CA1138591A - Process for producing a silicone elastomer emulsion and use thereof - Google Patents
Process for producing a silicone elastomer emulsion and use thereofInfo
- Publication number
- CA1138591A CA1138591A CA000356097A CA356097A CA1138591A CA 1138591 A CA1138591 A CA 1138591A CA 000356097 A CA000356097 A CA 000356097A CA 356097 A CA356097 A CA 356097A CA 1138591 A CA1138591 A CA 1138591A
- Authority
- CA
- Canada
- Prior art keywords
- silicon
- latex
- bonded hydrogen
- emulsion
- radicals
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 54
- 238000000034 method Methods 0.000 title claims description 19
- 229920002379 silicone rubber Polymers 0.000 title claims description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims abstract description 70
- 229910052697 platinum Inorganic materials 0.000 claims abstract description 35
- 239000004816 latex Substances 0.000 claims abstract description 33
- 229920000126 latex Polymers 0.000 claims abstract description 33
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 30
- 239000003054 catalyst Substances 0.000 claims abstract description 27
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 19
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 17
- 239000000758 substrate Substances 0.000 claims abstract description 16
- 238000010438 heat treatment Methods 0.000 claims abstract description 15
- 238000000576 coating method Methods 0.000 claims abstract description 13
- 150000003961 organosilicon compounds Chemical class 0.000 claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 9
- 239000008119 colloidal silica Substances 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 230000001804 emulsifying effect Effects 0.000 claims abstract description 7
- 239000004753 textile Substances 0.000 claims abstract description 3
- -1 organosiloxane compound Chemical class 0.000 claims description 34
- 239000000203 mixture Substances 0.000 claims description 21
- 238000001704 evaporation Methods 0.000 claims description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 10
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- ORGHESHFQPYLAO-UHFFFAOYSA-N vinyl radical Chemical group C=[CH] ORGHESHFQPYLAO-UHFFFAOYSA-N 0.000 claims description 4
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 239000013536 elastomeric material Substances 0.000 claims 2
- 150000003377 silicon compounds Chemical class 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 5
- 229920001971 elastomer Polymers 0.000 abstract 1
- 239000000806 elastomer Substances 0.000 abstract 1
- 238000009413 insulation Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 11
- 239000003112 inhibitor Substances 0.000 description 9
- 230000008020 evaporation Effects 0.000 description 7
- 239000000377 silicon dioxide Substances 0.000 description 7
- 239000008346 aqueous phase Substances 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000003860 storage Methods 0.000 description 6
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 5
- 229920000642 polymer Polymers 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 239000003085 diluting agent Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 239000012736 aqueous medium Substances 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- 239000004971 Cross linker Substances 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000003060 catalysis inhibitor Substances 0.000 description 2
