BR9913268B1 - composição para elementos estruturais eletroquìmicos, camada autoportante ou apoiada em substrato, compósito em camadas, célula eletroquìmica recarregável, processo para produção de uma composição, processo para produção de uma camada autoportante ou apoiada em substrato e processo para produção de um compósito em camadas. - Google Patents
composição para elementos estruturais eletroquìmicos, camada autoportante ou apoiada em substrato, compósito em camadas, célula eletroquìmica recarregável, processo para produção de uma composição, processo para produção de uma camada autoportante ou apoiada em substrato e processo para produção de um compósito em camadas.Info
- Publication number
- BR9913268B1 BR9913268B1 BRPI9913268-0A BR9913268A BR9913268B1 BR 9913268 B1 BR9913268 B1 BR 9913268B1 BR 9913268 A BR9913268 A BR 9913268A BR 9913268 B1 BR9913268 B1 BR 9913268B1
- Authority
- BR
- Brazil
- Prior art keywords
- producing
- self
- substrate
- supporting
- composition
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 3
- 239000002131 composite material Substances 0.000 title 2
- 239000011159 matrix material Substances 0.000 abstract 4
- 229920000620 organic polymer Polymers 0.000 abstract 2
- 239000004014 plasticizer Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 239000002904 solvent Substances 0.000 abstract 2
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000007772 electrode material Substances 0.000 abstract 1
- 229910010272 inorganic material Inorganic materials 0.000 abstract 1
- 239000011147 inorganic material Substances 0.000 abstract 1
- 239000011533 mixed conductor Substances 0.000 abstract 1
- 239000002243 precursor Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 230000008961 swelling Effects 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
- C08L101/12—Compositions of unspecified macromolecular compounds characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Conductive Materials (AREA)
- Electric Double-Layer Capacitors Or The Like (AREA)
- Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
- Semiconductor Lasers (AREA)
- Seasonings (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
- Noodles (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19839217A DE19839217C2 (de) | 1998-08-28 | 1998-08-28 | Pastöse Massen, Schichten und Schichtverbände, Zellen und Verfahren zur Herstellung |
| PCT/EP1999/006313 WO2000013249A1 (de) | 1998-08-28 | 1999-08-27 | Pastöse massen für elektrochemische bauelemente und daraus hergestellte schichten und elektrochemische bauelemente |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR9913268A BR9913268A (pt) | 2001-05-15 |
| BR9913268B1 true BR9913268B1 (pt) | 2010-10-05 |
Family
ID=7879050
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI9913268-0A BR9913268B1 (pt) | 1998-08-28 | 1999-08-27 | composição para elementos estruturais eletroquìmicos, camada autoportante ou apoiada em substrato, compósito em camadas, célula eletroquìmica recarregável, processo para produção de uma composição, processo para produção de uma camada autoportante ou apoiada em substrato e processo para produção de um compósito em camadas. |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US6706441B1 (enExample) |
| EP (1) | EP1108271B1 (enExample) |
| JP (2) | JP2002528849A (enExample) |
