BRPI1005329B1 - Composição polimérica, composição de poliolefina termoplástica enchida e processo para a fabricação de um artigo moldado - Google Patents
Composição polimérica, composição de poliolefina termoplástica enchida e processo para a fabricação de um artigo moldado Download PDFInfo
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- BRPI1005329B1 BRPI1005329B1 BRPI1005329-8A BRPI1005329A BRPI1005329B1 BR PI1005329 B1 BRPI1005329 B1 BR PI1005329B1 BR PI1005329 A BRPI1005329 A BR PI1005329A BR PI1005329 B1 BRPI1005329 B1 BR PI1005329B1
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- polypropylene
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- SVUQHVRAGMNPLW-UHFFFAOYSA-N glycerol monostearate Natural products CCCCCCCCCCCCCCCCC(=O)OCC(O)CO SVUQHVRAGMNPLW-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- WZHKDGJSXCTSCK-UHFFFAOYSA-N hept-3-ene Chemical compound CCCC=CCC WZHKDGJSXCTSCK-UHFFFAOYSA-N 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
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- 210000003127 knee Anatomy 0.000 description 1
- 238000002356 laser light scattering Methods 0.000 description 1
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- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
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- 229920006030 multiblock copolymer Polymers 0.000 description 1
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- IRUCBBFNLDIMIK-UHFFFAOYSA-N oct-4-ene Chemical compound CCCC=CCCC IRUCBBFNLDIMIK-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
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- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920005638 polyethylene monopolymer Polymers 0.000 description 1
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- 238000003908 quality control method Methods 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
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- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
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- 229910052709 silver Inorganic materials 0.000 description 1
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- 238000001374 small-angle light scattering Methods 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
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- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
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- 229910052889 tremolite Inorganic materials 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2310/00—Masterbatches
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Injection Moulding Of Plastics Or The Like (AREA)
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| US14854909P | 2009-01-30 | 2009-01-30 | |
| US61/148,549 | 2009-01-30 | ||
| PCT/US2010/022539 WO2010088488A1 (en) | 2009-01-30 | 2010-01-29 | Polymeric compositions and filled tpo articles having improved aesthetics |
Publications (2)
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| BRPI1005329A2 BRPI1005329A2 (pt) | 2016-06-07 |
| BRPI1005329B1 true BRPI1005329B1 (pt) | 2019-06-18 |
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| BRPI1005329-8A BRPI1005329B1 (pt) | 2009-01-30 | 2010-01-29 | Composição polimérica, composição de poliolefina termoplástica enchida e processo para a fabricação de um artigo moldado |
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| US (1) | US8529821B2 (OSRAM) |