- 229910052681 coesite Inorganic materials 0.000 description 2
- 229910052906 cristobalite Inorganic materials 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 239000003995 emulsifying agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 125000005375 organosiloxane group Chemical group 0.000 description 2
- 239000000123 paper Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 235000012239 silicon dioxide Nutrition 0.000 description 2
- 229910052682 stishovite Inorganic materials 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 229910052905 tridymite Inorganic materials 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 235000021438 curry Nutrition 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 229920005645 diorganopolysiloxane polymer Polymers 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000011953 free-radical catalyst Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920006136 organohydrogenpolysiloxane Polymers 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229920001558 organosilicon polymer Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001843 polymethylhydrosiloxane Chemical group 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
- C08J3/03—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques in aqueous media
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2383/00—Characterised by the use of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen, or carbon only; Derivatives of such polymers
- C08J2383/04—Polysiloxanes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31652—Of asbestos
- Y10T428/31663—As siloxane, silicone or silane
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71,459 | 1979-08-31 | ||
| US06/071,459 US4248751A (en) | 1979-08-31 | 1979-08-31 | Process for producing a silicone elastomer emulsion and use thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1138591A true CA1138591A (en) | 1982-12-28 |
Family
ID=22101461
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000356097A Expired CA1138591A (en) | 1979-08-31 | 1980-07-14 | Process for producing a silicone elastomer emulsion and use thereof |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4248751A (enExample) |
| JP (1) | JPS5817226B2 (enExample) |
| AU (1) | AU531812B2 (enExample) |
| BE (1) | BE885000A (enExample) |
| BR (1) | BR8005499A (enExample) |
| CA (1) | CA1138591A (enExample) |
| DE (1) | DE3031157C2 (enExample) |
| FR (1) | FR2464275A1 (enExample) |
| GB (1) | GB2057475B (enExample) |
| IT (1) | IT1141024B (enExample) |
| MX (1) | MX154979A (enExample) |
| NL (1) | NL190019C (enExample) |
| SE (1) | SE450125B (enExample) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3040758C2 (de) * | 1980-10-29 | 1986-10-16 | Wacker-Chemie GmbH, 8000 München | Verfahren zum Wasserabweisendmachen von Fasern |
| US4348431A (en) * | 1981-02-19 | 1982-09-07 | General Electric Company | Process for coating plastic films |
| US4360566A (en) * | 1981-03-05 | 1982-11-23 | Toray Silicone Co., Ltd. | Curable organopolysiloxane composition for heat fixing rolls |
| DE3304100A1 (de) * | 1983-02-08 | 1983-09-01 | Martin 7500 Karlsruhe Sackmann | Silikonisierte textilien |
| JPS6096650A (ja) * | 1983-10-31 | 1985-05-30 | Toray Silicone Co Ltd | シリコ−ン水性エマルジヨン組成物の製造方法 |
| US4584341A (en) * | 1984-06-26 | 1986-04-22 | Dow Corning Corporation | Emulsions of crosslinked polydiorganosiloxanes |
| US4567231A (en) * | 1984-06-26 | 1986-01-28 | Dow Corning Corporation | Emulsions of reinforced polydiorganosiloxane latex |
