RU2014138174A - Композиция твердого покрытия на основе полиметилметакрилата и изделие с покрытием - Google Patents

Композиция твердого покрытия на основе полиметилметакрилата и изделие с покрытием Download PDF

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RU2014138174A
RU2014138174A RU2014138174A RU2014138174A RU2014138174A RU 2014138174 A RU2014138174 A RU 2014138174A RU 2014138174 A RU2014138174 A RU 2014138174A RU 2014138174 A RU2014138174 A RU 2014138174A RU 2014138174 A RU2014138174 A RU 2014138174A
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coating composition
diacrylate
alkylene
cycloalkylene
copolymer
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Сюзанна С. КЛЕАР
Рагхунат РАДИЯТ
Гарри В. ЛАХМАНСИНГХ
Марк А. СТРОБЕЛ
Соня С. МАКЕЙ
Наийонг ДЖИНГ
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Зм Инновейтив Пропертиз Компани
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Abstract

1. Композиция покрытия, содержащая:полимер или сополимер полиметилметакрилата, имеющий среднюю молекулярную массу не менее 50000 грамм на моль;мономер, содержащий по крайней мере одно из веществ: алкилен-диакрилат, алкилен-диметакрилат, циклоалкилен-диакрилат или циклоалкилен-диметилакрилат, в котором по меньшей мере одно из веществ (алкилен-диакрилат, алкилен-диметакрилат, циклоалкилен-диакрилат или циклоалкилен-диметилакрилат) составляет не менее 80 процентов по массе мономера; истабилизатор ультрафиолетового излучения, причем стабилизатор содержит как минимум один УФ абсорбер или связанный аминовый светостабилизатор.2. Композиция покрытия по п. 1, где полимер или сополимер полиметилметакрилата имеет среднюю молекулярную массу не менее 75000 грамм на моль, 100 грамм на моль или 120 грамм на моль.3. Композиция покрытия по п. 1 или 2, где полимер или сополимер полиметилметакрилата представляет собой полиметилметакрилат или сополимер метилметакрилата и, по крайней мере, одно из следующих веществ: С-Салкил-акрилат или -метакрилат или С-Cциклоалкилакрилат или -метакрилат.4. Композиция покрытия по п. 3, где полимер или сополимер полиметилметакрилата представляет собой сополимер метилметакрилата и, по крайней мере, одно из следующих веществ: этилакрилат, этилметакрилат, бутилакрилат или бутилметакрилат.5. Композиция покрытия по п. 1, где мономер содержит по крайней мере, одно из следующих веществ: Салкилендиакрилат, Салкилендиметакрилат, Сциклоалкилендиакрилат, или Сциклоалкилендиметакрилат.6. Композиция покрытия по п. 1, где мономерный алкилендиакрилат или мономерный алкилендиметилакрилат содержит как минимум 1,6-гексанэдиолдиакриат, 1,6-гексанэдиолдимет

Claims (25)

1. Композиция покрытия, содержащая:
полимер или сополимер полиметилметакрилата, имеющий среднюю молекулярную массу не менее 50000 грамм на моль;
мономер, содержащий по крайней мере одно из веществ: алкилен-диакрилат, алкилен-диметакрилат, циклоалкилен-диакрилат или циклоалкилен-диметилакрилат, в котором по меньшей мере одно из веществ (алкилен-диакрилат, алкилен-диметакрилат, циклоалкилен-диакрилат или циклоалкилен-диметилакрилат) составляет не менее 80 процентов по массе мономера; и
стабилизатор ультрафиолетового излучения, причем стабилизатор содержит как минимум один УФ абсорбер или связанный аминовый светостабилизатор.
2. Композиция покрытия по п. 1, где полимер или сополимер полиметилметакрилата имеет среднюю молекулярную массу не менее 75000 грамм на моль, 100 грамм на моль или 120 грамм на моль.
