BR0102576A - Processo e equipamento de fabricação para a preparação de acetais ou cetais - Google Patents
Processo e equipamento de fabricação para a preparação de acetais ou cetaisInfo
- Publication number
- BR0102576A BR0102576A BR0102576-7A BR0102576A BR0102576A BR 0102576 A BR0102576 A BR 0102576A BR 0102576 A BR0102576 A BR 0102576A BR 0102576 A BR0102576 A BR 0102576A
- Authority
- BR
- Brazil
- Prior art keywords
- acetals
- ketals
- preparation
- ketone
- alcohol
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title abstract 4
- 238000002360 preparation method Methods 0.000 title abstract 4
- 150000001241 acetals Chemical class 0.000 title abstract 2
- 238000000034 method Methods 0.000 abstract 5
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 abstract 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 abstract 1
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 239000011951 cationic catalyst Substances 0.000 abstract 1
- 238000004821 distillation Methods 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 239000012528 membrane Substances 0.000 abstract 1
- 238000005373 pervaporation Methods 0.000 abstract 1
- 230000002441 reversible effect Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000011973 solid acid Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/36—Pervaporation; Membrane distillation; Liquid permeation
- B01D61/362—Pervaporation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/48—Preparation of compounds having groups
- C07C41/50—Preparation of compounds having groups by reactions producing groups
- C07C41/56—Preparation of compounds having groups by reactions producing groups by condensation of aldehydes, paraformaldehyde, or ketones
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
- C07C41/48—Preparation of compounds having groups
- C07C41/58—Separation; Purification; Stabilisation; Use of additives
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Water Supply & Treatment (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
Patente de Invenção: "PROCESSO E EQUIPAMENTO DE FABRICAçãO PARA A PREPARAçãO DE ACETAIS OU CETAIS". A presente invenção refere-se a um novo processo para a preparação de acetais e cetais. Como se sabe, os acetais e os cetais podem ser preparados por reação de um aldeido ou uma cetona com um álcool na presença de um catalisador catiónico. No entanto, a reação é reversível e, em temperatura ambiente ou acima, o equilibrio da reação é desviado para o lado dos materiais de partida, acetal ou cetona, e álcool. A invenção fornece um novo processo para a preparação contínua de acetais e cetais na forma concentrada e evita procedimentos de destilação de energia concentrada dos processos de fabricação convencionais, que freq³entemente tornam-se difíceis pela formação de azeótropos. A presente invenção refere-se ainda a um equipamento de fabricação para a realização do processo da invenção substancialmente como mostrado na figura 1 que compreende um reator (1) contendo um ácido sólido; um recipiente (2) que contém uma base sólida; e uma unidade de pervaporação (3) que tem uma membrana que é permeável para água.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00113463 | 2000-06-26 |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0102576A true BR0102576A (pt) | 2002-03-19 |
Family
ID=8169065
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0102576-7A BR0102576A (pt) | 2000-06-26 | 2001-06-26 | Processo e equipamento de fabricação para a preparação de acetais ou cetais |
Country Status (7)
Country | Link |