| EP (1) | EP2391677B1 (OSRAM) |
| JP (1) | JP5632395B2 (OSRAM) |
| KR (1) | KR101644301B1 (OSRAM) |
| CN (1) | CN102300922B (OSRAM) |
| BR (1) | BRPI1005329B1 (OSRAM) |
| WO (1) | WO2010088488A1 (OSRAM) |
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| US8653198B2 (en) * | 2009-03-26 | 2014-02-18 | Fina Technology, Inc. | Method for the preparation of a heterophasic copolymer and uses thereof |
| WO2013056177A1 (en) * | 2011-10-12 | 2013-04-18 | Honda Patents & Technologies North America, Llc | Composite material and related methods |
| US20130281596A1 (en) * | 2012-04-18 | 2013-10-24 | Rachna Mohan | Compositions Comprising a Propylene-Based Elastomer and a Polyalphaolefin, Methods of Making the Same, and Articles Made Therefrom |
| EP2669329A1 (en) | 2012-06-01 | 2013-12-04 | Basell Poliolefine Italia S.r.l. | Mineral-filled polypropylene composition for foaming |
| RU2015102051A (ru) * | 2012-09-11 | 2016-11-10 | Сикэ Текнолоджи Аг | Термопластичная смесь с высокой гибкостью и высокой температурой плавления |
| US9580586B2 (en) | 2012-12-12 | 2017-02-28 | Asahi Kasei Plastics North America, Inc. | Polypropylene compounds with enhanced haptics |
| KR101579615B1 (ko) * | 2013-11-22 | 2015-12-22 | 주식회사 엘지화학 | 폴리프로필렌계 수지 조성물 및 이로부터 제조되는 성형품 |
| CN103834110A (zh) * | 2014-03-12 | 2014-06-04 | 南通加隆塑胶有限公司 | 一种增韧型聚丙烯母粒配方 |
| FR3026446B1 (fr) * | 2014-09-30 | 2017-12-01 | Lisi Aerospace | Fixation en interference lubrifiee |
| US10792846B2 (en) | 2015-10-07 | 2020-10-06 | Magma Flooring LLC | Method for producing composite substrates |
| US10414911B2 (en) * | 2016-02-25 | 2019-09-17 | Interfacial Consultants Llc | Highly filled polymeric concentrates |
| US10821033B2 (en) * | 2016-05-26 | 2020-11-03 | Edgewell Personal Care Brands, Llc | Composition for thin walled molded parts |
| US10266685B2 (en) * | 2016-07-25 | 2019-04-23 | Exxonmobil Chemical Patents Inc. | Bimodal polypropylene compositions and method of making same |
| WO2018031564A1 (en) | 2016-08-08 | 2018-02-15 | Ticona Llc | Thermally conductive polymer composition for a heat sink |
| CN108690264A (zh) * | 2017-04-12 | 2018-10-23 | 合肥杰事杰新材料股份有限公司 | 一种低光泽、抗虎皮纹注塑缺陷的聚丙烯材料及其制备方法 |
| WO2019055304A1 (en) * | 2017-09-18 | 2019-03-21 | Dow Global Technologies Llc | COMPOSITIONS CONTAINING COATED POLYMER PARTICLES AND TPO COMPOSITIONS FORMED THEREFROM |
| DE202018101394U1 (de) * | 2018-03-13 | 2019-06-14 | Rehau Ag + Co | Polymerzusammensetzung für ein 3D-Druckverfahren |
| JP7570511B2 (ja) * | 2020-10-28 | 2024-10-21 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 再生ポリオレフィンから得られるポリオレフィン組成物 |
| US20230383109A1 (en) * | 2020-10-28 | 2023-11-30 | Basell Poliolefine Italia S.R.L. | Polyolefins compositions obtained from recycled polyolefins |
| MX2023013999A (es) * | 2021-05-28 | 2023-12-11 | Equistar Chem Lp | Composiciones de poliolefina con alta estabilidad dimensional para aplicaciones de lamina. |
| US20230018202A1 (en) * | 2021-07-16 | 2023-01-19 | GM Global Technology Operations LLC | Polyphenylene sulfide or polyphenylene sulfide alloy impact-resistant fuel quick connector |
| US12435168B2 (en) * | 2022-09-12 | 2025-10-07 | Formosa Plastics Corporation, U.S.A. | High ductility, high modulus and phthalate free impact resistant propylene copolymer |
| CN117924831A (zh) * | 2023-12-22 | 2024-04-26 | 南京聚隆科技股份有限公司 | 一种导热隔音动态硫化热塑性弹性体及其制备方法 |
Family Cites Families (124)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE563834A (OSRAM) | 1957-01-09 | 1900-01-01 | ||