3. Композиция покрытия по п. 1 или 2, где полимер или сополимер полиметилметакрилата представляет собой полиметилметакрилат или сополимер метилметакрилата и, по крайней мере, одно из следующих веществ: С2-С8 алкил-акрилат или -метакрилат или С3-C8 циклоалкилакрилат или -метакрилат.
4. Композиция покрытия по п. 3, где полимер или сополимер полиметилметакрилата представляет собой сополимер метилметакрилата и, по крайней мере, одно из следующих веществ: этилакрилат, этилметакрилат, бутилакрилат или бутилметакрилат.
5. Композиция покрытия по п. 1, где мономер содержит по крайней мере, одно из следующих веществ: С2-10 алкилендиакрилат, С2-10 алкилендиметакрилат, С4-6 циклоалкилендиакрилат, или С4-6 циклоалкилендиметакрилат.
6. Композиция покрытия по п. 1, где мономерный алкилендиакрилат или мономерный алкилендиметилакрилат содержит как минимум 1,6-гексанэдиолдиакриат, 1,6-гексанэдиолдиметакрилат, или неоптенил гликоль диметакрилат.
7. Композиция покрытия по п. 1, дополнительно включающая в себя кремнийсодержащий акриловый сополимер.
8. Композиция покрытия по одному из пп. 1 и 6, дополнительно включающая в себя кремнийсодержащий акриловый мономер.
9. Композиция покрытия по п. 1, дополнительно содержащая частицы диоксида кремния со средним размером частицы до 500 нанометров.
10. Композиция покрытия по п. 9, где поверхность частиц диоксида кремния модифицирована полиметилметакрилатом.
11. Композиция покрытия по п. 1, где соотношение мономера, содержащего по меньшей мере одно из веществ: алкилен-диакрилат, алкилен-диметакрилат, циклоалкилен-диакрилат или циклоалкилен-диметилакрилат к полимеру или сополимеру полиметилметакрилата составляет от 0,75:1 до 10:1.
12. Композиция покрытия по п. 1, дополнительно содержащая как минимум один органический растворитель или фотосенсибилизатор.
13. Композиция покрытия по п. 1, где стабилизатор против ультрафиолетового излучения содержит как минимум одно из следующих веществ: бензотриазол, бензофенон, триазин, или связанный аминовый светостабилизатор.
14. Изделие, содержащее полимерную подложку и первое покрытие поверхности полимерной подложки, где первое покрытие получается полимеризацией композиции покрытия по любому из пп. 1 и 13.
15. Изделие по п. 14, где полимерная подложка представляет собой термопластик, содержащий, по крайней мере, один из следующих компонентов: акриловый, полиэфирный, поликарбонатный или смесь поливинилиденового фтористого соединения и полиметилметакрилата.
16. Изделие по п. 15, где подложка содержит полиэтилен-терефталат.
17. Изделие по п. 14, где поверхность подложки загрунтована.
18. Изделие по п. 17, где поверхность подложки обработана электрическим коронным разрядом в атмосфере азота.
19. Изделие по п. 14, где подложка представляет собой акриловую зеркальную пленку, многослойную оптическую пленку, объектив, световозвращающий лист, или пленку с перфорацией.
20. Изделие по п. 19, где подложка представляет собой многослойную оптическую пленку.
21. Изделие по п. 14, где полимерная подложка включает в себя полиметилметакрилат, и где поверхность подложки обработана электрическим коронным разрядом в атмосфере азота.
22. Изделие по п. 14, дополнительно содержащее второе покрытие, нанесенное на первое покрытие, где второе покрытие содержит частицы диоксида кремния со средним размером частицы до 500 нанометров.
23. Изделие по п. 14, где толщина первого покрытия равна как минимум 8 микрометрам.
24. Изделие по п. 14, где первое покрытие проницаемо для видимой и инфракрасной части спектра.
25. Изделие по п. 14, где изделие находится под воздействием солнечного света.
