BR9714713A - Processos para o refino de acrilato de butila - Google Patents

Processos para o refino de acrilato de butila

Info

Publication number
BR9714713A
BR9714713A BR9714713-3A BR9714713A BR9714713A BR 9714713 A BR9714713 A BR 9714713A BR 9714713 A BR9714713 A BR 9714713A BR 9714713 A BR9714713 A BR 9714713A
Authority
BR
Brazil
Prior art keywords
butyl acrylate
butyl
bottoms
butanol
heavies
Prior art date
Application number
BR9714713-3A
Other languages
English (en)
Inventor
Fungau Ho
Vivek Julka
Original Assignee
Union Carbide Chem Plastic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/859,143 external-priority patent/US6605738B1/en
Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic
Publication of BR9714713A publication Critical patent/BR9714713A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/48—Separation; Purification; Stabilisation; Use of additives
    • C07C67/52—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation
    • C07C67/54—Separation; Purification; Stabilisation; Use of additives by change in the physical state, e.g. crystallisation by distillation
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

"PROCESSOS PARA O REFINO DE ACRILATO DE BUTILA" Correntes de acrilato de butila brutas, p.ex., a partir da reação de butanol e ácido acrílico, são refinadas usando uma coluna de destilação por fracionamento, para produzir uma fração de produtos de fundo contendo acrilato de butila e pesados, e uma fração de produto de topo contendo éter dibutílico, acetato de butila, butanol e acrilato de butila. A fração de produtos de fundo é então submetida à separação, p.ex., por destilação, para separar os pesados das frações de produtos de fundo, e para recuperar o acrilato de butila. Um processo para a produção de acrilato de butila é também divulgado, processo este que compreende não somente as etapas de refino acima mencionadas, como também inclui as etapas de retirar, da coluna de destilação por fracionamento, a fração de produto de topo e destilar a fração de produto de topo para recuperar uma corrente de produtos de fundo contendo butanol e acrilato de butila, pelo menos uma parte da mesma poderia ser reciclada para a reação com o ácido acrílico, para fazer o acrilato de butila, e recuperar os pesados separados, pelo menos uma parte dos mesmos poderia ser reciclada para uma zona de reação para a produção de acrilato de butila. São produzíveis quantidades de pelo menos 4540 kg (10.000 libras (avoir)) de um produto de acrilato de butila compreendendo pelo menos 99,8% em peso de acrilato de butila e contendo não mais do que cerca de 200 ppm de éter butílico e não mais do que cerca de 200 ppm de acetato de butila.
BR9714713-3A 1997-05-20 1997-05-27 Processos para o refino de acrilato de butila BR9714713A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/859,143 US6605738B1 (en) 1996-05-29 1997-05-20 Processes for refining butyl acrylate
PCT/US1997/008814 WO1998052904A1 (en) 1997-05-20 1997-05-27 Processes for refining butylacrylate

Publications (1)

Publication Number Publication Date
BR9714713A true BR9714713A (pt) 2000-07-04

Family

ID=25330156

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9714713-3A BR9714713A (pt) 1997-05-20 1997-05-27 Processos para o refino de acrilato de butila

Country Status (8)

Country Link
EP (1) EP0984918B1 (pt)
JP (1) JP3934163B2 (pt)
KR (1) KR100462266B1 (pt)
CN (1) CN1099405C (pt)
AT (1) ATE228109T1 (pt)
BR (1) BR9714713A (pt)
DE (1) DE69717314T2 (pt)
WO (1) WO1998052904A1 (pt)

Families Citing this family (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1028109A1 (en) * 1999-02-12 2000-08-16 Dsm N.V. Process for the preparation of epsilon-caprolactam
JP2003521478A (ja) * 1999-06-17 2003-07-15 ユニオン・カーバイド・ケミカルズ・アンド・プラスティックス・テクノロジー・コーポレイション 平衡律速反応を行う方法
US6482976B1 (en) 1999-06-17 2002-11-19 Union Carbide Chemicals & Plastics Technology Corporation Processes for conducting equilibrium-limited reactions
US6180820B1 (en) * 1999-09-14 2001-01-30 Celanese International Corporation Process for the production and purification of N-butyl acrylate
US6172258B1 (en) * 1999-09-14 2001-01-09 Celanese International Corporation Process for the production and purification of n-butyl acrylate
JP2001181233A (ja) * 1999-10-12 2001-07-03 Nippon Shokubai Co Ltd （メタ）アクリル酸エステルの製造方法
US6649787B1 (en) 1999-10-12 2003-11-18 Nippon Shokubai Co., Ltd. Method for preparing (meth) acrylic acid ester
WO2001085666A2 (en) * 2000-05-09 2001-11-15 Union Carbide Chemicals & Plastics Technology Corporation Improved refining processes
US7569721B2 (en) 2003-02-28 2009-08-04 Union Carbide Chemicals And Plastics Technology Corporation Process for conducting equilibrium-limited reactions
JP2008266159A (ja) * 2007-04-17 2008-11-06 Mitsubishi Chemicals Corp アクリル酸ブチルの精製方法
CN101932547A (zh) * 2008-01-18 2010-12-29 阿科玛股份有限公司 用于从丙烯酸酯重尾馏分中回收磺酸催化剂以及贵重产物的方法
JP5169899B2 (ja) * 2009-02-19 2013-03-27 東亞合成株式会社 アクリル酸アルキルエステルの製造方法
KR101144306B1 (ko) * 2010-08-26 2012-05-11 주식회사 엘지화학 알킬(메트)아크릴레이트의 제조 방법
FR3008971B1 (fr) * 2013-07-29 2016-08-19 Arkema France Procede de production en continu d'acrylates legers par esterification d'un acide acrylique de grade ester brut
FR3014870B1 (fr) * 2013-12-13 2015-12-11 Arkema France Procede de production d'esters (meth)acryliques
JP6287269B2 (ja) * 2014-01-30 2018-03-07 三菱ケミカル株式会社 アクリル酸ブチルの製造方法
KR101945322B1 (ko) 2014-11-28 2019-04-17 지멘스 메탈스 테크놀로지스 베르뫼겐스베르발퉁스 게엠베하 크라운 제어에 의한 금속 스트립 주조 방법
WO2016136930A1 (ja) * 2015-02-27 2016-09-01 株式会社クラレ （メタ）アクリル樹脂組成物の製造方法
CN104844456B (zh) * 2015-04-17 2017-06-13 江苏新东风化工科技有限公司 一种丙烯酸正丁酯废油回收工艺及装置
CN110937997A (zh) * 2019-12-09 2020-03-31 东营海德新材料有限公司 一种提高丙烯酸丁酯纯度的生产工艺
CN113121348A (zh) * 2021-03-15 2021-07-16 江苏新东风化工科技有限公司 一种丙烯酸正丁酯生产脱醚工艺
KR20240041972A (ko) 2021-07-29 2024-04-01 바스프 에스이 아크릴레이트의 연속 증류 방법
WO2023094252A1 (en) * 2021-11-25 2023-06-01 Basf Se Process for the production of c6-c12-alkyl (meth)acrylic esters

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2449811C2 (de) * 1974-10-19 1983-01-05 Hoechst Ag, 6000 Frankfurt Verfahren zur kontinuierlichen Herstellung von dibutylätherfreiem n-Butylacrylat
DE2552987C2 (de) * 1975-11-26 1983-09-29 Hoechst Ag, 6230 Frankfurt Verfahren zur kontinuierlichen Herstellung ätherfreier Acrylsäurealkylester
JPS5877845A (ja) * 1981-11-02 1983-05-11 Nippon Shokubai Kagaku Kogyo Co Ltd アクリル酸エステルまたはメタクリル酸エステルの製造方法
US4814493A (en) * 1983-07-05 1989-03-21 Hoechst Celanese Corporation Process for production of alkyl acrylates
JPH089567B2 (ja) * 1992-01-09 1996-01-31 株式会社日本触媒 アクリル酸製造においてアクリル酸を高純度に精製する方法
FR2723089B1 (fr) * 1994-07-28 1996-09-06 Atochem Elf Sa Procede de fabrication de l'acrylate de butyle par esterification directe
DE19536178A1 (de) * 1995-09-28 1997-04-03 Basf Ag Verfahren und Vorrichtung zur kontinuierlichen Herstellung von Alkylestern der (Meth)acrylsäure

Also Published As

Publication number Publication date
JP3934163B2 (ja) 2007-06-20
EP0984918B1 (en) 2002-11-20
ATE228109T1 (de) 2002-12-15
DE69717314D1 (de) 2003-01-02
JP2002507194A (ja) 2002-03-05
WO1998052904A1 (en) 1998-11-26
CN1254331A (zh) 2000-05-24
KR100462266B1 (ko) 2004-12-17
CN1099405C (zh) 2003-01-22
KR20010012468A (ko) 2001-02-15
DE69717314T2 (de) 2003-08-21
EP0984918A1 (en) 2000-03-15

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Legal Events

Date Code Title Description
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 04/11/2008, OBSERVADAS AS CONDICOES LEGAIS.

B25D Requested change of name of applicant approved

Owner name: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY LL

Free format text: ALTERADO DE: UNION CARBIDE CHEMICALS AND PLASTCS TECHNOLOGY CORPORATION

B25A Requested transfer of rights approved

Owner name: ARKEMA INC. (US)

Free format text: TRANSFERIDO DE: UNION CARBIDE CHEMICALS AND PLASTICS TECHNOLOGY LLC

B25A Requested transfer of rights approved

Owner name: THE DOW CHEMICAL COMPANY (US)

B25A Requested transfer of rights approved

Owner name: DOW GLOBAL TECHNOLOGIES LLC (US)

B21A Patent or certificate of addition expired [chapter 21.1 patent gazette]

Free format text: PATENTE EXTINTA EM 04.11.2018