| US4568718A (en) * | 1984-06-26 | 1986-02-04 | Dow Corning Corporation | Polydiorganosiloxane latex |
| CA1271398C (en) * | 1985-06-28 | 1990-07-10 | DIAGNOSTIC KIT | |
| IL78560A0 (en) | 1985-06-28 | 1986-08-31 | Miles Lab | Electrochemical sensor and membrane therefor |
| JPH0651863B2 (ja) * | 1986-03-19 | 1994-07-06 | 東レ・ダウコ−ニング・シリコ−ン株式会社 | シリコ−ン水性エマルジヨン被覆材 |
| EP0242069A3 (en) * | 1986-04-14 | 1988-08-03 | Dow Corning Corporation | Semipermeable composite membranes produced from silicone water based emulsions applied to porous substrates |
| JPS62243621A (ja) * | 1986-04-17 | 1987-10-24 | Toray Silicone Co Ltd | シリコ−ンゴム粒状物の製造方法 |
| EP0314848B1 (en) * | 1987-11-05 | 1991-03-13 | Toray Silicone Company, Ltd. | A method for producing silicone rubber powder |
| JPH0653863B2 (ja) * | 1987-06-12 | 1994-07-20 | 東レ・ダウコーニング・シリコーン株式会社 | 潤滑・離型剤 |
| US5126072A (en) * | 1987-10-21 | 1992-06-30 | General Electric Company | Stable, two package water emulsions of silicone hydride fluids |
| US4962153A (en) * | 1987-12-09 | 1990-10-09 | Dow Corning Corporation | Precured silicone emulsion |
| US5026768A (en) * | 1987-12-09 | 1991-06-25 | Dow Corning Corporation | Method of producing silicone emulsion |
| US4978710A (en) * | 1987-12-09 | 1990-12-18 | Dow Corning Corporation | Method of producing silicone emulsion |
| CA1328324C (en) * | 1987-12-09 | 1994-04-05 | Dow Corning Corporation | Precured silicone emulsion |
| US5026769A (en) * | 1987-12-09 | 1991-06-25 | Dow Corning Corporation | Method of producing silicone emulsion |
| FR2624874B1 (fr) * | 1987-12-18 | 1990-06-08 | Dow Corning Sa | Composition gelifiable a base d'organosiloxanes, gel produit a partir de cette composition, et pansement et prothese contenant ce gel |
| MX169040B (es) * | 1988-07-07 | 1993-06-17 | Rohm & Haas | Copolimeros estables de emulsion acuosa con funcionalidad de siloxano |
| JPH02180964A (ja) * | 1989-01-06 | 1990-07-13 | Shin Etsu Chem Co Ltd | 剥離用シリコーン組成物およびこの塗工物品 |
| FR2641789B1 (fr) * | 1989-01-19 | 1991-03-22 | Rhone Poulenc Chimie | Procede de preparation de particules non collantes a base d'une composition organopolysiloxane reticulee par des reactions de polyaddition |
| US5089537A (en) * | 1989-05-22 | 1992-02-18 | Dow Corning Corporation | UV curable silicone emulsions |
| US5001186A (en) * | 1989-09-11 | 1991-03-19 | Dow Corning Corporation | Method of producing silicone emulsion |
| DE4004946A1 (de) * | 1990-02-16 | 1991-08-22 | Wacker Chemie Gmbh | Feinteilige organopolysiloxanemulsionen |
| JP3059776B2 (ja) * | 1991-05-27 | 2000-07-04 | 東レ・ダウコーニング・シリコーン株式会社 | シリコーンゴム粉状物の製造方法 |
| US5371139A (en) * | 1991-06-21 | 1994-12-06 | Dow Corning Toray Silicone Co., Ltd. | Silicone rubber microsuspension and method for its preparation |
| US6730380B2 (en) | 1996-02-20 | 2004-05-04 | Safeskin Corp. | Readily-donned elastomeric articles |
| US5910535A (en) * | 1996-05-03 | 1999-06-08 | Decora, Incorporated | Water based coating composition having sacrificial layer for stain removal |
| US5811487A (en) * | 1996-12-16 | 1998-09-22 | Dow Corning Corporation | Thickening silicones with elastomeric silicone polyethers |
| GB9708182D0 (en) * | 1997-04-23 | 1997-06-11 | Dow Corning Sa | A method of making silicone in water emulsions |
| JP4823403B2 (ja) * | 1997-09-30 | 2011-11-24 | 東レ・ダウコーニング株式会社 | ヒドロシリル化反応用触媒、およびヒドロシリル化反応方法 |