RU2014138174A 2012-03-22 2013-03-14 Композиция твердого покрытия на основе полиметилметакрилата и изделие с покрытием RU2613408C2 (ru)

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Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104737039B (zh) 2012-07-30 2017-06-23 3M创新有限公司 包括多层光学膜的对紫外线稳定的组件
JP2016506544A (ja) 2012-12-20 2016-03-03 スリーエム イノベイティブ プロパティズ カンパニー 層ごとに自己集合された層を含む多層光学フィルム及び物品の製造方法
EP3004261A1 (en) 2013-05-31 2016-04-13 3M Innovative Properties Company Methods of layer by layer self-assembly of a polyelectrolyte comprising light absorbing or stabilizing compound and articles
US20160311991A1 (en) * 2013-06-14 2016-10-27 Covestro Deutschland Ag Low-oiling coated polycarbonate films
CN110094887A (zh) 2013-07-01 2019-08-06 3M创新有限公司 太阳能装置
JP2017504060A (ja) 2013-12-19 2017-02-02 スリーエム イノベイティブ プロパティズ カンパニー リン表面処理剤を有するナノ粒子を含む自己集合層を含む物品
US20150240108A1 (en) * 2014-02-26 2015-08-27 Armstrong World Industries, Inc. Surface coating compositions
MX2017006742A (es) 2014-12-09 2017-08-16 3M Innovative Properties Co Sistema que tiene un elemento de comunicaciones que es ocultado por una estructura reflectiva que comprende una pelicula optica de polimero de multiples capas.
EP3067948B1 (en) * 2015-03-09 2018-08-08 Heraeus Deutschland GmbH & Co. KG Conductive polymer in organic solvent with fluorinated non-ionic compound
KR101616081B1 (ko) * 2015-11-18 2016-04-27 (주)성광산업개발 이액형 차선 도료 조성물, 그 제조방법 및 차선 시공방법
EP3475369B1 (en) 2016-06-27 2023-01-18 3M Innovative Properties Company Compositions comprising nanoparticles functionalized with an alpha-hydroxy acid or salt, articles, and methods
WO2018093975A1 (en) 2016-11-21 2018-05-24 3M Innovative Properties Company Flexible hardcoat comprising urethane oligomer hydrogen bonded to an acrylic polymer
CN107674489B (zh) * 2017-11-08 2021-07-13 北京航天赛德科技发展有限公司 一种防沉淀的改性二氧化硅及其制备方法和应用
US10858541B2 (en) * 2017-12-19 2020-12-08 Rohm And Haas Electronic Materials Llc Curable composition
JP7110832B2 (ja) * 2018-08-30 2022-08-02 三菱ケミカル株式会社 積層体
CN111100489B (zh) * 2018-10-26 2022-03-15 3M创新有限公司 一种离型硬涂料、一种离型膜和一种光伏组件
WO2020100095A1 (en) 2018-11-18 2020-05-22 Asociația Transylvanian Institute Of Neuroscience Method, human machine interface, machine computing unit and computer programs to control at least one actuator to carry out at least one task
JP7138254B2 (ja) 2019-05-31 2022-09-15 スリーエム イノベイティブ プロパティズ カンパニー 複合冷却フィルム及び同フィルムを含む物品
EP4078049A4 (en) 2019-12-19 2024-01-24 3M Innovative Properties Company COMPOSITE COOLING FILM COMPRISING AN ORGANIC POLYMER LAYER, A UV-ABSORBING LAYER AND A REFLECTIVE METAL LAYER
CN114902087A (zh) 2020-01-16 2022-08-12 3M创新有限公司 包括反射性无孔有机聚合物层和uv保护层的复合冷却膜
WO2022109210A1 (en) * 2020-11-20 2022-05-27 Aculon, Inc. Surface-treated porous materials having filtration properties and methods of preparing them

Family Cites Families (77)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SE7415683L (ru) 1973-12-28 1975-06-30 Ciba Geigy Ag
US4486504A (en) 1982-03-19 1984-12-04 General Electric Company Solventless, ultraviolet radiation-curable silicone coating compositions
JPS61207476A (ja) 1985-03-12 1986-09-13 Hitachi Chem Co Ltd 絞り加工の表面保護フイルム用放射線硬化型粘着剤
US4728571A (en) 1985-07-19 1988-03-01 Minnesota Mining And Manufacturing Company Polysiloxane-grafted copolymer release coating sheets and adhesive tapes
US4732831A (en) 1986-05-01 1988-03-22 E. I. Du Pont De Nemours And Company Xeroprinting with photopolymer master