---|---|
US (2) | US6528025B1 (pt) |
JP (1) | JP2002020339A (pt) |
KR (1) | KR20020001588A (pt) |
CN (1) | CN1217884C (pt) |
BR (1) | BR0102576A (pt) |
CA (1) | CA2351124A1 (pt) |
TW (1) | TWI225047B (pt) |
Families Citing this family (39)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2001038811A1 (fr) | 1999-11-26 | 2001-05-31 | Nkk Corporation | Materiau de stockage thermique utilisant un dispositif de stockage hydrate et thermique et procede de production de ce materiau |
EP1510763B1 (en) * | 2002-05-31 | 2012-02-01 | JFE Engineering Corporation | Apparatus for producing hydrate slurry |
DE102004049056A1 (de) * | 2004-10-08 | 2006-04-13 | Ticona Gmbh | Verfahren zur Herstellung und Reinigung von zyklischen Formalen |
JP2006289158A (ja) * | 2005-04-05 | 2006-10-26 | Mitsubishi Heavy Ind Ltd | アセタール合成触媒及びアセタール製造方法 |
JP4690780B2 (ja) * | 2005-06-06 | 2011-06-01 | 三菱重工業株式会社 | ケタール合成装置及びケタール合成方法 |
JP4949643B2 (ja) * | 2005-06-06 | 2012-06-13 | 三菱重工業株式会社 | ケタール合成装置及びケタール合成方法 |
MY166613A (en) | 2005-11-22 | 2018-07-17 | Gfbiochemicals Ltd | Glycerol levulinate ketals and their use |
WO2009032905A1 (en) | 2007-09-04 | 2009-03-12 | Segetis, Inc. | Ketal compounds from polyols and oxocarboxylates |
MX325514B (es) * | 2007-10-09 | 2014-11-21 | Segetis Inc | Metodo para elaborar cetales y acetales. |
US8653223B2 (en) * | 2008-04-16 | 2014-02-18 | Segetis, Inc. | Transketalized compositions, synthesis, and applications |
US8575367B2 (en) * | 2008-09-25 | 2013-11-05 | Segetis, Inc. | Ketal ester derivatives |
WO2010088434A1 (en) * | 2009-02-02 | 2010-08-05 | Tate And Lyle Ingredients Americas, Inc. | Pre-treatment of crude alcohol or furan feed to a vapor permeation apparatus |
PT104496B (pt) * | 2009-04-08 | 2011-03-14 | Univ Do Porto | Reactor de membranas adsorptivo de leito móvel simulado, novo processo híbrido de saparação e respectivas utilizações |
US9012570B2 (en) * | 2009-04-18 | 2015-04-21 | Eastman Chemical Company | Continuous production of poly(vinyl butyral) |
US7960503B2 (en) | 2009-05-26 | 2011-06-14 | Solutia, Inc. | Continuous washing of poly(vinyl butyral) |
KR101808867B1 (ko) | 2009-06-22 | 2018-01-18 | 세게티스, 인코포레이티드. | 케탈 화합물 및 이의 용도 |
CN102970967A (zh) | 2010-05-10 | 2013-03-13 | 赛格提斯有限公司 | 芳香制剂、其制备方法以及包含其的制品 |
EP2601184B1 (en) | 2010-08-03 | 2015-12-16 | Segetis, Inc. | Methods for the manufacture of ketals |
JP5805764B2 (ja) | 2010-08-12 | 2015-11-10 | セゲティス インコーポレーテッドSegetis,Inc | カルボキシエステルケタール除去組成物、それらの製造方法及びそれらの使用 |
US9074065B2 (en) | 2010-08-12 | 2015-07-07 | Segetis, Inc. | Latex coating compositions including carboxy ester ketal coalescents, methods of manufacture, and uses thereof |
EP2613760A2 (en) | 2010-09-07 | 2013-07-17 | Segetis, Inc. | Compositions for dyeing keratin fibers |
CN103154158B (zh) | 2010-10-18 | 2017-04-05 | Gf生化有限公司 | 包含羧基酯缩酮的水可稀释型涂料组合物、其生产方法和用途 |
CN103189372A (zh) | 2010-11-11 | 2013-07-03 | 赛格提斯公司 | 多羟基缩酮酯加合物、其制造方法和用途 |
US8507718B2 (en) | 2010-11-11 | 2013-08-13 | Segetis, Inc. | Ketocarboxylic acids, methods of manufacture and uses thereof |
BR112013011149A2 (pt) | 2010-11-11 | 2016-08-02 | Segetis Inc | adutos poliacetal, métodos de fabricação e seus usos. |
CN102079740A (zh) * | 2010-12-07 | 2011-06-01 | 尹华芳 | 一种丁醛乙二醇缩醛的制备方法 |
WO2013004626A1 (en) | 2011-07-06 | 2013-01-10 | Dsm Ip Assets B.V. | Process for preparing acetals and ketals |
CN107673955A (zh) | 2011-07-06 | 2018-02-09 | 帝斯曼知识产权资产管理有限公司 | 通过渗透蒸发的方式制备或回收缩醛或缩酮的方法 |
CN102731273B (zh) * | 2012-07-09 | 2014-11-26 | 北京大学 | 一种缩醛的制备方法 |