| US3005795A (en) | 1957-12-10 | 1961-10-24 | Du Pont | Thermoplastic resins containing finely divided, fibrous polytetrafluoroethylene |
| US3142665A (en) | 1960-07-26 | 1964-07-28 | Du Pont | Novel tetrafluoroethylene resins and their preparation |
| CA849081A (en) | 1967-03-02 | 1970-08-11 | Du Pont Of Canada Limited | PRODUCTION OF ETHYLENE/.alpha.-OLEFIN COPOLYMERS OF IMPROVED PHYSICAL PROPERTIES |
| US3654219A (en) | 1968-06-19 | 1972-04-04 | William M Boyer | Novel fiber glass-reinforced resin compositions and processes for their preparation |
| US3669208A (en) | 1968-10-16 | 1972-06-13 | Int Harvester Co | Vehicle guidance systems |
| GB1292365A (en) | 1969-05-23 | 1972-10-11 | Windmoeller & Hoelscher | Mixing devices for plastics materials |
| US3746489A (en) | 1970-12-28 | 1973-07-17 | Usm Corp | Apparatus for injecting molding reinforced plastic articles |
| US3797707A (en) | 1971-04-20 | 1974-03-19 | Jenike And Johanson Inc | Bins for storage and flow of bulk solids |
| US3671487A (en) | 1971-05-05 | 1972-06-20 | Gen Electric | Glass reinforced polyester resins containing polytetrafluoroethylene and flame retardant additives |
| US4016345A (en) | 1972-12-22 | 1977-04-05 | E. I. Du Pont De Nemours And Company | Process for polymerizing tetrafluoroethylene in aqueous dispersion |
| US4286883A (en) | 1979-08-20 | 1981-09-01 | Jenike & Johanson, Inc. | Blending apparatus for bulk solids |
| JPS57179224A (en) | 1981-04-25 | 1982-11-04 | Nippon Oil Co Ltd | Preparation of pellet of hydrogenated petroleum resin composition containing filler |
| EP0103230B1 (de) | 1982-09-10 | 1988-06-22 | Bayer Ag | Flammwidrige Polymermischungen |
| EP0128893B1 (de) | 1982-12-20 | 1989-07-26 | Buss Ag | Verfahren zur kontinuierlichen herstellung von rieselfähigen und homogenen gemischen aus kunststoffen mit zusätzen |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| ZA844157B (en) | 1983-06-06 | 1986-01-29 | Exxon Research Engineering Co | Process and catalyst for polyolefin density and molecular weight control |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| EP0260999A1 (en) | 1986-09-19 | 1988-03-23 | Exxon Chemical Patents Inc. | High pressure, high temperature polymerization of ethylene |
| US4732926A (en) | 1986-09-29 | 1988-03-22 | General Motors Corporation | Dry blendable polypropylene composition |
| US5194509A (en) | 1986-11-20 | 1993-03-16 | Basf Aktiengesellschaft | Peroxide-free grafting of homopolymers and copolymers of ethylene having densities equal to or greater than 0.930 g/cm3, and use of the graft copolymers for the preparation of ionomers of adhesion promoters |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US4937301A (en) | 1987-12-17 | 1990-06-26 | Exxon Chemical Patents Inc. | Method for preparing a supported metallocene-alumoxane catalyst for gas phase polymerization |
| US4935397A (en) | 1988-09-28 | 1990-06-19 | Exxon Chemical Patents Inc. | Supported metallocene-alumoxane catalyst for high pressure polymerization of olefins and a method of preparing and using the same |
| EP0495099B2 (en) | 1988-12-26 | 2009-06-10 | Mitsui Chemicals, Inc. | Olefin copolymer and production thereof |
| US5272236A (en) | 1991-10-15 | 1993-12-21 | The Dow Chemical Company | Elastic substantially linear olefin polymers |
| DE4026957C2 (de) | 1990-08-25 | 1994-07-14 | Theysohn Friedrich Fa | Zuführvorrichtung für das einem Extruder in mehreren Komponenten zuzuführende, zu extrudierende Material |