| KR (1) | KR20010082182A (enExample) |
| CN (1) | CN100364166C (enExample) |
| AT (1) | ATE270003T1 (enExample) |
| AU (1) | AU5855999A (enExample) |
| BR (1) | BR9913268B1 (enExample) |
| CA (1) | CA2341756C (enExample) |
| DE (2) | DE19839217C2 (enExample) |
| DK (1) | DK1108271T3 (enExample) |
| ES (1) | ES2222729T3 (enExample) |
| ID (1) | ID27795A (enExample) |
| PT (1) | PT1108271E (enExample) |
| TW (1) | TW550597B (enExample) |
| WO (1) | WO2000013249A1 (enExample) |
Families Citing this family (43)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19916042A1 (de) * | 1999-04-09 | 2000-10-12 | Basf Ag | Naß-in-Naß-Beschichtungsverfahren zur Herstellung von Verbundkörpern, die zur Verwendung in Lithiumionenbatterien geeignet sind |
| DE19948548B4 (de) * | 1999-04-19 | 2006-04-13 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Pastöse Massen mit nanokristallinen Materialien für elektrochemische Bauelemente und daraus hergestellte Schichten und elektrochemische Bauelemente |
| DE19952335B4 (de) * | 1999-10-29 | 2007-03-29 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | In elektrochemischen Bauelementen verwendbare pastöse Masse, damit gebildete Schichten, Folien, Schichtverbünde und wiederaufladbare elektrochemische Zellen sowie Verfahren zur Herstellung der Schichten, Folien und Schichtverbünde |
| DE19957285A1 (de) | 1999-11-29 | 2001-06-21 | Fraunhofer Ges Forschung | Folien für elektrochemische Bauelemente sowie Verfahren zu deren Herstellung |
| DE10020031C2 (de) * | 2000-04-22 | 2002-05-29 | Franz W Winterberg | Verfahren zur Herstellung von wiederaufladbaren Lithium-Polymer-Batterien |
| DE10101299A1 (de) * | 2000-09-14 | 2002-04-04 | Fraunhofer Ges Forschung | Elektrochemisch aktivierbare Schicht oder Folie |
| US20030180610A1 (en) * | 2000-09-14 | 2003-09-25 | Felde Ulf Zum | Electrochemically activable layer or film |
| US8980477B2 (en) | 2000-12-22 | 2015-03-17 | Fmc Corporation | Lithium metal dispersion in secondary battery anodes |
| US7276314B2 (en) | 2000-12-22 | 2007-10-02 | Fmc Corporation | Lithium metal dispersion in secondary battery anodes |
| US6706447B2 (en) | 2000-12-22 | 2004-03-16 | Fmc Corporation, Lithium Division | Lithium metal dispersion in secondary battery anodes |
| DE10112613B4 (de) * | 2001-03-14 | 2007-04-12 | Dilo Trading Ag | Polymerelektrolyt für Lithium-Polymer-Batterien und dessen Verwendung |
| DE10122811B4 (de) * | 2001-05-10 | 2007-08-09 | Dilo Trading Ag | Elektrode für eine Lithium-Polymer-Wickelzellen-Batterie, Lithium-Polymer-Batterie und Verfahren zur Herstellung der Lithium-Polymer-Batterie |
| DE10134057B4 (de) * | 2001-07-13 | 2006-01-26 | Dilo Trading Ag | Verfahren zur Herstellung einer Lithium-Polymer-Batterie |
| US20030113613A1 (en) * | 2001-12-17 | 2003-06-19 | Takeuchi Esther S. | High energy density rechargeable cell for medical device applications |
| DK200200615A (da) * | 2001-12-19 | 2003-06-20 | Fmc Corp | Lithiummetaldispersion i sekundære batterianoder |
| DE10219423A1 (de) | 2002-05-02 | 2003-11-20 | Varta Microbattery Gmbh | Verfahren zur Herstellung eines galvanischen Elements |
| DE10231319B4 (de) * | 2002-07-11 | 2013-08-14 | Dilo Trading Ag | Verfahren zur Herstellung von Speichern für elektrische Energie auf Basis von wiederaufladbaren Lithium-Polymer-Zellen |
