AU2013235473B2 - Polymethylmethacrylate based hardcoat composition and coated article - Google Patents
Polymethylmethacrylate based hardcoat composition and coated article Download PDFInfo
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- AU2013235473B2 AU2013235473B2 AU2013235473A AU2013235473A AU2013235473B2 AU 2013235473 B2 AU2013235473 B2 AU 2013235473B2 AU 2013235473 A AU2013235473 A AU 2013235473A AU 2013235473 A AU2013235473 A AU 2013235473A AU 2013235473 B2 AU2013235473 B2 AU 2013235473B2
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- Prior art keywords
- coating
- coating composition
- diacrylate
- alkylene
- copolymer
- Prior art date
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- 229920003229 poly(methyl methacrylate) Polymers 0.000 title claims abstract description 80
- 239000004926 polymethyl methacrylate Substances 0.000 title claims description 63
- 239000000203 mixture Substances 0.000 title claims description 41
- 239000008199 coating composition Substances 0.000 claims abstract description 161
- 238000000576 coating method Methods 0.000 claims abstract description 121
- 239000011248 coating agent Substances 0.000 claims abstract description 105
- 239000000758 substrate Substances 0.000 claims abstract description 92
- 239000000178 monomer Substances 0.000 claims abstract description 66
- 229920001577 copolymer Polymers 0.000 claims abstract description 62
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 38
- 239000003381 stabilizer Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 90
- 239000002245 particle Substances 0.000 claims description 53
- 239000010408 film Substances 0.000 claims description 51
- -1 poly(methyl methacrylate) Polymers 0.000 claims description 47
- 229920001296 polysiloxane Polymers 0.000 claims description 43
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims description 33
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 23
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 claims description 22
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 22
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 16
- 229920006243 acrylic copolymer Polymers 0.000 claims description 16
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 11
- 125000005250 alkyl acrylate group Chemical group 0.000 claims description 8
- 239000002033 PVDF binder Substances 0.000 claims description 7
- 239000012788 optical film Substances 0.000 claims description 7
- 239000004417 polycarbonate Substances 0.000 claims description 7
- 229920000515 polycarbonate Polymers 0.000 claims description 7
- 229920000728 polyester Polymers 0.000 claims description 7
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 7
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 7
- SAPGBCWOQLHKKZ-UHFFFAOYSA-N 6-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCCCCOC(=O)C(C)=C SAPGBCWOQLHKKZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004611 light stabiliser Substances 0.000 claims description 6
- 229920001169 thermoplastic Polymers 0.000 claims description 6
- 239000004416 thermosoftening plastic Substances 0.000 claims description 6
- 150000001412 amines Chemical class 0.000 claims description 5
- ULQMPOIOSDXIGC-UHFFFAOYSA-N [2,2-dimethyl-3-(2-methylprop-2-enoyloxy)propyl] 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC(C)(C)COC(=O)C(C)=C ULQMPOIOSDXIGC-UHFFFAOYSA-N 0.000 claims description 4
- 239000006096 absorbing agent Substances 0.000 claims description 3
- 239000012965 benzophenone Substances 0.000 claims description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 229920000642 polymer Polymers 0.000 description 49
- 238000000034 method Methods 0.000 description 38
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 28
