BG107525A - Усъвършенстван катализатор за производство на акрилонитрил - Google Patents
Усъвършенстван катализатор за производство на акрилонитрил Download PDFInfo
- Publication number
- BG107525A BG107525A BG107525D BG10752503D BG107525A BG 107525 A BG107525 A BG 107525A BG 107525 D BG107525 D BG 107525D BG 10752503 D BG10752503 D BG 10752503D BG 107525 A BG107525 A BG 107525A
- Authority
- BG
- Bulgaria
- Prior art keywords
- mixtures
- catalyst
- acrylonitrile
- molybdenum
- bismuth
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title claims abstract description 77
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title description 8
- 239000000203 mixture Substances 0.000 claims abstract description 61
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000011777 magnesium Substances 0.000 claims abstract description 21
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 229910052749 magnesium Inorganic materials 0.000 claims abstract description 18
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 18
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims abstract description 18
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 17
- 229910052744 lithium Inorganic materials 0.000 claims abstract description 16
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 16
- 239000011734 sodium Substances 0.000 claims abstract description 16
- 238000000034 method Methods 0.000 claims abstract description 15
- 229910052701 rubidium Inorganic materials 0.000 claims abstract description 13
- 239000010941 cobalt Substances 0.000 claims abstract description 11
- 229910017052 cobalt Inorganic materials 0.000 claims abstract description 11
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052684 Cerium Inorganic materials 0.000 claims abstract description 10
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 10
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052792 caesium Inorganic materials 0.000 claims abstract description 10
- GWXLDORMOJMVQZ-UHFFFAOYSA-N cerium Chemical compound [Ce] GWXLDORMOJMVQZ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 10
- 150000001336 alkenes Chemical class 0.000 claims abstract description 9
- 229910052797 bismuth Inorganic materials 0.000 claims abstract description 9
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 9
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 9
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims abstract description 8
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims abstract description 8
- 230000003197 catalytic effect Effects 0.000 claims abstract description 8
- 229910052732 germanium Inorganic materials 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 8
- 229910052750 molybdenum Inorganic materials 0.000 claims abstract description 8
- 239000011733 molybdenum Substances 0.000 claims abstract description 8
- 229910052718 tin Inorganic materials 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims abstract description 7
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052716 thallium Inorganic materials 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000011591 potassium Substances 0.000 claims abstract description 6
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 claims abstract description 6
- IGLNJRXAVVLDKE-UHFFFAOYSA-N rubidium atom Chemical compound [Rb] IGLNJRXAVVLDKE-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 229910021529 ammonia Inorganic materials 0.000 claims description 9
- 229910052738 indium Inorganic materials 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- 239000007789 gas Substances 0.000 claims description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052726 zirconium Inorganic materials 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 229910001882 dioxygen Inorganic materials 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims 1
- 239000012808 vapor phase Substances 0.000 claims 1
- 229910052748 manganese Inorganic materials 0.000 abstract description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 16
- 238000007254 oxidation reaction Methods 0.000 description 15
- 230000003647 oxidation Effects 0.000 description 13
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 229910052760 oxygen Inorganic materials 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- HGINCPLSRVDWNT-UHFFFAOYSA-N Acrolein Chemical compound C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 4
- -1 alkali metal salt Chemical class 0.000 description 4
- 238000001354 calcination Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- DTDQFVRSJWCWNK-UHFFFAOYSA-N [Fe].[Bi].[Mo] Chemical compound [Fe].[Bi].[Mo] DTDQFVRSJWCWNK-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 238000000975 co-precipitation Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- QGAVSDVURUSLQK-UHFFFAOYSA-N ammonium heptamolybdate Chemical compound N.N.N.N.N.N.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo] QGAVSDVURUSLQK-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 2
- 150000002823 nitrates Chemical class 0.000 description 2
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910000608 Fe(NO3)3.9H2O Inorganic materials 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- BYUANIDVEAKBHT-UHFFFAOYSA-N [Mo].[Bi] Chemical compound [Mo].[Bi] BYUANIDVEAKBHT-UHFFFAOYSA-N 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- QGUAJWGNOXCYJF-UHFFFAOYSA-N cobalt dinitrate hexahydrate Chemical compound O.O.O.O.O.O.[Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O QGUAJWGNOXCYJF-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- RXPAJWPEYBDXOG-UHFFFAOYSA-N hydron;methyl 4-methoxypyridine-2-carboxylate;chloride Chemical compound Cl.COC(=O)C1=CC(OC)=CC=N1 RXPAJWPEYBDXOG-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002506 iron compounds Chemical class 0.000 description 1
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001960 metal nitrate Inorganic materials 0.000 description 1
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000002751 molybdenum Chemical class 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C253/00—Preparation of carboxylic acid nitriles
- C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
- C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/641,380 US6458742B1 (en) | 2000-08-17 | 2000-08-17 | Catalyst for the manufacture of acrylonitrile |
| PCT/US2001/024253 WO2002013963A2 (en) | 2000-08-17 | 2001-08-02 | Improved catalyst for the manufacture of acrylonitrile |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BG107525A true BG107525A (bg) | 2003-12-31 |
Family
ID=24572105
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG107525A BG66322A (en) | 2000-08-17 | 2003-02-05 | IMPROVED KATHIZER FOR PRODUCING ACRILLONTRYL |
| BG107525D BG107525A (bg) | 2000-08-17 | 2003-02-05 | Усъвършенстван катализатор за производство на акрилонитрил |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BG107525A BG66322A (en) | 2000-08-17 | 2003-02-05 | IMPROVED KATHIZER FOR PRODUCING ACRILLONTRYL |
Country Status (17)
| Country | Link |
|---|---|
| US (2) | US6458742B1 (ko) |
| EP (1) | EP1309402B1 (ko) |
| JP (1) | JP4937487B2 (ko) |
| KR (1) | KR100786051B1 (ko) |
| CN (1) | CN1255215C (ko) |
| AT (1) | ATE363944T1 (ko) |
| AU (1) | AU2001278136A1 (ko) |
| BG (2) | BG66322A (ko) |
| BR (1) | BR0113310B1 (ko) |
| CA (1) | CA2417987C (ko) |
| DE (1) | DE60128811T2 (ko) |
| ES (1) | ES2287146T3 (ko) |
| MX (1) | MXPA03001409A (ko) |
| RU (1) | RU2266784C2 (ko) |
| TW (1) | TWI284058B (ko) |
| WO (1) | WO2002013963A2 (ko) |
| ZA (1) | ZA200301006B (ko) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2343123B1 (en) * | 2001-11-08 | 2021-01-06 | Mitsubishi Chemical Corporation | METHOD FOR PREPARATION of a COMPOSITE OXIDE CATALYST |
| US7071140B2 (en) * | 2002-12-02 | 2006-07-04 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile |
| MXPA05005760A (es) * | 2002-12-02 | 2005-09-08 | Standard Oil Co | Catalizador de oxidos mixtos de k, cs, ce, cr, co, ni, fe, bi, y mo para la manufactura de acrilonitrilo. |
| CN100408173C (zh) * | 2005-08-15 | 2008-08-06 | 中国石油化工股份有限公司 | 制备丙烯腈的流化床催化剂 |
| US7456313B2 (en) * | 2006-01-10 | 2008-11-25 | Rohm And Haas Company | Liquid-phase (AMM)oxidation process |
| US7576232B2 (en) * | 2006-05-02 | 2009-08-18 | Ineos Usa Llc | In situ modification of molybdenum-based catalysts |
| JP5483818B2 (ja) * | 2006-10-26 | 2014-05-07 | 三菱レイヨン株式会社 | アクリロニトリル製造用流動床触媒およびアクリロニトリルの製造方法 |
| JP5491037B2 (ja) * | 2009-01-30 | 2014-05-14 | 旭化成ケミカルズ株式会社 | アクリロニトリルの製造用触媒及びアクリロニトリルの製造方法 |
| US8420566B2 (en) * | 2010-03-23 | 2013-04-16 | Ineos Usa Llc | High efficiency ammoxidation process and mixed metal oxide catalysts |
| US8455388B2 (en) * | 2010-03-23 | 2013-06-04 | Ineos Usa Llc | Attrition resistant mixed metal oxide ammoxidation catalysts |
| US8258073B2 (en) * | 2010-03-23 | 2012-09-04 | Ineos Usa Llc | Process for preparing improved mixed metal oxide ammoxidation catalysts |
| US8153546B2 (en) | 2010-03-23 | 2012-04-10 | Ineos Usa Llc | Mixed metal oxide ammoxidation catalysts |
| US9433929B2 (en) * | 2011-09-21 | 2016-09-06 | Ineos Europe Ag | Mixed metal oxide catalysts |
| US8835666B2 (en) * | 2012-11-26 | 2014-09-16 | Ineos Usa Llc | Pre calcination additives for mixed metal oxide ammoxidation catalysts |
| CN103894203B (zh) * | 2012-12-27 | 2017-02-08 | 中国石油化工股份有限公司 | 烯烃氨氧化反应高负荷催化剂 |
| FR3004713B1 (fr) * | 2013-04-17 | 2015-05-15 | Centre Nat Rech Scient | Procede de production de nitriles mettant en oeuvre un catalyseur a base d'antimoine et de fer. |
| BR112016027658B1 (pt) * | 2014-05-29 | 2021-09-28 | Ineos Europe Ag | Composições catalíticas |
| US9211527B1 (en) * | 2014-05-29 | 2015-12-15 | Ineos Europe Ag | Selective ammoxidation catalysts |
| JP6905531B2 (ja) | 2016-01-09 | 2021-07-21 | アセンド・パフォーマンス・マテリアルズ・オペレーションズ・リミテッド・ライアビリティ・カンパニーＡｓｃｅｎｄ Ｐｅｒｆｏｒｍａｎｃｅ Ｍａｔｅｒｉａｌｓ Ｏｐｅｒａｔｉｏｎｓ Ｌｌｃ | アクリロニトリル反応器供給物流れでのシアン化水素の直接生成のための触媒組成物および方法 |
| CN107282094B (zh) * | 2016-04-13 | 2020-04-17 | 中国石油化工股份有限公司 | 氨氧化法丙烯腈催化剂 |
| CN106000461A (zh) * | 2016-05-27 | 2016-10-12 | 张玲 | 一种甲基丙烯腈催化剂的制备方法 |
| US10626082B2 (en) | 2016-10-11 | 2020-04-21 | Ineos Europe Ag | Ammoxidation catalyst with selective co-product HCN production |
| KR102519507B1 (ko) * | 2019-09-30 | 2023-04-07 | 주식회사 엘지화학 | 프로필렌의 암모산화용 촉매, 이의 제조 방법, 및 이를 이용한 프로필렌의 암모산화 방법 |
| CN114669306B (zh) * | 2022-03-27 | 2023-11-28 | 上海师范大学 | (甲基)丙烯醛氨氧化法制(甲基)丙烯腈的催化剂及其制备方法和应用 |
Family Cites Families (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS57130548A (en) * | 1981-02-05 | 1982-08-13 | Mitsubishi Chem Ind Ltd | Catalyst composition |
| US4746753A (en) | 1981-04-29 | 1988-05-24 | The Standard Oil Company | Preparation of acrylonitrile from propylene, oxygen and ammonia in the presence of an alkali metal promoted bismuth, cerium, molybdenum, tungsten catalyst |
| US4939286A (en) | 1985-09-10 | 1990-07-03 | The Standard Oil Company | Promoted bismuth cerium molybdate catalysts |
| JPS63122642A (ja) * | 1986-11-11 | 1988-05-26 | Mitsubishi Rayon Co Ltd | メタクロレイン及びメタクリル酸の製造法 |
| JPH0267556A (ja) * | 1988-09-02 | 1990-03-07 | Fuji Photo Film Co Ltd | ハロゲン化銀感光材料の処理方法 |
| US5093299A (en) * | 1990-01-09 | 1992-03-03 | The Standard Oil Company | Catalyst for process for the manufacture of acrylonitrile and methacrylonitrile |
| US5212137A (en) * | 1990-01-09 | 1993-05-18 | Standard Oil Company | Catalyst for the manufacture of acrylonitrile and methacrylonitrile |
| US5175334A (en) | 1990-01-09 | 1992-12-29 | The Standard Oil Company | Process for the manufacture of acrylonitrile and methacrylonitrile |
| US5134105A (en) | 1990-03-19 | 1992-07-28 | The Standard Oil Company | Catalyst for propylene ammoxidation to acrylonitrile |
| US5235088A (en) | 1990-03-19 | 1993-08-10 | The Standard Oil Company | Process and catalyst for propylene ammoxidation to acrylonitrile |
| DE4220859A1 (de) * | 1992-06-25 | 1994-01-05 | Basf Ag | Multimetalloxidmassen |
| US5583086A (en) * | 1993-03-09 | 1996-12-10 | Basf Aktiengesellschaft | Cesium containing multimetal oxide catalyst compositions for the preparation of methacrolein by gas-phase-catalytic oxidation |
| JP3534431B2 (ja) | 1993-08-06 | 2004-06-07 | 旭化成ケミカルズ株式会社 | 不飽和ニトリルの製法 |
| US5658842A (en) | 1993-08-10 | 1997-08-19 | Asahi Kasei Kogyo Kabushiki Kaisha | Ammoxidation catalyst composition, and process for producing acrylonitrile or methacrylonitrile using the same |
| US5780664A (en) * | 1993-08-17 | 1998-07-14 | Asahi Kasei Kogyo Kabushi Kaisha | Ammoxidation catalyst composition |
| DE4332542A1 (de) * | 1993-09-24 | 1995-03-30 | Basf Ag | Katalysator auf der Basis von Fe-, Co-, Bi- und Mo-Oxiden |
| DE4405059A1 (de) * | 1994-02-17 | 1995-08-24 | Basf Ag | Multimetalloxidmassen |
| JP3214975B2 (ja) * | 1994-04-25 | 2001-10-02 | 旭化成株式会社 | アンモ酸化触媒組成物および製造方法 |
| JP3838705B2 (ja) | 1996-07-31 | 2006-10-25 | 旭化成ケミカルズ株式会社 | アンモ酸化用触媒組成物 |
| US5840648A (en) * | 1997-09-02 | 1998-11-24 | The Standard Oil Company | Catalyst for the manufacture of acrylonitrile and hydrogen cyanide |
| JP3875023B2 (ja) | 1998-02-13 | 2007-01-31 | コリア リサーチ インスティチュート オブ ケミカル テクノロジイ | コアー殻触媒相の固形触媒とその製造方法 |
| JP3680115B2 (ja) * | 1998-04-23 | 2005-08-10 | ダイヤニトリックス株式会社 | 不飽和ニトリル製造用触媒組成物 |