US4954591A (en) 1987-11-06 1990-09-04 Pilkington Visioncare Holdings, Inc. Abrasion resistant radiation curable coating for polycarbonate article
US4822828A (en) 1987-11-23 1989-04-18 Hoechst Celanese Corporation Radiation curable coating composition based on a silica/vinyl-functional silanol dispersion
US4902578A (en) 1987-12-31 1990-02-20 General Electric Company Radiation-curable coating for thermoplastic substrates
US4863802A (en) 1987-12-31 1989-09-05 General Electric Company UV-stabilized coatings
US4856670A (en) 1988-01-12 1989-08-15 Rca Licensing Corp. Low temperature processing transfer printing ink
US5254395A (en) 1988-08-23 1993-10-19 Thor Radiation Research, Inc. Protective coating system for imparting resistance to abrasion, impact and solvents
JPH07103255B2 (ja) 1988-12-02 1995-11-08 東芝シリコーン株式会社 プラスチック成形品の表面保護法
EP0386297A1 (en) 1989-03-10 1990-09-12 General Electric Company Uv curable thermoformable protective coatings
US5188900A (en) 1989-10-18 1993-02-23 Dow Corning Corporation Substrates having an abrasion-resistant coating formed thereon
US5162390A (en) 1990-03-05 1992-11-10 General Electric Company UV curable coating compositions, abrasion resistant UV stabilized thermoplastic composites and method
JPH04107144A (ja) 1990-08-28 1992-04-08 Kanegafuchi Chem Ind Co Ltd 表面硬化アクリル樹脂系フイルム
US5075348A (en) 1990-11-01 1991-12-24 Dow Corning Corporation Multifunctional acrylate based abrasion resistant coating composition
US5262450A (en) 1990-12-28 1993-11-16 Isp Investments Inc. Abrasion and water-resistant radiation curable coatings
US5318850A (en) 1991-11-27 1994-06-07 General Electric Company UV curable abrasion-resistant coatings with improved weatherability
US5214085A (en) 1992-02-03 1993-05-25 General Electric Company Abrasion-resistant coating compositions with improved weatherability
JPH0693210A (ja) 1992-04-30 1994-04-05 Minnesota Mining & Mfg Co <3M> 耐汚染性保護コーティング組成物
AU4123993A (en) 1992-06-25 1994-01-06 General Electric Company Radiation curable hardcoat compositions
IT1269796B (it) 1994-05-19 1997-04-15 Marco Rigamonti Processo per la preparazione di articoli formati antigraffio e antiabrasione,a base di polimeri acrilici
DE4443355A1 (de) 1994-12-06 1996-06-13 Roehm Gmbh Flugzeugverglasung mit erhöhter Lichtstabilität, verbesserter chemischer Stabilität und verbesserter Wärmeformbeständigkeit
US6218004B1 (en) 1995-04-06 2001-04-17 David G. Shaw Acrylate polymer coated sheet materials and method of production thereof
US5648407A (en) 1995-05-16 1997-07-15 Minnesota Mining And Manufacturing Company Curable resin sols and fiber-reinforced composites derived therefrom
US5677050A (en) 1995-05-19 1997-10-14 Minnesota Mining And Manufacturing Company Retroreflective sheeting having an abrasion resistant ceramer coating
JPH09194761A (ja) 1996-01-22 1997-07-29 Mitsubishi Rayon Co Ltd 無溶剤型光硬化性樹脂組成物
US5811472A (en) 1996-07-22 1998-09-22 General Electric Company Radiation curable compositions having improved moisture resistance
US5981113A (en) 1996-12-17 1999-11-09 3M Innovative Properties Company Curable ink composition and imaged retroreflective article therefrom
JPH10292004A (ja) 1997-04-18 1998-11-04 Nippon Oil Co Ltd 光硬化物の製造法
JP3864605B2 (ja) * 1998-02-27 2007-01-10 藤倉化成株式会社 紫外線硬化性被覆用樹脂組成物
FR2786776B1 (fr) 1998-12-07 2001-02-16 Clariant France Sa Compositions silico-acryliques, procede de preparation et application a l'obtention de revetements resistant a l'abrasion et aux rayures