- 238000011156 evaluation Methods 0.000 description 27
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 25
- 239000000428 dust Substances 0.000 description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 19
- 239000003999 initiator Substances 0.000 description 19
- ZDHCZVWCTKTBRY-UHFFFAOYSA-N omega-Hydroxydodecanoic acid Natural products OCCCCCCCCCCCC(O)=O ZDHCZVWCTKTBRY-UHFFFAOYSA-N 0.000 description 19
- 208000035874 Excoriation Diseases 0.000 description 18
- 238000005299 abrasion Methods 0.000 description 18
- 239000010410 layer Substances 0.000 description 17
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 16
- 239000002904 solvent Substances 0.000 description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 15
- 239000000377 silicon dioxide Substances 0.000 description 15
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 14
- 229910052809 inorganic oxide Inorganic materials 0.000 description 14
- 239000000523 sample Substances 0.000 description 14
- 238000009472 formulation Methods 0.000 description 13
- 239000000243 solution Substances 0.000 description 13
- 239000010954 inorganic particle Substances 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 238000012360 testing method Methods 0.000 description 12
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 11
- 230000005540 biological transmission Effects 0.000 description 11
- 239000011521 glass Substances 0.000 description 11
- 230000003287 optical effect Effects 0.000 description 11
- 230000005855 radiation Effects 0.000 description 10
- 238000001878 scanning electron micrograph Methods 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 230000000052 comparative effect Effects 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 238000005259 measurement Methods 0.000 description 9
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 7
- 238000003851 corona treatment Methods 0.000 description 7
- 239000012756 surface treatment agent Substances 0.000 description 7
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 6
- 125000002993 cycloalkylene group Chemical group 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 239000003607 modifier Substances 0.000 description 6
- 229920000889 poly(m-phenylene isophthalamide) Polymers 0.000 description 6
- 150000003254 radicals Chemical class 0.000 description 6
- 239000004576 sand Substances 0.000 description 6
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 125000004386 diacrylate group Chemical group 0.000 description 5
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 5
- 239000005022 packaging material Substances 0.000 description 5
- 230000002441 reversible effect Effects 0.000 description 5
- QNODIIQQMGDSEF-UHFFFAOYSA-N (1-hydroxycyclohexyl)-phenylmethanone Chemical compound C=1C=CC=CC=1C(=O)C1(O)CCCCC1 QNODIIQQMGDSEF-UHFFFAOYSA-N 0.000 description 4
- AVTLBBWTUPQRAY-UHFFFAOYSA-N 2-(2-cyanobutan-2-yldiazenyl)-2-methylbutanenitrile Chemical compound CCC(C)(C#N)N=NC(C)(CC)C#N AVTLBBWTUPQRAY-UHFFFAOYSA-N 0.000 description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 239000012986 chain transfer agent Substances 0.000 description 4
- 239000003153 chemical reaction reagent Substances 0.000 description 4
- 239000008119 colloidal silica Substances 0.000 description 4
- 238000009826 distribution Methods 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 125000000524 functional group Chemical group 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 125000005395 methacrylic acid group Chemical group 0.000 description 4
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 4
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- XRXANEMIFVRKLN-UHFFFAOYSA-N 2-hydroperoxy-2-methylbutane Chemical compound CCC(C)(C)OO XRXANEMIFVRKLN-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000012298 atmosphere Substances 0.000 description 3
- 235000019400 benzoyl peroxide Nutrition 0.000 description 3
- GAMFEMAXLMWCRG-UHFFFAOYSA-N bis(dimethylcarbamothioylsulfanyl)arsanyl n,n-dimethylcarbamodithioate Chemical compound CN(C)C(=S)S[As](SC(=S)N(C)C)SC(=S)N(C)C GAMFEMAXLMWCRG-UHFFFAOYSA-N 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008367 deionised water Substances 0.000 description 3
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical group CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 3
- 239000012933 diacyl peroxide Substances 0.000 description 3
- 230000005611 electricity Effects 0.000 description 3
- 229960004592 isopropanol Drugs 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 239000002491 polymer binding agent Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000011253 protective coating Substances 0.000 description 3
- 150000004756 silanes Chemical class 0.000 description 3
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 3
- 238000001542 size-exclusion chromatography Methods 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- ROEHNQZQCCPZCH-UHFFFAOYSA-N tert-butyl 2-tert-butylperoxycarbonylbenzoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1C(=O)OC(C)(C)C ROEHNQZQCCPZCH-UHFFFAOYSA-N 0.000 description 3
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 3
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 3
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- 150000003918 triazines Chemical class 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- 239000012956 1-hydroxycyclohexylphenyl-ketone Substances 0.000 description 2
- HWRLEEPNFJNTOP-UHFFFAOYSA-N 2-(1,3,5-triazin-2-yl)phenol Chemical compound OC1=CC=CC=C1C1=NC=NC=N1 HWRLEEPNFJNTOP-UHFFFAOYSA-N 0.000 description 2
- JSOZORWBKQSQCJ-UHFFFAOYSA-N 3-[ethoxy(dimethyl)silyl]propyl 2-methylprop-2-enoate Chemical compound CCO[Si](C)(C)CCCOC(=O)C(C)=C JSOZORWBKQSQCJ-UHFFFAOYSA-N 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229910003849 O-Si Inorganic materials 0.000 description 2
- 229910003872 O—Si Inorganic materials 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 125000005529 alkyleneoxy group Chemical group 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 229910000410 antimony oxide Inorganic materials 0.000 description 2
- 150000001565 benzotriazoles Chemical class 0.000 description 2
- NLMFVJSIGDIJBB-UHFFFAOYSA-N bis(2,2,6,6-tetramethyl-1-octoxypiperidin-3-yl) decanedioate Chemical compound CC1(C)N(OCCCCCCCC)C(C)(C)CCC1OC(=O)CCCCCCCCC(=O)OC1C(C)(C)N(OCCCCCCCC)C(C)(C)CC1 NLMFVJSIGDIJBB-UHFFFAOYSA-N 0.000 description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000001735 carboxylic acids Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000003618 dip coating Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- 239000003480 eluent Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical class OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 229920002313 fluoropolymer Polymers 0.000 description 2
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- 125000005842 heteroatom Chemical group 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 150000002432 hydroperoxides Chemical class 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
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- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 229910003455 mixed metal oxide Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
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- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 150000007524 organic acids Chemical class 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 2
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- 238000002360 preparation method Methods 0.000 description 2
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- 229910001887 tin oxide Inorganic materials 0.000 description 2
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical class [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- 238000011282 treatment Methods 0.000 description 2
- HJIAMFHSAAEUKR-UHFFFAOYSA-N (2-hydroxyphenyl)-phenylmethanone Chemical class OC1=CC=CC=C1C(=O)C1=CC=CC=C1 HJIAMFHSAAEUKR-UHFFFAOYSA-N 0.000 description 1
- IDXCKOANSQIPGX-UHFFFAOYSA-N (acetyloxy-ethenyl-methylsilyl) acetate Chemical compound CC(=O)O[Si](C)(C=C)OC(C)=O IDXCKOANSQIPGX-UHFFFAOYSA-N 0.000 description 1
- OGBWMWKMTUSNKE-UHFFFAOYSA-N 1-(2-methylprop-2-enoyloxy)hexyl 2-methylprop-2-enoate Chemical compound CCCCCC(OC(=O)C(C)=C)OC(=O)C(C)=C OGBWMWKMTUSNKE-UHFFFAOYSA-N 0.000 description 1
- ILVIYRLLZTXZQL-UHFFFAOYSA-N 1-dimethoxyphosphoryl-2,2-dimethylpropan-1-one Chemical compound COP(=O)(OC)C(=O)C(C)(C)C ILVIYRLLZTXZQL-UHFFFAOYSA-N 0.000 description 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 description 1
- PIZHFBODNLEQBL-UHFFFAOYSA-N 2,2-diethoxy-1-phenylethanone Chemical compound CCOC(OCC)C(=O)C1=CC=CC=C1 PIZHFBODNLEQBL-UHFFFAOYSA-N 0.000 description 1
- KWVGIHKZDCUPEU-UHFFFAOYSA-N 2,2-dimethoxy-2-phenylacetophenone Chemical compound C=1C=CC=CC=1C(OC)(OC)C(=O)C1=CC=CC=C1 KWVGIHKZDCUPEU-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/10—Homopolymers or copolymers of methacrylic acid esters
- C09D133/12—Homopolymers or copolymers of methyl methacrylate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
- C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
- C08G59/50—Amines
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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| US10858541B2 (en) * | 2017-12-19 | 2020-12-08 | Rohm And Haas Electronic Materials Llc | Curable composition |
| JP7110832B2 (ja) * | 2018-08-30 | 2022-08-02 | 三菱ケミカル株式会社 | 積層体 |
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| DE102019100650A1 (de) * | 2019-01-11 | 2020-07-16 | Krd Coatings Gmbh | Beschichtungssystem mit Nanopartikeln |
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| US20220355567A1 (en) | 2019-12-19 | 2022-11-10 | 3M Innovative Properties Company | Composite cooling film comprising a reflective microporous layer and a uv-absorbing layer |
| EP4091003A4 (en) | 2020-01-16 | 2024-01-24 | 3M Innovative Properties Company | COMPOSITE COOLING FOIL WITH A REFLECTIVE NONPOROUS ORGANIC POLYMER LAYER AND A UV PROTECTIVE LAYER |
| WO2022109210A1 (en) * | 2020-11-20 | 2022-05-27 | Aculon, Inc. | Surface-treated porous materials having filtration properties and methods of preparing them |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005040055A1 (de) * | 2003-10-21 | 2005-05-06 | Marabuwerke Gmbh & Co. Kg | Uv-härtende glasdruckfarbe und uv-härtender glasdrucklack sowie verfahren zum bedrucken von glassubstraten |
Family Cites Families (76)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE7415683L (enExample) * | 1973-12-28 | 1975-06-30 | Ciba Geigy Ag | |
| US4486504A (en) | 1982-03-19 | 1984-12-04 | General Electric Company | Solventless, ultraviolet radiation-curable silicone coating compositions |
| JPS61207476A (ja) | 1985-03-12 | 1986-09-13 | Hitachi Chem Co Ltd | 絞り加工の表面保護フイルム用放射線硬化型粘着剤 |
| US4728571A (en) | 1985-07-19 | 1988-03-01 | Minnesota Mining And Manufacturing Company | Polysiloxane-grafted copolymer release coating sheets and adhesive tapes |
| US4732831A (en) | 1986-05-01 | 1988-03-22 | E. I. Du Pont De Nemours And Company | Xeroprinting with photopolymer master |
| US4954591A (en) | 1987-11-06 | 1990-09-04 | Pilkington Visioncare Holdings, Inc. | Abrasion resistant radiation curable coating for polycarbonate article |
| US4822828A (en) | 1987-11-23 | 1989-04-18 | Hoechst Celanese Corporation | Radiation curable coating composition based on a silica/vinyl-functional silanol dispersion |
| US4863802A (en) | 1987-12-31 | 1989-09-05 | General Electric Company | UV-stabilized coatings |
| US4902578A (en) | 1987-12-31 | 1990-02-20 | General Electric Company | Radiation-curable coating for thermoplastic substrates |
| US4856670A (en) | 1988-01-12 | 1989-08-15 | Rca Licensing Corp. | Low temperature processing transfer printing ink |
| US5254395A (en) | 1988-08-23 | 1993-10-19 | Thor Radiation Research, Inc. | Protective coating system for imparting resistance to abrasion, impact and solvents |
| JPH07103255B2 (ja) | 1988-12-02 | 1995-11-08 | 東芝シリコーン株式会社 | プラスチック成形品の表面保護法 |
| EP0386297A1 (en) | 1989-03-10 | 1990-09-12 | General Electric Company | Uv curable thermoformable protective coatings |
| US5188900A (en) | 1989-10-18 | 1993-02-23 | Dow Corning Corporation | Substrates having an abrasion-resistant coating formed thereon |
| US5162390A (en) | 1990-03-05 | 1992-11-10 | General Electric Company | UV curable coating compositions, abrasion resistant UV stabilized thermoplastic composites and method |
| JPH04107144A (ja) | 1990-08-28 | 1992-04-08 | Kanegafuchi Chem Ind Co Ltd | 表面硬化アクリル樹脂系フイルム |
| US5075348A (en) | 1990-11-01 | 1991-12-24 | Dow Corning Corporation | Multifunctional acrylate based abrasion resistant coating composition |
| US5262450A (en) | 1990-12-28 | 1993-11-16 | Isp Investments Inc. | Abrasion and water-resistant radiation curable coatings |
| US5318850A (en) | 1991-11-27 | 1994-06-07 | General Electric Company | UV curable abrasion-resistant coatings with improved weatherability |
| US5214085A (en) | 1992-02-03 | 1993-05-25 | General Electric Company | Abrasion-resistant coating compositions with improved weatherability |
| JPH0693210A (ja) | 1992-04-30 | 1994-04-05 | Minnesota Mining & Mfg Co <3M> | 耐汚染性保護コーティング組成物 |
| AU4123993A (en) | 1992-06-25 | 1994-01-06 | General Electric Company | Radiation curable hardcoat compositions |
| IT1269796B (it) | 1994-05-19 | 1997-04-15 | Marco Rigamonti | Processo per la preparazione di articoli formati antigraffio e antiabrasione,a base di polimeri acrilici |
| DE4443355A1 (de) | 1994-12-06 | 1996-06-13 | Roehm Gmbh | Flugzeugverglasung mit erhöhter Lichtstabilität, verbesserter chemischer Stabilität und verbesserter Wärmeformbeständigkeit |
| US6218004B1 (en) | 1995-04-06 | 2001-04-17 | David G. Shaw | Acrylate polymer coated sheet materials and method of production thereof |
| US5648407A (en) | 1995-05-16 | 1997-07-15 | Minnesota Mining And Manufacturing Company | Curable resin sols and fiber-reinforced composites derived therefrom |
| US5677050A (en) | 1995-05-19 | 1997-10-14 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting having an abrasion resistant ceramer coating |
| JPH09194761A (ja) | 1996-01-22 | 1997-07-29 | Mitsubishi Rayon Co Ltd | 無溶剤型光硬化性樹脂組成物 |
| US5811472A (en) | 1996-07-22 | 1998-09-22 | General Electric Company | Radiation curable compositions having improved moisture resistance |
| US5981113A (en) | 1996-12-17 | 1999-11-09 | 3M Innovative Properties Company | Curable ink composition and imaged retroreflective article therefrom |
| JPH10292004A (ja) | 1997-04-18 | 1998-11-04 | Nippon Oil Co Ltd | 光硬化物の製造法 |
| JP3864605B2 (ja) | 1998-02-27 | 2007-01-10 | 藤倉化成株式会社 | 紫外線硬化性被覆用樹脂組成物 |
| FR2786776B1 (fr) | 1998-12-07 | 2001-02-16 | Clariant France Sa | Compositions silico-acryliques, procede de preparation et application a l'obtention de revetements resistant a l'abrasion et aux rayures |