| US7582343B1 (en) | 1999-06-15 | 2009-09-01 | Kimberly-Clark Worldwide, Inc. | Elastomeric article with fine colloidal silica surface treatment, and its preparation |
| FR2813608B1 (fr) * | 2000-09-01 | 2004-08-27 | Rhodia Chimie Sa | Procede de lutte contre l'apparition de brouillard lors de l'enduction de supports flexibles avec une composition silicone liquide reticulable, dans un dispositif a cylindres |
| US6479583B2 (en) | 2001-01-08 | 2002-11-12 | Dow Corning Corporation | Polymerization of silicone microemulsions |
| US20030118761A1 (en) | 2001-12-21 | 2003-06-26 | Kimberly-Clark Worldwide, Inc. | Elastomeric articles having improved chemical resistance |
| US20030226191A1 (en) * | 2002-06-03 | 2003-12-11 | Kimberly-Clark Worldwide, Inc. | Elastomeric gloves having improved gripping characteristics |
| US20030221240A1 (en) * | 2002-06-03 | 2003-12-04 | Kister Mary Elizabeth | Glove having improved donning characteristics |
| US6875391B2 (en) * | 2002-06-03 | 2005-04-05 | Kimberly-Clark Worldwide, Inc. | Method of making a glove having improved donning characteristics |
| BR0313710A (pt) * | 2002-08-30 | 2005-06-28 | Dow Corning Toray Silicone | Suspensões aquosas de partìculas de silicone encadeadas, emulsões aquosas de óleo que contém partìculas de silicone encadeadas e matérias-primas para cosméticos |
| US20040122382A1 (en) * | 2002-12-23 | 2004-06-24 | Kimberly-Clark Worldwide, Inc. | Elastomeric articles with beneficial coating on a surface |
| JP4279170B2 (ja) * | 2003-02-24 | 2009-06-17 | 新道繊維工業株式会社 | シリコーンゴムの製造方法 |
| JP4279052B2 (ja) * | 2003-05-23 | 2009-06-17 | 新道繊維工業株式会社 | シリコーンゴム用エマルション組成物。 |
| US7052642B2 (en) * | 2003-06-11 | 2006-05-30 | Kimberly-Clark Worldwide, Inc. | Composition for forming an elastomeric article |
| US20050031817A1 (en) * | 2003-08-07 | 2005-02-10 | Littleton Kermit R. | Readily donned, powder-free elastomeric article |
| WO2005085357A1 (ja) * | 2004-03-05 | 2005-09-15 | Dow Corning Toray Co., Ltd. | シリコーンゴムスポンジ用エマルション組成物、その製造方法およびシリコーンゴムスポンジの製造方法 |
| JP2007231030A (ja) * | 2006-02-27 | 2007-09-13 | Shin Etsu Chem Co Ltd | 皮膜形成シリコーンエマルジョン組成物 |
| FR2910291A1 (fr) * | 2006-12-20 | 2008-06-27 | Oreal | Kit de maquillage des matieres keratiniques comprenant des composes reactifs silicones et une huile compatible |
| CN101663358B (zh) * | 2007-02-07 | 2016-10-26 | 道康宁东丽株式会社 | 海绵形成用液体硅橡胶组合物以及由其制得的硅橡胶海绵 |
| TWI458780B (zh) * | 2007-07-31 | 2014-11-01 | Dow Corning Toray Co Ltd | 提供高透明矽酮硬化物之硬化性矽酮組合物 |
| CN102007166B (zh) * | 2008-03-12 | 2013-03-06 | 陶氏康宁公司 | 硅氧烷聚合物分散体及其形成方法 |
| EP2145912A1 (en) | 2008-07-19 | 2010-01-20 | Momentive Performance Materials GmbH | Method of coating substrates |
| WO2010013847A1 (ja) * | 2008-07-31 | 2010-02-04 | 東レ・ダウコーニング株式会社 | 多成分型スポンジ形成性液状シリコーンゴム組成物およびシリコーンゴムスポンジの製造方法 |
| JP5475295B2 (ja) | 2009-02-02 | 2014-04-16 | 東レ・ダウコーニング株式会社 | 高透明のシリコーン硬化物を与える硬化性シリコーン組成物 |
| JP5475296B2 (ja) | 2009-02-02 | 2014-04-16 | 東レ・ダウコーニング株式会社 | 高透明のシリコーン硬化物を与える硬化性シリコーン組成物 |
| KR20120101628A (ko) * | 2009-07-01 | 2012-09-14 | 다우 코닝 코포레이션 | 경화성 실록산을 함유하는 마이크로캡슐 |
| CN102612491A (zh) | 2009-11-02 | 2012-07-25 | 信越化学工业株式会社 | 球形碳化硅粉末、其制造方法、及使用其的碳化硅陶瓷成形体的制造方法 |
| JP5630333B2 (ja) | 2011-03-08 | 2014-11-26 | 信越化学工業株式会社 | 易焼結性炭化ケイ素粉末及び炭化ケイ素セラミックス焼結体 |
| US20140165263A1 (en) * | 2012-12-18 | 2014-06-19 | Ansell Limited | Fluid repellent elastomeric barrier |
| US10512602B2 (en) | 2016-06-07 | 2019-12-24 | Momentive Performance Materials Inc. | Crosslinked polyorganosiloxane and personal care composition containing same |
