BR0111340A - Copolìmeros de blocos de propileno de elevada fluidez - Google Patents
Copolìmeros de blocos de propileno de elevada fluidezInfo
- Publication number
- BR0111340A BR0111340A BR0111340-2A BR0111340A BR0111340A BR 0111340 A BR0111340 A BR 0111340A BR 0111340 A BR0111340 A BR 0111340A BR 0111340 A BR0111340 A BR 0111340A
- Authority
- BR
- Brazil
- Prior art keywords
- propylene
- bar
- ziegler
- polymerized
- propylene homopolymer
- Prior art date
Links
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 title abstract 5
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 title abstract 4
- 229920001400 block copolymer Polymers 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 abstract 4
- 229920001384 propylene homopolymer Polymers 0.000 abstract 4
- 239000011954 Ziegler–Natta catalyst Substances 0.000 abstract 3
- 239000007789 gas Substances 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 229920001577 copolymer Polymers 0.000 abstract 1
- 239000012530 fluid Substances 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000000178 monomer Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/06—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
- C08F297/08—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F10/04—Monomers containing three or four carbon atoms
- C08F10/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Artificial Filaments (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
"COPOLìMEROS DE BLOCOS DE PROPILENO DE ELEVADA FLUIDEZ". Compostos de 50 a 80% em peso de um homopolímero de propileno e de 10 a 70% em peso de um copolímero de propileno com 5 a 50% em peso de um C~ 2~-C~ 8~ alq-1-eno nele polimerizado, diferente do propileno, obtenível a partir da fase gasosa pela polimerização em dois estágios através de um sistema catalisador Ziegler-Natta, por meio do qual, em uma primeira etapa de polimerização, o propileno é polimerizado com uma pressão de 10 a 50 bar, uma temperatura de 50 a 100<198>C e um tempo médio de permanência da mistura de reação de 0,3 a 5 horas na presença de no mínimo 2,0% em volume - em relação ao volume total - de hidrogênio; então, o homopolímero de propileno obtido na primeira fase juntamente com o sistema catalisador Ziegler-Natta, é colocado em um reservatório intermediário, onde primeiramente permanece durante 0,01 a 5 minutos sob pressões inferiores a 5 bar e sob uma temperatura de 10 a 80<198>C e, em seguida, por compressão de uma mistura de gases, a pressão no reservatório intermediário é elevada novamente para 5 a 60 bar; após isso, o homopolímero de propileno, com o sistema catalisador Ziegler-Natta, é conduzido a uma segunda etapa de polimerização, onde, sob uma pressão de 10 a 50 bar, uma temperatura de 50 a 100<198>C e um tempo médio de permanência de 0,5 a 5 horas, no homopolímero de propileno é polimerizada uma mistura de propileno e C~ 2~-C~ 8~ alq-1-eno, sendo a proporção em peso dos monómeros reagentes na primeira e na segunda etapa de polimerização determinada de tal forma a se situar na faixa de 4:1 a 1:1.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10025727A DE10025727A1 (de) | 2000-05-25 | 2000-05-25 | Hochfließfähige Propylenblockcopolymerisate |
PCT/EP2001/005911 WO2001090208A1 (de) | 2000-05-25 | 2001-05-23 | Hochfliessfähige propylenblockcopolymerisate |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0111340A true BR0111340A (pt) | 2003-06-17 |
Family
ID=7643405
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0111340-2A BR0111340A (pt) | 2000-05-25 | 2001-05-23 | Copolìmeros de blocos de propileno de elevada fluidez |
Country Status (17)
Country | Link |
---|---|
US (1) | US7196140B2 (pt) |
EP (1) | EP1290053B1 (pt) |
JP (1) | JP2003535162A (pt) |
KR (1) | KR20030014243A (pt) |
CN (1) | CN1187387C (pt) |
AR (1) | AR030935A1 (pt) |
AT (1) | ATE271080T1 (pt) |
AU (1) | AU779011B2 (pt) |
BR (1) | BR0111340A (pt) |
CA (1) | CA2422598A1 (pt) |
DE (2) | DE10025727A1 (pt) |
ES (1) | ES2223859T3 (pt) |
PL (1) | PL360844A1 (pt) |
RU (1) | RU2268896C2 (pt) |
TR (1) | TR200402352T4 (pt) |
TW (1) | TW593375B (pt) |
WO (1) | WO2001090208A1 (pt) |
Families Citing this family (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7067591B2 (en) | 2001-01-10 | 2006-06-27 | Basell Poliolefine Italia S.P.A. | Block copolymers and process for their preparation |
DE10163075A1 (de) * | 2001-12-20 | 2003-07-10 | Basell Polyolefine Gmbh | Katalysatorsysteme von Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung |
EP1523509A1 (en) * | 2002-07-24 | 2005-04-20 | Basell Polyolefine GmbH | At least two-stage process for preparing propylene polymer compositions |
US20060003154A1 (en) * | 2004-06-30 | 2006-01-05 | Snowden Hue S | Extruded thermoplastic articles with enhanced surface segregation of internal melt additive |
JP2008539290A (ja) * | 2005-04-28 | 2008-11-13 | バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ | 熱成形用プロピレンポリマー組成物 |
EP1935938A1 (en) * | 2006-12-18 | 2008-06-25 | Borealis Technology Oy | Improved high melt flow heterophasic polypropylene copolymers |
KR101284938B1 (ko) * | 2008-09-22 | 2013-07-10 | 미쓰이 가가쿠 가부시키가이샤 | 프로필렌계 블록 공중합체, 이 공중합체를 포함하는 조성물 및 이들로부터 얻어지는 성형체 |
US20120010362A1 (en) * | 2009-04-02 | 2012-01-12 | Total Petrochemicals Research Feluy | Method for optimizing energy consumption in an extrusion process |
CN102731692A (zh) * | 2011-04-02 | 2012-10-17 | 中国石油化工股份有限公司 | 消除聚合物发粘的方法和阻粘剂 |
CN104558335B (zh) * | 2013-10-11 | 2017-06-09 | 中国石油化工股份有限公司 | 一种基于丙烯的三元共聚物的制备方法 |
BR112016010928B1 (pt) * | 2013-11-15 | 2021-03-09 | W.R. Grace & Co.-Conn. | processo para produzir polímero à base de propileno com porção reduzida de peso molecular alto |
US10400096B2 (en) * | 2014-03-14 | 2019-09-03 | Milliken & Company | Modified heterophasic polyolefin composition |
CN108351252B (zh) * | 2015-10-05 | 2021-03-09 | 海曼传感器有限责任公司 | 具有单片集成信号处理的高分辨率热电堆红外传感器阵列 |
WO2019094216A1 (en) * | 2017-11-13 | 2019-05-16 | W.R. Grace & Co.-Conn. | Catalyst components for propylene polymerization |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4621952A (en) * | 1981-07-28 | 1986-11-11 | Union Carbide Corporation | Fluidized bed discharge process |
DE3144312A1 (de) * | 1981-11-07 | 1983-05-19 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von propylen-ethylen-polymerisaten vom typ der sogenannten block-copolymerisate |
DE3214246A1 (de) * | 1982-04-17 | 1983-10-27 | Basf Ag, 6700 Ludwigshafen | Verfahren zum herstellen von propylen-ethylen-polymerisaten vom typ der sogenannten "block-copolymerisate" |
FR2577558B1 (fr) * | 1985-02-19 | 1987-03-06 | Bp Chimie Sa | Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse |
US4734448A (en) | 1985-07-10 | 1988-03-29 | Idemitsu Petrochemical Co., Ltd. | Propylene polymer composition |
DE3827565A1 (de) * | 1988-08-13 | 1990-02-15 | Basf Ag | Verfahren zum herstellen von propylen-ethylen-polymerisaten vom typ der sogenannten "schlagzaehmodifizierten polypropylene" |
EP0357394B1 (en) | 1988-08-31 | 1995-08-02 | Mitsubishi Chemical Corporation | Process for producing propylene block copolymer |
JP2664741B2 (ja) | 1988-10-05 | 1997-10-22 | 三菱化学株式会社 | 流動性の改良された粒状プロピレン共重合体の製造法 |
US5280074A (en) * | 1989-12-21 | 1994-01-18 | Hoechst Ag | Process for the preparation of a polypropylene molding composition |
DE4004087A1 (de) | 1990-02-10 | 1991-08-14 | Basf Ag | Copolymerisate des propylens |
EP0457455B2 (en) | 1990-05-14 | 2008-07-02 | Union Carbide Chemicals & Plastics Technology Corporation | Polymer compositions |
DE4117144A1 (de) * | 1991-05-25 | 1992-11-26 | Basf Ag | Hochfliessfaehige propylen-ethylen-copolymerisate |
DE4117842A1 (de) * | 1991-05-31 | 1992-12-03 | Basf Ag | Propylen-ethylen-copolymerisate aus drei verschiedenen bestandteilen |
US6300434B1 (en) * | 1991-05-31 | 2001-10-09 | Basell Polyolefin Gmbh | Propylene-ethylene copolymers made from three different constituents |
EP0534776A1 (en) | 1991-09-27 | 1993-03-31 | Sumitomo Chemical Company, Limited | Block copolymers of ethylene and propylene |
KR100341040B1 (ko) * | 1994-08-18 | 2002-11-23 | 칫소가부시키가이샤 | 고강성프로필렌-에틸렌블록공중합체조성물및이의제조방법 |
JP3355864B2 (ja) | 1995-04-24 | 2002-12-09 | チッソ株式会社 | 高剛性プロピレン・エチレンブロック共重合体の連続製造法 |
USH1722H (en) * | 1995-05-05 | 1998-04-07 | Goode; Mark Gregory | Process for producing polypropylene impact block copolymers |
DE19522283A1 (de) * | 1995-06-20 | 1997-01-02 | Basf Ag | Vorrichtung zurGasphasenpolymerisation von C¶2¶-C¶8¶-Alk-1-enen |
WO1997008218A1 (fr) * | 1995-08-31 | 1997-03-06 | Chisso Corporation | Compositions de copolymere propylene-ethylene et leur procede de production |
US6204336B1 (en) * | 1996-04-08 | 2001-03-20 | Sumitomo Chemical Company | High-rigidity ethylene/propylene block copolymer and process for the production thereof |
US6057407A (en) | 1997-01-08 | 2000-05-02 | Bp Amoco Corporation | High melt flow propylene polymer produced by gas-phase polymerization |
FI111848B (fi) | 1997-06-24 | 2003-09-30 | Borealis Tech Oy | Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi |
AU7921198A (en) | 1997-06-24 | 1999-01-04 | Borealis As | Process for preparing propylene polymers |
JP3558860B2 (ja) * | 1998-03-12 | 2004-08-25 | 三菱化学株式会社 | プロピレン系ブロック共重合体のゲル含量の推定方法 |
-
2000
- 2000-05-25 DE DE10025727A patent/DE10025727A1/de active Pending
-
2001
- 2001-05-23 AU AU62314/01A patent/AU779011B2/en not_active Ceased
- 2001-05-23 DE DE50102859T patent/DE50102859D1/de not_active Revoked
- 2001-05-23 PL PL36084401A patent/PL360844A1/xx not_active Application Discontinuation
- 2001-05-23 AT AT01936391T patent/ATE271080T1/de not_active IP Right Cessation
- 2001-05-23 CA CA002422598A patent/CA2422598A1/en not_active Abandoned
- 2001-05-23 ES ES01936391T patent/ES2223859T3/es not_active Expired - Lifetime
- 2001-05-23 WO PCT/EP2001/005911 patent/WO2001090208A1/de active IP Right Grant
- 2001-05-23 AR ARP010102448A patent/AR030935A1/es active IP Right Grant
- 2001-05-23 KR KR1020027015929A patent/KR20030014243A/ko active IP Right Grant
- 2001-05-23 JP JP2001587018A patent/JP2003535162A/ja active Pending
- 2001-05-23 RU RU2002134901/04A patent/RU2268896C2/ru not_active IP Right Cessation
- 2001-05-23 EP EP01936391A patent/EP1290053B1/de not_active Revoked
- 2001-05-23 TR TR2004/02352T patent/TR200402352T4/xx unknown
- 2001-05-23 CN CNB018132626A patent/CN1187387C/zh not_active Expired - Fee Related
- 2001-05-23 US US10/296,256 patent/US7196140B2/en not_active Expired - Lifetime
- 2001-05-23 BR BR0111340-2A patent/BR0111340A/pt not_active Application Discontinuation
- 2001-06-26 TW TW090112672A patent/TW593375B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
TR200402352T4 (tr) | 2004-12-21 |
EP1290053A1 (de) | 2003-03-12 |
CN1187387C (zh) | 2005-02-02 |
DE10025727A1 (de) | 2002-01-03 |
TW593375B (en) | 2004-06-21 |
AU779011B2 (en) | 2005-01-06 |
ES2223859T3 (es) | 2005-03-01 |
CA2422598A1 (en) | 2003-03-13 |
ATE271080T1 (de) | 2004-07-15 |
CN1444610A (zh) | 2003-09-24 |
EP1290053B1 (de) | 2004-07-14 |
RU2268896C2 (ru) | 2006-01-27 |
AU6231401A (en) | 2001-12-03 |
PL360844A1 (en) | 2004-09-20 |
US7196140B2 (en) | 2007-03-27 |
DE50102859D1 (en) | 2004-08-19 |
WO2001090208A1 (de) | 2001-11-29 |
US20050038208A1 (en) | 2005-02-17 |
AR030935A1 (es) | 2003-09-03 |
JP2003535162A (ja) | 2003-11-25 |
KR20030014243A (ko) | 2003-02-15 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B25D | Requested change of name of applicant approved |
Owner name: BASELL POLIOLEFINE ITALIA S.R.L. (IT) Free format text: ALTERADO DE: BASELL POLIOLEFINE ITALIA S.P.A. |
|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O DA LPI. |
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B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL. |