| DE10231949B4 (de) * | 2002-07-15 | 2007-05-16 | Dilo Trading Ag | Lithium-Polymer Batterie und Verfahren zur Herstellung von Lithium-Polymer Batterien |
| DE10251241B4 (de) * | 2002-11-04 | 2006-11-02 | Dilo Trading Ag | Verfahren zur Herstellung von Lithium-Polymer-Batterien |
| EP1431423A1 (de) * | 2002-12-16 | 2004-06-23 | Basf Aktiengesellschaft | Verfahren zur Herstellung eines Lithiumionenleiters |
| US20050181275A1 (en) * | 2004-02-18 | 2005-08-18 | Jang Bor Z. | Open electrochemical cell, battery and functional device |
| US8231810B2 (en) | 2004-04-15 | 2012-07-31 | Fmc Corporation | Composite materials of nano-dispersed silicon and tin and methods of making the same |
| US7771874B2 (en) | 2005-06-29 | 2010-08-10 | Fmc Corporation | Lithium manganese compounds and methods of making the same |
| US7588623B2 (en) | 2005-07-05 | 2009-09-15 | Fmc Corporation Lithium Division | Stabilized lithium metal powder for li-ion application, composition and process |
| US20090035663A1 (en) | 2006-10-13 | 2009-02-05 | Fmc Corporation, Lithium Division | Stabilized lithium metal powder for li-ion application, composition and process |
| DE102007031477A1 (de) | 2007-03-12 | 2008-09-18 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Elektrolyte für elektrochemische Bauelemente |
| US8021496B2 (en) | 2007-05-16 | 2011-09-20 | Fmc Corporation | Stabilized lithium metal powder for Li-ion application, composition and process |
| DE102008040941A1 (de) | 2008-08-01 | 2010-02-18 | Dilo Trading Ag | Lithium-Ionen-Zellen mit aktiviertem Elektrolyt |
| DE102008043625A1 (de) | 2008-11-10 | 2010-05-20 | Dilo Trading Ag | Lithium-Ionen-Zellen mit speziellen Ableitern und modifziertem Separator |
| EP2287945A1 (de) | 2009-07-23 | 2011-02-23 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Leistungs- und energiedichteoptimierte Flächenelektroden für elektrochemische Energiespeicher |
| DE102010048919A1 (de) | 2010-10-07 | 2012-04-12 | Schott Ag | Elektrochemischer Energiespeicher und Verwendung eines glasbasierten Materials zur Herstellung eines Separators für einen solchen |
| DE102010048922A1 (de) | 2010-10-07 | 2012-04-12 | Schott Ag | Elektrochemischer Energiespeicher und Verwendung eines glasbasierten Materials zur Herstellung eines Separators für einen solchen |
| KR20130135856A (ko) | 2010-10-07 | 2013-12-11 | 쇼오트 아게 | 전기화학 에너지 축전지 및 이 축전지용 세퍼레이터를 제조하기 위한 유리계 물질 |
| DE102011076177A1 (de) | 2011-05-20 | 2012-11-22 | Robert Bosch Gmbh | Schichtanordnung, Energiespeicher und Verfahren zum Herstellen eines Energiespeichers |
| DE102013106021A1 (de) | 2013-06-10 | 2014-12-11 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Ungefüllte und gefüllte Gussmasse, insbesondere zur Herstellung beschichteter Metallfolien, und deren Verwendung für Elektroden oder Separatoren in Akkumulatoren |
| US11344382B2 (en) * | 2014-01-24 | 2022-05-31 | Elucent Medical, Inc. | Systems and methods comprising localization agents |
| KR20170032001A (ko) * | 2015-09-14 | 2017-03-22 | 주식회사 엘지화학 | 리튬금속 전극 및 이를 포함하는 리튬 이차전지 |
| CN105870382B (zh) * | 2016-05-18 | 2020-04-14 | 宁波力能鑫新材料科技有限公司 | 一种锂离子电池复合隔膜及其制备方法 |
| KR102227802B1 (ko) * | 2016-10-07 | 2021-03-15 | 주식회사 엘지화학 | 전극 활물질 슬러리 조성물 및 이를 이용한 전극을 포함하는 리튬 이차전지 |
| CN108417890B (zh) * | 2018-03-22 | 2021-01-29 | 上海力信能源科技有限责任公司 | 一种聚合物固态电解质材料、固态电解质膜及其制备方法 |