| US5130076A (en) | 1990-08-27 | 1992-07-14 | E. I. Du Pont De Nemours And Company | Direct fabrication |
| US5282272A (en) | 1990-12-21 | 1994-01-25 | Intel Corporation | Interrupt distribution scheme for a computer bus |
| JP2887379B2 (ja) * | 1991-10-09 | 1999-04-26 | 住友化学工業株式会社 | 硬質熱可塑性樹脂組成物およびその射出成形体 |
| US5278272A (en) | 1991-10-15 | 1994-01-11 | The Dow Chemical Company | Elastic substantialy linear olefin polymers |
| CA2132728C (en) | 1992-03-25 | 2001-10-16 | Pallatheri Manackal Subramanian | Process for molding fiber-reinforced thermoplastic polymer articles |
| US5298587A (en) | 1992-12-21 | 1994-03-29 | The Dow Chemical Company | Protective film for articles and method |
| RU2041889C1 (ru) | 1993-07-26 | 1995-08-20 | Товарищество с ограниченной ответственностью - Научно-производственное предприятие "Макромер" | Алкилфталаты полиоксиалкиленфталиллактамов и способ их получения |
| US5433786A (en) | 1993-08-27 | 1995-07-18 | The Dow Chemical Company | Apparatus for plasma enhanced chemical vapor deposition comprising shower head electrode with magnet disposed therein |
| EP0695781B1 (en) * | 1994-08-02 | 1999-11-10 | Chisso Corporation | Polyolefin resin composition for interior automative trim parts |
| US5468808A (en) | 1994-09-12 | 1995-11-21 | Exxon Chemical Patents Inc. | Reduction of flow marks in rubber modified polypropylene |
| JPH08283528A (ja) * | 1995-04-10 | 1996-10-29 | Tonen Chem Corp | 熱可塑性樹脂組成物 |
| JPH08295785A (ja) * | 1995-04-24 | 1996-11-12 | Tonen Chem Corp | ポリオレフィン組成物 |
| US5599099A (en) | 1995-08-11 | 1997-02-04 | K-Tron Technologies, Inc. | Material blending apparatus having a pivotally mounted hopper |
| DE19532412C2 (de) | 1995-09-01 | 1999-09-30 | Agrodyn Hochspannungstechnik G | Vorrichtung zur Oberflächen-Vorbehandlung von Werkstücken |
| JPH09124857A (ja) | 1995-10-30 | 1997-05-13 | Nippon Poriorefuin Kk | ポリプロピレン系樹脂組成物及びその製造方法 |
| EP0958118B1 (en) | 1995-12-11 | 2003-04-23 | Maguire Products, Inc. | Gravimetric blender |
| US6297301B1 (en) | 1996-08-06 | 2001-10-02 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions having improved processing properties |
| US6254956B1 (en) | 1996-09-04 | 2001-07-03 | The Dow Chemical Company | Floor, wall or ceiling covering |
| US6111206A (en) | 1997-02-15 | 2000-08-29 | Maguire; Stephen B. | Apparatus and method for gravimetric blending with horizontal material feed |
| DE975695T1 (de) | 1997-04-16 | 2000-06-29 | The Dow Chemical Co., Midland | Zusammensetzungen, enthaltend gleit- und antiblockmittel |
| US6262161B1 (en) | 1997-06-26 | 2001-07-17 | The Dow Chemical Company | Compositions having improved ignition resistance |
| JP2001512770A (ja) | 1997-08-08 | 2001-08-28 | ザ ダウ ケミカル カンパニー | 床、壁または天井被覆材として用いるに適したシート材料およびそれの製造方法および中間体 |
| US6525157B2 (en) | 1997-08-12 | 2003-02-25 | Exxonmobile Chemical Patents Inc. | Propylene ethylene polymers |
| US6417240B1 (en) | 1998-08-28 | 2002-07-09 | Dow Global Technologies Inc. | Foams prepared from blends of syndiotactic polypropylenes and thermoplastic polymers |
| CN1247795A (zh) | 1998-09-16 | 2000-03-22 | 严而明 | 注塑成型 |
| JP4205786B2 (ja) | 1998-10-05 | 2009-01-07 | 住友化学株式会社 | ポリプロピレン系樹脂組成物およびその射出成形体 |
| US6177515B1 (en) | 1998-12-17 | 2001-01-23 | Montell Technology Company Bv | Polypropylene graft copolymers with improved scratch and mar resistance |
| JP3832129B2 (ja) | 1999-02-05 | 2006-10-11 | 株式会社プライムポリマー | ポリプロピレン樹脂組成物および射出成形品 |