| CN106633117B (zh) * | 2016-09-30 | 2018-11-30 | 涌奇材料技术（上海）有限公司 | 一种连续且无排放制备有机硅微米球的方法 |
| JP6733562B2 (ja) * | 2017-01-20 | 2020-08-05 | 信越化学工業株式会社 | 水性シリコーン分散液、皮膜及び化粧料 |
| JP2021107487A (ja) * | 2019-12-27 | 2021-07-29 | 信越化学工業株式会社 | 水性シリコーンエラストマーの水分散物である繊維処理剤、及び皮膜 |
| CN114716690B (zh) * | 2022-05-12 | 2024-03-29 | 浙江新安化工集团股份有限公司 | 一种硅橡胶乳液、制备方法及应用 |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2595928A (en) * | 1951-03-07 | 1952-05-06 | Dow Corning | Antifoam emulsion |
| US2891920A (en) * | 1955-01-26 | 1959-06-23 | Dow Corning | Polymerization of organopolysiloxanes in aqueous emulsion |
| US3098833A (en) * | 1959-11-27 | 1963-07-23 | Gen Electric | Organopolysiloxane emulsion containing a curing catalyst comprising zinc stearate, a metal salt and an alkanolamine-fatty acid condensate |
| GB981824A (en) | 1962-03-29 | 1965-01-27 | Dow Corning | Improvements in or relating to organosilicon compounds |
| GB1024024A (en) * | 1963-04-08 | 1966-03-30 | Dow Corning | Improvements in or relating to polymerising or co-polymerising organosilicon compounds |
| US3355406A (en) * | 1965-01-21 | 1967-11-28 | Dow Corning | Silicone rubber latexes reinforced with silsesquioxanes |
| NL128026C (enExample) * | 1965-12-09 | |||
| NL129346C (enExample) * | 1966-06-23 | |||
| US3706695A (en) * | 1970-10-12 | 1972-12-19 | Dow Corning | Method of preparing a silicone emulsion and regenerating same and electrically conductive product |
| US3900617A (en) * | 1973-11-27 | 1975-08-19 | Gen Electric | Method of rendering flexible sheet material non-adherent and article produced thereby |
| DE2601159C3 (de) * | 1976-01-14 | 1982-02-04 | Wacker-Chemie GmbH, 8000 München | Verfahren zum Herstellen von klebrige Stoffe abweisenden Überzügen |
-
1979
- 1979-08-31 US US06/071,459 patent/US4248751A/en not_active Expired - Lifetime
-
1980
- 1980-07-14 CA CA000356097A patent/CA1138591A/en not_active Expired
- 1980-08-14 GB GB8026494A patent/GB2057475B/en not_active Expired
- 1980-08-18 DE DE3031157A patent/DE3031157C2/de not_active Expired
- 1980-08-21 MX MX183623A patent/MX154979A/es unknown
- 1980-08-28 IT IT24335/80A patent/IT1141024B/it active
- 1980-08-28 JP JP55118997A patent/JPS5817226B2/ja not_active Expired
- 1980-08-28 FR FR8018691A patent/FR2464275A1/fr active Granted
- 1980-08-29 AU AU61882/80A patent/AU531812B2/en not_active Ceased
- 1980-08-29 SE SE8006055A patent/SE450125B/sv not_active IP Right Cessation
- 1980-08-29 BR BR8005499A patent/BR8005499A/pt not_active IP Right Cessation
- 1980-08-29 BE BE0/201927A patent/BE885000A/fr not_active IP Right Cessation
- 1980-08-29 NL NLAANVRAGE8004897,A patent/NL190019C/xx not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| DE3031157A1 (de) | 1981-03-26 |
| NL8004897A (nl) | 1981-03-03 |
| DE3031157C2 (de) | 1984-08-16 |
| SE450125B (sv) | 1987-06-09 |
| IT8024335A0 (it) | 1980-08-28 |
| GB2057475B (en) | 1983-04-07 |
| SE8006055L (sv) | 1981-03-01 |
| BE885000A (fr) | 1981-03-02 |
| IT1141024B (it) | 1986-10-01 |
| AU531812B2 (en) | 1983-09-08 |
| NL190019B (nl) | 1993-05-03 |
| FR2464275A1 (fr) | 1981-03-06 |
| AU6188280A (en) | 1981-03-05 |
| JPS5636546A (en) | 1981-04-09 |
| JPS5817226B2 (ja) | 1983-04-05 |
| US4248751A (en) | 1981-02-03 |
| FR2464275B1 (enExample) | 1983-12-30 |
| GB2057475A (en) | 1981-04-01 |
| NL190019C (nl) | 1993-10-01 |
| BR8005499A (pt) | 1981-03-10 |
| MX154979A (es) | 1988-01-15 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |