based on microemulsions |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |