BR0111340A - Copolìmeros de blocos de propileno de elevada fluidez - Google Patents

Copolìmeros de blocos de propileno de elevada fluidez

Info

Publication number
BR0111340A
BR0111340A BR0111340-2A BR0111340A BR0111340A BR 0111340 A BR0111340 A BR 0111340A BR 0111340 A BR0111340 A BR 0111340A BR 0111340 A BR0111340 A BR 0111340A
Authority
BR
Brazil
Prior art keywords
propylene
bar
ziegler
polymerized
propylene homopolymer
Prior art date
Application number
BR0111340-2A
Other languages
English (en)
Inventor
Ulrich Dahn
Wolfgang Bidell
Hans-Juergen Zimmermann
Roland Hingmann
Joachim Roesch
Guenther Schweier
Juergen Oelze
Original Assignee
Basell Poliolefine Spa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=7643405&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR0111340(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Basell Poliolefine Spa filed Critical Basell Poliolefine Spa
Publication of BR0111340A publication Critical patent/BR0111340A/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F297/00Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
    • C08F297/06Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type
    • C08F297/08Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the coordination type polymerising mono-olefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/04Monomers containing three or four carbon atoms
    • C08F210/06Propene

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Artificial Filaments (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

"COPOLìMEROS DE BLOCOS DE PROPILENO DE ELEVADA FLUIDEZ". Compostos de 50 a 80% em peso de um homopolímero de propileno e de 10 a 70% em peso de um copolímero de propileno com 5 a 50% em peso de um C~ 2~-C~ 8~ alq-1-eno nele polimerizado, diferente do propileno, obtenível a partir da fase gasosa pela polimerização em dois estágios através de um sistema catalisador Ziegler-Natta, por meio do qual, em uma primeira etapa de polimerização, o propileno é polimerizado com uma pressão de 10 a 50 bar, uma temperatura de 50 a 100<198>C e um tempo médio de permanência da mistura de reação de 0,3 a 5 horas na presença de no mínimo 2,0% em volume - em relação ao volume total - de hidrogênio; então, o homopolímero de propileno obtido na primeira fase juntamente com o sistema catalisador Ziegler-Natta, é colocado em um reservatório intermediário, onde primeiramente permanece durante 0,01 a 5 minutos sob pressões inferiores a 5 bar e sob uma temperatura de 10 a 80<198>C e, em seguida, por compressão de uma mistura de gases, a pressão no reservatório intermediário é elevada novamente para 5 a 60 bar; após isso, o homopolímero de propileno, com o sistema catalisador Ziegler-Natta, é conduzido a uma segunda etapa de polimerização, onde, sob uma pressão de 10 a 50 bar, uma temperatura de 50 a 100<198>C e um tempo médio de permanência de 0,5 a 5 horas, no homopolímero de propileno é polimerizada uma mistura de propileno e C~ 2~-C~ 8~ alq-1-eno, sendo a proporção em peso dos monómeros reagentes na primeira e na segunda etapa de polimerização determinada de tal forma a se situar na faixa de 4:1 a 1:1.
BR0111340-2A 2000-05-25 2001-05-23 Copolìmeros de blocos de propileno de elevada fluidez BR0111340A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10025727A DE10025727A1 (de) 2000-05-25 2000-05-25 Hochfließfähige Propylenblockcopolymerisate
PCT/EP2001/005911 WO2001090208A1 (de) 2000-05-25 2001-05-23 Hochfliessfähige propylenblockcopolymerisate

Publications (1)

Publication Number Publication Date
BR0111340A true BR0111340A (pt) 2003-06-17

Family

ID=7643405

Family Applications (1)

Application Number Title Priority Date Filing Date
BR0111340-2A BR0111340A (pt) 2000-05-25 2001-05-23 Copolìmeros de blocos de propileno de elevada fluidez

Country Status (17)

Country Link
US (1) US7196140B2 (pt)
EP (1) EP1290053B1 (pt)
JP (1) JP2003535162A (pt)
KR (1) KR20030014243A (pt)
CN (1) CN1187387C (pt)
AR (1) AR030935A1 (pt)
AT (1) ATE271080T1 (pt)
AU (1) AU779011B2 (pt)
BR (1) BR0111340A (pt)
CA (1) CA2422598A1 (pt)
DE (2) DE10025727A1 (pt)
ES (1) ES2223859T3 (pt)
PL (1) PL360844A1 (pt)
RU (1) RU2268896C2 (pt)
TR (1) TR200402352T4 (pt)
TW (1) TW593375B (pt)
WO (1) WO2001090208A1 (pt)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7067591B2 (en) 2001-01-10 2006-06-27 Basell Poliolefine Italia S.P.A. Block copolymers and process for their preparation
DE10163075A1 (de) * 2001-12-20 2003-07-10 Basell Polyolefine Gmbh Katalysatorsysteme von Typ der Ziegler-Natta-Katalysatoren und ein Verfahren zu deren Herstellung
EP1523509A1 (en) * 2002-07-24 2005-04-20 Basell Polyolefine GmbH At least two-stage process for preparing propylene polymer compositions
US20060003154A1 (en) * 2004-06-30 2006-01-05 Snowden Hue S Extruded thermoplastic articles with enhanced surface segregation of internal melt additive
JP2008539290A (ja) * 2005-04-28 2008-11-13 バーゼル・ポリオレフィン・イタリア・ソチエタ・ア・レスポンサビリタ・リミタータ 熱成形用プロピレンポリマー組成物
EP1935938A1 (en) * 2006-12-18 2008-06-25 Borealis Technology Oy Improved high melt flow heterophasic polypropylene copolymers
KR101284938B1 (ko) * 2008-09-22 2013-07-10 미쓰이 가가쿠 가부시키가이샤 프로필렌계 블록 공중합체, 이 공중합체를 포함하는 조성물 및 이들로부터 얻어지는 성형체
US20120010362A1 (en) * 2009-04-02 2012-01-12 Total Petrochemicals Research Feluy Method for optimizing energy consumption in an extrusion process
CN102731692A (zh) * 2011-04-02 2012-10-17 中国石油化工股份有限公司 消除聚合物发粘的方法和阻粘剂
CN104558335B (zh) * 2013-10-11 2017-06-09 中国石油化工股份有限公司 一种基于丙烯的三元共聚物的制备方法
BR112016010928B1 (pt) * 2013-11-15 2021-03-09 W.R. Grace & Co.-Conn. processo para produzir polímero à base de propileno com porção reduzida de peso molecular alto
US10400096B2 (en) * 2014-03-14 2019-09-03 Milliken & Company Modified heterophasic polyolefin composition
CN108351252B (zh) * 2015-10-05 2021-03-09 海曼传感器有限责任公司 具有单片集成信号处理的高分辨率热电堆红外传感器阵列
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4621952A (en) * 1981-07-28 1986-11-11 Union Carbide Corporation Fluidized bed discharge process
DE3144312A1 (de) * 1981-11-07 1983-05-19 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von propylen-ethylen-polymerisaten vom typ der sogenannten block-copolymerisate
DE3214246A1 (de) * 1982-04-17 1983-10-27 Basf Ag, 6700 Ludwigshafen Verfahren zum herstellen von propylen-ethylen-polymerisaten vom typ der sogenannten "block-copolymerisate"
FR2577558B1 (fr) * 1985-02-19 1987-03-06 Bp Chimie Sa Polymerisation en plusieurs etapes d'alpha-olefines en phase gazeuse
US4734448A (en) 1985-07-10 1988-03-29 Idemitsu Petrochemical Co., Ltd. Propylene polymer composition
DE3827565A1 (de) * 1988-08-13 1990-02-15 Basf Ag Verfahren zum herstellen von propylen-ethylen-polymerisaten vom typ der sogenannten "schlagzaehmodifizierten polypropylene"
EP0357394B1 (en) 1988-08-31 1995-08-02 Mitsubishi Chemical Corporation Process for producing propylene block copolymer
JP2664741B2 (ja) 1988-10-05 1997-10-22 三菱化学株式会社 流動性の改良された粒状プロピレン共重合体の製造法
US5280074A (en) * 1989-12-21 1994-01-18 Hoechst Ag Process for the preparation of a polypropylene molding composition
DE4004087A1 (de) 1990-02-10 1991-08-14 Basf Ag Copolymerisate des propylens
EP0457455B2 (en) 1990-05-14 2008-07-02 Union Carbide Chemicals & Plastics Technology Corporation Polymer compositions
DE4117144A1 (de) * 1991-05-25 1992-11-26 Basf Ag Hochfliessfaehige propylen-ethylen-copolymerisate
DE4117842A1 (de) * 1991-05-31 1992-12-03 Basf Ag Propylen-ethylen-copolymerisate aus drei verschiedenen bestandteilen
US6300434B1 (en) * 1991-05-31 2001-10-09 Basell Polyolefin Gmbh Propylene-ethylene copolymers made from three different constituents
EP0534776A1 (en) 1991-09-27 1993-03-31 Sumitomo Chemical Company, Limited Block copolymers of ethylene and propylene
KR100341040B1 (ko) * 1994-08-18 2002-11-23 칫소가부시키가이샤 고강성프로필렌-에틸렌블록공중합체조성물및이의제조방법
JP3355864B2 (ja) 1995-04-24 2002-12-09 チッソ株式会社 高剛性プロピレン・エチレンブロック共重合体の連続製造法
USH1722H (en) * 1995-05-05 1998-04-07 Goode; Mark Gregory Process for producing polypropylene impact block copolymers
DE19522283A1 (de) * 1995-06-20 1997-01-02 Basf Ag Vorrichtung zurGasphasenpolymerisation von C¶2¶-C¶8¶-Alk-1-enen
WO1997008218A1 (fr) * 1995-08-31 1997-03-06 Chisso Corporation Compositions de copolymere propylene-ethylene et leur procede de production
US6204336B1 (en) * 1996-04-08 2001-03-20 Sumitomo Chemical Company High-rigidity ethylene/propylene block copolymer and process for the production thereof
US6057407A (en) 1997-01-08 2000-05-02 Bp Amoco Corporation High melt flow propylene polymer produced by gas-phase polymerization
FI111848B (fi) 1997-06-24 2003-09-30 Borealis Tech Oy Menetelmä ja laitteisto propeenin homo- ja kopolymeerien valmistamiseksi
AU7921198A (en) 1997-06-24 1999-01-04 Borealis As Process for preparing propylene polymers
JP3558860B2 (ja) * 1998-03-12 2004-08-25 三菱化学株式会社 プロピレン系ブロック共重合体のゲル含量の推定方法

Also Published As

Publication number Publication date
TR200402352T4 (tr) 2004-12-21
EP1290053A1 (de) 2003-03-12
CN1187387C (zh) 2005-02-02
DE10025727A1 (de) 2002-01-03
TW593375B (en) 2004-06-21
AU779011B2 (en) 2005-01-06
ES2223859T3 (es) 2005-03-01
CA2422598A1 (en) 2003-03-13
ATE271080T1 (de) 2004-07-15
CN1444610A (zh) 2003-09-24
EP1290053B1 (de) 2004-07-14
RU2268896C2 (ru) 2006-01-27
AU6231401A (en) 2001-12-03
PL360844A1 (en) 2004-09-20
US7196140B2 (en) 2007-03-27
DE50102859D1 (en) 2004-08-19
WO2001090208A1 (de) 2001-11-29
US20050038208A1 (en) 2005-02-17
AR030935A1 (es) 2003-09-03
JP2003535162A (ja) 2003-11-25
KR20030014243A (ko) 2003-02-15

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Legal Events

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B25D Requested change of name of applicant approved

Owner name: BASELL POLIOLEFINE ITALIA S.R.L. (IT)

Free format text: ALTERADO DE: BASELL POLIOLEFINE ITALIA S.P.A.

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09B Patent application refused [chapter 9.2 patent gazette]

Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O DA LPI.

B09B Patent application refused [chapter 9.2 patent gazette]

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