US6299799B1 (en) 1999-05-27 2001-10-09 3M Innovative Properties Company Ceramer compositions and antistatic abrasion resistant ceramers made therefrom
DE19924674C2 (de) * 1999-05-29 2001-06-28 Basf Coatings Ag Thermisch und mit aktinischer Strahlung härtbarer Beschichtungsstoff und seine Verwendung
US6462884B2 (en) 1999-07-16 2002-10-08 Technology Resource International Corporation Polymerizable composition and optical articles using the same
US6500877B1 (en) 1999-11-05 2002-12-31 Krohn Industries, Inc. UV curable paint compositions and method of making and applying same
KR100383090B1 (ko) 2000-07-20 2003-05-12 주식회사 엘지화학 내마모성이 우수한 방현성 필름용 코팅액 조성물, 그의제조방법, 그를 사용하여 제조된 필름 및 그의 제조 방법
MXPA03003997A (es) 2000-11-09 2004-02-12 3M Innovative Properties Co Composiciones fluidas de tinta, eyectables, curables por radiacion, resistentes a la intemperie, particularmente adecuadas para aplicaciones exteriores.
CN1174059C (zh) 2001-08-01 2004-11-03 机械工业部广州电器科学研究所 溶剂型有机硅改性丙烯酸酯涂料的生产方法
EP1425352B1 (en) 2001-09-11 2005-01-12 3M Innovative Properties Company Smudge resistant nanocomposite hardcoats and methods for making same
US6682872B2 (en) 2002-01-22 2004-01-27 International Business Machines Corporation UV-curable compositions and method of use thereof in microelectronics
KR100813953B1 (ko) 2002-04-22 2008-03-14 삼성전자주식회사 대전방지성을 갖는 광경화성 수지 조성물
JP4041968B2 (ja) * 2002-10-09 2008-02-06 信越化学工業株式会社 下塗り剤組成物、該組成物を用いたコーティング方法、及びコーティング物品
NZ541264A (en) 2002-12-19 2008-01-31 Roehm Gmbh Coating compositions for producing formable scratchproof coatings with dirt repellency effect, scratchproof formable dirt-repellent mouldings and processes for producing them
DE10336129A1 (de) 2003-08-04 2005-02-24 Röhm GmbH & Co. KG Kratzunempfindlicher Rückprojektionsschirm und Verfahren zu dessen Herstellung
US20050064183A1 (en) 2003-09-23 2005-03-24 3M Innovative Properties Company Adhesive articles including a nanoparticle primer and methods for preparing same
JP4414188B2 (ja) 2003-09-30 2010-02-10 大日本印刷株式会社 ハードコート層の滑り性を改善した積層体
DE10349394A1 (de) * 2003-10-21 2005-05-25 Marabuwerke Gmbh & Co. Kg UV-härtendes Bindemittel für Farben oder Lacke zur Bedruckung von Glas und Verfahren zur Bedruckung von Glassubstraten
DE10352177A1 (de) * 2003-11-05 2005-06-02 Röhm GmbH & Co. KG Antistatisch beschichteter Formkörper und Verfahren zu seiner Herstellung
US20050106333A1 (en) 2003-11-18 2005-05-19 Lehmann Maria J. Anti-reflective optical film for display devices
US20050245636A1 (en) 2004-04-29 2005-11-03 Ashland Inc. Radiation-curable coatings for wood substrates from multifunctional acrylate oligomers
JP4945064B2 (ja) 2004-04-30 2012-06-06 ソニーケミカル＆インフォメーションデバイス株式会社 光ディスク保護膜用組成物
US7442442B2 (en) 2004-07-01 2008-10-28 3M Innovative Properties Company Methods, systems, and polymer substances relating to consideration of H2O levels present within an atmospheric-pressure nitrogen dielectric-barrier discharge
CN100478410C (zh) 2004-12-31 2009-04-15 北京有色金属研究总院 亲水涂料及其制备方法
CN100345874C (zh) * 2005-02-28 2007-10-31 仪征多科特水性化学品有限责任公司 环境温度交联水性涂料用有机硅改性丙烯酸酯乳液及其制备方法
DE102006016642A1 (de) 2006-04-08 2007-10-18 Bayer Materialscience Ag UV-härtende Schutzschicht für thermoplastische Substrate
EP1884959B1 (en) 2006-07-31 2011-09-14 Agfa HealthCare NV Phosphor or scintillator screens or panels having a topcoat layer.
