ATE319751T1 - Verfahren zur herstellung von polymermischungen mit einer breiten molekulargewichtsverteilung in einem einzigen reaktor - Google Patents
Verfahren zur herstellung von polymermischungen mit einer breiten molekulargewichtsverteilung in einem einzigen reaktorInfo
- Publication number
- ATE319751T1 ATE319751T1 AT00959254T AT00959254T ATE319751T1 AT E319751 T1 ATE319751 T1 AT E319751T1 AT 00959254 T AT00959254 T AT 00959254T AT 00959254 T AT00959254 T AT 00959254T AT E319751 T1 ATE319751 T1 AT E319751T1
- Authority
- AT
- Austria
- Prior art keywords
- single reactor
- molecular weight
- weight distribution
- polymer mixtures
- broad molecular
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/18—Suspension polymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/083—Copolymers of ethene with aliphatic polyenes, i.e. containing more than one unsaturated bond
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
- C08F210/18—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers with non-conjugated dienes, e.g. EPT rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/943—Polymerization with metallocene catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Wrappers (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US14985399P | 1999-08-19 | 1999-08-19 |
Publications (1)
Publication Number | Publication Date |
---|---|
ATE319751T1 true ATE319751T1 (de) | 2006-03-15 |
Family
ID=22532064
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
AT00959254T ATE319751T1 (de) | 1999-08-19 | 2000-08-16 | Verfahren zur herstellung von polymermischungen mit einer breiten molekulargewichtsverteilung in einem einzigen reaktor |
Country Status (13)
Country | Link |
---|---|
US (2) | US6369176B1 (de) |
EP (1) | EP1214365B1 (de) |
JP (2) | JP5633996B2 (de) |
KR (1) | KR100700765B1 (de) |
CN (1) | CN1210314C (de) |
AT (1) | ATE319751T1 (de) |
AU (1) | AU772057B2 (de) |
BR (1) | BR0013335B1 (de) |
CA (1) | CA2382182C (de) |
DE (1) | DE60026545T2 (de) |
ES (1) | ES2255506T3 (de) |
MX (1) | MXPA02001763A (de) |
WO (1) | WO2001014434A1 (de) |
Families Citing this family (50)
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JP3157163B2 (ja) * | 1991-12-30 | 2001-04-16 | ザ・ダウ・ケミカル・カンパニー | エチレンインターポリマーの重合 |
MXPA01004337A (es) * | 1998-11-02 | 2002-04-24 | Pont Dow Elastomers L L C Du | Interpolimeros de alfa-olefina/etileno que disminuyen el esfuerzo cortante. |
US6369176B1 (en) * | 1999-08-19 | 2002-04-09 | Dupont Dow Elastomers Llc | Process for preparing in a single reactor polymer blends having a broad molecular weight distribution |
CA2323307A1 (en) * | 2000-10-16 | 2002-04-16 | Peter Jackson | Crosslinked, heat shrinkable polypropylene compositions |
MY137183A (en) | 2001-03-16 | 2009-01-30 | Dow Global Technologies Inc | Method of making interpolymers and products made therefrom |
US20040087743A1 (en) * | 2001-03-27 | 2004-05-06 | Xinlai Bai | Gas phase process for polymers with group 4 metal complex catalyst addition |
CN100575405C (zh) * | 2002-06-04 | 2009-12-30 | 联合碳化化学及塑料技术有限责任公司 | 聚合物组合物和由其制作管子的方法 |
JP4482448B2 (ja) * | 2002-08-02 | 2010-06-16 | ダウ グローバル テクノロジーズ インコーポレイティド | 4−アリール−置換三環状インデニル誘導体含有第4族金属錯体 |