| CN112786890A (zh) * | 2021-01-28 | 2021-05-11 | 合肥国轩高科动力能源有限公司 | 一种低界面阻抗的固态电池及其制备方法 |
| EP4418350A4 (en) * | 2021-10-14 | 2025-10-15 | Daikin Ind Ltd | MIXTURE COMPOSITION FOR SECONDARY BATTERY ELECTRODE, ELECTRODE MIXTURE SHEET AND METHOD FOR PRODUCING SAME, ELECTRODE, AND SECONDARY BATTERY |
| US20240332611A1 (en) * | 2023-03-30 | 2024-10-03 | Rivian Ip Holdings, Llc | Sulfide-based composite solid state electrolytes and related methods |
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| JP3774980B2 (ja) * | 1997-03-27 | 2006-05-17 | 株式会社ジーエス・ユアサコーポレーション | 非水電解質二次電池用電極の製造方法 |
| US5738691A (en) * | 1997-04-28 | 1998-04-14 | Valence Technology, Inc. | Ultrasonic extraction of plasticizer from electrochemical cells |
| JPH1131414A (ja) * | 1997-07-10 | 1999-02-02 | Showa Denko Kk | 重合性組成物及びその用途 |
| KR100573655B1 (ko) * | 1998-02-24 | 2006-04-26 | 텔-아비브 유니버시티 퓨처 테크놀로지 디벨롭먼트 엘.피. | 이온 전도성 매트릭스, 상기 매트릭스를 포함하는 막 및 복합 전극, 상기 막 또는 전극의 캐스팅 또는 제조 방법, 및 상기 막 또는 전극을 포함하는 전기화학 전지, 연료 전지 및 수 전해조 |
-
1998
- 1998-08-28 DE DE19839217A patent/DE19839217C2/de not_active Expired - Fee Related
-
1999
- 1999-08-27 AT AT99946046T patent/ATE270003T1/de active
- 1999-08-27 KR KR1020017002585A patent/KR20010082182A/ko not_active Ceased
- 1999-08-27 WO PCT/EP1999/006313 patent/WO2000013249A1/de not_active Ceased
- 1999-08-27 BR BRPI9913268-0A patent/BR9913268B1/pt not_active IP Right Cessation
- 1999-08-27 JP JP2000568135A patent/JP2002528849A/ja active Pending
- 1999-08-27 ES ES99946046T patent/ES2222729T3/es not_active Expired - Lifetime
- 1999-08-27 AU AU58559/99A patent/AU5855999A/en not_active Abandoned
- 1999-08-27 US US09/786,595 patent/US6706441B1/en not_active Expired - Lifetime
- 1999-08-27 ID IDW20010675A patent/ID27795A/id unknown
- 1999-08-27 EP EP99946046A patent/EP1108271B1/de not_active Expired - Lifetime
- 1999-08-27 DE DE59909815T patent/DE59909815D1/de not_active Expired - Lifetime
- 1999-08-27 PT PT99946046T patent/PT1108271E/pt unknown
- 1999-08-27 DK DK99946046T patent/DK1108271T3/da active
- 1999-08-27 CA CA2341756A patent/CA2341756C/en not_active Expired - Lifetime
- 1999-08-27 CN CNB998104914A patent/CN100364166C/zh not_active Expired - Lifetime
- 1999-08-30 TW TW088114810A patent/TW550597B/zh not_active IP Right Cessation
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2012
- 2012-10-15 JP JP2012227674A patent/JP5978090B2/ja not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN100364166C (zh) | 2008-01-23 |
| US6706441B1 (en) | 2004-03-16 |
| DE59909815D1 (de) | 2004-07-29 |
| DE19839217A1 (de) | 2000-03-09 |
| CA2341756C (en) | 2011-02-08 |
| DK1108271T3 (da) | 2004-10-11 |
| BR9913268A (pt) | 2001-05-15 |
| AU5855999A (en) | 2000-03-21 |
| ES2222729T3 (es) | 2005-02-01 |
| TW550597B (en) | 2003-09-01 |
| JP2013065560A (ja) | 2013-04-11 |
| JP5978090B2 (ja) | 2016-08-24 |
| CA2341756A1 (en) | 2000-03-09 |
| EP1108271B1 (de) | 2004-06-23 |
| WO2000013249A1 (de) | 2000-03-09 |
| PT1108271E (pt) | 2004-11-30 |
| EP1108271A1 (de) | 2001-06-20 |
| KR20010082182A (ko) | 2001-08-29 |
| DE19839217C2 (de) | 2001-02-08 |
| ID27795A (id) | 2001-04-26 |
| CN1317159A (zh) | 2001-10-10 |
| JP2002528849A (ja) | 2002-09-03 |
| ATE270003T1 (de) | 2004-07-15 |
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