| JP3320031B2 (ja) | 1999-03-19 | 2002-09-03 | 日本ポリケム株式会社 | 高濃度タルクマスターバッチ |
| US6102562A (en) | 1999-05-04 | 2000-08-15 | Jenike & Johanson, Inc. | Removable container insert |
| SE518553C2 (sv) | 1999-06-09 | 2002-10-22 | Borealis As | Profil för fönster och dörrar av propensegmentsampolymer med kärnbildande medel och fyllmedel |
| US6329454B1 (en) | 1999-12-08 | 2001-12-11 | The Dow Chemical Company | Filled propylene polymer composition |
| US6300419B1 (en) | 1999-12-08 | 2001-10-09 | The Dow Chemical Company | Propylene polymer composition |
| US6806330B1 (en) | 1999-12-17 | 2004-10-19 | Dow Global Technologies Inc. | Amine organoborane complex polymerization initiators and polymerizable compositions |
| MXPA02007500A (es) | 2000-02-04 | 2003-01-28 | Dow Global Technologies Inc | Un proceso para producir lamina de espuma termoformable usando un agente fisico de soplado. |
| US6544450B2 (en) | 2000-02-04 | 2003-04-08 | Dow Global Technologies Inc. | Process for producing thermoformable foam sheet using a physical blowing agent |
| FR2804964B1 (fr) | 2000-02-14 | 2006-09-29 | Omya Sa | Utilisation de polypropylenes isotactiques de tres grande fluidite pour la preparation de concentres de charges utilisables dans les thermoplastiques de type olefinique, concentres de charges et thermoplastiques ainsi obtenus |
| BR0112607A (pt) | 2000-07-20 | 2003-06-10 | Dow Global Technologies Inc | Composições de espuma a partir de uma mescla de polìmeros aromáticos alquenìlicos e interpolìmeros aromáticos alfa-olefìnicos/vinìlicos ou vinilidênicos |
| US20040048967A1 (en) | 2000-09-07 | 2004-03-11 | Ryuzo Tomomatsu | Process for producing thermoplastic resin composition and thermoplastic resin composition obtained thereby |
| AU2001286657A1 (en) | 2000-09-15 | 2002-03-26 | The Dow Chemical Company | Propylene polymer composition |
| US6586531B2 (en) | 2000-10-04 | 2003-07-01 | Basell Poliolefine Italia S.P.A. | Polyolefin masterbatch and composition suitable for injection molding |
| FR2818077A1 (fr) | 2000-12-07 | 2002-06-14 | Cit Alcatel | Procede de regie des frequences allouees pour des communications radiomobiles, infrastructure de reseau radiomobile, et systeme de communication pour la mise en oeuvre de ce procede |
| KR100412452B1 (ko) | 2001-03-08 | 2003-12-31 | 현대자동차주식회사 | 폴리프로필렌 수지 조성물 |
| US6403692B1 (en) | 2001-04-19 | 2002-06-11 | Dow Global Technologies Inc. | Filled thermoplastic composition |
| US20050070673A1 (en) | 2001-10-01 | 2005-03-31 | Novak Leo R. | Thermoformable propylene polymer compositions |
| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| SG147306A1 (en) | 2001-11-06 | 2008-11-28 | Dow Global Technologies Inc | Isotactic propylene copolymers, their preparation and use |
| SG120908A1 (en) | 2002-01-24 | 2006-04-26 | Sumitomo Chemical Co | Polypropylene-based resin composition and injection molded article comprising the same |
| KR100475946B1 (ko) | 2002-06-05 | 2005-03-10 | 한일이화주식회사 | 내충격성 및 내스크래치성이 우수한 자동차 도어 트림용폴리프로필렌 수지 조성물 |
| US20060052541A1 (en) * | 2002-06-25 | 2006-03-09 | Erling Hagen | Polyolefin with improved scratch resistance and process for producing the same |
| JP2004042416A (ja) | 2002-07-11 | 2004-02-12 | Hitachi Cable Ltd | ドライブレンド材料の吸引供給装置 |
| JP4041705B2 (ja) | 2002-07-19 | 2008-01-30 | 日産自動車株式会社 | 自動車内装成形品 |
| US6734253B2 (en) | 2002-07-19 | 2004-05-11 | Dow Global Technologies, Inc. | Scratch and mar resistant propylene polymer composition |