EP1620479B1 (de) | 2002-10-15 | 2013-07-24 | ExxonMobil Chemical Patents Inc. | Polyolefinklebstoffzusammensetzungen und daraus hergestellte gegenstände |
US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
US7550528B2 (en) * | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
US7223822B2 (en) * | 2002-10-15 | 2007-05-29 | Exxonmobil Chemical Patents Inc. | Multiple catalyst and reactor system for olefin polymerization and polymers produced therefrom |
EP1641847A2 (de) | 2003-07-09 | 2006-04-05 | DSM IP Assets B.V. | Verfahren zur herstellung eines polymers mit ethylen- alpha-olefin- und vinylnorbornen-monomereinheiten |
US7000131B2 (en) * | 2003-11-14 | 2006-02-14 | Via Technologies, Inc. | Apparatus and method for assuming mastership of a bus |
US20050209403A1 (en) * | 2003-12-09 | 2005-09-22 | Walton Kim L | Thermoplastic olefinic compositions |
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EP2345677A3 (de) * | 2004-06-16 | 2014-04-16 | Dow Global Technologies LLC | Verfahren zur Auswahl von Polymerisationsmodifikatoren |
US7456231B2 (en) * | 2005-02-02 | 2008-11-25 | Shawcor Ltd. | Radiation-crosslinked polyolefin compositions |
EP1882014B1 (de) * | 2005-05-12 | 2009-03-11 | Dow Global Technologies Inc. | Thermogeformte und extrudierte folie mit reduziertem glanz |
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CN101003595B (zh) * | 2006-01-18 | 2010-12-15 | 住友化学株式会社 | 制备乙烯-α-烯烃-多烯无规共聚物的方法 |
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WO2008080111A1 (en) * | 2006-12-21 | 2008-07-03 | Dow Global Technologies Inc. | Polyolefin compositions and articles prepared therefrom, and methods for making the same |
US8653191B2 (en) * | 2007-07-27 | 2014-02-18 | Dow Global Technologies Llc | Polyolefin compositions and articles prepared therefrom, and methods for making the same |
JP5563989B2 (ja) * | 2008-12-01 | 2014-07-30 | 三井化学株式会社 | 共重合体、ゴム組成物、架橋ゴム、架橋発泡体およびそれらの用途 |
US20100227966A1 (en) * | 2009-03-06 | 2010-09-09 | Shawcor Ltd. | Moisture-crosslinked polyolefin compositions |
BRPI1010079B1 (pt) * | 2009-07-15 | 2019-10-08 | Dow Global Technologies Llc | Composição polimérica e artigo |
US8679639B2 (en) * | 2009-11-24 | 2014-03-25 | Dow Global Technologies Llc | Extrusion coating composition |
JP5476172B2 (ja) * | 2010-03-18 | 2014-04-23 | 三井化学株式会社 | 難燃性ゴム組成物およびゴム成形体 |
EP2571935B1 (de) | 2010-05-21 | 2014-12-17 | Dow Global Technologies LLC | Thermoplastische zusammensetzungen und formartikel daraus |
JP2014133785A (ja) * | 2013-01-08 | 2014-07-24 | Mitsui Chemicals Inc | エチレン・炭素数4〜20のα−オレフィン・非共役ポリエン共重合体からなるフィルム |
EP3013900B1 (de) | 2013-06-24 | 2018-05-02 | Dow Global Technologies LLC | Verstärkte polypropylenzusammensetzung |
KR101585204B1 (ko) | 2013-06-28 | 2016-01-13 | 주식회사 엘지화학 | 디엔을 포함하는 3원계 탄성 공중합체 및 이의 제조 방법 |
EP2883890A4 (de) * | 2013-06-28 | 2016-07-20 | Lg Chemical Ltd | Ternäres elastisches copolymer mit einem dien und verfahren zur herstellung davon |
CN104768986A (zh) | 2013-06-28 | 2015-07-08 | 株式会社Lg化学 | 弹性二烯三元共聚物及其制备方法 |
EP2883889A4 (de) | 2013-06-28 | 2016-06-01 | Lg Chemical Ltd | Ternäres elastisches copolymer mit einem dien und verfahren zur herstellung davon |
US9803037B1 (en) * | 2016-05-03 | 2017-10-31 | Exxonmobil Chemical Patents Inc. | Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof |
KR101846412B1 (ko) * | 2016-12-06 | 2018-05-18 | 한화케미칼 주식회사 | 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀 |
CN109627366A (zh) * | 2017-10-09 | 2019-04-16 | 中国石化扬子石油化工有限公司 | 一种茂金属催化剂及在环烯烃共聚物制备中的应用 |
CN109251265A (zh) * | 2018-07-20 | 2019-01-22 | 北京理工大学 | 一种cgc型胺芴稀土金属催化剂、制备方法及应用 |
WO2020169552A1 (en) | 2019-02-18 | 2020-08-27 | Total Research & Technology Feluy | Polyolefin compositions and process to produce such compositions by the addition of ionomers |
KR20210076701A (ko) | 2019-12-16 | 2021-06-24 | 현대자동차주식회사 | 연료전지용 에틸렌-프로필렌-디엔 공중합체 및 그 제조방법 |
BR112022012694A2 (pt) * | 2019-12-27 | 2022-09-06 | Dow Global Technologies Llc | Copolímero em multiblocos de etileno/buteno e processo para produzir o mesmo |
EP4047026A4 (de) * | 2020-04-16 | 2023-01-18 | Lg Chem, Ltd. | Ethylen-/alpha-olefin-copolymer mit ausgezeichneter elektrischer isolierung |
KR102387101B1 (ko) * | 2020-04-16 | 2022-04-18 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름 |
WO2021210749A1 (ko) | 2020-04-16 | 2021-10-21 | 주식회사 엘지화학 | 에틸렌/알파-올레핀 공중합체를 포함하는 봉지재 필름용 조성물 및 이를 포함하는 봉지재 필름 |
US20230002526A1 (en) * | 2020-04-16 | 2023-01-05 | Lg Chem, Ltd. | Ethylene/Alpha-Olefin Copolymer with Excellent Electrical Insulation |
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-
2000
- 2000-08-14 US US09/638,846 patent/US6369176B1/en not_active Expired - Lifetime
- 2000-08-16 AT AT00959254T patent/ATE319751T1/de not_active IP Right Cessation
- 2000-08-16 BR BRPI0013335-3A patent/BR0013335B1/pt not_active IP Right Cessation
- 2000-08-16 CN CNB008115648A patent/CN1210314C/zh not_active Expired - Lifetime
- 2000-08-16 CA CA002382182A patent/CA2382182C/en not_active Expired - Fee Related
- 2000-08-16 EP EP00959254A patent/EP1214365B1/de not_active Expired - Lifetime
- 2000-08-16 WO PCT/US2000/022500 patent/WO2001014434A1/en active IP Right Grant
- 2000-08-16 ES ES00959254T patent/ES2255506T3/es not_active Expired - Lifetime
- 2000-08-16 KR KR1020027002171A patent/KR100700765B1/ko active IP Right Grant
- 2000-08-16 DE DE60026545T patent/DE60026545T2/de not_active Expired - Lifetime
- 2000-08-16 JP JP2001518762A patent/JP5633996B2/ja not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
---|---|
EP1214365B1 (de) | 2006-03-08 |
KR20020029752A (ko) | 2002-04-19 |
BR0013335A (pt) | 2002-04-02 |
US20020143122A1 (en) | 2002-10-03 |
JP5633996B2 (ja) | 2014-12-03 |
ES2255506T3 (es) | 2006-07-01 |
CA2382182C (en) | 2009-10-06 |
CN1210314C (zh) | 2005-07-13 |
DE60026545T2 (de) | 2006-08-10 |
EP1214365A1 (de) | 2002-06-19 |
JP2003507541A (ja) | 2003-02-25 |
KR100700765B1 (ko) | 2007-03-27 |
DE60026545D1 (de) | 2006-05-04 |
US6369176B1 (en) | 2002-04-09 |
MXPA02001763A (es) | 2003-09-25 |
AU1638701A (en) | 2001-03-19 |
JP2014208840A (ja) | 2014-11-06 |
WO2001014434A1 (en) | 2001-03-01 |
US6610800B2 (en) | 2003-08-26 |
CA2382182A1 (en) | 2001-03-01 |
AU772057B2 (en) | 2004-04-08 |
CN1368982A (zh) | 2002-09-11 |
JP6165685B2 (ja) | 2017-07-19 |
BR0013335B1 (pt) | 2010-05-04 |
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