| CN1155439C (zh) | 1998-04-23 | 2004-06-30 | 三菱丽阳株式会社 | 用于生产不饱和腈类的催化剂 |
| WO1999054037A1 (fr) * | 1998-04-23 | 1999-10-28 | Mitsubishi Rayon Co., Ltd. | Catalyseur de production de nitrile insature |
| US6143690A (en) * | 1998-05-07 | 2000-11-07 | Asahi Kasei Kogyo Kabushiki Kaisha | Ammoxidation catalyst for use in producing acrylonitrile or methacrylonitrile from propane or isobutane |
| MXPA02001574A (es) | 1999-08-19 | 2003-07-21 | China Petrochemical Corp | Catalizador de lecho fluidificado para la amoxidacion de propileno a acrilonitrilo. |
| RO121181B1 (ro) * | 1999-10-18 | 2007-01-30 | Mitsubishi Rayon Co., Ltd. | Procedeu pentru producerea acrilonitrilului, catalizator utilizabil în acest procedeu şi procedeupentru prepararea acestuia |
-
2000
- 2000-08-17 US US09/641,380 patent/US6458742B1/en not_active Expired - Lifetime
-
2001
- 2001-08-02 RU RU2003107043/04A patent/RU2266784C2/ru active
- 2001-08-02 JP JP2002519095A patent/JP4937487B2/ja not_active Expired - Lifetime
- 2001-08-02 CN CNB018141366A patent/CN1255215C/zh not_active Expired - Lifetime
- 2001-08-02 AU AU2001278136A patent/AU2001278136A1/en not_active Abandoned
- 2001-08-02 EP EP01956103A patent/EP1309402B1/en not_active Expired - Lifetime
- 2001-08-02 KR KR1020037002308A patent/KR100786051B1/ko active IP Right Grant
- 2001-08-02 CA CA002417987A patent/CA2417987C/en not_active Expired - Fee Related
- 2001-08-02 AT AT01956103T patent/ATE363944T1/de not_active IP Right Cessation
- 2001-08-02 WO PCT/US2001/024253 patent/WO2002013963A2/en active IP Right Grant
- 2001-08-02 BR BRPI0113310-1A patent/BR0113310B1/pt not_active IP Right Cessation
- 2001-08-02 DE DE60128811T patent/DE60128811T2/de not_active Expired - Lifetime
- 2001-08-02 MX MXPA03001409A patent/MXPA03001409A/es active IP Right Grant
- 2001-08-02 ES ES01956103T patent/ES2287146T3/es not_active Expired - Lifetime
- 2001-08-16 TW TW090120073A patent/TWI284058B/zh not_active IP Right Cessation
-
2002
- 2002-08-06 US US10/213,755 patent/US6965046B2/en not_active Expired - Lifetime
-
2003
- 2003-02-05 ZA ZA200301006A patent/ZA200301006B/xx unknown
- 2003-02-05 BG BG107525A patent/BG66322A/en unknown
- 2003-02-05 BG BG107525D patent/BG107525A/bg unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1309402B1 (en) | 2007-06-06 |
| JP2004505766A (ja) | 2004-02-26 |
| US6458742B1 (en) | 2002-10-01 |
| EP1309402A2 (en) | 2003-05-14 |
| AU2001278136A1 (en) | 2002-02-25 |
| MXPA03001409A (es) | 2004-05-04 |
| KR20030027036A (ko) | 2003-04-03 |
| TWI284058B (en) | 2007-07-21 |
| BG66322B1 (bg) | 2013-05-31 |
| US6965046B2 (en) | 2005-11-15 |
| BR0113310B1 (pt) | 2012-01-24 |
| KR100786051B1 (ko) | 2007-12-17 |
| CN1255215C (zh) | 2006-05-10 |
| DE60128811T2 (de) | 2008-02-21 |
| ES2287146T3 (es) | 2007-12-16 |
| ZA200301006B (en) | 2004-02-13 |
| BG66322A (en) | 2013-05-31 |
| RU2266784C2 (ru) | 2005-12-27 |
| CN1450934A (zh) | 2003-10-22 |
| US20020198398A1 (en) | 2002-12-26 |
| CA2417987C (en) | 2007-10-23 |
| JP4937487B2 (ja) | 2012-05-23 |
| WO2002013963A2 (en) | 2002-02-21 |
| WO2002013963A3 (en) | 2002-05-02 |
| BR0113310A (pt) | 2003-06-24 |
| ATE363944T1 (de) | 2007-06-15 |
| CA2417987A1 (en) | 2002-02-21 |
| DE60128811D1 (de) | 2007-07-19 |
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