CN101033358A (zh) 2007-04-23 2007-09-12 大连交通大学 有机硅改性丙烯酸酯/纳米SiO2低表面能防污涂料及制作方法
DE102007028601A1 (de) * 2007-06-19 2008-12-24 Evonik Röhm Gmbh Reaktivgemisch zur Beschichtung von Formkörpern mittels Reaktionsspritzguss sowie beschichteter Formkörper
US7705101B2 (en) 2007-06-22 2010-04-27 3M Innovative Properties Company Branched polydiorganosiloxane polyamide copolymers
DE102007032886A1 (de) 2007-07-14 2009-01-15 Bayer Materialscience Ag Hydrophile Hardcoatbeschichtungen
KR20090065254A (ko) 2007-12-17 2009-06-22 한국전자통신연구원 광반응성 유기고분자 게이트 절연막 조성물 및 이를 이용한유기 박막 트랜지스터
US20090181242A1 (en) 2008-01-11 2009-07-16 Enniss James P Exterior window film
US20090214969A1 (en) 2008-02-26 2009-08-27 Xerox Corporation Protective overcoat of photoreceptor having a charge transport compound
WO2009131907A1 (en) 2008-04-22 2009-10-29 E. I. Du Pont De Nemours And Company Coating composition containing polytrimethylene ether diol
US20090283144A1 (en) 2008-05-14 2009-11-19 3M Innovative Properties Company Solar concentrating mirror
US8507726B2 (en) 2008-11-03 2013-08-13 Basf Se Photoinitiator mixtures
US9523516B2 (en) 2008-12-30 2016-12-20 3M Innovative Properties Company Broadband reflectors, concentrated solar power systems, and methods of using the same
CN102317381B (zh) 2009-02-12 2014-09-24 拜尔材料科学股份公司 抗反射/抗翳影涂料
KR20100121281A (ko) 2009-05-08 2010-11-17 동우 화인켐 주식회사 고경도 하드코팅 필름, 이를 포함하는 편광판 및 표시 장치
US8216357B2 (en) 2009-09-25 2012-07-10 General Electric Company Protective coating compositions and devices
US8176716B2 (en) 2010-08-31 2012-05-15 Deere & Company Flexible reel for an agricultural harvesting head
US20120047877A1 (en) 2010-08-31 2012-03-01 General Electric Company Exhaust treatment system and method of operation
WO2012047867A2 (en) 2010-10-06 2012-04-12 3M Innovative Properties Company Coatings for optical components of solar energy systems
WO2012047877A2 (en) 2010-10-06 2012-04-12 3M Innovative Properties Company Coatings for optical components of solar energy systems
RU2635229C2 (ru) 2013-05-17 2017-11-09 3М Инновейтив Пропертиз Компани Легкоочищаемая поверхность и способ ее изготовления

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US10072173B2 (en) 2018-09-11
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