| US8003725B2 (en) | 2002-08-12 | 2011-08-23 | Exxonmobil Chemical Patents Inc. | Plasticized hetero-phase polyolefin blends |
| EP1549712B1 (en) | 2002-10-02 | 2012-11-28 | Dow Global Technologies LLC | Polymer compositions comprising a low viscosity, homogeneously branched ethylene/alpha-olefin extender |
| JP2004168879A (ja) | 2002-11-19 | 2004-06-17 | Fujikura Ltd | エチレン系難燃性樹脂組成物と難燃性電線・ケーブル |
| JP2004168957A (ja) | 2002-11-22 | 2004-06-17 | Yokohama Rubber Co Ltd:The | 1液湿気硬化型ポリウレタン組成物 |
| ITMI20022696A1 (it) | 2002-12-20 | 2004-06-21 | Lico Spa | Procedimento per la produzione di tubi, profili, cavi e calandrati in pvc rigido e plastificato |
| GB0304276D0 (en) | 2003-02-25 | 2003-03-26 | Dow Benelux | Reactive hot melt adhesive |
| US6777512B1 (en) | 2003-02-28 | 2004-08-17 | Dow Global Technologies Inc. | Amine organoborane complex initiated polymerizable compositions containing siloxane polymerizable components |
| JP2004323546A (ja) * | 2003-04-21 | 2004-11-18 | Mitsui Chemicals Inc | 自動車内装用ポリプロピレン樹脂組成物 |
| US6967225B2 (en) | 2003-05-05 | 2005-11-22 | Honda Motor Co., Ltd. | Scratch-resistant polypropylene composition |
| EP1648944A1 (en) | 2003-06-09 | 2006-04-26 | The Dow Global Technologies Inc. | Stabilized organoborane polymerization initiators and polymerizable compositions |
| DE10332233B4 (de) | 2003-07-16 | 2006-04-20 | Motan Materials Handling Gmbh | Mischsilo |
| US7803865B2 (en) | 2003-08-25 | 2010-09-28 | Dow Global Technologies Inc. | Aqueous dispersion, its production method, and its use |
| US20050116390A1 (en) | 2003-08-29 | 2005-06-02 | Nailite International | Method for injection molding |
| US20050046367A1 (en) | 2003-08-29 | 2005-03-03 | Johnson Controls Technology Company | Circuit for providing power to multiple electrical devices |
| US7268185B2 (en) | 2003-09-24 | 2007-09-11 | Sumitomo Chemical Company, Limited | Thermoplastic resin composition and its injection molded article |
| DE10355109A1 (de) | 2003-11-24 | 2005-06-23 | Coperion Waeschle Gmbh & Co. Kg | Mischsilo für Pulver oder sonstiges Schütt- oder Mischgut |
| JP4464676B2 (ja) | 2003-12-18 | 2010-05-19 | カルプ工業株式会社 | 自動車用部品の成形方法 |
| DE602004015841D1 (de) | 2003-12-22 | 2008-09-25 | Dow Global Technologies Inc | Organoboran-amin-komplex initiierte, beschleunigte polymerisierbare zusammensetzungen |
| US8501886B2 (en) | 2003-12-22 | 2013-08-06 | Dow Global Technologies Llc | Accelerated organoborane amine complex initiated polymerizable compositions |
| CA2553687C (en) * | 2004-02-10 | 2012-04-17 | Dow Global Technologies Inc. | Electrically-dissipative propylene polymer composition |
| US20050250890A1 (en) | 2004-05-06 | 2005-11-10 | Yan Chen | Filler masterbatch for thermoplastic compositions |
| BRPI0511307A (pt) * | 2004-06-08 | 2007-12-04 | Basell Poliolefine Srl | composição poliolefìnica tendo um alto balanço de dureza, resistência a impacto e alongamento na ruptura e um baixo encolhimento térmico |
| US8034858B2 (en) | 2004-09-15 | 2011-10-11 | Sumitomo Chemical Company, Limited | Polypropylene resin composition and injection molded article made from the same |
| ATE435730T1 (de) | 2004-10-22 | 2009-07-15 | Dow Global Technologies Inc | Verbundartikel aus kunststoff und herstellungsverfahren dafür |
| KR101506824B1 (ko) | 2005-03-17 | 2015-03-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 에틸렌/α-올레핀 블록 혼성중합체 |