WO2014047428A1 (en) | 2012-09-21 | 2014-03-27 | Segetis, Inc. | Cleaning, surfactant, and personal care compositions |
AU2013352172A1 (en) | 2012-11-29 | 2015-06-11 | Gfbiochemicals Limited | Carboxy ester ketals, methods of manufacture, and uses thereof |
CN104326888B (zh) * | 2014-09-27 | 2016-06-08 | 安徽华甬新材料有限公司 | 一种2,2-二甲氧基丙烷制备方法 |
CN105817228B (zh) * | 2016-04-15 | 2018-11-23 | 黄山学院 | 直接使用粉煤灰催化制备环己酮二醇缩酮类化合物的方法 |
CN106540550A (zh) * | 2016-11-02 | 2017-03-29 | 东方红升江苏新能源有限公司 | 用于制取聚甲氧基二甲醚的原料膜脱水方法 |
CN106631720B (zh) * | 2016-11-02 | 2020-06-05 | 东方红升江苏新能源有限公司 | 以稀甲醛和甲缩醛为原料直接合成聚甲氧基二甲醚的方法 |
CN110304997B (zh) * | 2018-03-20 | 2022-02-11 | 中国石油化工股份有限公司 | 一种2,2-二甲氧基丙烷的生产方法 |
CN110227558B (zh) * | 2019-06-18 | 2022-03-11 | 万华化学集团股份有限公司 | 一种用于制备缩醛/酮的固体酸催化剂及其制备方法和应用 |
CN112250659B (zh) * | 2020-10-21 | 2021-12-21 | 江苏阿尔法药业股份有限公司 | 一种阿托伐他汀钙中间体的合成方法 |
CN113461498B (zh) * | 2021-07-19 | 2023-04-25 | 老河口光联科技有限公司 | 一种缩醛的环保型制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2929827A1 (de) | 1979-07-23 | 1981-02-26 | Basf Ag | Verfahren zur kontinuierlichen herstellung von 2,2-dimethoxypropan |
DE3220570A1 (de) | 1982-06-01 | 1983-12-01 | GFT Ingenieurbüro für Industrieanlagenbau, 6650 Homburg | Mehrschichtige membran und ihre verwendung zur trennung von fluessigkeitsgemischen nach dem pervaporationsverfahren |
US5156740A (en) | 1982-06-01 | 1992-10-20 | Gft Ingenieurburo Fur Industrieanlagenbau | Multi-layer membrane and the use thereof for the separation of liquid mixtures according to the pervaporation process |
US4775447A (en) * | 1984-06-18 | 1988-10-04 | Sun Refining And Marketing Company | Process for the production of 2,2-dimethoxypropane |
US5717081A (en) | 1993-09-17 | 1998-02-10 | Unichema Chemie B.V. | Process for producing an alkylglycoside using a pervaporation membrane to remove reaction water |
DE4431994A1 (de) | 1994-09-08 | 1996-03-14 | Degussa | Verfahren zur Herstellung von 1,1,3-Trialkoxypropan |
DE19617893C1 (de) * | 1996-05-04 | 1997-10-02 | Hoechst Ag | Verfahren zur Herstellung von Polyvinylacetalen und -ketalen |
DE19811451C1 (de) | 1998-03-17 | 1999-10-14 | Henkel Kgaa | Verfahren zur Acetalisierung bzw. Ketalisierung |
-
2000
- 2000-06-29 US US09/606,918 patent/US6528025B1/en not_active Expired - Fee Related
-
2001
- 2001-06-20 CA CA002351124A patent/CA2351124A1/en not_active Abandoned
- 2001-06-21 TW TW090115172A patent/TWI225047B/zh not_active IP Right Cessation
- 2001-06-22 JP JP2001189872A patent/JP2002020339A/ja not_active Withdrawn
- 2001-06-25 KR KR1020010036250A patent/KR20020001588A/ko not_active Application Discontinuation
- 2001-06-26 CN CN011226013A patent/CN1217884C/zh not_active Expired - Fee Related
- 2001-06-26 BR BR0102576-7A patent/BR0102576A/pt not_active IP Right Cessation
-
2002
- 2002-11-07 US US10/290,018 patent/US6806392B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
JP2002020339A (ja) | 2002-01-23 |
CN1330058A (zh) | 2002-01-09 |
CA2351124A1 (en) | 2001-12-26 |
US6528025B1 (en) | 2003-03-04 |
CN1217884C (zh) | 2005-09-07 |
KR20020001588A (ko) | 2002-01-09 |
US6806392B2 (en) | 2004-10-19 |
US20040106832A1 (en) | 2004-06-03 |
TWI225047B (en) | 2004-12-11 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B25A | Requested transfer of rights approved |
Free format text: DSM IP ASSETS B.V. (NL) |
|
B03H | Publication of an application: rectification [chapter 3.8 patent gazette] |
Free format text: REFERENTE A RPI 1628 DE 19/03/2002, ITEM 72. |
|
B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 8A ANUIDADE. |
|
B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 DA RPI 2012 DE 28/07/2009. |