| US6299799B1 (en) | 1999-05-27 | 2001-10-09 | 3M Innovative Properties Company | Ceramer compositions and antistatic abrasion resistant ceramers made therefrom |
| DE19924674C2 (de) * | 1999-05-29 | 2001-06-28 | Basf Coatings Ag | Thermisch und mit aktinischer Strahlung härtbarer Beschichtungsstoff und seine Verwendung |
| US6462884B2 (en) | 1999-07-16 | 2002-10-08 | Technology Resource International Corporation | Polymerizable composition and optical articles using the same |
| US6500877B1 (en) | 1999-11-05 | 2002-12-31 | Krohn Industries, Inc. | UV curable paint compositions and method of making and applying same |
| KR100383090B1 (ko) | 2000-07-20 | 2003-05-12 | 주식회사 엘지화학 | 내마모성이 우수한 방현성 필름용 코팅액 조성물, 그의제조방법, 그를 사용하여 제조된 필름 및 그의 제조 방법 |
| KR100856444B1 (ko) | 2000-11-09 | 2008-09-04 | 쓰리엠 이노베이티브 프로퍼티즈 캄파니 | 옥외 용도에 특히 적합한 내후성의 잉크 분사가능한방사선 경화성 유체 조성물 |
| CN1174059C (zh) | 2001-08-01 | 2004-11-03 | 机械工业部广州电器科学研究所 | 溶剂型有机硅改性丙烯酸酯涂料的生产方法 |
| US7101616B2 (en) | 2001-09-11 | 2006-09-05 | 3M Innovative Properties Company | Smudge resistant nanocomposite hardcoats and methods for making same |
| US6682872B2 (en) | 2002-01-22 | 2004-01-27 | International Business Machines Corporation | UV-curable compositions and method of use thereof in microelectronics |
| KR100813953B1 (ko) | 2002-04-22 | 2008-03-14 | 삼성전자주식회사 | 대전방지성을 갖는 광경화성 수지 조성물 |
| JP4041968B2 (ja) | 2002-10-09 | 2008-02-06 | 信越化学工業株式会社 | 下塗り剤組成物、該組成物を用いたコーティング方法、及びコーティング物品 |
| NZ541264A (en) | 2002-12-19 | 2008-01-31 | Roehm Gmbh | Coating compositions for producing formable scratchproof coatings with dirt repellency effect, scratchproof formable dirt-repellent mouldings and processes for producing them |
| DE10336129A1 (de) * | 2003-08-04 | 2005-02-24 | Röhm GmbH & Co. KG | Kratzunempfindlicher Rückprojektionsschirm und Verfahren zu dessen Herstellung |
| US20050064183A1 (en) | 2003-09-23 | 2005-03-24 | 3M Innovative Properties Company | Adhesive articles including a nanoparticle primer and methods for preparing same |
| JP4414188B2 (ja) | 2003-09-30 | 2010-02-10 | 大日本印刷株式会社 | ハードコート層の滑り性を改善した積層体 |
| DE10352177A1 (de) * | 2003-11-05 | 2005-06-02 | Röhm GmbH & Co. KG | Antistatisch beschichteter Formkörper und Verfahren zu seiner Herstellung |
| US20050106333A1 (en) | 2003-11-18 | 2005-05-19 | Lehmann Maria J. | Anti-reflective optical film for display devices |
| US20050245636A1 (en) | 2004-04-29 | 2005-11-03 | Ashland Inc. | Radiation-curable coatings for wood substrates from multifunctional acrylate oligomers |
| JP4945064B2 (ja) | 2004-04-30 | 2012-06-06 | ソニーケミカル＆インフォメーションデバイス株式会社 | 光ディスク保護膜用組成物 |
| US7442442B2 (en) | 2004-07-01 | 2008-10-28 | 3M Innovative Properties Company | Methods, systems, and polymer substances relating to consideration of H2O levels present within an atmospheric-pressure nitrogen dielectric-barrier discharge |
| CN100478410C (zh) * | 2004-12-31 | 2009-04-15 | 北京有色金属研究总院 | 亲水涂料及其制备方法 |
| CN100345874C (zh) | 2005-02-28 | 2007-10-31 | 仪征多科特水性化学品有限责任公司 | 环境温度交联水性涂料用有机硅改性丙烯酸酯乳液及其制备方法 |
| DE102006016642A1 (de) | 2006-04-08 | 2007-10-18 | Bayer Materialscience Ag | UV-härtende Schutzschicht für thermoplastische Substrate |
| EP1884959B1 (en) | 2006-07-31 | 2011-09-14 | Agfa HealthCare NV | Phosphor or scintillator screens or panels having a topcoat layer. |
| CN101033358A (zh) * | 2007-04-23 | 2007-09-12 | 大连交通大学 | 有机硅改性丙烯酸酯/纳米SiO2低表面能防污涂料及制作方法 |
| DE102007028601A1 (de) * | 2007-06-19 | 2008-12-24 | Evonik Röhm Gmbh | Reaktivgemisch zur Beschichtung von Formkörpern mittels Reaktionsspritzguss sowie beschichteter Formkörper |
| US7705101B2 (en) | 2007-06-22 | 2010-04-27 | 3M Innovative Properties Company | Branched polydiorganosiloxane polyamide copolymers |
| DE102007032886A1 (de) | 2007-07-14 | 2009-01-15 | Bayer Materialscience Ag | Hydrophile Hardcoatbeschichtungen |
| KR20090065254A (ko) | 2007-12-17 | 2009-06-22 | 한국전자통신연구원 | 광반응성 유기고분자 게이트 절연막 조성물 및 이를 이용한유기 박막 트랜지스터 |
| US20090181242A1 (en) | 2008-01-11 | 2009-07-16 | Enniss James P | Exterior window film |
| US20090214969A1 (en) | 2008-02-26 | 2009-08-27 | Xerox Corporation | Protective overcoat of photoreceptor having a charge transport compound |
| EP2274389B1 (en) | 2008-04-22 | 2011-08-24 | E. I. du Pont de Nemours and Company | Coating composition containing polytrimethylene ether diol |
| US20090283144A1 (en) | 2008-05-14 | 2009-11-19 | 3M Innovative Properties Company | Solar concentrating mirror |
| CN102203136B (zh) | 2008-11-03 | 2013-11-13 | 巴斯夫欧洲公司 | 光敏引发剂混合物 |
| EP2382427A4 (en) | 2008-12-30 | 2017-06-21 | 3M Innovative Properties Company | Broadband reflectors, concentrated solar power systems, and methods of using the same |
| KR20110124232A (ko) | 2009-02-12 | 2011-11-16 | 바이엘 머티리얼사이언스 아게 | 반사-방지/연무-방지 코팅 |
| KR20100121281A (ko) | 2009-05-08 | 2010-11-17 | 동우 화인켐 주식회사 | 고경도 하드코팅 필름, 이를 포함하는 편광판 및 표시 장치 |
| US8216357B2 (en) * | 2009-09-25 | 2012-07-10 | General Electric Company | Protective coating compositions and devices |
| US8176716B2 (en) | 2010-08-31 | 2012-05-15 | Deere & Company | Flexible reel for an agricultural harvesting head |
| US20120047877A1 (en) | 2010-08-31 | 2012-03-01 | General Electric Company | Exhaust treatment system and method of operation |
| CN103155170B (zh) | 2010-10-06 | 2016-05-04 | 3M创新有限公司 | 用于太阳能系统的光学元件的涂料 |
| CN103140937A (zh) | 2010-10-06 | 2013-06-05 | 3M创新有限公司 | 用于太阳能系统的光学元件的涂料 |
| AU2014265845B2 (en) | 2013-05-17 | 2016-11-17 | 3M Innovative Properties Company | Easy-clean surface and method of making the same |
-
2013
- 2013-03-14 DK DK13714759.1T patent/DK2828345T3/da active
- 2013-03-14 CN CN201380015736.XA patent/CN104540905B/zh active Active
- 2013-03-14 KR KR1020147029170A patent/KR102094765B1/ko active Active
- 2013-03-14 SG SG11201405938VA patent/SG11201405938VA/en unknown
- 2013-03-14 EP EP13714759.1A patent/EP2828345B1/en active Active
- 2013-03-14 CA CA 2868354 patent/CA2868354A1/en not_active Abandoned
- 2013-03-14 JP JP2015501769A patent/JP6174674B2/ja active Active
- 2013-03-14 BR BR112014023480-9A patent/BR112014023480B1/pt not_active IP Right Cessation
- 2013-03-14 RU RU2014138174A patent/RU2613408C2/ru not_active IP Right Cessation
- 2013-03-14 US US14/387,072 patent/US10072173B2/en active Active
- 2013-03-14 AU AU2013235473A patent/AU2013235473B2/en not_active Ceased
- 2013-03-14 WO PCT/US2013/031249 patent/WO2013142239A1/en not_active Ceased
- 2013-03-14 ES ES13714759.1T patent/ES2606641T3/es active Active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005040055A1 (de) * | 2003-10-21 | 2005-05-06 | Marabuwerke Gmbh & Co. Kg | Uv-härtende glasdruckfarbe und uv-härtender glasdrucklack sowie verfahren zum bedrucken von glassubstraten |
Also Published As
| Publication number | Publication date |
|---|---|
| KR102094765B1 (ko) | 2020-03-30 |
| RU2014138174A (ru) | 2016-05-20 |
| CN104540905B (zh) | 2017-12-19 |
| AU2013235473A1 (en) | 2014-10-09 |
| ES2606641T3 (es) | 2017-03-24 |
| BR112014023480B1 (pt) | 2021-03-16 |
| SG11201405938VA (en) | 2014-11-27 |
| CN104540905A (zh) | 2015-04-22 |
| KR20140138986A (ko) | 2014-12-04 |
| US20150037567A1 (en) | 2015-02-05 |
| JP2015510968A (ja) | 2015-04-13 |
| EP2828345A1 (en) | 2015-01-28 |
| WO2013142239A1 (en) | 2013-09-26 |
| RU2613408C2 (ru) | 2017-03-16 |
| EP2828345B1 (en) | 2016-10-05 |
| CA2868354A1 (en) | 2013-09-26 |
| DK2828345T3 (da) | 2017-01-02 |
| US10072173B2 (en) | 2018-09-11 |
| JP6174674B2 (ja) | 2017-08-02 |
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