| MX2007011344A (es) | 2005-03-17 | 2007-10-05 | Dow Global Technologies Inc | Composiciones de polimero rellenas preparadas a partir de interpolimeros de etileno/a-olefinas y sus usos. |
| WO2006102155A2 (en) | 2005-03-17 | 2006-09-28 | Dow Global Technologies Inc. | IMPACT MODIFICATION OF THERMOPLASTICS WITH ETHYLENE/α-OLEFIN INTERPOLYMERS |
| WO2007002435A1 (en) | 2005-06-24 | 2007-01-04 | Dow Global Technologies Inc. | Automotive articles prepared from filled tpo compositions, and methods of making the same |
| EP1920002B1 (en) | 2005-08-19 | 2011-11-09 | Styron Europe GmbH | Improved appearance propylene polymer composition |
| US20070117909A1 (en) | 2005-10-27 | 2007-05-24 | Dow Global Technologies Inc. | Process for forming a reinforced polymeric material and articles formed therewith |
| CA2634040A1 (en) | 2005-12-15 | 2007-07-12 | Dow Global Technologies Inc. | Improved cellulose articles containing an additive composition |
| US8043713B2 (en) | 2005-12-15 | 2011-10-25 | Dow Global Technologies Llc | Compositions and aqueous dispersions |
| US7528080B2 (en) | 2005-12-15 | 2009-05-05 | Dow Global Technologies, Inc. | Aqueous polyolefin dispersions for textile impregnation |
| CN101583476A (zh) | 2006-04-19 | 2009-11-18 | 陶氏环球技术公司 | 在挤出机中共混材料的方法,制品和材料预混合 |
| BRPI0713204A8 (pt) | 2006-06-29 | 2017-12-12 | Dow Global Technologies Inc | Processo para fazer um artigo conformado, kit para uso em um processo para fazer um artigo conformado e artigo |
| US8785531B2 (en) | 2006-07-06 | 2014-07-22 | Dow Global Technologies Llc | Dispersions of olefin block copolymers |
| US8080607B2 (en) | 2006-08-16 | 2011-12-20 | Dow Global Technologies Llc | Polymeric material and process for forming and using same |
| US7524907B2 (en) | 2006-10-12 | 2009-04-28 | Dow Global Technologies, Inc. | Accelerated organoborane initiated polymerizable compositions |
| JP4637157B2 (ja) * | 2006-11-17 | 2011-02-23 | 日本ポリプロ株式会社 | プロピレン系重合体及びその製造方法 |
| US7862671B2 (en) | 2007-01-11 | 2011-01-04 | Dow Global Technologies Inc. | Welding of a polymeric material and structures formed thereby |
| KR101406772B1 (ko) | 2007-10-22 | 2014-06-19 | 다우 글로벌 테크놀로지스 엘엘씨 | 중합체 조성물 및 제품의 성형방법 |
| EP2254737B1 (en) | 2008-03-14 | 2014-04-23 | Dow Global Technologies LLC | Process for manufacturing a polymeric article |
| US8217116B2 (en) * | 2009-07-15 | 2012-07-10 | Braskem America, Inc. | Polypropylene composition for buried structures |
-
2010
- 2010-01-29 US US13/142,966 patent/US8529821B2/en active Active
- 2010-01-29 KR KR1020117020137A patent/KR101644301B1/ko active Active
- 2010-01-29 CN CN2010800058089A patent/CN102300922B/zh active Active
- 2010-01-29 BR BRPI1005329-8A patent/BRPI1005329B1/pt active IP Right Grant
- 2010-01-29 JP JP2011548334A patent/JP5632395B2/ja active Active
- 2010-01-29 WO PCT/US2010/022539 patent/WO2010088488A1/en not_active Ceased
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Also Published As
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|---|---|
| CN102300922A (zh) | 2011-12-28 |
| US8529821B2 (en) | 2013-09-10 |
| EP2391677B1 (en) | 2016-09-28 |
| WO2010088488A1 (en) | 2010-08-05 |
| CN102300922B (zh) | 2013-07-31 |
| KR101644301B1 (ko) | 2016-07-29 |
| BRPI1005329A2 (pt) | 2016-06-07 |
| JP2012516385A (ja) | 2012-07-19 |
| KR20110113760A (ko) | 2011-10-18 |
| US20110272860A1 (en) | 2011-11-10 |
| EP2391677A1 (en) | 2011-12-07 |
| JP5632395B2 (ja) | 2014-11-26 |
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